Rechargeable Research Articles

Optimization of liquid cooled heat dissipation structure for vehicle energy storage batteries based on NSGA-II

Introduction: With the development of the new energy vehicle industry, the research aims to improve the energy utilization efficiency of electric vehicles by optimizing their composite power supply parameters.Methods: An optimization model based on non-dominated sorting genetic algorithm II was designed to optimize the parameters of liquid cooling structure of vehicle energy storage battery. The objective function and constraint conditions in the optimization process were defined to maximize the heat dissipation performance of the battery by establishing the heat transfer and hydrodynamic model of the electrolyzer.Results: The results showed that the optimization method had excellent performance on multiple evaluation indicators, the material degradation rate after optimization was reduced by 42%, the corrosion rate was reduced by 36%, and the battery life was increased by 17%. The optimization method ensured the maximum temperature control for the safe operation of the lithium-ion battery pack. The temperature of the battery pack was effectively controlled. The temperature difference was kept within 5°C, preventing the battery from overheating and extending its service life.Discussion: The proposed liquid cooling structure design can effectively manage and disperse the heat generated by the battery. This method provides a new idea for the optimization of the energy efficiency of the hybrid power system. This paper provides a new way for the efficient thermal management of the automotive power battery.

Energy sources as a function of electric vehicle emission: The case of Bosnia and Herzegovina

This paper deals with the analysis of challenges and perspectives of the transition to electric vehicles as a sustainable solution for the transport sector in the context of global energy challenges and the need to reduce negative environmental impacts. With an emphasis on the energy situation in Bosnia and Herzegovina, the paper explores the possibilities of switching to electric vehicles (EVs) and analyses the effects of energy sources on CO2 emissions. The paper highlights the motivation to switch to EVs, driven by the need to reduce greenhouse gas emissions and rely on renewable energy sources. After analysing relevant studies, it is concluded that smaller and lighter electric vehicles have lower CO2 emissions and that the participation of renewable sources in electricity production reduces these emissions. The conducted analysis of the vehicle fleet specifies that the CO2 emissions of electric vehicles are not zero and that they depend on the source of electricity. Furthermore, other factors, such as the production of batteries, also play an important role in the overall environmental impact. Although the motivation to switch to electric vehicles is emphasized to reduce greenhouse gas emissions and use renewable energy sources, it has been shown that the CO2 emissions of electric vehicles (EVs) are not zero and significantly depend on the energy sources. Calculations performed on the vehicle fleet of the Federation of Bosnia and Herzegovina for the year 2021, using Copert as the tool, showed that vehicles driven by fossil fuels emit about 1.6 million tonnes of CO2. In comparison, if all vehicles were replaced with electrical ones, the CO2 emissions would be about 1.15 million tonnes. As for the required electricity to power EVs, it is calculated that the required amount would be about 1,539 GWh per year. This paper acknowledges the presence of emissions associated with battery production, storage, and disposal, as well as vehicles themselves. However, it does not delve into this issue in detail. Future research will aim to address this matter more thoroughly.

Advancing Electric Vehicle Infrastructure: A Review and Exploration of Battery-Assisted DC Fast Charging Stations

Concerns over fossil fuel depletion, fluctuating fuel prices, and CO2 emissions have accelerated the development of electric vehicle (EV) technologies. This article reviews advancements in EV fast charging technology and explores the development of battery-assisted DC fast charging stations to address the limitations of traditional chargers. Our proposed approach integrates battery storage, allowing chargers to operate independently of the electric grid by storing electrical energy during off-peak hours and releasing it during peak times. This reduces dependence on grid power and enhances grid stability. Moreover, the transformer-less, modular design of the proposed solution offers greater flexibility, scalability, and reduced installation costs. Additionally, the use of smart energy management systems, incorporating artificial intelligence and machine learning techniques to dynamically adjust charging rates, will be discussed to optimize efficiency and cost-effectiveness.

Alpha nickel hydroxide electrodes improve aqueous rechargeable batteries capacity

Nickel hydroxide electrode materials have been improved for the use in Ni-based rechargeable batteries such as Ni-H2, NiMH, NiCd, NiFe, and NiZn batteries. A stabilized α-phase Ni1-xAlx(OH)2, synthesized using wet chemical coprecipitation methods while controlling pH accurately followed by hydrothermal treatments at 165 °C, is reported. Variations in synthetic routes, dopants and morphology had strong influence on the electrochemical performance. Morphological control, crystallinity and surface modification by Co(OH)2 were important for the better performance. Conventional battery grade β-Ni(OH)2 is usually made of a spherical particles, but we find that circular shaped particles can be advantageous. Hydrothermal treatments increase sample crystallinity and discharge capacity. A hydrothermal treated Ni0.8Al0.2(OH)2-LDH sample reaches a discharge capacity of 368 mAh g−1 and a corresponding Ni0.9Al0.1(OH)2 reaches 405 mAh g−1. Both have a circular-like morphology and the later shows a tap density of 1.52 g cm−3 and volumetric energy density of 531 mAh cm−3. Only a modest Co(OH)2 surface coating is needed to reduce the polarization behavior, increase the redox reaction reversibility and electrode kinetics via formation of CoOOH species after electrochemical oxidation.

Research Progress and Future Expectations in Anode of Secondary Zinc-Air Batteries: A Review

Research Progress and Future Expectations in Anode of Secondary Zinc-Air Batteries: A Review

Energy Management for Smart GDS with Hybrid AC/DC Microgrid and Renewable Energy: SCO-GBDT Approach

This manuscript proposes a hybrid method for energy management (EM) of a solar photovoltaic (PV) hybrid microgrid (MG) for the residential distribution system (DS). The proposed approach integrates the single candidate optimizer algorithm (SCOA), and gradient boost decision tree algorithm (GBDT), called the SCOA-GBDT algorithm. The main contribution of this manuscript is to (a) effectively achieve battery storage, solar PV, and loads to improve energy savings and lessen the loss of conversion; (b) effectively handle solar photovoltaic, battery storage, and loads to recognize cost-effective power distribution using the proposed technique; and (c) effectively handle weak photovoltaic power prevalent in the DC side of MG by an auxiliary-battery arrangement to preserve energy. The proposed energy management strategy lowers the conversion losses in the residential DS. Here, the dc loads are provided by a solar photovoltaic, the utility-grid provides the AC loads, and an auxiliary-battery bank is considered for storing the energy. Then, the performance of the proposed technique is done in MATLAB software and is compared to different existing approaches. From the simulation outcome, it is concluded that the proposed approach reduces costs and losses compared to the existing approaches.

Enhancement of Li intercalation kinetics of LiFePO4 nanoparticles with mesoporous carbon

Carbon-assisted energy storage in Li-ion batteries is a crucial topic in the era of carbon neutrality. This work reports a remarkable synergistic effect between lithium iron phosphate (LiFePO4, LFP) nanoparticles and mesoporous carbon (MC) that greatly improves the rate performance and cycle performance. The rapid capacitive effect of MC helps establish a local Li+-rich environment for LFP, enhancing the Li intercalation kinetics inside LFP nanoparticles during discharge. This synergistic effect is quantificationally evaluated using a single-particle model to compare the Li intercalation extent of LFP particles under the presence and absence of MC, which is further confirmed by high-resolution transmission electron microscopy observation, in-situ X-ray diffraction characterization and electrochemical impedance spectroscopy test. In addition, the LFP/MC composite cathode exhibits a nearly 100% capacity retention after 1,000 cycles under 1C charge and 10C discharge. Overall, the addition of MC proves to be a very simple but robust method to increase the capacity, power density and cycle life of LFP-based devices.

Homogeneous Adsorption of Multiple Potassiation Products of Red Phosphorus Anode toward Stable Potassium Storage

Homogeneous Adsorption of Multiple Potassiation Products of Red Phosphorus Anode toward Stable Potassium Storage

Enhancing performance and longevity of solid-state zinc-iodine batteries with fluorine-rich solid electrolyte interphase

Rechargeable zinc-iodine (ZnI2) batteries have gained popularity within the realm of aqueous batteries due to their inherent advantages, including natural abundance, intrinsic safety, and high theoretical capacity. However, challenges persist in their practical applications, notably battery swelling and vulnerability in aqueous electrolytes, primarily linked to the hydrogen evolution reaction and zinc dendrite growth. To address these challenges, this study presents an innovative approach by designing a solid-state ZnI2 battery featuring a solid perfluoropolyether based polymer electrolyte. The results demonstrate the formation of a solid electrolyte interphase layer on zinc, promoting horizontal zinc growth, mitigating dendrite penetration, and enhancing battery cycle life. Moreover, the solid electrolyte hinders the iodine ion shuttle effect, reducing zinc foil corrosion. Symmetric batteries employing this electrolyte demonstrate excellent cycle performance, maintaining stability for approximately 5000 h at room temperature, while solid-state ZnI2 batteries exhibit over 7000 cycles with a capacity retention exceeding 72.2%. This work offers a promising pathway to achieving reliable energy storage in solid-state ZnI2 batteries and introduces innovative concepts for flexible and wearable zinc batteries.

Investigation on Al3+ ion storage in Bi2MoO6 and Bi2WO6 for rechargeable aqueous aluminum-ion battery

Reversible and stable electrochemical Al3+ ion storage process defines the functioning of a rechargeable aluminum-ion battery. Herein, we illustrate the electrochemistry of Bi2MoO6 and Bi2WO6 for Al3+ ion storage in aqueous electrolyte. It was found that the electrochemical characteristics are quite dependent on the nature of the electrolyte. While the charge-discharge profiles are almost identical for both Bi2MoO6 and Bi2WO6, it is to be noted that Bi2WO6 exhibits better electrochemical long-term stability and severe capacity decline is noticeable for Bi2MoO6. The specific discharge capacity is 94 mAhg−1 at a current density of 1 Ag−1 over 50 cycles for Bi2WO6 in an optimized AlCl3 aqueous electrolyte. By adopting an optimized current collector, the specific capacity could be significantly enhanced to above 200 mAhg−1 at a current density of 1 Ag−1. A mechanistic study conducted through ex-situ XRD, XPS, Raman, FTIR, UV–Visible, FESEM and HRTEM reveals probable transformation of Bi2WO6 to BiOCl during the electrochemical process.

Lead-acid battolysers for hydrogen cooking: A comparison with electric cooking for sub-Saharan Africa

A battolyser combines the function of battery and electrolyser in one device, i.e. it provides both electrical energy storage and a means to produce hydrogen. A battolyser with lead-acid chemistry has recently been proposed, and this has potential as a particularly low-cost solution. Here, the battolyser is considered for the production of hydrogen as a cooking fuel (“hCooking”) in sub-Saharan Africa, a region where cooking typically employs polluting fuels (firewood and charcoal). The more conventional approach for decarbonisation of cooking is the introduction of electric cookers (e.g. hotplate, induction hob, pressure cooker) which can be powered by PV and possibly battery storage; accordingly these electric cooking (“eCooking”) systems are considered as the competing decarbonised technology. Multi-objective optimisation is used to design both battolyser and eCooking systems for a notional off-grid community, with solar PV as the main energy source. Objectives are the minimisation of net present cost and lifetime greenhouse gas emissions, and Pareto frontiers are produced to show the play-off between these. Results show that a battolyser system could eliminate 95.6 % of CO2 emissions when compared with a baseline using charcoal, at an annualised cost of $507 per household, over a system lifetime of 20 years. However, eCooking systems appear superior to the battolyser, with the cleanest battery + eCook system achieving 95.8 % emissions reduction at annualised cost $422/household. More generally, hCooking systems are nearly always Pareto dominated by eCooking systems, even under a realistic range of sensitivity scenarios. This result is due to the inherently higher energy intensity of cooking over a flame compared to the eCooking options. Priorities to make the battolyser a more viable solution include extending its lifetime as far as possible, cheaper PV systems, and improved hydrogen burner efficiencies. We also show that eCooking together with some continued use of charcoal may be the cheapest possible cooking solution, whilst simultaneously curtailing 60 % of lifetime greenhouse gas emissions.

Solvation Structures and Transport Mechanisms of Cations in Water-in-Bisalt Electrolytes for High-Concentration Lithium-Ion Batteries Revealed by Molecular Dynamics Simulations.

The development of safe and cost-effective electrolytes for rechargeable batteries is currently underway. While water-based electrolytes hold promise, their restricted electrochemical stability window poses a challenge. Combining multiple ionic species emerges as a promising strategy to broaden this stability window and optimize Li-ion battery performance. This study focuses on dual-cation electrolytes, which blend lithium and potassium acetates to enhance the electrochemical characteristics of the solution at high concentrations. We investigated the solvation structure of each ion and its interactions on a molecular level. Our analysis reveals that ion clusters and aggregates are formed through shared acetate and water molecules at high salt concentrations. Furthermore, the residence time analyses of atom pairs indicate that cations diffuse in vehicular mode at low concentrations. In contrast, they switch to a structural mode at high concentrations due to diminishing water content. This study offers a comprehensive model for exploring diverse solvation structures of cations and gaining insights into their diffusion mechanisms within water-in-bisalt electrolytes for aqueous Li-ion batteries.

A Facile Strategy for Constructing High‐Performance Polymer Electrolytes via Anion Modification and Click Chemistry for Rechargeable Magnesium Batteries

Polymer electrolytes play a crucial role in advancing rechargeable magnesium batteries (RMBs) owing to their exceptional characteristics, including high flexibility, superior interface compatibility, broad electrochemical stability window, and enhanced safety features. Despite these advantages, research in this domain remains nascent, plagued by single preparation approaches and challenges associated with the compatibility between polymer electrolytes and Mg metal anode. In this study, we present a novel synthesis strategy to fabricate a glycerol α,α'‐diallyl ether‐3,6‐dioxa‐1,8‐octanedithiol‐based polymer electrolyte supported by glass fiber substrate (GDT@GF) through anion modification and thiol‐ene click chemistry polymerization. The developed route exhibits novelty and high efficiency, leading to the production of GDT@GF membranes featuring exceptional mechanical properties, heightened ionic conductivity, elevated Mg2+ transference number, and commendable compatibility with Mg anode. The assembled modified Mo6S8||GDT@GF||Mg cells exhibit outstanding performance across a wide temperature range and address critical safety concerns, showcasing the potential for applications under extreme conditions. Our innovative preparation strategy offers a promising avenue for the advancement of polymer electrolytes in high‐performance rechargeable magnesium batteries, while also opens up possibilities for future large‐scale applications and the development of flexible electronic devices.

Recent Progress in Using Covalent Organic Frameworks to Stabilize Metal Anodes for Highly-Efficient Rechargeable Batteries.

Alkali metals (Li, Na, and K) and multivalent metals (Zn, Mg, Ca, and Al) have become star anodes for developing high-energy-density rechargeable batteries due to their high theoretical capacity and excellent conductivity. However, the inevitable dendrites and unstable interfaces of metal anodes pose challenges to the safety and stability of batteries. To address these issues, covalent organic frameworks (COFs), as emerging materials, have been widely investigated due to their regular porous structure, flexible molecular design, and high specific surface area. In this minireview, we summarize the research progress of COFs in stabilizing metal anodes. First, we present the research origins of metal anodes and delve into their advantages and challenges as anodes based on the physical/chemical properties of alkali and multivalent metals. Then, special attention has been paid to the application of COFs in the host design of metal anodes, artificial solid electrolyte interfaces, electrolyte additives, solid-state electrolytes, and separator modifications. Finally, a new perspective is provided for the research of metal anodes from the molecular design, pore modulation, and synthesis of COFs.

Recent Progress in Using Covalent Organic Frameworks to Stabilize Metal Anodes for Highly‐Efficient Rechargeable Batteries

AbstractAlkali metals (e.g. Li, Na, and K) and multivalent metals (e.g. Zn, Mg, Ca, and Al) have become star anodes for developing high‐energy‐density rechargeable batteries due to their high theoretical capacity and excellent conductivity. However, the inevitable dendrites and unstable interfaces of metal anodes pose challenges to the safety and stability of batteries. To address these issues, covalent organic frameworks (COFs), as emerging materials, have been widely investigated due to their regular porous structure, flexible molecular design, and high specific surface area. In this minireview, we summarize the research progress of COFs in stabilizing metal anodes. First, we present the research origins of metal anodes and delve into their advantages and challenges as anodes based on the physical/chemical properties of alkali and multivalent metals. Then, special attention has been paid to the application of COFs in the host design of metal anodes, artificial solid electrolyte interfaces, electrolyte additives, solid‐state electrolytes, and separator modifications. Finally, a new perspective is provided for the research of metal anodes from the molecular design, pore modulation, and synthesis of COFs.

New insights into the interfacial characteristics of Poly(Acrylic Acid) binder and hydrated V2O5 cathode material for zinc-ion secondary batteries

Hydrated vanadium pentoxide and poly(acrylic acid) (PAA) are employed as a cathode active material and a binder, respectively, for aqueous zinc-ion secondary batteries (AZIBs). This study investigates the physicochemical interfacial characteristics of the PAA binder, with a particular focus on the intermolecular interactions between the binder and the hydrated V2O5 cathode materials. The PAA binder enables rapid Zn2+ diffusion by providing ion diffusion pathways, thereby enhancing the kinetics of the V2O5 cathode. The PAA binder improves hardness and ion conductivity while reducing the modulus, which results in AZIBs with stable cycle performance under our experimental conditions. The significantly enhanced electrochemical performance is attributed to the strong hydrogen bond and chelation interactions between the PAA and the surface of the hydrated V2O5 cathode materials. Thus, a Zn–V2O5 battery employing a PAA binder outperformed existing AZIBs, showing an impressive capacity of 504.5 mAh g−1 at 0.1 A g−1 and a robust cycling retention of 99.9 % over 1000 cycles, demonstrating the potential of aqueous binders in vanadium-based cathode materials.

Possibility of defective monolayer graphene as potential anode material of metal-ion batteries

The necessitates exploration in the field of rechargeable metal ion batteries demands safe, cost-efficient, and face significant challenges in their development. Defect engineering may be helpful for the ion storage and diffusion in the battery anodes. In this paper, we use density functional theory to investigate the adsorption and diffusion behavior of Li, Mg, and Al atom on single vacancy (SV), Stone-Wales vacancy (SWV), double vacancy (DV) and quadruple vacancy (QV) defective monolayer graphene. It is evident that metal exhibits the strongest adsorption strengthen at the defect center. The DV and QV defective graphene shows the ideal diffusion energy barrier for three metals. Importantly, the QV structure exhibit maximum storage capacities of the 775 mAh/g for Li, 911 mAh/g for Mg, and 1543.4 mAh/g for Al respectively. Additionally, their open-circuit voltages are all in a very safe range. This study can support a strong basis for the experimental research for metal-ion battery anodes.

Toward Sustainable Polymer Materials for Rechargeable Batteries: Utilizing Natural Feedstocks and Recycling/Upcycling of Polymer Waste.

The ever-increasing demand for rechargeable battery systems in the era of electric vehicles has spurred extensive research into developing polymeric components for batteries, such as separators, polymer electrolytes, and binders. However, current battery systems rely on expensive and nonrenewable resources, which potentially have a negative environmental impact. Therefore, polymer materials derived from natural resources have gained significant attention, primarily due to their cost-effective and environmentally sustainable features. Moreover, natural feedstocks often possess highly polar functional groups and high molecular weights, offering desirable electro-chemo-mechanical features when applied as battery materials. More recently, various recycling and upcycling strategies for polymeric battery components have also been proposed given the substantial waste generation from end-of-life batteries. Recycling polymeric materials includes an overall process of recovering the components from spent batteries followed by regeneration into new materials. Polymer upcycling into battery materials involves transforming daily-used plastic waste into high-value-added battery components. This review aims to give a state-of-the-art overview of contemporary methods to develop sustainable polymeric materials and recycling/upcycling strategies for various battery applications.

Designer Anions for Better Rechargeable Lithium Batteries and Beyond.

Non-aqueous electrolytes, generally consisting of metal salts and solvating media, are indispensable elements for building rechargeable batteries. As the major sources of ionic charges, the intrinsic characters of salt anions are of particular importance in determining the fundamental properties of bulk electrolyte, as well as the features of the resulting electrode-electrolyte interphases/interfaces. To cope with the increasing demand for better rechargeable batteries requested by emerging application domains, the structural design and modifications of salt anions are highly desired. Here, salt anions for lithium and other monovalent (e.g., sodium and potassium) and multivalent (e.g., magnesium, calcium, zinc, and aluminum) rechargeable batteries are outlined. Fundamental considerations on the design of salt anions are provided, particularly involving specific requirements imposed by different cell chemistries. Historical evolution and possible synthetic methodologies for metal salts with representative salt anions are reviewed. Recent advances in tailoring the anionic structures for rechargeable batteries are scrutinized, and due attention is paid to the paradigm shift from liquid to solid electrolytes, from intercalation to conversion/alloying-type electrodes, from lithium to other kinds of rechargeable batteries. The remaining challenges and key research directions in the development of robust salt anions are also discussed. This article is protected by copyright. All rights reserved.

Interfacial regulation engineering in anode‐free rechargeable batteries

AbstractAnode‐free rechargeable batteries (AFRBs), equipped with bare collectors at the anode, are potential electrochemical energy storage technology attributed to their simplified cell configuration, high energy density, and cost reduction. Nevertheless, issues including insufficient Coulombic efficiency as well as the formation of the dendrites restrict their practical implementation. In recent years, various strategies have been proposed to overcome the critical issues of AFRBs. Among which, interfacial properties play key roles for achieving high stable AFRBs. In this review, an overview of AFRBs is discussed in the first part. Then, the main strategies based on interfacial regulation engineering toward high‐performance AFRBs are summarized including designing of current collectors, introducing of surface coating layers, modification of electrolytes, separators engineering, cathode materials regulation, and so forth. In addition, some future perspectives for developing AFRBs are proposed. This review will create new avenues on constructing stable AFRBs for advanced energy storage devices.