Salt Flux Research Articles

EuSi7P10: An Inorganic Supramolecular Nonlinear Optical Crystal Exhibiting Strong Second-Harmonic Generation Response.

Inorganic supramolecular compounds are the emergent class of infrared (IR) nonlinear optical (NLO) materials. However, the reported inorganic supramolecular IR NLO pnictides are still scarce. In this work, a new inorganic supramolecular IR NLO phosphide, EuSi7P10, has been synthesized using the metal salt flux method. The structure of EuSi7P10 features an anionic host framework containing the oriented [Si7P16] dual-T2 supertetrahedra with the guest Eu2+ cations filling in the intervals. Additionally, EuSi7P10 exhibits strong phase-matched (PM) second-harmonic generation (SHG) (4.0 × AgGaS2), large birefringence (0.087 @2050 nm), and wide infrared transparency. This study highlights the potential of inorganic supramolecular pnictides for exploring high-performance IR NLO crystals.

Temperature effects on ion migration and energy consumption during brackish water electrodialysis desalination

Electrodialysis (ED) is a well-established brackish water (BW) desalination technology based on the selective electro-transfer mechanism of ions for meeting freshwater demands in scarce water regions. While the influence laws of water temperature difference caused by changing seasons on the performance of BWED need to be clarified further. This study examined the effect of temperature on the desalination efficiency and energy consumption of BWED by controlling the water temperature with a constant temperature tank. Results showed that higher temperature significantly increased the current density and salt flux of BWED, but also caused a decrease and then an increase in energy consumption. The apparent activation energy of BWED system in low temperature range is about 40 % higher than that in high temperature range, indicating that higher temperature is contributed to reduce the ion transport resistance. While higher temperature increased ion diffusivity and membrane pore size, with a corresponding rise in LCD of ∼0.41 mA/cm2 and an increase in desalination ratio of ∼7.75 % for increment of every 10 °C, thus enhanced reverse salt diffusion. The running parameters of BWED system should be regularly regulated with the seasonal temperature based on the trade-off between desalination efficiency and energy consumption to ensure an efficient operation.

Controlling amine monomers via UiO-66-NH2 defect sites to enhance forward osmosis membrane performance for lithium recovery

The excessive thickness of the separation layer and the presence of cracks cause low water flux and poor lithium recovery in conventional forward osmosis (FO) membranes. According to the influence of the diffusion behavior of amine monomers in interfacial polymerization, the use of an interlayer optimizes the separation layer structure of traditional thin-film composite FO membrane. However, it is difficult to accurately control the separation layer structure by simply adjusting the amount of the interlayer material loaded. Herein, FO membranes with defect-containing metal–organic framework (MOF) interlayers were constructed. By adjusting the concentrations of competitive ligands, the MOFs showed different degrees of linker loss, which exposed the metal ions in the MOFs to different extents. The defective sites of the constructed MOFs increased the interaction between the interlayer and m-phenylenediamine (MPD), and density functional theory (DFT) simulations also revealed an increase in the binding energy of the two materials. Therefore, MPD attachment and diffusion were controlled by changing the proportion of defects in the MOFs, thereby finely regulating the separation layer structure. Additionally, tannic acid (TA) was predeposited to improve the stability of the interlayer. The prepared membrane exhibited water fluxes of 33.84 and 65.81 LMH and reverse salt fluxes of 0.58 and 2.38 gMH in the active layer facing feed solution (AL-FS) and active layer facing draw solution (AL-DS) modes, respectively. Excellent lithium ion recovery and fouling resistance was also demonstrated in battery wastewater treatment.

Structurally tuned polyamide membranes via the polyvinylpyrrolidone-modulated interfacial polymerization reaction for enhanced forward osmosis performance

Controllable interfacial polymerization (IP) reaction is an important strategy to fabricate high-performance polyamide (PA) thin-film composite (TFC) membranes. In this work, a new TFC membrane was successfully fabricated by incorporating polyvinylpyrrolidone (PVP) with different molecular weights (K15, K30 and K60) at different concentrations into the aqueous phase of IP process. Due to an increased solution viscosity and interaction between PVP and amine monomers, the lower diffusion rate of amine monomers resulted into a thin (the thinnest basal PA layer of approximately 30 nm) and smooth PA layer with a high crosslinking degree. Among, the optimum PVP K60–0.25 TFC membranes with the highest molecular weights and lower incorporating concentrations had a more positive effect on forward osmosis performance, which presented a pure water flux of 11.2 L m−2 h−1, 25 % higher, and a specific salt flux of 0.04 g L−1, 43 % lower than the original membrane. Our work provides a low-cost and simple approach to obtain high-performance TFC membrane with an improved trade-off effect, and helps to deeply understand the role played by additives in PA layer modulation.

High performance Zn–Al LDH modified forward osmosis membrane with antibacterial, anti-membrane fouling, and photocatalytic degradation ability

Forward osmosis membrane has shown great potential in the fields of seawater desalination and sewage treatment. However, the concentration polarization phenomenon and membrane fouling in the water treatment process greatly reduce the water treatment performance and restrict its application. To address these challenges, we employed a pre-buried seed-in-situ growth method to facilitate the Zn–Al layered double hydroxide (Zn–Al LDH) growth on the thin nanofiber membrane, and use it as the support layer for the preparation of a Zn–Al LDH modified forward osmosis membrane. Studies have shown that the introduction of Zn–Al LDH significantly improves the water treatment efficiency of the forward osmosis membrane (In Al-DS mode, the water flux increased by 87.5 %, up to 50.50 LMH, with a low specific salt flux of 0.13 g L−1). It also exhibits exceptional antibacterial, anti-membrane fouling, and photocatalytic degradation properties. This research presents a novel approach for the development of advanced high-efficiency forward osmosis membranes.

Effects of substrate (track-etched filter) properties on the performance of forward osmosis membranes

Highly permeable membranes can improve the validity of water treatment using forward osmosis (FO) membranes. This study aims to identify the effects of substrate (track-etched (TE) filter) properties on the permeability of FO membranes. The polyamide active layer properties of three types of TE filters with similarly-sized pore diameters (0.2 μm) were observed to be equivalent regardless of the substrate porosity (13.7%–15.8 %) and substrate thickness (10–25 μm). Under the same fabrication protocol using 1.5 wt% m-phenylenediamine (MPD) solution with 0.25 wt% sodium dodecyl sulfate (SDS) addition, the increased porosity of the TE filter increased water flux. This suggested that further reduction in thickness and increase in porosity can enhance the water flux. The addition of SDS to an MPD solution was crucial in maximizing the water flux of TE filter-based FO membranes, and the other approaches (no surfactant addition or the addition of Tween80 or hexadecyltrimethylammonium bromide) produced lower water flux. The optimized fabrication protocol presented the highest water flux of 43 L/m2h and reverse salt flux of 10 g/m2h with the draw (1.0 M NaCl) and feed (pure water) solutions. This study determined the best approach for forming a highly permeable PA active layer on TE filters.

Concept and investigation of Selective Forward Osmosis (SFO) for Salt-Salt Separation as a Pretreatment of Seawater for Resource Utilization

Seawater utilization is crucial for the sustainable human development. Despite growing interest in forward osmosis (FO) due to its unique properties, conventional FO membranes with salt-water selectivity have limitations in applying to specific salt-salt separation processes, which hinders their application in resource utilization. In this work, a new concept, “selective forward osmosis (SFO)”, was proposed, which ingeniously employed an SFO membrane consisting of an ion-selective layer on a denser substrate. The denser substrate is designed to control water flux so as to alleviate the solution dilution and improve the salt-salt separation. Moreover, the sucrose and pure water were used separately as feed solution to provide different water flux to influence the various salt fluxes, showing that pure water feed could enhance the salt-salt separation efficiency, although it could dilute the draw solution to some extent. Therefore, pure water was selected as feed in the subsequent experiments. The optimized SFO membrane achieved high Na2SO4/NaCl selectivity (∼54.8) and MgCl2/NaCl selectivity (∼9.2) in single-salt draw solutions. With mixed-salt and heavy-metal-mixed-salt draw solutions, the Mg2+/Na+ selectivity was enhanced to ∼14.5, and further to 29.3. In real seawater tests, the SFO system effectively permeated monovalent elements (such as Na flux of ∼68.6 g m−2 h−1) while maintaining a higher rejection for bivalent elements (such as Mg flux of ∼0.08 g m−2 h−1), showing high selectivities for Mg/Na, U/Na, Sr/Na, Ni/Na, and Ca/Na. These results demonstrate the potential of SFO for resource utilization, especially in complex saline environments. This work contributes a new route for salt-salt separation in the pretreatment of seawater resources.

High-performance thin film composite forward osmosis membrane for efficient rejection of antimony and phenol from wastewater: Characterization, performance, and MD-DFT simulation

The effective removal of heavy metals and phenolic pollutants from aqueous solutions has received widespread attention in the field of wastewater treatment. In this work, a novel PAN/CNTs/UiO-66-NH2 modified forward osmosis (FO) membrane was prepared for efficient removal of antimony (Sb) and phenol from wastewater. The membrane was synthesized using a facile and cost-effective method. The PAN/CNTs substrate membrane was prepared using electrospinning technology, and UiO-66-NH2 MOF particles were loaded onto the surface of the active layer during the interfacial polymerization (IP) process. The presence of CNTs in the spinning solution regulated the pore structure and properties of nanofibers. Characterization of the membrane confirmed its unique structure and enhanced properties. When the CNTs addition was 0.01 g, and UiO-66-NH2 addition was 0.05 wt%, the FO membrane exhibited the optimal operational performance. In the AL-FS mode, the water flux, reverse salt flux (RSF), and Js/Jw ratio were 14.68 LMH, 0.17 gMH, and 0.01 g/L, respectively. As a comparison, the water flux, RSF, and Js/Jw ratio were 21.19 LMH, 0.65 gMH, and 0.032 g/L in the AL-DS mode, respectively. Simultaneously, efficient removal of antimony and phenol was achieved in both modes, with antimony removal efficiencies of 99.26 % and 97.98 %, and phenol removal efficiencies of 96.61 % and 93.18 %, respectively. The modified membrane exhibited excellent performance in rejecting Sb and phenol. Molecular dynamics simulations and density functional theory calculations provide theoretical support for the excellent performance of membranes. The membrane demonstrated a high water flux, making it promising for practical applications. Additionally, it exhibited remarkably low reverse salt flux, highlighting its suitability for desalination processes. The exceptional removal efficiency of Sb and phenol, coupled with the membrane's impressive hydraulic performance, makes it a promising candidate for the treatment of industrial effluents containing these challenging contaminants. The results presented in this study underscore the potential of PAN/CNTs/UiO-66-NH2 FO membranes as an advanced solution for addressing water pollution challenges.

Arctic Thin Ice Detection Using AMSR2 and FY-3C MWRI Radiometer Data

Thin ice with a thickness of less than half a meter produces strong salt and heat fluxes which affect deep water circulation and weather in the polar oceans. The identification of thin ice areas is essential for ship navigation. We have developed thin ice detection algorithms for the AMSR2 and FY-3C MWRI radiometer data over the Arctic Ocean. Thin ice (<20 cm) is detected based on the classification of the H-polarization 89–36-GHz gradient ratio (GR8936H) and the 36-GHz polarization ratio (PR36) signatures with a linear discriminant analysis (LDA) and thick ice restoration with GR3610H. The brightness temperature (TB) data are corrected for the atmospheric effects following an EUMETSAT OSI SAF correction method in sea ice concentration retrieval algorithms. The thin ice detection algorithms were trained and validated using MODIS ice thickness charts covering the Barents and Kara Seas. Thin ice detection is applied to swath TB datasets and the swath charts are compiled into a daily thin ice chart using 10 km pixel size for AMSR2 and 20 km for MWRI. On average, the likelihood of misclassifying thick ice as thin in the ATIDA2 daily charts is 7.0% and 42% for reverse misclassification. For the MWRI chart, these accuracy figures are 4% and 53%. A comparison of the MWRI chart to the AMSR2 chart showed a very high match (98%) for the thick ice class with SIC > 90% but only a 53% match for the thin ice class. These accuracy disagreements are due to the much coarser resolution of MWRI, which gives larger spatial averaging of TB signatures, and thus, less detection of thin ice. The comparison of the AMSR2 and MWRI charts with the SMOS sea ice thickness chart showed a rough match in the thin ice versus thick ice classification. The AMSR2 and MWRI daily thin ice charts aim to complement SAR data for various sea ice classification tasks.

Resilient forward osmosis membranes against microplastics fouling enhanced by MWCNTs/UiO-66-NH2 hybrid nanoparticles

The escalating presence of microplastics (MPs) in wastewater necessitates the investigation of effective tertiary treatment process. Forward osmosis (FO) emerges as an effective non-pressurized membrane process, however, for the effective implementation of FO systems, the development of fouling-resistance FO membranes with high-performance is essential. This study focuses on the integration of MWCNT/UiO-66-NH2 as metal-organic frameworks (MOFs) and multi-wall carbon nanotubes (MWCNT) nanocomposites in thin film composite (TFC) FO membranes, harnessing the synergistic power of hybrid nanoparticles in FO membranes. The results showed that the addition of MWCNT/UiO-66-NH2 in the aqueous phase during polyamide formation changed the polyamide surface structure, and enhanced membranes’ hydrophilicity by 44%. The water flux of the modified FO membrane incorporated with 0.1 wt% MWCNTs/UiO-66-NH2 increased by 67% and the reverse salt flux decreased by 22% as in comparison with the control membrane. Moreover, the modified membrane showed improved antifouling behavior against both organic foulant and MPs. The MWCNT/UiO-66-NH2 membrane experienced 35% flux decline while the control membrane experienced 65% flux decline. This proves that the integration of MWCNT/UiO-66-NH2 nanoparticles into TFC FO membranes is a viable approach in creating advanced FO membranes with high antifouling propensity with potential to be expanded further to other membrane applications.

Harnessing overlapped temperature-salinity gradient in solar-driven interfacial seawater evaporation for efficient steam and electricity generation

Solar-driven interfacial water evaporation (SIWE) offers a superb way to leverage concentrated solar heat to minimize energy dissipation during seawater desalination. It also engenders overlapped temperature-salinity gradient (TSG) between water-air interface and adjacent seawater, affording opportunities of harnessing electricity. However, the efficiency of conventional SIWE technologies is limited by significant challenges, including salt passivation to hinder evaporation and difficulties in exploiting overlapped TSG simultaneously. Herein, we report self-sustaining hybrid SIWE for not only sustainable seawater desalination but also efficient electricity generation from TSG. It enables spontaneous circulation of salt flux upon seawater evaporation, inducing a self-cleaning evaporative interface without salt passivation for stable steam generation. Meanwhile, this design enables spatial separation and simultaneous utilization of overlapped TSG to enhance electricity generation. These benefits render a remarkable efficiency of 90.8% in solar energy utilization, manifesting in co-generation of solar steam at a fast rate of 2.01 kg m−2 h−1 and electricity power of 1.91 W m−2 with high voltage. Directly interfacing the hybrid SIWE with seawater electrolyzer constructs a system for water-electricity-hydrogen co-generation without external electricity supply. It produces hydrogen at a rapid rate of 1.29 L h−1 m−2 and freshwater with 22 times lower Na+ concentration than the World Health Organization (WHO) threshold.

Brain-inspired computing with fluidic iontronic nanochannels

The brain's remarkable and efficient information processing capability is driving research into brain-inspired (neuromorphic) computing paradigms. Artificial aqueous ion channels are emerging as an exciting platform for neuromorphic computing, representing a departure from conventional solid-state devices by directly mimicking the brain's fluidic ion transport. Supported by a quantitative theoretical model, we present easy-to-fabricate tapered microchannels that embed a conducting network of fluidic nanochannels between a colloidal structure. Due to transient salt concentration polarization, our devices are volatile memristors (memory resistors) that are remarkably stable. The voltage-driven net salt flux and accumulation, that underpin the concentration polarization, surprisingly combine into a diffusionlike quadratic dependence of the memory retention time on the channel length, allowing channel design for a specific timescale. We implement our device as a synaptic element for neuromorphic reservoir computing. Individual channels distinguish various time series, that together represent (handwritten) numbers, for subsequent in silico classification with a simple readout function. Our results represent a significant step toward realizing the promise of fluidic ion channels as a platform to emulate the rich aqueous dynamics of the brain.

Transformation of internal solitary waves at the edge of ice cover

Abstract. Internal wave-driven mixing is an important factor in the balance of heat and salt fluxes in the polar regions of the ocean. Transformation of internal waves at the edge of the ice cover can enhance the mixing and melting of ice in the Arctic Ocean and Antarctica. In the polar oceans, internal solitary waves (ISWs) are generated by various sources, including tidal currents over bottom topography, the interaction of ice keels with tides, time-varying winds, vortices, and lee waves. In this study, a numerical investigation of the transformation of ISWs propagating from open water in the stratified sea under the edge of the ice cover is carried out to compare the depression ISW transformation and loss of energy on smooth ice surfaces, including those on the ice shelf and glacier outlets, with the processes beneath the ridged underside of the ice. They were carried out using a non-hydrostatic model that is based on the Reynolds-averaged Navier–Stokes equations in the Boussinesq approximation for a continuously stratified fluid. The Smagorinsky turbulence model extended for stratified fluid was used to describe the small-scale turbulent mixing explicitly. Two series of numerical experiments were carried out in an idealized 2D setup. The first series aimed to study the processes of the ISWs of depression transformation under an ice cover of constant submerged ice thickness. Energy loss was estimated based on a budget of depth-integrated pseudoenergy before and after the wave transformation. The transformation of ISWs of depressions is controlled by the blocking parameter β, which is the ratio of the minimum thickness of the upper layer under the ice cover to the incident wave amplitude. The energy loss was relatively small for large positive and large negative values of β. The maximal value of energy loss was about 38 %, and it was reached at β≈0 for ISWs. In the second series of experiments, a number of keels were located on the underside of the constant-thickness ice layer. The ISW transformation under ridged ice also depends on the blocking parameter β. For large keels (β<0), more than 40 % of energy is lost on the first keel, while for relatively small keels (β>0.3), the losses on the first keel are less than 6 %. Energy losses due to all keels depend on the distance between them, which is characterized by the parameter μ, i.e. the ratio of keel depth to the distance between keels. In turn, for a finite length of the ice layer, the distance between keels depends on the keel quantity.

Defect-Healed Carbon Nanomembranes for Enhanced Salt Separation: Scalable Synthesis and Performance.

Carbon nanomembranes (CNMs), with a high density of subnanometer channels, enable superior salt separation performance compared to conventional membranes. However, defects that occur during the synthesis and transfer processes impede their technical realization on a macroscopic scale. Here, we introduce a practical and scalable interfacial polymerization method to effectively heal defects while preserving the subnanometer pores within CNMs. The defect-healed freestanding CNMs show an exceptional performance in forward osmosis (FO), achieving a water flux of 105 L m-2 h-1 and a specific reverse salt flux of 0.1 g L-1 when measured with 1 M NaCl as draw solution. This water flux is 10 times higher than that of commercially available FO membranes, and the reverse salt flux is 70% lower. Through successful implementation of the defect-healing method and support optimization, we demonstrate the synthesis of fully functional, centimeter-scale CNM-based composite membranes showing high water permeance and a high salt rejection. Our defect-healing method presents a promising pathway to overcome limitations in CNM synthesis, advancing their potential for practical salt separation applications.

Diffusive-convection staircases in the polar oceans: the interplay between double diffusion and turbulence

Numerical simulations have been conducted to examine the structure of diffusive-convection staircases in the presence of vortical-mode-induced turbulent forcing. By modulating the input power $P$ and the background density ratio $R_\rho$ , we have identified three distinct types of staircase structures in these simulations: namely staircases maintained in the system driven by double-diffusion, by turbulence or by a combination of both double-diffusion and turbulence. While we showed that staircases maintained in the double-diffusion-dominated system are accurately characterised by the existing model originally proposed by Linden & Shirtcliffe (J. Fluid Mech., vol. 87, no. 3, 1978, pp. 417–432), we introduced new physical models to describe the staircase structures maintained in the turbulence-dominated system and the system driven by both turbulence and double-diffusion. Our integrated model reveals that turbulence fundamentally governs the entire life cycle of the diffusive-convection staircases, encompassing their formation, maintenance and eventual disruption in the Arctic Ocean's thermohaline staircases. While our previous work of Ma & Peltier (J. Fluid Mech., vol. 931, 2022b) demonstrated that turbulence could initiate the formation of Arctic staircases, these staircases are sustained by both turbulence and double-diffusion acting together after formation has occurred. Strong turbulence may disrupt staircase structures; however, the presence of weak turbulence could lead to unstable stratification within mixed layers of the staircases, as well as enhancing vertical heat and salt fluxes. Turbulence can even sustain a stable staircase structure factor when $R_\rho$ is relatively large, following a similar mechanism to the density staircases observed in laboratory experiments. Consequently, previous parameterisations (e.g. Kelley, J. Geophys. Res.: Oceans, vol. 95, no. C3, 1990, pp. 3365–3371) on the vertical heat flux across the diffusive-convection staircases may provide a significant underestimation of the heat transport by ignoring the influences of turbulence.

Circulation and Stratification Changes in a Hypersaline Estuary Due to Mean Sea Level Rise

Hypersaline Hamelin Pool, with mean salinity >65, is located in Shark Bay, Western Australia. The high salinity has reduced its biodiversity, but it is home to a diverse assemblage of modern marine stromatolites. The limited exchange of water between Hamelin Pool and the rest of Shark Bay, due to the presence of the shallow Faure Sill together with high evaporation and low rainfall-runoff have resulted in a hypersaline environment. With climate-change-induced mean sea level rise (MSLR), hydrodynamic processes that maintain the hypersaline environment may be affected and are the focus of this paper. Oceanographic observations, together with hydrodynamic model results, were used to examine the hydrodynamic processes under present and future MSLR scenarios. A large attenuation in the tidal range, changes in the tidal characteristics, and current speeds together with a strong salinity gradient were observed across the Faure Sill under present-day conditions. Under an MSLR scenario of 1 m, the tidal amplitude decreased by up to 10% to the north, whilst to the south, the tidal range increased by up to 15%. Regions of strong vertical stratification were present on both sides of the Faure Sill. The simulations indicated that, under MSLR scenarios, these regions expanded in area and exhibited higher levels of vertical stratification. The salt flux across the Faure Sill was maintained as a diffusive process under MSLR scenarios.

Productivity, selectivity, and energy consumption of pilot-scale vacuum assisted air-gap membrane distillation for the desalination of high-salinity streams

The implementation of air gap membrane distillation systems is limited by a lack of overall performance predictions which rely on few available pilot-scale studies. This study evaluates the productivity, energy consumption, and selectivity of a pilot-scale air gap membrane distillation system by combining experiments and modeling activities. The effect of operating conditions, i.e., applied vacuum, feed flow rate, and feed stream salinity, was investigated to identify regulating factors and quantify dependencies. Response surface methodology was applied to model the phenomena and provide statistical analysis. Increasing flow rates produced a near linear increase of productivity within the investigated range. Operating at higher applied vacuum also translated into enhanced productivity, though the distillate flux increased by a maximum of 10 % when vacuum increased from −100 mbar to −500 mbar. Flow rate and vacuum also governed the observed salt flux by a similar magnitude because salt flux resulted mainly from liquid pore flow phenomena. The trans-membrane pressure regulated the membrane rejection: increasing the pressure difference led to a lower rejection. Moreover, high feed stream salinity lowered both the productivity and the distillate quality. The productivity gains were typically achieved at the expense of an increase in specific thermal energy consumption; however, an interesting relation was observed with feed stream salinity, with a minimum of specific thermal energy consumption of roughly 300kWhth⋅m−3 identified in the treatment of a stream with a salinity of 150g/L.

Holistic approach for fabrication of superhydrophobic MXene-based membrane for enhanced membrane distillation

There is growing interest in membrane distillation (MD) as a means of desalinating seawater with 100 % theoretical salt rejection which has the capacity to address freshwater scarcity. MD has huge potential for commercial applications owing to its low operating temperature and pressure requirements. However, wetting polymeric membranes inhibits water permeance and lowers salt rejection. MXene nanosheet-incorporated polyvinylidene (PVDF) membranes have been constructed for enhanced vapor transport with high water repellence and antiwetting properties. MXene nanosheets in PVDF polymeric matrices are responsible for their high super-hydrophobicity, which can mitigate membrane fouling and wetting during the MD process. As far as experimental outcomes are concerned, the pristine PVDF membrane exhibited severe wetting with salt leakage. Ti3C2Tx MXene nanosheets allow the formation of hierarchical polymeric micro/nanostructures, changing the intrinsic hydrophilicity to super-hydrophobicity. Surface engineering of a PVDF membrane with MXene nanosheets enables efficient saline desalination during the MD process. The surface-engineered MXene/PVDF membrane demonstrated a high-water contact angle of 143° with extremely high self-cleaning characteristics as compared to that of pristine PVDF membrane. As far as the performance of the membrane is concerned, the water flux of the pristine PVDF membrane decreased from 6.5 LMH to 6 LMH after the 14th hour which can be attributed to partial pores wetting during MD operation. Eventually, the pristine PVDF membrane exhibited a continuous salt flux (SF) increase. However, MXene/PVDF membrane showed stable water flux (8 LMH) and negligible SF. The study therefore demonstrates a facile and holistic approach for constructing MXene-based PVDF membranes that exhibit superior antiwetting performance during MD operation.

A feasibility study of hybrid forward osmosis-solar evaporation process using melamine sponge loaded with polypyrrole (PPy@MS) solar evaporator for desalination of brackish water

The application of the osmotic pressure-driven forward osmosis (FO) process is limited due to the high costs for regeneration and replacement of draw solution. A hybrid FO-solar evaporation (SE) hybrid process was systematically investigated to produce fresh water from desalination of brackish water. The melamine sponge loaded with polypyrrole (PPy@MS) composite material was synthesized by loading light-absorbing polypyrrole (PPy) into a network of melamine sponge (MS) substrates. As a solar evaporator, PPy@MS material showed high light absorption, water evaporation, and anti-pollution abilities in the FO-SE process. Feasibility for operating the hybrid desalination process was studied in terms of solar evaporation rate, salinity tolerance, hydrophilicity, and mechanical strength of PPy@MS, and desalination performance, including water flux, ion removal, reverse salt flux, and membrane fouling. Characterization results indicated that PPy@MS performed a high interfacial molecular transformation, solar energy accessing ability, salt-tolerance, and mechanical stability in a long-term FO-SE operation, achieving an evaporation rate up to 2.80 kg·m−2·h−1 (1 sun, 1 h) and ion removal rate of 99.9 %. A maximum evaporation flux of 17.4 L·m−2·h−1 was monitored in the FO-SE process using 2 M NaCl as the draw solution (FO film area: 5 cm2). Solar-driven evaporation via PPy@MS was able to assist the continuous operation of the FO-SE process with high water flux. This work proposes a novel sustainable hybrid FO-SE technology for FO desalination of brackish water and other saline water bodies.

Mixed matrix membranes based on morpholinium-functionalized CardoPES and MgAl-LDH: Structures, properties and electrodialysis performance

A simple, inexpensive, and effective method based on the MMMs prepared from morpholinium-functionalized CardoPES and MgAl-LDHs is proposed to improve the ED capabilities of AEMs. The microphase separation and ED performance of mixed matrix AEMs were substantially enhanced by LDH introduction, which was attributed to the surface OH groups of the LDH nanosheets; these interactions induced polymer chain self-assembly. The AEM with 8 % LDH exhibited the highest salt flux (92.5 mg/m2·s) during ED, which was 19.6 % and 14.1 % greater than those of the commercial Type 10 membrane and the mixed matrix AEM, respectively. Hydrogen bonding interactions and the ED capabilities of the AEMs were readily regulated by adjusting the feed ratios of the LDH and morpholinium groups. With increasing LDH content, the Rm and ED performance increased, while the hydrophilicity and mechanical properties initially decreased. When the OH content of an LDH nanosheet was higher than the morpholinium content, as the LDH content increased, the Rm and ED performance decreased, while the hydrophilicity and mechanical properties increased, which may be attributed to internal structural discrepancies between the complete and incomplete core-shell structures of the AEMs caused by different hydrogen bonding patterns.