The durability of concrete materials in harsh environmental conditions, particularly in cold regions, has garnered significant attention in civil engineering research in recent years. Concrete structures in these areas are often damaged by the combined effects of alkali-silica reaction (ASR) and freeze-thaw cycles, leading to structural cracks and significant safety hazards. Numerous studies have demonstrated that polypropylene fiber concrete exhibits excellent crack resistance and durability, making it promising for applications in cold regions. This study elucidates the impact of alkali content on concrete durability by comparing the mechanical properties and durability of different alkali-aggregate concretes. The principal experimental methodologies employed include freeze-thaw cycle experiments, which examine patterns of mass loss; fluctuations in the dynamic modulus of elasticity; and changes in mechanical properties before and after freeze cycles. The findings indicate that increased alkali content in concrete reduces its strength and durability. At 100% alkali-aggregate content, compressive strength decreases by 35.5%, flexural strength by 32.9%, mass loss increases by 35.85%, relative dynamic elastic modulus by 39.4%, and residual strength by 97.28%, indicating higher alkali content leads to diminished durability. Additionally, this paper introduces a constitutive damage model, validated by a strong correlation with experimental stress-strain curves, to effectively depict the stress-strain relationship of concrete under varying alkali contents. This research contributes to a broader understanding of concrete durability in cold climates and guides the selection of materials for sustainable construction in such environments.