NiFeMo is prevalently employed in the field of aerospace and electronic devices owing to its excellent soft magnetic properties. Besides, the incorporation of elements through in-situ alloying presents a novel strategy for performance modulation in Selective Laser Melting (SLM), presenting a novel pathway toward the advancement of soft magnetic materials. In this study, (NiFeMo)100-xCrx alloys (x=0 wt%, 0.5 wt%, 1.0 wt%, 1.5 wt%, 2.0 wt%, 2.5 wt%) were prepared utilizing Cr in-situ alloying SLM. The magnetic properties as well as microstructural characterization were conducted by employing X-ray diffraction (XRD), scanning electron microscopy (SEM), electron backscatter diffraction (EBSD), high-resolution transmission electron microscopy (HRTEM) (Tecnai-G2-F30), and direct current B-H hysteresis curve testing equipment (MATS-2010S). The results indicate that the microstructure of the SLM-formed NiFeMo alloy through in-situ chromium alloying is predominantly characterized by columnar grains growing along the build direction. With an increase in the in-situ alloying ratio of chromium, the lattice parameters of the FCC phase structure of the NiFeMo alloy decrease from 3.582 Å to 3.503 Å, the average grain size monotonically decreases, and the maximum texture strength monotonically weakens. Furthermore, during the in-situ alloying SLM process, chromium is dissolved into the FCC γ-(Ni, Fe) of the NiFeMo alloy, forming dispersed, chromium-rich precipitates of larger sizes. This leads to a reduction in the intrinsic magnetic properties of the NiFeMo alloy, affecting the exchange coupling interaction between magnetic atoms and the motion of magnetic domains. Compared to the NiFeMo alloy, the saturation magnetization of the (NiFeMo)97.5Cr2.5 alloy is reduced to 0.4685 T, and the coercive force is increased to 37.7 A/m. However, when the chromium content is 1 wt%, the initial magnetic permeability of the (NiFeMo)99Cr1 alloy is 2.337 mH/m, which is an enhancement of 1.9422 mH/m compared to the NiFeMo alloy.
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