Infrared-blue composite laser cladding technology is used to prepare highly conductive and wear-resistant CoCrFeNi-(Mo, Ti, W) HEA coatings on the surface of the copper alloy to overcome the problem of high reflectivity of copper alloy aiming to enhance the surface performance of copper alloy current-carrying friction part. The microstructure and electrical properties of the high-entropy alloy coating were investigated. The wear resistance of the coatings was tested under high-speed and high-current conditions using a self-made current-carrying friction and wear testing machine. The results show that fine-grain and second-phase strengthening significantly enhances the hardness of the high-entropy alloy coating. The high-entropy alloy coating maintains the excellent electrical conductivity of the copper alloy, with an overall conductivity remaining above 60 % IACS. During the current-carrying friction process, the CoCrFeNi-(Mo, Ti, W) HEA coatings exhibited good wear resistance, with wear rates of 0.84 g/h, 1.08 g/h, and 1.32 g/h, respectively. The wear mechanisms observed included varying degrees of adhesive wear, abrasive wear, fatigue wear, and arc erosion.