Saturated Brine Research Articles

Soluble mineral flotation paradox: Improved recovery with no sign of collector adsorption on minerals signifies colloidal attraction between bubble-bound collector colloids and mineral particles

Froth flotation uses air bubbles to separate mineral particles based on the difference in mineral surface hydrophobicity. Collectors are needed to selectively hydrophobize the surface of targeted minerals to augment the difference in surface hydrophobicity between wanted minerals and unwanted ones. Here, we showed that this classical (well-established) principle fails to describe the flotation of water-soluble minerals. Our systematic micro-flotation tests using soluble minerals (NaCl and KCl crystals) in brines and three popular collectors (dodecylamine hydrochloride, sodium dodecylsulfate, and sodium laurate) showed a substantial flotation recovery of the salt minerals without detected collector adsorption at the mineral surfaces by X-ray photoelectron spectroscopy (XPS). Complementary particle size distribution measurement indicated the occurrence of sub-micron collector colloids in saturated brines. Moreover, the flotation recovery agreed well with the measured contact angle, suggesting the attraction between bubble-bound collector colloids and salt crystal surfaces. These paradoxical results signify a new principle underlying the flotation of soluble minerals, i.e., the selective colloidal attraction between bubble-bound collector colloids and salt particles enables the flotation separation of soluble minerals.

A new type of submarine chimneys built of halite

In contrast to the subaquatic sulphide and carbonate chimneys, which are known from Mid Ocean Ridges and abyssal submarine volcanoes, chimneys built of salts have not been described yet. Here we present such halite chimneys as a new form of cold-water smokers in hypersaline environments. The here described structures rise up from the bottom of the Dead Sea and result from the submarine discharge of saturated halite-dissolution brines into the salt lake, which is at halite saturation and holds remarkable chloride excess. At the interface with the lake brine, halite precipitates instantaneously, forming chimneys up to several meters in height. The brines leading to the formation of these chimneys vary in composition, while their generation processes are similar. Fresh groundwater from surrounding aquifers enters the saline lake sediments and considerably leaches halite in the adjacencies of the lake. Simultaneously, it mixes with ancient brines before it emerges from the lake floor. The distinct differences in composition between the Dead Sea and the emerging chimney brines lead to the instantaneous crystallisation of halite and few other mineral phases. The chimney structure result from the buoyancy flow of the chimney brines, which are less dense then the ambient Dead Sea.The chimneys indicate intense cavitation of massive halite bodies in the subsurface of the Dead Sea environment, a process that leads to increasing formation of hazardous sinkholes. Since chimneys are proven in shallow water but may be expected in deeper parts too, they are comfortably mappable by echo-sounding or aerial imaging. They thus provide in the Dead Sea as in any likewise setting a potent predictive tool to locate dangerous subsurface cavitation and hence areas that are at risk of collapse in the near future.

Modeling and Mitigating Gas Hazards during Potash Mine Closure

The planned closure of potash mines achieved through the injection of highly mineralized brines into the worked-out area is a complex process. A critical concern arises when brines obstruct the aerodynamic connections between the flooded mine’s airspace and the atmosphere, potentially leading to the formation of closed cavities where explosive gases can accumulate. To address this hazard, it is imperative to develop systems capable of extracting the gas–air mixture from the unflooded part of the worked-out area. Two distinct scenarios are examined: the first involves controlled flooding with saturated brines, while the second contemplates flooding resulting from a hypothetical breakthrough of supra-salt strata, leading to the ingress of groundwater into the worked-out area. A novel mathematical model is introduced to predict the evolution of gas–air mixture parameters in the unflooded part of the worked-out area. Utilizing this model, we assess the effectiveness of proposed measures designed to eliminate explosive gases from the worked-out area. Specifically, a pipeline system is proposed for the removal of gases. The findings from this study contribute valuable insights into ensuring the safe and efficient closure of potash mines, shedding light on potential risks and effective mitigation strategies for gas-related hazards during planned flooding.

Comparative Study of the Proximate Composition and Sensory Evaluation of Fresh and Smoke-dried Fish Species from Omambala River, Anambra State, Nigeria

This study investigates the proximate composition and organoleptic properties of fish species from the Omambala River in Anambra State. A total of 40 fresh fish samples, specifically Clarias gariepinus and Heterotis niloticus, with a mean length of 25 cm and mean weight of 380 g, were analyzed. The fish samples, initially scaled, had their viscera removed and were washed in clean water before undergoing brining. This involved immersing the fish in a 75% saturated brine solution, prepared by dissolving 27 g of NaCl in 100 ml of water for 30 seconds. The samples were then smoke-dried in a smoking kiln. Proximate composition was assessed using standard methods from the Association of Analytical Chemists (AOAC), while organoleptic properties were evaluated using a 9-point hedonic scale. Data were collated and analyzed using a two-way analysis of variance (ANOVA) with GENSTAT version 4 software, and mean separation was performed using the Least Significant Difference at a 5% probability level. Results indicated that the proximate analyses revealed an increase in all nutrient compositions after smoke-drying, except for moisture and carbohydrates, which significantly decreased from 44.58% to 14.15% and from 37.10% to 7.88%, respectively, for C. gariepinus. In the case of H. niloticus, increases were noted in ash, fiber, fat, and protein, while moisture decreased significantly (p<0.05) from 44.87% to 17.89%. Organoleptic evaluation showed a preference for C. gariepinus, which had a significantly higher overall acceptability mean score of 8.40±0.66 compared to 6.70±2.26 for H. niloticus. This research demonstrates that smoke-drying fish effectively reduces moisture content, enhances nutrient composition, and improves organoleptic properties, thereby increasing shelf life. It is recommended that both C. gariepinus and H. niloticus be hygienically smoke-dried to maximize organoleptic qualities, nutrient composition, and shelf life, ultimately yielding better economic returns. Keywords: Nutrient composition, organoleptic properties, Smoking kiln, Fish species

An insight into hydrogen and carbon dioxide displacement and trapping efficiencies in carbonate formations through NMR and core flooding

The complex pore structure of carbonates can influence gas storage process to different extents, depending on stored gas type. Hence, investigating gas displacement and residual trapping in such formations is crucial. Here, several CO2 and H2 core flooding experiments were performed using three carbonate samples. The drainage process is followed by brine imbibition to test gas residual trapping. Additionally, nuclear magnetic resonance (NMR) T2 spectra measurements were conducted at different stages. The results show that H2 had less displacement efficiency in carbonates compared to CO2. The pore structure has a noticeable impact on CO2 displacement efficiency. However, H2 displacement efficiency is less sensitive to rock properties. The NMR-T2 measurements show that CO2 partially saturated medium-sized pores and almost filled all macropores during drainage. After imbibition, large pores are slightly re-saturated with brine with varying degrees compared to their initial brine saturations. H2 shows lower residual trapping efficiency compared to CO2.

Preparation of high-strength and low-shrinkage composite salt cores by binder jetting and vacuum impregnation

ABSTRACT Binder jetting (BJ) technology was employed combined with vacuum impregnation to fabricate alumina-reinforced Na2SO4-NaCl water soluble composite salt cores (WSCSC), intended for manufacturing aluminum alloy castings featuring intricate cavity structures. The bending strength and sintering shrinkage rate of WSCSC were investigated to discern the influences of alumina content, vacuum impregnation pressure and time, accompanied by a detailed analysis of the microstructure and reinforcement mechanism. The findings reveal that WSCSC containing 40 wt.% alumina exhibits exceptional mechanical properties, demonstrating a bending strength of 29.13 MPa, which is 197% higher than that of WSCSC without alumina. Furthermore, when the vacuum impregnation of saturated brine is conducted at a pressure of 30 KPa for 90 s, the resulting WSCSC possesses a sintering shrinkage rate of 4.94%, reflecting a significant reduction of 73.5% compared to that of WSCSC without vacuum impregnation treatment. Microstructural analyses show that alumina, as a stable secondary phase, can refine the NaCl grains within WSCSC, deflecting cracks and elongating their propagation paths, thereby remarkably enhancing the bending strength. Moreover, the fine inorganic salt particles crystallized and precipitated from saturated brine during the drying process are filled in the internal pores of WSCSC through vacuum impregnation, dramatically reducing the sintering shrinkage rate. Ultimately, the high-strength and low-shrinkage WSCSC parts were successfully manufactured.

Study on synthesis and mechanism of high temperature resistant suspension stabilizer for spacer fluid

With 2-acrylamido-2-methylpropanesulfonic acid (AMPS), YX-1 (a monomer containing an amide group) as the main chain, DX-2 (a monomer containing a hydrophobic group), N-vinylpyrrolidone (NVP) as the side chain, the high temperature resistant suspension stabilizer for spacer was prepared by free radical aqueous solution polymerization and characterized. The structure was characterized by fourier transform infrared (FTIR) spectroscopy and thermogravimetry-differential thermal analysis (TG-DTA), which proved that the synthesized product was the target product. The performance of the copolymer was evaluated. The experimental results showed that it could be used in the spacer fluid at 30 ∼ 210 °C, and its sedimentation performance could also meet the requirements in the spacer fluid system containing saturated brine. In order to explore the mechanism of the polymer, the polymer solution was tested by six-speed rotational viscometer, pyrene fluorescence probe test, environmental scanning electron microscopy (ESEM) test, and the isolation solution containing the copolymer was tested by Zeta potential test and X-ray diffraction (XRD). Based on the above test results, it is shown that the suspension stabilizer synthesized in this paper has the characteristics of thickening, physical plugging, chemical and physical adsorption, which can effectively ensure that the spacer fluid has excellent suspension performance at high temperature.

Influence of temperature on corrosion behavior of additively manufactured SS316L stainless steel in CO2-saturated brine solution

The present study investigates the influence of temperature on corrosion of AM SS316L in CO2 saturated brine solution. As the temperature increased from 25 °C to 70 °C, the corrosion rate rose nearly fivefold, from 1.78 to 10.06 mpy. The pitting potential decreased from 818 mV to 450 mV, with the gap between |Epit – Erep| widening from 669 mV to 853 mV. EIS results corroborated these results, revealing a decline in Rct from 4755 to 858 Ωcm2 and an increase in Yct from 38 to 119 snΩ-1cm−2. Subsequent surface morphology analysis post-corrosion testing revealed increased corrosion severity with rising temperature. In summary, elevated temperature led to increased corrosion rates, more susceptibility to pitting corrosion, and hindered repassivation.

Effects of CO2-saturated brine imbibition on the mechanical and seepage characteristics of Longmaxi shale

Supercritical carbon dioxide (SC– CO2) serves as a promising anhydrous fracturing fluid that has the potential to simultaneously enhance shale gas recovery and accomplish CO2 sequestration within shale reservoirs. However, the hydromechanical properties of shale are considerably affected by CO2-brine-shale interaction. This study conducted shale imbibition experiments involving subcritical/supercritical CO2 saturated brine (Sub/SC-CO2+brine). Triaxial compressive strength tests were performed to evaluate the impact of Sub/SC-CO2+brine imbibition on the mechanical properties of shale, as well as the influence of SC-CO2+brine imbibition on shale permeability. The results indicate that, after SC-CO2 brine imbibition, noticeable macroscopic cracks are formed parallel to the bedding plane. The imbibition of Sub/SC-CO2+brine results in the reduction in axial stress and Young's modulus, while simultaneously increasing the axial strain of shales. Compared to Sub-CO2+brine, SC-CO2+brine exhibits a higher imbibition pressure and a more intense geochemical reaction with shale. Due to increased compressibility sensitivity, the averaged permeability after SC-CO2+brine imbibition shows a reduction of nearly 70 % compared to that before imbibition. The insights from this research are expected to provide theoretical support for shale gas recovery and CO2 geological sequestration.

Temperature swing solvent extraction for salt and glycerin separation from wastewater

A relatively novel temperature-swing solvent extraction (TSSE) technology was investigated for the separation of salt and glycerol from high-salt wastewater containing glycerol. Diisopropylamine (DIPA) was employed as the solvent for successfully treating ultrahigh-salinity wastewater. Experimental results indicated that the salt removal rate of TSSE technology reached up to 93.86% in saturated brine containing 10.00 wt% glycerol. After five cycles of solvent recovery, the salt removal rate remained at 84.55%. Additionally, when the glycerol mass fraction in saturated brine was 80.00 wt%, the water recovery rate of TSSE technology was 60.27%, with a salt removal rate of 92.88%. The study also analyzed the mechanism of TSSE, revealing that the difference in solubility between DIPA and NaCl in water is crucial for achieving TSSE. The unique capability of TSSE technology in treating high-salt wastewater containing organics was highlighted, achieving not only effective salt removal but also glycerol concentration. The findings of this research not only demonstrate the remarkable effectiveness of TSSE technology in addressing high-salt wastewater containing glycerol but also forecast its promising outlook and immense potential for widespread adoption in various industrial wastewater treatment sectors.

Evaluation of SC-CO2–brine on the micro-mechanical properties of lamina shales by micro-scratch test

The mechanism of SC-CO2–brine–rock interaction (SCBRI) and its effect on the mechanical properties of shale are crucial for shale oil development and CO2 sequestration. To clarify the influence of SCBRI on the micromechanics of shale, the lamina and matrix of shale were saturated with SC-CO2–brine for 2, 4, 6, and 8 days, respectively. The micro-scratch technique was then used to measure the localized fracture toughness before and after SC-CO2–brine saturation. Combining the micro-scratch results with SEM-QEMSCAN-EDS analysis, the differences in mineral composition and mechanical properties of lamina (primarily composed of carbonate minerals) and matrix (primarily composed of clay minerals) were studied. The QEMSCAN analysis and micro-scratch results indicate distinct mineralogical compositions and mechanical properties between the lamina and the matrix. The results showed that: (1) SCBRI leads to the decrease in carbonate mineral content and the significant increase in matrix porosity and laminar cracks. In addition, the damage degree increased at saturation for 6 days. (2) SCBRI weakens the mechanical properties of shale. The scratch depth of laminar and matrix increased by 34.38% and 1.02%, and the fracture toughness decreased by 34.38% and 13.11%. It showed a trend of first increasing and then decreasing. (3) SCBRI enhances the plastic deformation behavior of shale, and the plastic index of lamina and matrix increases by 18.75% and 21.58%, respectively. These results are of great significance for evaluating the mechanical properties of shale oil and gas extraction by CO2.

Kirigami enabled reconfigurable three-dimensional evaporator arrays for dynamic solar tracking and high efficiency desalination.

A kirigami-engineered composite hydrogel membrane is exploited for the construction of three dimensional (3D) solar-tracking evaporator arrays with outstanding evaporation performance and salt tolerance. The hybrid nanofiber network in the hydrogel membrane offers favorable water transport dynamics combined with excellent structural robustness, which are beneficial for the engineering of 3D dynamic structures. Periodic triangular cuts patterned into the membrane allow formation and reconfiguration of 3D conical arrays controlled by uniaxial stretching. With these structures, the tilt angles of the membrane surface are actively tuned to follow the solar trajectory, leading to a solar evaporation rate ~80% higher than that of static planar devices. Furthermore, the tapered 3D flaps and their micro-structured surfaces are capable of localized salt crystallization for prolonged solar desalination, enabling a stable evaporation rate of 3.4 kg m-2 hour-1 even in saturated brine. This versatile design may facilitate the implementation of solar evaporators for desalination and provide inspirations for other soft functional devices with dynamic 3D configurations.

Investigation of gas residuals in sandstone formations via X-ray core-flooding experiments: Implication for subsurface hydrogen storage

The production and utilization of hydrogen (H2) as a clean energy source offer a promising solution towards achieving net-zero carbon emissions. Utilizing sandstone formations for geological hydrogen storage presents a viable option for the practical implementation of the hydrogen economy, offering both safe and large-scale containment capabilities. Accurate assessment of gas displacement behavior in porous media plays a critical role in understanding gas saturation, gas residual, and long-term storage duration. However, there are limited studies available on dynamic displacements for hydrogen storage applications. This study aims to enhance the understanding of gas flow behavior in sandstone rocks for different gas types and determine the role of capillary pressure and gas wettability during hydrogen storage. A series of gas core-flooding experiments are performed on a brine-saturated sandstone core sample using three different gases (CO2, CH4, and H2). X-ray scanning technique is applied to detect the gas saturation and gas residual after the core-flooding experiments. The results indicate that the average gas saturation ranges between 25 and 40%, with zero gas residual for all gases, suggesting that the gas residuals in this clean sandstone sample are unaffected by the gas type. Initially, the capillary pressure profile for the sample displayed low brine saturation at 200 psi, indicating very low capillary pressure in the sample due to the high permeability and large pore radius, despite the strong water-wetting behavior of the sample. Moreover, the obtained results indicate the high potential for gas recovery (especially for hydrogen during withdrawal cycles), and the high displacement efficiency in sandstone rocks. The reported low gas residual suggests that the wettability of the rock is not affected by gas injection, and it appears that the wettability and capillary pressure are not the controlling factors for gas storage in this sandstone sample. This observation suggests that the structural trapping mechanism is most likely to be the dominant trapping mechanism in this shallow high permeable sandstone rock. Also, the injection of cushion gases such as CO2 and CH4 indicated similar results to hydrogen injection, due to the low capillary pressure and high permeability in this sandstone sample. The findings of this study can greatly enhance the understanding of gas injection, displacement behavior, and gas residuals in sandstone rocks related to underground hydrogen storage.

Steady-state relative permeability measurements in rough-walled fractures: The effects of wettability and aperture

Tight subsurface geosystems provide significant prospects for the recovery and storage of mass and energy. Because of the tightness of these systems, natural and engineered fractures are the main conveyance conduits transporting the fluids from the tight rock matrix to the wellbore or vice versa. During the fracturing process, most of the newly induced fractures are considered water-wet, however during injection/production, the wettability of the fractures gradually changes. These changes are mainly due to the interactions between the resident and injected fluids, or the exposure of the virgin fracture surfaces to the resident fluids during production. This alteration in wettability can affect the trapping and flow dynamics, e.g., relative permeability, of the fluids flowing in the fracture. Furthermore, fluid injection and production into and from these systems impact the fractures pore pressure and hence the effective stress they are exposed to, resulting in variations in the fracture aperture. In this study, we present a comprehensive macro-scale experimental investigation focusing on the impact of wettability and aperture on steady-state two-phase relative permeability in rough-walled fractures. Using the stead-state measurement technique, we meticulously characterized oil-brine relative permeabilities and residual trapping in water-wet, oil-wet, and mixed-wet rough-walled fractures induced in Eagle Ford shale rock samples. Additionally, we assessed the influence of fracture aperture size on these properties during both drainage and imbibition flow processes. Our results indicate significant phase interference in oil-brine flow in non-water-wet rough-walled fractures, which renders the commonly used x-curve and Corey models inadequate to represent the steady-state oil-brine relative permeabilities measured in our study, leading to substantial overestimations. Mixed-wet fractures exhibited reduced relative permeabilities compared to oil-wet fractures, which in turn demonstrated lower relative permeabilities than water-wet counterparts. The observed trends stem from evolving fluid configuration and transport dynamics within the fractures as surface wettability transitions. Furthermore, an increase in fracture aperture corresponded with an increase in relative permeability. This was attributed to a broader flow area, diminished capillarity, attenuated impact of fracture wall roughness and tortuosity effects, and a reduction in bypassing and trapping events, all synergistically contributing to the mitigation of phase interference. Similarly, an increase in fracture aperture led to a marked decrease in post-waterflooding endpoint oil saturation and post-oil flooding endpoint brine saturation. Finally, we provided generalized correlation models based on experimental results from fractures with varying conductivities and wettability, yielding a more accurate representation of fracture relative permeabilities compared to traditional models. The data and correlation models produced in this study improve our understanding and prediction of multiphase flow in subsurface fractures and offer insights into rapid production decline in unconventional shale reservoirs.

Influence of the CO2–brine–rock interaction on the plastic zone of sandstone

During the long-term CO2 storage process, the CO2–brine–rock interaction (CBRI) may change the elastic-plastic behaviors of sandstone reservoirs, potentially leading to rock damage and CO2 leakage. A good understanding of the influence of the CBRI on the plastic zone of sandstone is crucial for evaluating the rock fracturing processes. In this paper, three-point bending tests were conducted under both monotonic and cyclic loading conditions, and the digital image correlation technique was used to analyze the elastic and plastic characteristics of the samples. The experimental results showed that the CBRI decreases the yield strength and corresponding crack mouth opening displacement by 25 % and 65%, respectively, thus increasing the probability of fracturing. Additionally, it was found that the CBRI enlarges the plastic zone by about 20 %. The size of the theoretical plastic zone in the sandstone sample for different loads was determined, and the ratio of the plastic zone size in the samples with CO2–brine saturation to that without CO2–brine saturation was found to be about 1.18. Finally, the mesoscale factors affecting the plastic zone size after CO2–brine saturation were analyzed. This study helps to understand the effect of the elastic-plastic behavior of sandstone on reservoir stability during long-term CO2 storage.

Relative permeability evolution with thermo-poromechanical process during N2 and scCO2 injection in brine saturated Deadwood sandstone from Aquistore

This study delves into the intrinsic and multiphase flow properties, specifically steady-state drainage relative permeability, of a subsurface Deadwood sandstone from the Aquistore CO2 storage site in Canada. Consecutive core-flooding experiments were conducted utilizing N2- and scCO2-brine pairs across a broad range of temperatures (20–70 °C) and isotropic effective stress (0–30 MPa). Moreover, we monitored crack initiation and propagation of the sandstone during uniaxial loading at an elevated temperature using an integrated approach that combines microCT scanning with an in-situ heating/loading test. Our findings reveal a 54 % decrease and a 3 % increase in the absolute permeability of the sandstone through isothermal compaction followed by thermal expansion processes, respectively. Elevating the temperature from 20 °C to 70 °C results in a systematic 24 % increase in irreducible brine saturation and nearly doubles the end-point N2 mobility, indicating an increased tendency of the rock surface towards the brine phase with temperature. Substituting N2 with scCO2 demonstrates a leftward shift in relative permeability and a decrease in irreducible brine saturation (from 0.36 to 0.31), consistent with low interfacial tension and the de-wetting effect during cyclic scCO2-brine injections. Micro-CT image analysis reveals micro-crack initiation at 10 MPa stress and 70 °C temperature, suggesting that a mixed impact of induced cracks, dynamic wettability, and thermo-mechanical deformation is responsible for the substantial increase in well injectivity over time in Aquistore. This novel experimental program provides indispensable insight into thermo-poromechanical and wettability controls on multiphase flow at the Aquistore injection site in Canada, with potential applicability to similar scenarios globally.

Spatiotemporal X-Ray Imaging of Neat and Viscosified CO2 in Displacement of Brine-Saturated Porous Media

Summary CO2 storage in saline aquifers may contribute to a 90% share in preventing emissions to the atmosphere. Due to low CO2 viscosity at the subsurface often found in supercritical (sc) conditions, the injected CO2 may spread quickly at the formation top and increase the probability of leakage. This work relates to improved CO2 storage in saline aquifers by effective viscosification of the sc-CO2 at very low concentrations of engineered oligomers and the effectiveness of slug injection of viscosified CO2 (vis-CO2). We present the results from X-ray computed tomography (CT) imaging to advance the understanding of two-phase CO2-brine flow in porous media and firmly establish the transport mechanisms. X-ray CT imaging of displacement experiments is conducted to quantify the in-situ sc-CO2 saturation spatiotemporally. In neat CO2 injection, gravity override and adverse mobility ratio may result in early breakthrough and low sweep efficiency. We find cumulative brine production from the fraction collector to be lower than X-ray CT imaging at 2 pore volume (PV) injection. The difference between the two is attributed to the solubility of the produced water in the produced CO2 at atmospheric pressure. We show that when the solubility is accounted for, there is a good agreement between direct measurements and in-situ saturation results. There are three reports (two by the same group) that oligomers of 1-decene (O1D) with six repeat units may have marginal CO2 viscosification. The majority of published work by other groups shows that O1D with six repeat units and higher are effective CO2 viscosifiers. In the past, we have demonstrated the effectiveness of an O1D in the displacement of brine by CO2 at a concentration of 1.5 wt%. The effectiveness is examined and identified by three different methods. In this work, we show that the same oligomer is effective at a low concentration of 0.6 wt%. The oligomer slows the breakthrough by 1.6 times and improves the brine production by 34% in the horizontal orientation. X-ray CT imaging results reveal that such a large effect may be from the increase in the interfacial elasticity. We also show that there is no need for continuous injection of the oligomer. A slug of 0.3 PV injection (PVI) of vis-CO2 followed by neat CO2 injection has the same effectiveness as the continuous injection of the vis-CO2. In this work, we also demonstrate the effectiveness of a new engineered molecule at 0.3 wt% that may increase residual trapping by about 35%. The combination of mobility control and residual brine saturation reduction is expected to improve CO2 storage by effective viscosification with low concentrations of oligomers.

Doping heteroatoms to form multiple hydrogen bond sites for enhanced interfacial reconstruction and separations

Interfacial challenges in unconventional oil extraction include heavy oil–water–solid multiphase separation and corrosion inhibition. Herein, a novel strategy based on interfacial hydrogen bonding reconstruction is proposed for constructing multifunctional interfacially active materials (MIAMs) to address multi-interfacial separation needs. A simple one-pot method is applied to successfully synthesize four different MIAM varieties, integrating site groups (–NH2, OSO, –COOH, and Si–O–Si) with multiple hydrogen bonds (HBs) into allyl polyether chains. The results indicate that all synthesized MIAMs excel in demulsification, detergency, and corrosion inhibition simultaneously, even at 25 °C. Their dehydration efficiency for different water-in-oil emulsions (even heavy oil emulsion) surpasses 99.9 % even at 16 °C, showing their excellent energy-saving potential for field applications. Furthermore, they demonstrate effective, nondestructive static cleaning (up to 86 %) of adhered oil from solid surfaces at 25 °C and provide corrosion inhibition effects (up to 92.09 %) on mild steel immersed in saturated brine. Mechanistic tests reveal that incorporating multiple HB sites in MIAMs dramatically enhances their effectiveness in interfacial separations. Based on these findings, an HB-dominated noncovalent interaction reconstruction strategy is tentatively proposed to develop advanced materials for low-carbon, efficient interfacial separations.

Study of processes for the recovery of lithium ions from extremely saturated formation brines

Study of processes for the recovery of lithium ions from extremely saturated formation brines

Experimental Study of Seismic Wave Attenuation in Carbonate Rocks

Summary Seismic wave attenuation has a great potential for studying saturated and fractured media, due to its high sensitivity to the physical properties of geological media. However, accurately estimating this parameter can be challenging due to its sensitivity to signal noise, particularly in heterogeneous media such as carbonate rocks. This explains the paucity of attenuation studies carried out in carbonate rocks compared with sandstones, and the ambiguity around its mechanisms and its relationship with petrophysical properties. To investigate further, we conducted an experimental study of ultrasonic waveform signals (0.5–3 MHz) reordered under dry and fully saturation conditions in 13 samples covering a wide range of petrophysical values and subjected them to differential pressure reaching reservoir pressure. The resulting increase in attenuation magnitudes and their variation with pressure due to brine saturation were more pronounced than in velocity magnitudes, confirming the higher sensitivity of attenuation to fluid content. However, understanding the relationship between attenuation and petrophysical properties required a careful examination of the results and more elucidation about attenuation mechanisms. We suggested that multiple attenuation mechanisms coexist, including scattering, cracks slipping, solid frictional relative motion, and global and squirt flow. This explains the frequency dependence of attenuation, with higher magnitudes at sonic frequencies, where the squirt flow mechanism may be dominant. In contrast to sandstone, the magnitude of compressional to shear attenuation ratio (QP−1/QS−1) was found to be greater than unity in both dry and brine fully saturated carbonate samples at ultrasonic frequencies. This result may be due to the complex porosity structure of carbonate rocks, which makes it not appropriate to the sandstone rock physics models.