The objective of this work was to study water- and tissue-equivalent properties of some gel dosimeters, human tissues and water, for scattering of photons using the effective atomic number (Z eff). The Rayleigh to Compton scattering ratio (R/C) was used to obtain Z eff and electron density (N e ) of gel dosimeters, human tissues and water considering a 10-2-109 momentum transfer, q (Å-1). In the present work, a logarithmic interpolation procedure was used to estimate R/C as well as Z eff of the chosen materials in a wide scattering angle (1°-180°) and energy range (0.001-100MeV). The Z eff of the chosen materials was found to increase as momentum transfer increases, for q>~1Å-1. At fixed scattering angle and energy, Z eff of the material first increases and then becomes constant for high momentum transfers (q≥3Å-1), which indicates that Z eff is almost independent of energy and scattering angle for the chosen materials. Based on the Z eff data and the continuous momentum transfer range (10-2-109Å-1), MAGIC, PAGAT and soft tissue were found to be water-equivalent materials, since their differences (%) relative to water are significantly low (≤3.2% for MAGIC up to 103Å-1, ≤2.9% for PAGAT up to 109Å-1, and ≤3.8% for soft tissue up to 109Å-1), while the Fricke gel was not found to be water equivalent. PAGAT was found to be a soft tissue-equivalent material in the entire momentum transfer range (<4.3%), while MAGAT has shown to be tissue equivalent for brain (≤8.1% up to 10Å-1) and lung (<8.2% up to 10Å-1) tissues. The Fricke gel dosimeter has shown to be adipose tissue equivalent for most of the momentum range considered (<10%).