S-type Granites Research Articles

Petrological insights into connections between the S- and I-type magmatic associations in metamorphic core complexes: a case study of the Çataldağ metamorphic core complex (NW Turkey)

As one of the Cordilleran-type metamorphic core complexes in the western Anatolian extensional province and the broader Aegean region, the Çataldağ metamorphic core complex is composed of a granite-gneiss-migmatite complex and a synkinematic pluton, bounded by a detachment fault zone. The plutonic rocks within the footwall of the Çataldağ metamorphic core complex consist of Eo-Oligocene anatectic S-type leucogranites associated with gneiss-migmatite complex forming the core rocks and an I-type synkinematic pluton that emplaced into the core rocks in the Early Miocene. This paper presents the petrography, mineral chemistry, major-trace element geochemistry, and Sr-Nd-Pb isotope compositions of the Çataldağ I-type synkinematic pluton. It discusses the magma source evolution from the Eo-Oligocene to the Early Miocene and their relations to the Çataldağ metamorphic core complex formation by comparing two contrasting granitic associations from a petrological perspective. The Çataldağ I-type synkinematic pluton primarily comprises porphyritic granodiorite, granite, and peripheral rocks including evolved granite and pegmatite dikes. Thermobarometry calculations estimate crystallisation conditions of approximately 795 °C at 1–2 kbar (averaging 1.5 kbar), corresponding to a shallow crustal magma chamber (⁓5 km deep). The pluton is metaluminous to slightly peraluminous and of a high-K calc-alkaline character. The 87Sr/86Sr(i) and εNd values of the studied samples range from 0.70684 to 0.70772 and from −6.1 to −2.3, respectively. Pb isotopic compositions are 18.74–19.29 for 206Pb/204Pb, 15.69–15.78 for 207Pb/204Pb, and 38.89–39.39 for 208Pb/204Pb. Geochemical modelling shows that a large amount of metasomatised lithospheric mantle-derived melt component (up to 70%) and a minor crustal component (<50%) contributed to the source region of the magma. The combination of isotopic data and thermodynamic modelling suggests that the compositional variations within the pluton were primarily the result of open system processes, predominantly the assimilation of crustal rocks with a dominance of fractional crystallisation. The Sr-Nd-Pb isotopic signatures and trace element characteristics of I-type pluton, as well as their comparisons with those of S-type leucogranites within the Çataldağ core complex, indicate heterogeneous magma sources, evolving from crust-dominated to mantle-dominated magma from Eo-Oligocene to the early Miocene, reflecting mantle upwelling beneath NW Anatolia. We infer that the long-lived, mantle-driven Eocene plutonic activity that preceded the development of core complexes may have led to thermal weakening, melting, and crustal flow in the lower-middle crust beneath NW Anatolia, facilitating the formation of the granite-gneiss-migmatite complex during the incipient phase of extension in the Eo-Oligocene. Coinciding with the rapid exhumation of the S-type granite and migmatite complex, the formation and emplacement of I-type synkinematic pluton along the detachment fault zone of the Çataldağ core complex were developed as a result of asthenospheric upwelling driven by lithospheric removal processes. This inferred lithospheric removal was triggered by Hellenic slab rollback affecting the entire western Anatolia since the Oligocene. The transition from S- to I-type granites observed in the Çataldağ core complex and other Aegean massifs may indeed be a manifestation of the intensity or accumulation of this crustal extension.

O–Hf isotope ratios of Alvand S-type granite, western Iran, reveal crustal melting in an extensional regime

There are a few intrusive bodies in the central Sanandaj-Sirjan Zone (C-SaSZ), which is parallel to the Zagros suture zone, in western Iran. The Alvand batholith in the Hamedan area is one of these bodies and consists of rock types with large variation, in particular, two-mica garnet-bearing granite with an S-type signature. Zircon UPb dating gives crystallization ages of 170–163 Ma for the S-type granite. The 176Hf/177Hf ratios in the zircon grains vary from 0.282001 to 0.282780 (rim), with low 176Lu/177Hf ratios (0.002 to 0.018). The εHf(t) values (rim) are clustered into two main groups: a negative εHf(t) group (−6.9 to 0.0, n = 39), with some highly negative εHf(t) values (−25.8 to −21.9, n = 3), and slightly positive εHf(t) values (+0.3 to +2.9, n = 14) of inherited grains. The δ18O values for the zircon grains are positive and range from +10.4‰ to +11.8‰. The high δ18O (positive) and mostly negative εHf(t) values are more consistent with continental crustal sources for these rocks, and the Hf model ages (TDM2) show a wide range from 2.7 to 0.8 Ga, suggesting the heterogeneity of the crustal components. The long incubation time (2089 to 544 Ma) indicates a long history of crustal residence and crustal reworking. The incubation age of the zircon grains, >300 Ma, confirms the recycling of crustal material by partial melting. The simultaneous occurrence of S-type granites with mafic bodies, such as gabbro and diorite members with tholeiitic signatures, suggests that the injection of mafic magma increased the geothermal gradient from the bottom and sides along the major faults, which was the trajectory for the injection of hot mafic melts to shallow depths. These processes abnormally increased the geothermal gradients locally, and the partial melting of crustal and supracrustal materials produced S-type granites and migmatization among the hot blade-shaped mafic bodies. Therefore, the partial melting of crustal material in an extensional tectonic regime and/or in a thin continental crust occurred in a continental rift and/or in the Neo-Tethys passive margin. The present work concludes that the passive margin can be suggested as the tectonic setting for the generation of S-type granites, without the collisional regime that has been widely considered for the sources of this type of granite in the world.

Extreme Sn isotope fractionation in highly evolved granites

Stable Sn isotopes have been widely used to trace the planetary differentiation processes, the provenance and trade paths of ancient bronze artifacts, the mineralization history of tin ore deposits, and the terrestrial magmatic processes. However, systematic Sn isotope studies of felsic igneous rocks especially the Sn mineralization-related highly evolved granites are still lacking. In this study, we present the first high-precision Sn isotope data of two Sn-rich highly evolved S-type granites (Laochang and Kafang) from the world-class Gejiu Sn ore district. These granite samples show remarkably variable δ122/118Sn values (relative to the Sn standard solution NIST 3161a) ranging from 0.11 ± 0.02‰ to 0.93 ± 0.02‰ (2σ), which is the largest variation range reported in granites so far. The absence of correlations between Sn isotopes and LOI (loss-on-ignition) and εNd(t) values, along with the low magmatic oxygen fugacity (△FMQ < 0) for these granites, rule out hydrothermal alteration, wall-rock assimilation, source composition heterogeneity, and anatexis processes as causes of the Sn isotope fractionation. The Laochang granites show negative correlations between δ122/118Sn values and magmatic differentiation indicators (e.g., CaO, Fe2O3, Ti, Eu/Eu*, F/Cl), suggesting fractional crystallization increased the δ122/118Sn isotopes in the residual melts. The fractional crystallized minerals are mainly composed of biotite, plagioclase, and minor ilmenite. Compared with the Laochang granites, the Kafang granites show higher SiO2 contents, F/Cl ratios, and δ122/118Sn values, suggesting the magma at this stage was fluid-saturated and fluid exsolution coupled with fractional crystallization would further enrich the heavy Sn isotopes in the residual melts. We further quantified the contributions of crystal fractionation and fluid exsolution on Sn isotopic variability using a Rayleigh fractionation model. The modeling indicates that △122/118Sncrystal-melt = −0.6 to −0.5‰ and △122/118Snfluid-melt = −1.9 to −0.7‰ with an initial H2O content of 2 wt.% can explain the observed δ122/118Sn values of Gejiu granites. This study implies that both crystal fractionation and fluid exsolution processes cause increase of Sn isotopic values in the highly evolved granites and Sn isotopes are useful for tracing the evolution of highly differentiated igneous rocks.

Geochemical Evidence for Genesis of Nb–Ta–Be Rare Metal Mineralization in Highly Fractionated Leucogranites at the Lalong Dome, Tethyan Himalaya, China

Leucogranites in the Lalong Dome are composed of two-mica granite, muscovite granite, albite granite, and pegmatite from core to rim. Albite granite-type Be–Nb–Ta rare metal ore bodies are hosted by albite granite and pegmatite. Based on field and petrographic observations and whole-rock geochemical data, highly differentiated leucogranites have been identified in the Lalong Dome. Two-mica granites, albite granites, and pegmatites yielded monazite ages of 23.6 Ma, 21.9 Ma, and 20.6 Ma, respectively. The timing of rare metal mineralization is 20.9 Ma using U–Pb columbite dating. Leucogranites have the following characteristics: high SiO2 content (&gt;73 wt.%); peraluminosity with high Al2O3 content (13.6–15.2 wt.%) and A/CNK (mostly &gt; 1.1); low TiO2, CaO, and MgO content; enrichment of Rb, Th, and U; depletion of Ba, Nb, Zr, Sr, and Ti; strong negative Eu anomalies; low εNd(t) values ranging from −12.7 to −9.77. These features show that the leucogranites are crust-derived high-potassium calc-alkaline and peraluminous S-type granites derived from muscovite dehydration melting under the water-absent condition, which possibly resulted from structural decompression responding to the activity of the South Tibetan detachment system (STDS). Geochemical data imply a continuous magma fractional crystallization process from two-mica granites through muscovite granites to albite granites and pegmatites. The differentiation index (Di) gradually strengthens from two-mica granite, muscovite granite, and albite granite to pegmatite, in which albite granite and pegmatite are highest (Di = 94). The Nb/Ta and Zr/Hf ratios of albite granite and pegmatite were less than 5 and 18, respectively, which suggests that albite granite and pegmatite belong to rare metal granites and have excellent potential for rare metal mineralization.

Late Cryogenian Circum-Rodinia Syn-Subduction Extension: Insights from Highly Fractionated S-Type and A-Type Granitoids in the Northern Tarim Craton

Late Cryogenian–Ediacaran magmatism represents the latest Precambrian tectonothermal event in the Tarim Craton. However, its geodynamic setting and geological significance are controversial. Here, we report the geochronology, whole-rock geochemistry, and Sr-Nd-Hf isotopic compositions of newly identified late Cryogenian A-type and highly fractionated S-type granites from two locations in the northern Tarim Craton. LA-ICP-MS zircon U-Pb analyses yield ages of 642 ± 7 Ma for a syenogranite and 643 ± 4.5 Ma for a mylonitized granite. The syenogranite is weakly peraluminous and shows an A-type granite affinity, as indicated by its high K2O + Na2O contents (8.35–8.64 wt.%), high field strength elements (Zr + Nb + Ce + Y = 435.8 − 463.4 × 10−6), Ga/Al ratios (2.79−2.83), and zircon saturation temperatures (829–844 °C). In contrast, the mylonitized granite contains Al-oversaturated minerals (e.g., garnet) and has high a differentiation index (DI = of 98.9–99.4), with lower zircon saturation temperatures (786–792 °C); the samples display high SiO2 contents (72.99–74.00 wt.%) and A/CNK values (1.16–1.17) and low Nb/Ta and Zr/Hf ratios and are enriched in Rb and depleted in Ba, Sr, which all point to a highly fractionated S-type granite affinity. The granites are characterized by elevated large-ion lithosphere elements (LILEs) and flat high-field-strength elements (HFSEs) patterns, with deep Nb and Ta troughs and pronounced negative Eu anomalies (Eu/Eu* = 0.17–0.38). They show apparently negative εNd(t) values (−10.1 to −9.8 and −6.8 to −7.9, respectively) and εHf(t) values (−9.66 to −1.77 and −33.5 to −1.3, respectively) with Paleoproterozoic crustal model ages, indicating that they were mainly generated by the partial melting of mature crustal materials with a minor contribution from a mantle-derived magmatic source. By integrating with previously published geological, sedimentological, and structural data, we suggest that the granites formed due to a high-temperature gradient in a syn-subduction extensional setting that was probably induced by northward slab rollback of the Paleo-Asian Oceanic lithosphere. Our new data highlight an upper-plate extension in the northern Tarim Craton that constitutes the northern periphery of the Rodinia supercontinent. The linear distribution of late Cryogenian magmatic rocks provides critical evidence for the orogen strike extension of the terminal suture between the Tarim Craton and southwestern Altaids.

Nature of early Mesoproterozoic magmatism in the Qilian-North Qaidam tectonic belt, NW China: Implications for prolonged extension processes and transition from Columbia to Rodinia

Precambrian basement rocks exposed in uplift zones and orogenic belts provide accessible opportunities for paleogeographic reconstruction, especially for microcontinents and cratons with thick covers. Here we report early Mesoproterozoic rifting-related mafic and granitic metaigneous rocks preserved in the Qilian-North Qaidam tectonic belt, NE Tibetan Plateau. Mafic rocks include garnet amphibolite emplaced at 1.40 Ga and metagabbro that were emplaced at 1.39 Ga, exposed in the North Wulan area. They are derived from low-degree (<7 %) partial melting of slab-modified lithospheric mantle lherzolites with Sp:Grt ranging from 90:10 to 60:40. The calculated low P-T conditions of mantle melting (Tpmax < 1472–1451 °C at P = 2.0 Ga) are also consistent with a thermal normal lithospheric mantle upwelling event. Granitic rocks comprise ca. 1.44 Ga garnet-bearing and ca. 1.41 Ga two-mica granites that were emplaced in the North Wulan and Central Qilian areas, respectively. They are S-type granites derived from crustal reworking of psammitic-rich and/or clay-rich metasedimentary rocks. In addition, the two-mica granites represent the oldest basement rocks yet identified in Central Qilian and indicate the existence of ancient basement rocks older than ca. 1.41 Ga. All the mafic and granitic rocks belong to a part of intense Mesoproterozoic rift-related magmatism in the composite Qilian-Quanji block (QQB), and subsequently underwent 1.18–0.9 Ga metamorphic modifications. The composite QQB in the NE Tibetan Plateau was involved in the long-term processes including crustal reworking and mantle upwelling (1.5–1.35 Ga) correspond to the breakup of Columbia followed by oceanic subduction (1.2–1.0 Ga) and subsequent collision and exhumation (0.9–0.8 Ga) at the periphery of Rodinia. Our results improve the understanding of the Mesoproterozoic tectonic evolution for the whole QQB and provide important constrains on the transition from Columbia to Rodinia.

Chemistry and boron isotope composition of tourmaline as a robust tool to characterize the origin of porphyry molybdenum systems: The case of Donggebi deposit in East Tianshan, China

Tourmaline is a chemically and mechanically stable mineral that commonly occurs in hydrothermal mineral systems, and has been used to trace the mineralization processes of many genetic types of ore deposits. Here we apply tourmaline chemistry and isotopic composition to trace the genesis of a porphyry Mo system for the first time. Tourmaline is widespread in the Donggebi Mo deposit in East Tianshan, NW China, where it occurs in five distinct associations: type PG disseminated in the porphyritic granite, TS as hydrothermal tourmalite in the country rocks (strata), V1 in quartz-molybdenite vein, V2 in quartz-polymetallic sulfide vein, and V3 quartz-calcite-fluorite vein. All the tourmaline types belong to the alkali group, with the V3 being schorl and the other types being dravite and schorl. The PG-type tourmalines partly inherit the features of the porphyritic granite, and are rich in F, Na, Al and Sc, and poor in Fe, Mg, Ca, Sr, Ba, Pb, V and Mo compared to the other types. They have low Fe3+ concentrations and low Fe3+/(Fe3++Fe2+) ratios, suggesting a reducing fluid system. They also display weaker Eu-depletion (with an average (Eu/Eu*)N value of 0.96) than the porphyritic granite, and are considered to be the products of interaction of the reducing fluids and the granites. The average (Eu/Eu*)N values of tourmalines decrease from 6.66 of type V1, 5.65 of type V2, to 4.80 of type V3, indicating that the fluids became progressively less reducing along with sulfide precipitation. The δ11B values of the tourmalines range between −15.9 ‰ and −12.5 ‰, resembling those of S-type granites or clastic sediment-sourced hydrothermal fluids. The tourmaline grains in our study do not display any remarkable δ11B variation from the cores to rims, indicating that the δ11B values of the fluids and their source were relatively constant.

Boron isotope constraints on the migration and accumulation of rare alkali metals in the geyserite cesium deposits in Southern Tibet

Geothermal waters in the Shiquanhe-Yarlun Zangbo geothermal field of southern Tibet are highly enriched in rare alkali metals (RAMs), which form a globally unique geyserite Cs-deposit. Boron isotopes, together with the geochemistry of a local leucogranite, geothermal springs and geyserite were investigated to constrain the migration and accumulation of RAMs in the geyserite cesium deposit. The δ11B values of −9.7‰ to −8.4‰ in tourmalines from the Himalayan leucogranite have shown typical S-type granites. A mass balance calculation indicates that the magma of the S-type granite contained < 10 % dehydrated fluid, which resulted in an enrichment of RAMs by 4–5 times during the partial melting of crustal materials, compared to that in the UCC. The linear relationships of ΣRAMs vs. B and Na + K vs. soluble Si, indicate that further enrichment of RAMs in the geothermal fluids was promoted by intense water–rock interaction at temperatures of 210 to 250 °C in the geothermal system reservoir. A strong adsorption process controlled the hyper enrichment of RAMs (especially Cs) during silica precipitation from the upwelling geothermal water, with the sharp decreases in temperature and pressure leading to the enrichment of Cs in fresh geyserites. Despite loss of RAMs during dehydration of the geyserite during phase transformation from opal-A, opal-CT, and chalcedony to quartz, freshly deposited geyserites have great potential for exploration of RAMs resources in this area.

Geochronology and geochemistry of early Paleozoic magmatism in the Qilian orogen: Constraints on closure of the Proto-Tethys Ocean

The Proto-Tethys Ocean was a Neoproterozoic to early Paleozoic ocean that opened upon the breakup of Rodinia and closed by Paleozoic oceanic and continental subduction. The Qilian orogenic belt is the northernmost orogen of the Proto-Tethys domain and consists of the North Qilian belt, the Central Qilian block and the South Qilian belt. The processes responsible for extensive early Paleozoic magmatism in the Qilian orogen are crucial to understanding the closure of the ocean. This paper presents a systematic investigation of early Paleozoic mafic and felsic rocks in the Qilian orogen. Gabbroic dikes from the Central Qilian block have LA-ICP-MS zircon U-Pb ages of 499–497 Ma with a wide range of εHf(t) values of −9.94 to + 4.28 and TDM1 model ages of 1557–929 Ma, and dioritic dikes have a LA-ICP-MS zircon U-Pb age of 489 ± 3 Ma, positive εHf(t) values of +7.61 to +10.53, TDM1 model ages of 684–790 Ma, and an amphibole 40Ar/39Ar age of 486.3 ± 4.3 Ma. Both sets of dikes were derived from partial melting of a heterogeneous spinel-facies lherzolite lithospheric mantle that was modified by fluids and melts from a subducted slab. The protolith of amphibolites from the Hualong block in the South Qilian belt was a mafic intrusion of 454 ± 2 Ma with negative εHf(t) values of −9.69 to −7.79 and TDM1 model ages of 1390–1478 Ma. Its trace element signature indicates that sediment-derived melts were involved in the magma formation. An amphibole 40Ar/39Ar age of 418.7 ± 3.8 Ma from an amphibolite records the timing of amphibolite facies metamorphism. Felsic volcanic tuffs and granitic intrusions from the Central Qilian block have zircon U-Pb ages of 507–440 Ma with a broad range of zircon εHf(t) values of −9.60 to + 11.87 and TDM2 model ages of 2037–584 Ma. They have geochemical characteristics similar to I-type and S-type granites that were sourced from partial melting of juvenile and ancient continental crust with minor input of mantle materials. The formation of the felsic rocks indicates the transition from an arc-related setting to a post-collisional setting. Combining our results with existing data, we suggest that the Central Qilian block was affected by both southward subduction of the North Qilian ocean and the northward subduction of the South Qilian ocean, resulting in the formation of an Andean-type continental arc along the northern margin of the Central Qilian block and a subduction-accretion system along the southern margin of the Hualong block at ca. 530–440 Ma. Collision of the Central Qilian, Hualong, Quanji and Qaidam blocks at ca. 440–418 Ma marks the final closure of the Proto-Tethys Ocean.

Geochemistry, zircon U–Pb geochronology, and Hf isotopes of S-type granite in the Baoshan block, constraints on the age and evolution of the Proto-Tethys

Geochemistry, zircon U–Pb geochronology, and Hf isotopes of S-type granite in the Baoshan block, constraints on the age and evolution of the Proto-Tethys

Geochemistry and U–Pb zircon geochronology of S-type granites in the Karagwe Ankolean Belt, northwestern Tanzania: Implications for rare-metals mineralization

The Mesoproterozoic Karagwe Ankolean Belt in the Central Eastern Africa region hosts suites of granites that intruded supracrustal rocks and are associated with Sn–W mineralization. In northwestern Tanzania, the granites are S-type, peraluminous and calc-alkalic to alkalic-calcic in composition. Geochemical analyses of the granites reveal the following concentrations: SiO2 (71–77 wt%), Al2O3 (11–15 wt%), K2O (3–7 wt%), MgO (0.06–0.86 wt%), TiO2 (0.07–0.36 wt%) and Fe2O3T (0.71–2.40 wt%). The SiO2 contents correlate negatively with MgO, CaO and K2O and positively correlate with Nb, Ta, Zr, Sr, Ba, Hf, Th and the REE (Eu, Ce and Sm). Primitive mantle normalized spider plots show elevated LILE against depletions in Ba, Nb, Ti and La, suggesting inherited arc-magmatic signatures from the protolith. Chondrite-normalized REE spider plots show elevated LREE and relatively flat MREE and HREE as indicated by (La/Yb)cn = 2–9 and negative Eu* anomalies (0.05–0.24). Modelling of nearby Uha group sedimentary rocks partial melts, supports fractional crystallization and upper crustal contamination for generation of the KAB granites. Trace elemental ratios of Y/Nb, Nb/Ta, Zr/Hf and P205 suggest the granites are weakly mineralized to barren in Sn–W.The U–Pb zircon ages point to two successive and overlapping periods: from 1418 ± 15 Ma to 1395 ± 6 Ma (mean = 1406 Ma) and from 1385 ± 8 Ma to 1376 ± 11 Ma (mean = 1381 Ma). Inheritance U–Pb dates of xenocryst zircons, comprise early to late Paleoproterozoic ages ranging from 2376 ± 30 Ma, 2000 ± 27 Ma to 1901 ± 39 Ma, and from 1795 ± 7 Ma to 1738 ± 7 Ma, implying the participation of the Paleoproterozoic sedimentary rocks in the petrogenesis of the granites. A zircon rim overgrowth age of 1015 ± 26 Ma is interpreted to date a metamorphic/anatexis event that coincided with the c.1000 Ma amalgamation of the supercontinent Rodinia and the emplacement of Sn–W enriched granites. The ages of S-type granite magmatism (1418–1376 Ma) obtained from this study are restricted to the Mesoproterozoic within the widespread bimodal magmatism event c.1375 Ma.

Mantle contributions to granitoids associated with Sn mineralization: Geochemical and isotopic evidence from the giant Dachang deposit, South China

Major Sn deposits are commonly linked to crust-derived and highly evolved granites, with magma generation aided by mantle heating. However, whether and how the mantle components contribute to Sn polymetallic mineralization remains unclear. In this study, in combination with a compilation of equivalent data in the region, we provide new constraints on this issue based on detailed investigations on the petrogenesis and metallogenic significance of granitoids including the causative batholith and later granodiorite porphyry dike in the giant Dachang Sn deposit from South China. The former has zircon U-Pb ages of 93–91 Ma and belongs to highly evolved S-type biotite granite, which experienced fractionation of massive feldspar. The latter shows zircon U-Pb ages of 90 Ma and displays I-type granite features. The batholith was mainly derived from the dehydration melting of biotite in the metasedimentary sources, as revealed by the relatively low whole-rock Pb contents (<30 ppm) and high Ba/Pb ratios (2.71–17.1) and initial T(ti-zr) of 790 ℃. Compared with the adjacent crust-derived S-type granites (−24.8 – −5.1) and I-type granites (−11.0 to −5.2), the Dachang S-type biotite granites present higher zircon εHf(t) values (−9.1 to −2.1). Furthermore, the low magmatic zircon δ18O values (6.2 ‰) and higher apatite LREE (3277–4114 ppm) and Sr (1137–1357 ppm) contents than of arc-type basic rocks were discerned. These characteristics jointly hint the contributions of mantle components. The higher initial T(ti-zr) (>850 °C), whole-rock Mg# (52 to 58), apatite εNd(t) (−9.2 to −6.5) and zircon εHf(t) (−7.6 to 2.5) values but lower zircon δ18O values (6.33 to 8.30 ‰) of the later granodiorite porphyry dike than those of the batholith also suggest that mantle material was involved in the generation of the dikes, which is evident by the variational features of zircon and apatite trace elements. In addition, at the zircon Hf <12000 ppm and Eu/Eu* > 0.05, the higher zircon ΔFMQ values (mostly from −1.8 to 2.0) and H2O contents (100–1100 ppm) of the Dachang granitoids than the pure crust-derived S-type granites (ΔFMQ = mostly from −3.7 to −1.5; H2O < 100 ppm) imply that mantle materials involved are relatively rich in water and oxidized. These suggest that the addition of mantle components is conducive to the extraction of Sn from metasedimentary sources, and moderately facilitates the increase of oxygen fugacity which still maintains the incompatibility of Sn in magmas with ΔFMQ < 2. Also, the involvement of mantle components upgrades the H2O contents in S-type magmas, favoring the migration of ore-forming elements from magmas to hydrothermal fluids. The sediment-derived causative granites displayed higher εHf(t) and εNd(t) values with greater Sn tonnages of their associated world-class Sn polymetallic deposits, supporting the opinion that the contributions of mantle components play an important role in the generation of giant Sn deposits.

Mercury abundance and isotopic composition in granitic rocks: Implications for Hg cycling in the upper continental crust

Mercury (Hg) is a highly volatile metal exhibiting both isotope mass-dependent (MDF, defined as δ202Hg) and mass-independent (MIF, expressed as Δ199Hg) fractionation. Assessing the Hg isotopic composition of the upper continental crust is crucial for the use of this new geochemical tool for petrogenetic tracing, particularly for understanding crust-mantle interaction. Here, we report Hg isotopic compositions of granitic rocks with distinct source affinity (I-, A-, and S-type) and of metasedimentary enclaves from the South China Craton. The results of more than 100 rock samples show large δ202Hg variations of −2.03 to 0.47 ‰ and small Δ199Hg variations of −0.16 to 0.09 ‰. The S-type granites studied here exhibit higher δ202Hg values (−0.58 to 0.00 ‰; n = 57) than their sedimentary protoliths (metasedimentary enclaves; −2.03 to −0.91 ‰; n = 7), suggesting significant Hg-MDF during magmatic processes. The Δ199Hg values of S-type granites (−0.08 to 0.09 ‰) are indistinguishable from their sedimentary protoliths (−0.16 to 0.02 ‰), suggestive of the absence of Hg-MIF during crustal anatexis and subsequent magmatic differentiation. The I- and A-type granites studied have smaller Δ199Hg variations of −0.11 to 0.04 ‰ (n = 28) and −0.07 to 0.04 ‰ (n = 15), respectively, but are within the range of the S-type granites. The compositional range of all granite variants may be explained by the variable intensity of large-scale MASH (melting-assimilation-storage-homogenization) processes. Our new data combined with previously published data of igneous, sedimentary, and metamorphic rocks allow us to estimate that the upper continental crust (UCC) has a Hg abundance of 13.5 ppb and a weighted average δ202Hg of −1.15 ± 1.01 ‰ (2SD), both of which are higher than the corresponding values of the primitive mantle. However, the weighted average Δ199Hg value of the UCC (0.03 ± 0.15 ‰; 2SD) is nondistinguished from the primitive mantle, suggesting no obvious Hg-MIF during the formation and differentiation of the continental crust.

Sources and petrogenesis of Late Triassic granitoids in the Yajiang gneiss dome group (eastern Songpan-Ganze orogenic belt) with tectonic implications

Numerous Mesozoic granitoid plutons with a substantial variety of petrologic and geochemical signatures intrude the Triassic metasedimentary rocks of the Songpan-Ganze accretionary-orogenic wedge in the eastern Tibetan Plateau. These granitoid rocks generally exhibit sharp contact with the Triassic sedimentary rocks. To better understand the genesis and emplacement of magmas associated with tectonic accretion along convergent plate boundaries, we present new LA-ICP-MS zircon U-Pb geochronology, major and trace elements, and Sr–Nd–Pb–Hf isotopic compositions for intermediate-to-felsic plutons in the Yajiang gneiss dome group (YGDG), including the Changzheng pluton, the Jiajika (Majingzi) pluton, the Rongxuka pluton, the Xiya pluton, the Xinduqiao pluton, and the Waduo diorite dikes in the eastern margin of the Songpan-Ganze orogenic belt (SGOB). By their typical petrological and geochemical characteristics, these plutons are classified as I-type granodiorite-diorite (Rongxuka, Xiya, Xinduqiao plutons, Waduo dikes) or S-type granite (Changzheng and Jiajika plutons). I-type granodiorite-diorites exhibit a high Mg# (average 49), medium-K cala-alkiline signature and are enriched in large-ion lithophile elements (e.g., Rb, Th, and U) but depleted in high field strength elements (e.g., Nb, Ta, and Ti), and with lower initial 87Sr/86Sr values (0.70622 to 0.70863) but a relatively high and concentrated εHf(t) (−27 to −1.9) and εNd(t) (−4.02 to −7.51); while S-type granites exhibit a high silica, high-K cala-alkiline signature with strong negative Eu anomalies (Eu/Eu* = 0.17–0.64), and possess high initial 87Sr/86Sr values but low εHf(t) (−40.1 to −0.9) and εNd(t) (−8.72 to −12.14) signatures, forming through partial melting of metasedimentary rocks from an ancient crust source. LA–ICP–MS zircon U-Pb dating indicates that they were emplacement between 207.2 ± 1.4 and 223.6 ± 2.2 Ma. Both types of granitoid rock were formed by the crustal partial melting followed by extensive fractional crystallization under high-temperature (700–850 °C), low-pressure (<15 kb) conditions. In combination with previous studies, our data provide evidence for an affinity between the eastern Songpan-Ganze andthe Yangtze craton basements, and suggest that the granitoid plutons formed in a syn-collisional to post-collisional setting at ca. 207–223 Ma.

A newly defined latest Carboniferous-Permian ridge subduction in the southern Altaids: Insights from adakitic, S-type, and I-type granitoids in the northern East Junggar (NW China)

ABSTRACT Late Palaeozoic evolution of the Chinese Altai-East Junggar orogenic collage is vital for a better understanding of the accretionary evolution in the southern Altaids. This paper reports new geochronological, geochemical, and isotopic data for the magmatic rocks collected from the northern part of the Dulate arc. The ~304.6 Ma tonalite samples present typical adakitic features of high Sr (396–714 ppm), low Y (1.42–2.60 ppm), Yb (0.11–0.24 ppm), and high Sr/Y (177.25–440.23) ratios. Combining high Mg# (55.35–57.21) and depleted isotopic composition (εHf(t): +9.89 to +13.37 and εNd(t): +5.36 to +6.06), we suggest that they were derived from the partial melting of a subducted oceanic slab. The ~299.4 Ma monzogranite samples have high A/CNK values (1.08 to 1.25), CIPW normative corundum contents (1.28–3.25 wt.%), and positive εHf(t) (+5.14 to +8.63) and εNd(t) (+1.08) values, which are similar to S-type granite that may be generated by the melting of greywackes. The monzogranite (~286.9 Ma) and rhyolitic porphyry (~283.9 Ma) are high-K calc-alkaline and similar to the highly fractionated I-type granites with depleted isotopic features (εHf(t): +11.68 to +14.99 and +0.75 to +7.18, εNd(t): +5.91 and +6.18). The monzogranite and rhyolitic porphyry could have been derived from a depleted mantle source, but the rhyolitic porphyry probably suffered partial assimilation of the overlying crust materials. Combining regional rock associations of mafic-ultramafic complexes, adakitic rocks, high-Mg diorites, and A-type granites with close spatial-temporal relationship, we conclude that a mid-oceanic ridge of the Ob-Zaisan Ocean subducted southward beneath the Dulate arc during the latest Carboniferous to Permian. With the opening of the slab window, the upwelling asthenosphere provided high heat flux and triggered various magmatism in the upper plate. We propose that ridge subduction is one of the most effective mechanisms of continental growth in the southern Altaids.

Mineralogical, geochemical and radioactivity of Gabal Nasb Hebili, Arabian Nubian Shield, Egypt: Implication for rare metals mineralization

Field geology, geochemical studies and spectrometric prospecting were used to detect rare metals and uranium mineralization in Neoproterozoic garnetiferous muscovite granites from Gabal Nasb Hebili area in the South Eastern Desert of the Egypt from the Arabian-Nubian Shield (ANS). They intrude the surrounding metaultramafic rocks, metagabbros, mélange matrix, older granitoids, younger granitoids (garnetiferous muscovite granites) and post-granitic dykes. The present study will focus on the garnetiferous muscovite granites, which occur as stocks of domal shape and composed of quartz, plagioclase, potash feldspars, muscovite and garnet. These garnetiferous muscovite granites were affected by sericitization, silicification and fluoritization processes. These alteration products are associated with visible uranium mineralization. Mineralogical study of the mineralized zones in the garnetiferous muscovite granites reveals the uranium minerals (zippeite, uranophane, kasolite and autunite) and rare earth-bearing minerals (monazite, allanite, bastnäsite, coronadite and garnet). The presence of these different paragenetic minerals with the various alterations in the studied granites, indicate that these rocks were subjected to the effect of mineralizing acidic and alkaline solutions in post magmatic stage. Geochemically, the garnetiferous muscovite granites are peraluminous (A/CNK= > 1.1) and showing of S-type granites which formed in a syn-collision tectonic regime. The Gabal Nasb Hebili granites exhibit positive slopes of LREEs (Ce/Sm)n (3.2) with negative HREE slopes [(Gd/Lu)n from 4.6). The negative Eu anomaly in the granite is very strong, suggesting serious addition of Eu during the alteration. The increase in the LREE, and other light isovalents, can be supported by the petrographic observations where monazite and allanite appear to be important refractory minerals in the sheared granite. Gabal Nasb Hebili is markedly enriched in eU, where its content varies between 4.3 and 199.2 ppm (averaging 34.4 ppm) with eU/eTh ratio (0.9–7.1), while eTh content varies between 2.2 and 95.3 ppm (averaging 13.8 ppm).

Petrogenesis of the Yunling Sn-rich magma in the Baoshan Block, SW China: Constraints from mineral and whole-rock geochemistry

Southwest Yunnan is one of the most important tin (Sn) metallogenic belts in China. The Sn mineralization is mainly linked with the Cretaceous and Cenozoic magmatism. Triassic granitoids are also widely developed in this region, where the Yunling granitoids are considered to represent an essential target for the localization of Sn mineralization. However, the source characteristics of these ore-related granitoids are still unclear. Here we present geochronology, petrology, and mineral geochemistry to reveal the petrogenesis of Sn-rich magma. Zircon U-Pb dating indicates that the Yunling samples were emplaced at 220–209 Ma, suggesting that the Late Triassic magmatism in the Yunling district along the S–N trending Changning-Menglian suture zone (CMSZ) was generated at the post-collisional stage. Samples from the Yunling pluton exhibit a variable SiO2 content of 54.8–68.5 wt% and are characterized by a high normative corundum content (>1 wt%) and aluminum saturation index (A/CNK = 0.84–1.17). Systemic zircon geochemistry suggests that these samples belong to S-type granite. Moreover, the granitoids have extremely enriched Nd-Hf isotopic signatures with εNd(t) values of −11.5 to −10.7 and εHf(t) values of −21.6 to −10.6. These findings, together with the elevated Ba/Pb ratios and high zircon Ti temperatures (≥800 °C), indicate that the Yunling S-type granitoids were likely to have been derived from the dehydrating partial melting of biotite in the metasedimentary rocks at high temperatures. In addition, the magmatic oxygen fugacity obtained from the magmatic accessory minerals suggests that the ore-related granitic magmas are highly reduced, with the estimated ΔFMQ (fayalite-magnetite-quartz buffer) generally ranging from −5.45 to −0.22 (-3.48 on average). Based on these results, we conclude that the decomposition of biotite in the source effectively extracted Sn, thus forming initial Sn-rich melts which crystallized and differentiated at a low oxygen fugacity and were eventually deposited in the shallow crust to form the Yunling Sn-bearing granitoids.

Cretaceous magmatic migration and flare-up in Pamir–Karakoram

The Pamir–Karakoram terrain contains abundant Cretaceous granitoids, and minor coeval volcanic rocks and mafic intrusions, which represent a wide (ca. 400 km) continental arc developed during northward subduction of Neo-Tethys oceanic lithosphere. However, little is known of the tectonic controls on the magmatic flare-ups and their implications for crustal thickening. In this paper, we report new zircon UPb age and Hf isotope data for Cretaceous biotite granites, two-mica granites and mafic microgranular enclaves (MMEs) from the large-scale granitic batholiths in Pamir. These and previously published results show there were four episodes of Cretaceous magmatism (124–108, 107–103, 102–92, and 80–70 Ma). The Cretaceous arc migrated progressively landward from Karakoram to Central Pamir with a maximum arc–trench distance of ca. 400 km during the first magmatic episode (124–108 Ma). The igneous rocks are mainly S-type granites with enriched zircon Hf isotopic compositions (ɛHf(t) = −19.8 to −5.4), indicating derivation by partial melting of metasedimentary units. A magmatic flare-up at 105 ± 2 Ma generated voluminous I-type granites and minor mafic igneous rocks that cover ca. 30% of the study area. The I-type granites have higher zircon ɛHf(t) values (−19.0 to −2.0) as compared with those of the earlier S-type granites, which reflect the addition of mantle-derived materials (ca. 30%). The third episode of magmatism (102–92 Ma) generated mainly intermediate–silicic volcanic rocks, which are geochemically similar to I-type granites and have ɛHf(t) values of −15.0 to −1.5. The final episode of magmatism (80–70 Ma) was dominated by alkaline and mafic igneous rocks formed in a post-collisional setting, which have variable ɛHf(t) values of −6.6 to 10.5. Our study highlights that the Early Cretaceous magmatic flare-up in the Pamir–Karakoram terrain was related to foundering of the flat-slab of Neo-Tethys oceanic lithosphere that was previously subducted, which induced voluminous underplating of mantle-derived magma in the lower crust. This process had a key role in crustal thickening in the Pamir–Karakoram terrain prior to the Cenozoic India–Asia collision.

Large-scale rare-metal pegmatite deposit formation driven by supercontinent assembly

Abstract Triassic rare-metal pegmatite deposits are widespread in East Asia; e.g., the western Kunlun and Songpan-Ganze belt in northern Tibet and the Altai belt in the heart of the Central Asian Orogenic Belt. However, rare-metal enrichment processes and deposit formation mechanisms are enigmatic. Most rare-metal pegmatites in East Asia formed at ca. 220–200 Ma in the Late Triassic and are genetically related to S-type granites. Whole-rock and zircon Li and Cs contents indicate that sedimentary rocks represent a fertile rare-metal source for the pegmatite deposits and that long-term chemical weathering plays a key role in the enrichment of rare metals. The formation of these widespread deposits in East Asia was associated with lithospheric extension induced by slab retreat along the periphery of the supercontinent during Pangea assembly.

Geochronology, petrogenesis, and mineralization potential of the syenogranites in the Yama fluorite deposit, Tataleng granitic batholith, Qilian Orogen, NW China

The Yama fluorite deposit in the Qilian Orogen in NW China is characterized by predominant granitic magmatism and fluorite mineralization. The wall rocks hosting the fluorite–quartz veins in the Yama area consist of the Yama porphyritic syenogranite and the Wulandawu syenogranite. In this study, the major and trace element compositions, zircon U–Pb ages, and zircon Hf isotopes and trace element compositions were investigated. Two samples for the Yama porphyritic syenogranite yielded weighted mean 206Pb/238U zircon ages of 440.7 ± 4.8 and 447.9 ± 6.0 Ma, and one sample for the Wulandawu syenogranite yielded a weighted mean 206Pb/238U zircon age of 441.2 ± 5.0 Ma, all of which indicate a Late Ordovician to Early Silurian crystallization age. Geochemically, both syenogranites are peraluminous, with high alkali contents, low Zr + Nb + Ce + Y contents, relatively low (K2O + Na2O)/CaO ratios, and high Rb/Sr and Rb/Ba ratios, suggesting that they are fractionated S-type granites. They have zircon εHf( t) values of −14.9 to −4.4 and −12.2 to −4.5, respectively, suggesting that they were derived from the partial melting of pelitic-rich sources within the relatively shallow Paleoproterozoic reworked crust. The detailed geochronological and geochemical data suggest that the studied syenogranites were emplaced in a post-collisional setting related to the closure of the South Qilian Ocean. Finally, they have relatively low quantitative oxygen fugacity values, indicating relatively reduced redox states, but their very low zircon Ce4+/Ce3+ ratios, low whole-rock K/Rb ratios, relatively high Nb/Ta ratios, and low Zr/Hf ratios suggest that they are not likely to form important W–Sn deposits and related fluorite deposits.