Scarce Resources Research Articles

Phase transfer-assisted indium recovery from spent liquid crystal display panels and its extension in preparing indium-based electrocatalysts for CO2 reduction

Transforming discarded electronic devices into low-cost and high-efficiency catalysts presents a win–win approach to address the scarcity of rare resources and sustainable energy challenges. Herein, we report an effective strategy that combines an ethanol-mediated dodecylamine (DDA) phase transfer with hydrothermal methods for facilitating the facile synthesis of indium (In)-based nanomaterials from the leachates of liquid crystal display panels (LCDPs) toward high-efficiency electrochemical CO2 reduction reaction (eCO2RR). In this strategy, the rapid formation of coordinating compounds between the –NH2 group of DDA and metal ions facilitates the separation of In3+ cations from the acidic LCDPs leach solution by transferring them into an organic phase, which are then converted into InOOH nanoparticles with abundant oxygen vacancies (denoted as In-LCDPs and hereafter) through a low-temperature hydrothermal process. The eCO2RR evaluations confirm the superior electrocatalytic performance of the In-based nanoparticles produced from the LCDPs. In specific, within a broad potential range (−0.77 to −1.17 V vs RHE), the In-LCDPs show a Faradaic efficiency for formate (FEformate) of 85 %, with the highest FEformate of 90.23 % at −0.97 V vs RHE, which is comparable to the FEformate (93.8 % at −0.97 V vs RHE) of In-based catalyst prepared from pure In precursors using the same method. Further investigations reveal that the Sn and Al impurities have minimal impact on the catalytic performance of In-LCDPs, while the presence of Fe3+ impurities significantly enhance the production of hydrogen during the eCO2RR. This work might have provided a scalable pathway to transform LCDPs into value-added electrocatalysts for eCO2RR.

Reducing nitrogen and deficit irrigation is a practical solution for optimal forage barley production in semi-arid cropping systems

Given the scarcity of arable land and water resources in semi-arid regions, it becomes imperative to achieve maximum yield and early maturity for winter grains. In this regard, the present research was conducted to synchronize grain and shoot maturity in high-yielding barley (cv. Behrokh) by reducing nitrogen and deficit irrigation. The experimental factors included three levels of nitrogen (50, 75, and 100% plant nitrogen requirement; PNR) and three levels of irrigation (full irrigation, cutoff irrigation in the milk stage, and dough stage). Results showed that cutoff irrigation and nitrogen fertilizer caused early ripening. The interactions of irrigation and nitrogen were significant for the number of grains/spike, grain yield, straw yield, aboveground biomass, and protein yield. Grain yield in cutoff irrigation in the dough stage plus reducing 25% PNR was similar to full irrigation plus 100% PNR. In full and cutoff irrigation in the dough stage, reducing 25% PNR did not cause a significant change in straw yield. Cutoff irrigation in the dough and milk stages did not cause a significant difference in the grain protein content. In general, it is concluded that to maintain grain, straw yield, and protein quality, it is more appropriate to use 150 kg/ha of nitrogen in the conditions of cutoff irrigation in the dough stage, which could reduce the cost of fertilizer and water in addition to early ripening of the crop and minimize the environmental consequences of consuming these inputs. Early harvesting of barley also helps to prevent summer crops from encountering late-season chilling.

Robust prediction of workability properties for 3D printing with steel slag aggregate using bayesian regularization and evolution algorithm

This study addresses the growing interest in utilizing steel slag as a sustainable alternative to river sand in additive manufacturing of concrete, driven by the increasing scarcity of natural resources. The rheological properties of fresh material significantly impact the quality of 3D-printed filament, necessitating suitable workability for printability. The research focuses on evaluating the influence of steel slag aggregate and key admixtures, such as silica fume and superplasticizer, on the workability properties of fresh concrete. Through an extensive series of 90 slump tests, optimal combinations ensuring the desired workability for 3D printing applications were identified. To enhance the manufacturing of fresh concrete and develop user-friendly tools, a novel soft computing approach is introduced—Adaptive Elitist Differential Evolution coupled with Bayesian Regularization Artificial Neural Network (aeDE-BRANN). This advanced model considers five critical input parameters: silica fume to Portland cement ratio, steel slag to cement ratio, water to cement ratio, cement content, and superplasticizer dosage. The model outputs crucial workability metrics, including slump flow and slump. In a comprehensive comparative study, the aeDE-BRANN framework demonstrates superior performance in terms of both simplicity and efficiency when compared to other forecasting models. Feature analysis techniques, including Shapley values from game theory and partial dependence plots, provide valuable insights into the intricate relationships between input variables and workability properties. The findings underscore the water to cement ratio as the most influential factor on workability, followed by silica fume to Portland cement ratio and steel slag to cement ratio. This study contributes a reliable tool for predicting workability properties, aiding in the selection of suitable steel slag aggregate and admixtures. Ultimately, it facilitates the sustainable and innovative evolution of 3D concrete printing practices.

Incommensurability and healthcare priority setting

AbstractThis paper argues that accepting incommensurability can be a useful step for developing attractive hybrid theories to how to distribute scarce health-related resources. If one provides opportunity for distributive options to be incommensurable with respect to substantive criteria, one can hold on to substantive criteria while also providing room for decision processes to play a significant role. The paper also argues that the strategy of accepting incommensurability is preferable to the strategy of having substantive criteria establish sets of options that are equally, explains why incommensurability gives us reason to go hybrid, and argues that reasons grounded in decision processes have properties that make them appropriate as “tiebreakers” in choice situations characterized by incommensurability.

DO CFOs HAVE HEARTS? A REVEALING PHENOMENOLOGICAL INTERVIEW

This article sought to understand how Chief Financial Officers (CFOs) deal with feelings and emotions. Criticized for their strictly positivist view while reconciling scarce resources and diverse needs, financial directors are recognized for their coldness in dealing with sensitive issues such as massive layoffs, benefits, and investments cuts, referring to the numbers through a results-oriented perspective. Through an interview with a financial director using the phenomenological approach, it was possible to reveal little-known aspects of these professionals, related to the management of their feelings and emotions. The answers, based on her real experience, confirm the perceptions of the author, also a financial manager, that statements of positive emotions are better accepted than negative ones, not only in the finance area, but in the corporate environment in general. The importance of a supportive net and gender issues also appeared, such as the connection between feelings and weakness, attributed to women. Finally, the ability to deal with complex situations and external factors through emotional intelligence and a calm and balanced approach constitutes valuable quality to be achieved, inspiring respect and credibility.

The synergistic impact of Universal Health Coverage and Global Health Security on health service delivery during the Coronavirus Disease-19 pandemic: A difference-in-difference study of childhood immunization coverage from 192 countries.

Universal Health Coverage (UHC) and Global Health Security (GHS) are two high-priority global health agendas that seek to foster health system resilience against health emergencies. Many countries have had to prioritize one agenda over the other due to scarce resources and political pressures. To aid policymakers' decision-making, this study investigated the individual and synergistic effects of countries' UHC and GHS capacities in safeguarding essential health service delivery during the COVID-19 pandemic. We used a quasi-experimental difference-in-difference methodology to quantify the relationship between 192 countries' progress towards UHC and GHS and those countries' abilities to provide 12 essential childhood immunization services between 2015 and 2021. We used the 2019 UHC Service Coverage Index (SCI) to divide countries into a "high UHC group" (UHC SCI≥75) and the rest (UHC SCI 75), and similarly used the 2019 GHS Index (GHSI) to divide countries into a "high GHS group" (GHSI≥65) and the rest (GHSI<65). All analyses were adjusted for potential confounders. Countries with high UHC scores prevented a 1.14% (95% CI: 0.39%, 1.90%) reduction in immunization coverage across 2020 and 2021 whereas countries with high GHSI scores prevented a 1.10% (95% CI: 0.57%, 1.63%) reduction in immunization coverage over the same time period. The stratified DiD models showed that across both years, high UHC capacity needed to be augmented with high GHS capacity to prevent a decline in immunization coverage while high GHS alone was able to safeguard immunization coverage. This study found that greater progress towards both UHC and GHS capacities safeguarded essential health service delivery during the pandemic but only progress towards GHS capacity was both a necessary and likely sufficient element for yielding this protective effect. Our results call for strategic investments into both health agendas and future research into possible synergistic effects of the two health agendas.

La iluminación como una infraestructura de cuidado

This integrative literature review addresses the relevance of illumination. Through the lens of infrastructures of care, it proposes three analysis categories: (a) "illumination, culture, and life in society" gather studies on cultural and social aspects involving lighting; (b) "access to lighting, technology, and sustainability" demonstrates how access to light and technologies needs discussion considering structural disparities, resource scarcity, and sustainability; (c) "illumination in healthcare" explores its influence on the environment and perception of users in care settings. These themes intersect and demand a transdisciplinary approach. Analyses suggest that lighting projects and systems can contribute to feelings of welcoming, well-being, and belonging, while ensuring good visibility for services and procedures, alongside controlling glare and reflectance. Expanding exploratory research in social and community settings through case studies and prototype implementation is recommended. There is room for additional research considering illumination as an infrastructure of care, focusing on access and the positive experience of users and citizens.

Water Pricing and Quotas: A Quantitative Analysis from a Private and Social Perspective

AbstractThe current situation of structural water scarcity due to the rise in demand, the reduction in supply as a consequence of climate change, increasingly frequent drought periods, and overall quantitative pressure on water resources creates a need for economic instruments to reduce the amount of water used, especially in the agricultural sector. Thus, water pricing and allocation quotas (proportional reduction of allocations) may be suitable tools to reduce demand or allocate scarce water resources. For a comparative analysis of the performance of these two measures, a Positive Mathematical Programming model has been developed, using the Guadalquivir River Basin as a case study. Additionally, the analysis takes into account the revenue generated from water pricing and the marginal cost of public funds. The results indicate that, from the farmer’s perspective, quotas result in smaller losses than water pricing. However, when considering water pricing along with the revenue generated from this measure, this mechanism would be more beneficial for society as a whole, since the taxes collected could be used for other purposes, albeit with efficiency losses measured by the marginal cost of public funds and the excess burden of taxation.

Efficiency and sustainability: Evaluating and optimizing energy use and environmental impact in cucumber production

This study assesses the energy-economic-environmental aspects of cucumber production in the face of environmental issues and resource scarcity, which threaten global food security and demand sustainable agriculture solutions. Data were collected by questionnaire and analyzed for inputs from planting to harvesting. The results indicated that diesel fuel (37.41%) and nitrate fertilizer (37.22%) constitute the primary inputs. The energy ratio, energy efficiency and net energy gain were 0.43, 0.54 kgMJ−1 and -30,153.31 MJha−1, respectively. Input optimization by Data Envelopment Analysis (DEA) reduced the carbon footprint from 178.433 to 168.900 kg CO2 per ton, the abiotic depletion from 1228.291 to 964.305 MJ and the acidification from 0.838 to 0.749 kg SO2 eq. Also, the results of DEA showed that 52.5% and 35% of the units were fully efficient under Variable Return to Scale (VRS) and Constant Return to Scale (CRS) models, respectively, while the others were inefficient to varying degrees. The average of technical, pure technical and scale efficiencies were 92.88%, 97.64%, and 95.07%, respectively. The results of economic evaluation showed that production cost is 6058.84 $ha−1 with a benefit-cost ratio of 1.71. Based on the primary results, it is suggested to use precision agriculture techniques and the exploration of alternative energy sources, such as biofuel for machinery. Additionally, using slow-release fertilizers or organic substitutes can decrease nitrogen fertilizer dependency while maintaining crop yields and improve the sustainability in this production.

The Relationship Between Energy Consumption, Population and Economic Growth in Developing Countries

The need for energy is increasing due to population growth and industrialization. The scarcity of energy resources on earth has pushed countries to research alternative energy sources and take new measures regarding energy. In the study, the relationship between variables was investigated using population, economic growth and energy consumption data of 7 countries in the developing countries category (China, India, South Africa, Indonesia, Turkey, Mexico, Thailand). The direction and magnitude of the impact of economic growth and population growth on energy consumption were examined using 1990-2022 data for 7 countries. The relationship between the variables was examined with Swamy's Random Coefficients Model and Seemingly Unrelated Regression (SUR) models, and the positive effect of economic growth on energy consumption was observed. The parameter of the economic growth variable varies between 0.49% and 0.81% for countries. However, it was concluded that the population variable had no effect on energy consumption in the 2 countries included in the analysis. The population variable is significant in explaining energy consumption at the 5% significance level for South Africa, Mexico and Thailand, and at the 10% significance level for Turkey and China, its statistically insignificant for India and Indonesia.

A Review on Underwater Collection and Transportation Equipment of Polymetallic Nodules in Deep-Sea Mining

In response to the anticipated scarcity of terrestrial land resources in the coming years, the acquisition of marine mineral resources is imperative. This paper mainly summarizes the development of underwater collection and transportation equipment of polymetallic nodules in deep-sea mining. Firstly, the collection equipment is reviewed. The deep-sea mining vehicle (DSMV), as the key equipment of the collection equipment, mainly includes the collecting device and the walking device. The micro and macro properties of sediments have a great influence on the collection efficiency of mining vehicles. For the collecting device, the optimization of the jet head structure and the solid–liquid two-phase flow transport of the hose are discussed. The structure of the walking device restricts mining efficiency. The optimization of the geometric structure is studied, and the geometric passability and lightweight design of the walking device are discussed. Secondly, the core of transportation equipment is the lifting device composed of a riser and lifting pump. In order to explore the key factors affecting mineral transport, the lifting device is summarized, and the design optimization of the lifting pump and the factors affecting the stability of the riser are discussed. Then, the relationship between each device is discussed, and the overall coupling of the device is summarized. Finally, the existing problems and future research focus are summarized.

Viability and life cycle assessment of Fuller's Earth as a low-cost adsorbent for zinc removal from aqueous solutions: Operating parameters, removal mechanisms and environmental impacts

Zinc is a heavy metal that has several health risks and must be removed from wastewater effluents before discharge to water bodies or reuse. Fuller's earth is a sedimentary clay and characterized by its low cost and availability. In this research, Fuller's earth (FE) was investigated as an adsorbent for the Zinc (Zn) removal from aqueous solutions to understand its performance, the mechanism of removal, and the potential environmental impacts. Life cycle assessment (LCA) was conducted using ReCiPe 2016 midpoint method. Zn adsorption studies on FE were conducted at various pH (2.5–9), temperatures (10°C, 25°C, and 40°C), initial concentrations of Zn (25, - 150 mg/L) and adsorbent doses of (0.25–4 g/ 50 ml). The Zn removal efficiency reached 99% at pH = 9 at an initial Zn concentration = 100 mg/L and the adsorbent dose = 0.25 g/ 50 ml. The experimental data fit into the Temkin isotherm, while kinetics were best expressed by pseudo-second order. The controlling step of the adsorption process was the film diffusion according to Boyd model. Thermodynamic experiments showed that adsorption is endothermic with an accompanying rise in randomness in the system. The adsorption capacity was 3.56 mg/g. Images by SEM confirmed the occurrence of adsorption. The desorption was successful at different concentrations of HCl. LCA results showed that the maximum negative and positive environmental impacts were associated with mineral resource scarcity (7.5*10–5 kg Cu eq) and human non-carcinogenic toxicity (−0.821 kg 1,4-DCB), respectively.

Effect of wood flour and compatibilizer content on the properties of wood-plastic composites

Wood-plastic composites (WPC) with are prepared by melting and mixing wood flour (WF) and thermoplastics which has green and biodegradable advantages and is of great significance in the development of the era of global resource scarcity. In this work, recycled polypropylene and WF were used as raw materials and commercially available maleic anhydride grafted polypropylene (MAH-g-PP) was used as a compatibilizer. The extrusion injection molding method was used and investigated by varying the amount of WF and compatibilizer added. The composites were analyzed for micro-morphology, melt mass flow rate, mechanical properties, and thermal stability by scanning electron microscopy (SEM), melt flow rate tester (MFR), electronic universal testing machine, and thermogravimetric analysis (TGA). According to the results, WF shows a positive effect in terms of storage and loss modulus of the composites, but it shows a negative effect in terms of thermal stability and mechanical properties. As an effective compatibilizer, MAH-g-PP plays an important role in improving the mechanical properties of the composites, especially at an additional level of 4 wt%, which maximized the overall performance of the composites.

Evaluation of a Multisectoral Health Security Alliance Program Through Perceptions of Member States: African Partnership Outbreak Response Alliance (APORA).

U.S. DoD global health engagements offer opportunities for strategic engagement and building capability in collaboration with foreign military and civilian counterparts. Global health engagement activities can take the form of health security alliances and allow the USA and its allies and partners to prepare for, mitigate, and respond to emerging biothreats and other harmful health events that may negatively impact national security. One such example is the African Partnership Outbreak Response Alliance (APORA), which was designed to expand African Partner Nation militaries' infectious disease outbreak response capabilities. This publication evaluates the development, implementation, and outcomes of APORA to better understand the program's effectiveness in developing Partner Nation medical capabilities and the efficacy of health security alliances more broadly. Key informant interviews, focus groups, and questionnaires were used to collect responses from a sample of participants who attended an in-person APORA event in May 2022. The research team conducted thematic analysis of all responses to identify common themes and sub-themes in participants' perspectives and to elucidate findings and recommendations for future endeavors. The analysis determined that participants attended the APORA event primarily to disseminate and apply knowledge, skills, and abilities gained at the event to their own health system structures. Overall, participants indicated that APORA contributed to their countries' military medical and civilian cooperation, as well as their countries' military medical capabilities. Longer-term partners (i.e., 4+ years of APORA membership) agreed more strongly with these sentiments; newer partners (i.e., 1-3 years of APORA membership) were more likely to be neutral or agree to some extent. Participants also valued the opportunity to solidify global, regional, local, and peer partnerships and considered the ability to create partnerships of great importance to their countries' national health security. Language barriers were often listed as a hindrance to event participation and the overall integration of a regional health system response. Participants also cited resource scarcity, network erosion (particularly because of the coronavirus disease 2019 pandemic), and a lack of disseminating and communicating value-add in how APORA could/is providing to their member countries' health systems as key barriers. As a whole, these findings support APORA's objectives to develop and leverage partnerships to support medical capacity building, promote collaboration between military and civilian sectors, and increase access to opportunities and financial resources. Further evaluation is required to capture additional civilian perspectives while continuing to expand upon military perspectives in order to produce more generalizable findings. That said, this study enables key stakeholders to understand how to strengthen and expand future alliances to improve both health and security outcomes.

Utilizing metabolomics and network analysis to explore the effects of artificial production methods on the chemical composition and activity of agarwood.

Introduction: Agarwood is a traditional aromatic southern medicine. It has a long history of being used in traditional Chinese aromatherapy to treat insomnia, anxiety and depression. Due to the scarcity of wild resources, people have planted trees successfully and begun to explore various agarwood-inducing techniques. This study comparative analysis of volatile metabolites in agarwood produced by various inducing techniques and its potential sleep-promoting, anti-anxiety and anti-depressant network pharmacological activities. Methods: A total of 23 batches of two types of agarwood were collected, one of which was produced by artificial techniques, including 6 batches of TongTi (TT) agarwood produced by "Agar-Wit" and 6 batches of HuoLao (HL) agarwood produced by "burning, chisel and drilling", while the other was collected from the wild, including 6 batches of BanTou (BT) agarwood with trunks broken due to natural or man-made factors and 5 batches of ChongLou (CL) agarwood with trunks damaged by moth worms. The study employed metabolomics combined with network analysis to compare the differences in volatile metabolites of agarwood produced by four commonly used inducing techniques, and explored their potential roles and possible action targets in promoting sleep, reducing anxiety, and alleviating depression. Results: A total of 147 volatile metabolites were detected in agarwood samples, mainly including small aromatic hydrocarbons, sesquiterpenes and 2-(2-phenylethyl) chromone and their pyrolysis products. The results showed composition of metabolites was minimally influenced by the agarwood induction method. However, their concentrations exhibited significant variations, with 17 metabolites showing major differences. The two most distinct metabolites were 6-methoxy-2-(2-phenylethyl) chromone and 6,7-dimethoxy-2-(2-phenylethyl) chromone. Among the volatile metabolites, 142 showed promising potential in treating insomnia, anxiety, and depression, implicating various biological and signaling pathways, predominantly ALB and TNF targets. The top three active metabolites identified were 2-(2-phenylethyl) chromone, 1,5-diphenylpent-1-en-3-one, and 6-methoxy-2-[2-(4'-methoxyphenyl) ethyl] chromone, with their relative content in the four types of agarwood being TT>HL>CL>BT. Conclusion: The differences in the content of 2-(2-phenylethyl) chromones suggest that they may be responsible for the varying therapeutic activities observed in different types of agarwood aromatherapy. This study offers theoretical support for the selection of agarwood in aromatherapy practices.

The role of healthcare providers and caregivers in monitoring critically ill children: a qualitative study in a tertiary hospital, southern Malawi

BackgroundCritically ill children require close monitoring to facilitate timely interventions throughout their hospitalisation. In low- and middle-income countries with a high disease burden, scarce paediatric critical care resources complicates effective monitoring. This study describes the monitoring practices for critically ill children in a paediatric high-dependency unit (HDU) in Malawi and examines factors affecting this vital process.MethodsA formative qualitative study based on 21 in-depth interviews of healthcare providers (n = 12) and caregivers of critically ill children (n = 9) in the HDU along with structured observations of the monitoring process. Interviews were transcribed and translated for thematic content analysis.ResultsThe monitoring of critically ill children admitted to the HDU was intermittent, using devices and through clinical observations. Healthcare providers prioritised the most critically ill children for more frequent monitoring. The ward layout, power outages, lack of human resources and limited familiarity with available monitoring devices, affected monitoring. Caregivers, who were present throughout admission, were involved informally in monitoring and flagging possible deterioration of their child to the healthcare staff.ConclusionBarriers to the monitoring of critically ill children in the HDU were related to ward layout and infrastructure, availability of accurate monitoring devices and limited human resources. Potential interventions include training healthcare providers to prioritise the most critically ill children, allocate and effectively employ available devices, and supporting caregivers to play a more formal role in escalation.

Exploring the Scarcity of Municipal Resources as Contributors to Illegal Strikes and Protests in the City of Tshwane Metropolitan Municipality, South Africa

The shortage of resources at municipalities are a national problem in so many ways. By lacking resources and maintenance municipalities are unable to provide communities with quality service delivery. This article aims to highlight the impact of scarcity of resources in the City of Tshwane (CoT) Metropolitan Municipality which bring about illegal and unprotected strikes by employees, and protests by the local community. When residents or employees are unhappy with poor municipal services, be it no water or electricity for days, poor service delivery, low employee salaries or better working conditions, people tend to take to the streets and show their discontentment with lack of proper services by local government. Strikes and protests arise for a number of reasons, though principally in response to economic conditions. When employees strike for better wages or residence for proper services, both demonstrations have an impact on the economic welfare of any country. The methodological rigor of this paper is ethnographical in nature and data was collected through literature study. Major contributions is to identify advanced methods of policing through intelligence gathering and enforcement when or before illegal strikes and protests take place. This will assist in eliminating fear from the public, tourists, non-striking employees, law enforcement officers and local business operators, etc. The implications should instill the norm of zero tolerance to violence and intimidation, and punishments are inevitable within the prescripts of the law of the Republic of South Africa. Enforcing the law by ensuring that legal mechanisms are reactive and punitive will hinder anyone to partake in illegal strikes or protests.

Legumes and common beans in sustainable diets: nutritional quality, environmental benefits, spread and use in food preparations.

In recent decades, scarcity of available resources, population growth and the widening in the consumption of processed foods and of animal origin have made the current food system unsustainable. High-income countries have shifted towards food consumption patterns which is causing an increasingly process of environmental degradation and depletion of natural resources, with the increased incidence of malnutrition due to excess (obesity and non-communicable disease) and due to chronic food deprivation. An urgent challenge is, therefore, to move towards more healthy and sustainable eating choices and reorientating food production and distribution to obtain a human and planetary health benefit. In this regard, legumes represent a less expensive source of nutrients for low-income countries, and a sustainable healthier option than animal-based proteins in developed countries. Although legumes are the basis of many traditional dishes worldwide, and in recent years they have also been used in the formulation of new food products, their consumption is still scarce. Common beans, which are among the most consumed pulses worldwide, have been the focus of many studies to boost their nutritional properties, to find strategies to facilitate cultivation under biotic/abiotic stress, to increase yield, reduce antinutrients contents and rise the micronutrient level. The versatility of beans could be the key for the increase of their consumption, as it allows to include them in a vast range of food preparations, to create new formulations and to reinvent traditional legume-based recipes with optimal nutritional healthy characteristics.

Different M-doped Ni3S2/FeS (M=Co, Cr, Cu, Zn) hybrid nanosheet arrays for overall urea splitting and seawater oxidation reaction

Hydrogen production by electrolysis of water is gradually becoming the main way to obtain green energy, but due to the scarcity of fresh water resources in the world, so the study of urea and seawater electrolysis has become an important work. In this experiment, different metal ions M (M=Co, Cr, Cu, Zn) doped Ni3S2/FeS were investigated as catalysts with good catalytic activity in hydrogen evolution reaction (HER) as well as in urea oxidation reaction (UOR) in urea electrolyte, and Co-Ni3S2/FeS and Cr-Ni3S2/FeS, which performed well in HER and UOR, were assembled into an electrolytic cell for the overall urea decomposition (1.50 V @ 10 mA cm−2). Density Functional Theory (DFT) calculations demonstrated that Co-Ni3S2 possesses a lower free energy for H, while FeS possesses a higher density of states (DOS) near the Fermi energy level, and such a composite structure promotes significantly the catalytic activity of HER. The catalytic effect of oxygen evolution reaction (OER) was further investigated in the seawater electrolyte, and the results showed that the performance of Co-Ni3S2/FeS catalyst was better, and certain ions in seawater affected durability of the catalyst. The electronic structure of the catalyst was investigated through the characterization of the catalyst and combined with the special morphology jointly promote the catalytic reaction in electrolysis experiments, which provides a candidate catalyst for electrolysis of urea and seawater oxidation reaction.

Crop HTP Technologies: Applications and Prospects

In order to rapidly breed high-quality varieties, an increasing number of plant researchers have identified the functions of a large number of genes, but there is a serious lack of research on plants’ phenotypic traits. This severely hampers the breeding process and exacerbates the dual challenges of scarce resources and resource development and utilization. Currently, research on crop phenotyping has gradually transitioned from traditional methods to HTP technologies, highlighting the high regard scientists have for these technologies. It is well known that different crops’ phenotypic traits exhibit certain differences. Therefore, in rapidly acquiring phenotypic data and efficiently extracting key information from massive datasets is precisely where HTP technologies play a crucial role in agricultural development. The core content of this article, starting from the perspective of crop phenomics, summarizes the current research status of HTP technology, both domestically and internationally; the application of HTP technology in above-ground and underground parts of crops; and its integration with precision agriculture implementation and multi-omics research. Finally, the bottleneck and countermeasures of HTP technology in the current agricultural context are proposed in order to provide a new method for phenotype research. HTP technologies dynamically monitor plant growth conditions with multi-scale, comprehensive, and automated assessments. This enables a more effective exploration of the intrinsic “genotype-phenotype-environment” relationships, unveiling the mechanisms behind specific biological traits. In doing so, these technologies support the improvement and evolution of superior varieties.