Geochronology and geochemistry of early Paleozoic magmatism in the Qilian orogen: Constraints on closure of the Proto-Tethys Ocean

Abstract

The Proto-Tethys Ocean was a Neoproterozoic to early Paleozoic ocean that opened upon the breakup of Rodinia and closed by Paleozoic oceanic and continental subduction. The Qilian orogenic belt is the northernmost orogen of the Proto-Tethys domain and consists of the North Qilian belt, the Central Qilian block and the South Qilian belt. The processes responsible for extensive early Paleozoic magmatism in the Qilian orogen are crucial to understanding the closure of the ocean. This paper presents a systematic investigation of early Paleozoic mafic and felsic rocks in the Qilian orogen. Gabbroic dikes from the Central Qilian block have LA-ICP-MS zircon U-Pb ages of 499–497 Ma with a wide range of εHf(t) values of −9.94 to + 4.28 and TDM1 model ages of 1557–929 Ma, and dioritic dikes have a LA-ICP-MS zircon U-Pb age of 489 ± 3 Ma, positive εHf(t) values of +7.61 to +10.53, TDM1 model ages of 684–790 Ma, and an amphibole 40Ar/39Ar age of 486.3 ± 4.3 Ma. Both sets of dikes were derived from partial melting of a heterogeneous spinel-facies lherzolite lithospheric mantle that was modified by fluids and melts from a subducted slab. The protolith of amphibolites from the Hualong block in the South Qilian belt was a mafic intrusion of 454 ± 2 Ma with negative εHf(t) values of −9.69 to −7.79 and TDM1 model ages of 1390–1478 Ma. Its trace element signature indicates that sediment-derived melts were involved in the magma formation. An amphibole 40Ar/39Ar age of 418.7 ± 3.8 Ma from an amphibolite records the timing of amphibolite facies metamorphism. Felsic volcanic tuffs and granitic intrusions from the Central Qilian block have zircon U-Pb ages of 507–440 Ma with a broad range of zircon εHf(t) values of −9.60 to + 11.87 and TDM2 model ages of 2037–584 Ma. They have geochemical characteristics similar to I-type and S-type granites that were sourced from partial melting of juvenile and ancient continental crust with minor input of mantle materials. The formation of the felsic rocks indicates the transition from an arc-related setting to a post-collisional setting. Combining our results with existing data, we suggest that the Central Qilian block was affected by both southward subduction of the North Qilian ocean and the northward subduction of the South Qilian ocean, resulting in the formation of an Andean-type continental arc along the northern margin of the Central Qilian block and a subduction-accretion system along the southern margin of the Hualong block at ca. 530–440 Ma. Collision of the Central Qilian, Hualong, Quanji and Qaidam blocks at ca. 440–418 Ma marks the final closure of the Proto-Tethys Ocean.