Fluororubber (FKM) is recognized for its outstanding performance, yet there is a pressing need for materials with superior mechanical, thermal, and electromagnetic shielding properties to meet the demands of high-tech industries. The existing research is limited by the lack of a filler that can significantly enhance these properties without trade-offs. This study introduces the innovative synthesis of a ternary composite filler, multi-walled carbon nanotubes/ silica/amorphous carbon (MWCNTs@SiO2-C), through an in-situ polymerization and carbonization method, which is incorporated into FKM to systematically improve its performance. The unique silicon-coated MWCNTs@SiO2-C, optimized at 7 phr (parts per hundred parts of resin), has been shown to increase tensile strength by 206 % and reduce compression set by 17 %, while also elevating the initial decomposition temperature and achieving maximum electromagnetic interference shielding effectiveness in the X-band. Plasma treatment further enhances these properties, with a 175 % increase in tensile strength and improved surface wettability. The integration of MWCNTs@SiO2-C thus addresses a critical gap in material science, offering a substantial advancement for applications in aerospace, military, and semiconductor manufacturing where high-performance materials are essential.
Read full abstract