Role Of Aerosols Research Articles

Effects of aerosols on the surface ozone generation via a study of the interaction of ozone and its precursors during the summer in Shanghai, China

Previous studies have shown that heavy aerosol pollution can inhibit the surface ozone generation. More recent studies, however, have revealed that aerosol loading is positively correlated with ozone concentrations in large cities, such as Shanghai, particularly during the summer. Whether the correlation between aerosol pollution and ozone concentrations is positive or negative, it is an issue that needs to be considered by atmospheric scientists. Although the presence of ozone precursors, such as nitrogen oxide (NOx) and volatile organic compounds (VOCs), affect ozone concentrations, the roles of aerosols in the formation of ozone have rarely been investigated. Therefore, an analysis of the effect of aerosols on photochemical ozone generation via a study of the interaction of ozone and its precursors is important. In our research, we found that both aerosol and ozone concentrations were higher in Shanghai under polluted conditions than they were under clean conditions during the summer, but the ozone formation was controlled by VOCs, not by aerosol loading. The decrease in the AOD (SSA) increased (decreased) the surface UV radiation and promoted (inhibited) photochemical ozone production. We also found that the lower the concentration of photochemically active VOCs, the weaker the effect of the AOD on the ozone concentrations. The other results were shown as follows: (1) Aerosol pollution decreased the amount of UV radiation reaching the Earth's surface, but the surface UV radiation increased with increasing aerosol particle scattering; (2) Aerosol pollution inhibited the photolysis of nitrogen dioxide (NO2), while the scattering property of aerosols facilitated this phenomenon; (3) When both the concentration of ozone precursors and the SSA were constant, the ozone concentration decreased, but the attenuation rate increased significantly with an increase in AOD.

Chemical and Biological Components of Urban Aerosols in Africa: Current Status and Knowledge Gaps.

Aerosolized particulate matter (PM) is a complex mixture that has been recognized as the greatest cause of premature human mortality in low- and middle-income countries. Its toxicity arises largely from its chemical and biological components. These include polycyclic aromatic hydrocarbons (PAHs) and their nitro-derivatives (NPAHs) as well as microorganisms. In Africa, fossil fuel combustion and biomass burning in urban settings are the major sources of human exposure to PM, yet data on the role of aerosols in disease association in Africa remains scarce. This review is the first to examine studies conducted in Africa on both PAHs/NPAHs and airborne microorganisms associated with PM. These studies demonstrate that PM exposure in Africa exceeds World Health Organization (WHO) safety limits and carcinogenic PAHs/NPAHs and pathogenic microorganisms are the major components of PM aerosols. The health impacts of PAHs/NPAHs and airborne microbial loadings in PM are reviewed. This will be important for future epidemiological evaluations and may contribute to the development of effective management strategies to improve ambient air quality in the African continent.

The role of aerosols and greenhouse gases in Sahel drought and recovery

We exploit the multi-model ensemble produced by phase 5 of the Coupled Model Intercomparison Project (CMIP5) to synthesize current understanding of external forcing of Sahel rainfall change, past and future, through the lens of oceanic influence. The CMIP5 multi-model mean simulates the twentieth century evolution of Sahel rainfall, including the mid-century decline toward the driest years in the early 1980s and the partial recovery since. We exploit a physical argument linking anthropogenic emissions to the change in the temperature of the sub-tropical North Atlantic Ocean relative to the global tropical oceans to demonstrate indirect attribution of late twentieth century Sahel drought to the unique combination of aerosols and greenhouse gases that characterized the post-World War II period. The subsequent reduction in aerosol emissions around the North Atlantic that resulted from environmental legislation to curb acid rain, occurring as global tropical warming continued unabated, is consistent with the current partial recovery and with projections of future wetting. Singular Value Decomposition (SVD) applied to the above-mentioned sea surface temperature (SST) indices provides a succinct description of oceanic influence on Sahel rainfall and reveals the near-orthogonality in the influence of emissions between twentieth and twenty-first centuries: the independent effects of aerosols and greenhouse gases project on the difference of SST indices and explain past variation, while the dominance of greenhouse gases projects on their sum and explains future projection. This result challenges the assumption that because anthropogenic warming had a hand in past Sahel drought, continued warming will result in further drying. In fact, the twenty-first century dominance of greenhouse gases, unchallenged by aerosols, results in projections consistent with warming-induced strengthening of the monsoon, a response that has gained in coherence in CMIP5 compared to prior multi-model exercises.

On the role of aerosols, humidity, and vertical wind shear in the transition of shallow-to-deep convection at the Green Ocean Amazon 2014/5 site

Abstract. The preconditioning of the atmosphere for a shallow-to-deep convective transition during the dry-to-wet season transition period (August–November) is investigated using Department of Energy (DOE) Atmospheric Radiation Measurement (ARM) GoAmazon2014/5 campaign data from March 2014 to November 2015 in Manacapuru, Brazil. In comparison to conditions observed prior to shallow convection, anomalously high humidity in the free troposphere and boundary layer is observed prior to a shallow-to-deep convection transition. An entraining plume model, which captures this leading dependence on lower tropospheric moisture, is employed to study indirect thermodynamic effects associated with vertical wind shear (VWS) and cloud condensation nuclei (CCN) concentration on preconvective conditions. The shallow-to-deep convective transition primarily depends on humidity, especially that from the free troposphere, which tends to increase plume buoyancy. Conditions preceding deep convection are associated with high relative humidity, and low-to-moderate CCN concentration (less than the 67th percentile, 1274 cm−3). VWS, however, shows little relation to moisture and plume buoyancy. Buoyancy estimates suggest that the latent heat release due to freezing is important to deep convective growth under all conditions analyzed, consistent with potential pathways for aerosol effects, even in the presence of a strong entrainment. Shallow-only convective growth, however, shows an association with a strong (weak) low (deep) level VWS and with higher CCN concentration.

Radiative absorption enhancement of dust mixed with anthropogenic pollution over East Asia

Abstract. The particle mixing state plays a significant yet poorly quantified role in aerosol radiative forcing, especially for the mixing of dust (mineral absorbing) and anthropogenic pollution (black carbon absorbing) over East Asia. We have investigated the absorption enhancement of mixed-type aerosols over East Asia by using the Aerosol Robotic Network observations and radiative transfer model calculations. The mixed-type aerosols exhibit significantly enhanced absorbing ability than the corresponding unmixed dust and anthropogenic aerosols, as revealed in the spectral behavior of absorbing aerosol optical depth, single scattering albedo, and imaginary refractive index. The aerosol radiative efficiencies for the dust, mixed-type, and anthropogenic aerosols are −101.0, −112.9, and −98.3 Wm-2τ-1 at the bottom of the atmosphere (BOA); −42.3, −22.5, and −39.8 Wm-2τ-1 at the top of the atmosphere (TOA); and 58.7, 90.3, and 58.5 Wm-2τ-1 in the atmosphere (ATM), respectively. The BOA cooling and ATM heating efficiencies of the mixed-type aerosols are significantly higher than those of the unmixed aerosol types over the East Asia region, resulting in atmospheric stabilization. In addition, the mixed-type aerosols correspond to a lower TOA cooling efficiency, indicating that the cooling effect by the corresponding individual aerosol components is partially counteracted. We conclude that the interaction between dust and anthropogenic pollution not only represents a viable aerosol formation pathway but also results in unfavorable dispersion conditions, both exacerbating the regional air pollution in East Asia. Our results highlight the necessity to accurately account for the mixing state of aerosols in atmospheric models over East Asia in order to better understand the formation mechanism for regional air pollution and to assess its impacts on human health, weather, and climate.

Long-term study of aerosol–cloud–precipitation interaction over the eastern part of India using satellite observations during pre-monsoon season

This study attempts to analyze possible aerosol–cloud–precipitation interaction over the eastern part of India including Bhubaneswar city and the whole Odisha region primarily using a long-term satellite-based dataset from 2000 to 2016 during pre-monsoon period. Relationship between aerosol optical depth (AOD), rainfall, and cloud properties is examined by taking convectively driven rain events. The two-sample student’s t test is used to compute “p” value of datasets that are statically significant. Role of aerosols in governing cloud properties is analyzed through the variation of COD (cloud optical depth) and CER (cloud effective radius) in the AOD ranges 0.2–0.8. A relatively stronger and affirmative AOD–CER relationship is observed over Bhubaneswar city compared to Odisha region though the aerosols still play an appreciable role for the later too. The AOD–COD relationship is weak over both the regions. For Odisha, relationships between aerosol and cloud parameters are insignificant irrespective of rainfall regimes. Fostering of heavy rainfall over these regions takes place due to invigoration and microphysical effect during pre-monsoon months, depending upon meteorological conditions. Liquid water content and presence of a mixed-phase zone, both seem to be quite important in the convectively driven precipitation over Odisha region including Bhubaneswar city.

Impact of varying lidar measurement and data processing techniques in evaluating cirrus cloud and aerosol direct radiative effects

Abstract. In the past 2 decades, ground-based lidar networks have drastically increased in scope and relevance, thanks primarily to the advent of lidar observations from space and their need for validation. Lidar observations of aerosol and cloud geometrical, optical and microphysical atmospheric properties are subsequently used to evaluate their direct radiative effects on climate. However, the retrievals are strongly dependent on the lidar instrument measurement technique and subsequent data processing methodologies. In this paper, we evaluate the discrepancies between the use of Raman and elastic lidar measurement techniques and corresponding data processing methods for two aerosol layers in the free troposphere and for two cirrus clouds with different optical depths. Results show that the different lidar techniques are responsible for discrepancies in the model-derived direct radiative effects for biomass burning (0.05 W m−2 at surface and 0.007 W m−2 at top of the atmosphere) and dust aerosol layers (0.7 W m−2 at surface and 0.85 W m−2 at top of the atmosphere). Data processing is further responsible for discrepancies in both thin (0.55 W m−2 at surface and 2.7 W m−2 at top of the atmosphere) and opaque (7.7 W m−2 at surface and 11.8 W m−2 at top of the atmosphere) cirrus clouds. Direct radiative effect discrepancies can be attributed to the larger variability of the lidar ratio for aerosols (20–150 sr) than for clouds (20–35 sr). For this reason, the influence of the applied lidar technique plays a more fundamental role in aerosol monitoring because the lidar ratio must be retrieved with relatively high accuracy. In contrast, for cirrus clouds, with the lidar ratio being much less variable, the data processing is critical because smoothing it modifies the aerosol and cloud vertically resolved extinction profile that is used as input to compute direct radiative effect calculations.

Dome effect of black carbon and its key influencing factors: a one-dimensional modelling study

Abstract. Black carbon (BC) has been identified to play a critical role in aerosol–planetary boundary layer (PBL) interaction and further deterioration of near-surface air pollution in megacities, which has been referred to as the “dome effect”. However, the impacts of key factors that influence this effect, such as the vertical distribution and aging processes of BC, as well as the underlying land surface, have not been quantitatively explored yet. Here, based on available in situ measurements of meteorology and atmospheric aerosols together with the meteorology–chemistry online coupled model WRF-Chem, we conduct a set of parallel simulations to quantify the roles of these factors in influencing the BC dome effect and surface haze pollution. Furthermore, we discuss the main implications of the results to air pollution mitigation in China. We found that the impact of BC on the PBL is very sensitive to the altitude of aerosol layer. The upper-level BC, especially that near the capping inversion, is more essential in suppressing the PBL height and weakening the turbulent mixing. The dome effect of BC tends to be significantly intensified as BC mixed with scattering aerosols during winter haze events, resulting in a decrease in PBL height by more than 15 %. In addition, the dome effect is more substantial (up to 15 %) in rural areas than that in the urban areas with the same BC loading, indicating an unexpected regional impact of such an effect to air quality in countryside. This study indicates that China's regional air pollution would greatly benefit from BC emission reductions, especially those from elevated sources from chimneys and also domestic combustion in rural areas, through weakening the aerosol–boundary layer interactions that are triggered by BC.

Implication of Light Absorption Enhancement and Mixing State of Black Carbon (BC) by Coatings in Hong Kong

Simultaneous measurements of black carbon (BC) and non-refractory PM1 aerosol chemical compositions were performed in autumn 2016 at a suburban site in Hong Kong. A thermodenuder (TD) was employed at different heating temperatures to remove semi-volatile aerosol fractions to varying degrees. The light absorption enhancement (Eabs) of BC due to semi-volatile coatings at seven wavelengths was evaluated, and the coating fractions were further analyzed. Results showed that the overall Eabs ranged from 1.58 ± 0.13 (470 nm) to 1.64 ± 0.16 (660 nm) at 280°C and increased very little from 50°C (1.02–1.04) to 200°C (1.13–1.20). The lensing-effect-related Eabs was probably attributable to the presence of ammonium and sulfate. Furthermore, the ratio of the coating thickness to the BC core radius was around 1.0–2.0 based on Mie calculations. This work evaluated the Eabs from coatings in Hong Kong and implied the BC mixing state, thus providing a critical reference for climate models on the role of aerosol in global warming.

Role of Aerosols in Climate Change and Cloud Formation Emitted from Coal Based Power Plant

Role of Aerosols in Climate Change and Cloud Formation Emitted from Coal Based Power Plant

Application of remote sensing techniques to study aerosol water vapour uptake in a real atmosphere

In this work, a study of several observations of aerosol water uptake in a real (non-controlled) atmosphere, registered by remote sensing techniques, are presented. In particular, three events were identified within the Atmospheric Boundary Layer (ABL) and other two events were detected in the free troposphere (beyond the top of the ABL). Then, aerosol optical properties were measured at different relative humidity (RH) conditions by means of a multi-wavelength (MW) Raman lidar located at CIEMAT (Centro de Investigaciones Energéticas, Medioambientales y Tecnológicas, Research Centre for Energy, Environment and Technology) facilities in Madrid (Spain). Additionally, aerosol optical and microphysical properties provided by automatic sun and sky scanning spectral radiometers (CIMEL CE-318) and a meteorological analysis complement the study. However, a detailed analysis only could be carried out for the cases observed within the ABL since well-mixed atmospheric layers are required to properly characterize these processes. This characterization of aerosol water uptake is based on the curve described by the backscatter coefficient at 532nm as a function of RH which allows deriving the enhancement factor. Thus, the Hänel parameterization is utilized, and the results obtained are in the range of values reported in previous studies, which shows the suitability of this approach to study such hygroscopic processes. Furthermore, the anti-correlated pattern observed on backscatter-related Ångström exponent (532/355nm) and RH indicates plausible signs of aerosol hygroscopic growth. According to the meteorological analysis performed, we attribute such hygroscopic behaviour to marine aerosols which are advected from the Atlantic Ocean to the low troposphere in Madrid. We have also observed an interesting response of aerosols to RH at certain levels which it is suggested to be due to a hysteresis process.The events registered in the free troposphere, which deal with volcano and wild fire plumes transported at higher altitudes, indicate that these processes can take place in the free troposphere, where the climate relevance can be rather different considering the role of aerosol as cloud condensation nuclei.

Relationship between aerosol and lightning over Indo-Gangetic Plain (IGP), India

The relationship between aerosol and lightning over the Indo-Gangetic Plain (IGP), India has been evaluated by utilising aerosol optical depth (AOD), cloud droplet effective radius and cloud fraction from Moderate Resolution Imaging Spectroradiometer. Lightning flashes have been observed by the lightning Imaging sensor on the board of Tropical Rainfall and Measuring Mission and humidity from modern-era retrospective-analysis for research and applications for the period of 2001–2012. In this study, the role of aerosol in lightning generation over the north-west sector of IGP has been revealed. It is found that lightning activity increases (decreases) with increasing aerosols during normal (deficient) monsoon rainfall years. However, lightning increases with increasing aerosol during deficient rainfall years when the average value of AOD is less than 0.88. We have found that during deficient rainfall years the moisture content of the atmosphere and cloud fraction is smaller than that during the years with normal or excess monsoon rainfall over the north-west IGP. Over the north-east Bay of Bengal and its adjoining region the variations of moisture and cloud fraction between the deficient and normal rainfall years are minimal. We have found that the occurrence of the lightning over this region is primarily due to its topography and localised circulation. The warm-dry air approaching from north-west converges with moist air emanating from the Bay of Bengal causing instability that creates an environment for deep convective cloud and lightning. The relationship between lightning and aerosol is stronger over the north-west sector of IGP than the north-east, whereas it is moderate over the central IGP. We conclude that aerosol is playing a major role in lightning activity over the north-west sector of IGP, but, local meteorological conditions such as convergences of dry and moist air is the principal cause of lightning over the north-east sector of IGP. In addition, atmospheric humidity also plays an important role in regulating the effect of aerosol on the microphysical properties of clouds over IGP region.

Understanding the drivers of marine liquid-water cloud occurrence and properties with global observations using neural networks

Abstract. The role of aerosols, clouds and their interactions with radiation remain among the largest unknowns in the climate system. Even though the processes involved are complex, aerosol–cloud interactions are often analyzed by means of bivariate relationships. In this study, 15 years (2001–2015) of monthly satellite-retrieved near-global aerosol products are combined with reanalysis data of various meteorological parameters to predict satellite-derived marine liquid-water cloud occurrence and properties by means of region-specific artificial neural networks. The statistical models used are shown to be capable of predicting clouds, especially in regions of high cloud variability. On this monthly scale, lower-tropospheric stability is shown to be the main determinant of cloud fraction and droplet size, especially in stratocumulus regions, while boundary layer height controls the liquid-water amount and thus the optical thickness of clouds. While aerosols show the expected impact on clouds, at this scale they are less relevant than some meteorological factors. Global patterns of the derived sensitivities point to regional characteristics of aerosol and cloud processes.

Chemical Composition and Properties of the Liquid-Vapor Interface of Aqueous C1 to C4 Monofunctional Acid and Alcohol Solutions.

The liquid-vapor interface is playing an important role in aerosol and cloud chemistry in cloud droplet activation by aerosol particles and potentially also in ice nucleation. We have employed the surface sensitive and chemically selective X-ray photoelectron spectroscopy (XPS) technique to examine the liquid-vapor interface for mixtures of water and small alcohols or small carboxylic acids (C1 to C4), abundant chemicals in the atmosphere in concentration ranges relevant for cloud chemistry or aerosol particles at the point of activation into a cloud droplet. A linear correlation was found between the headgroup carbon 1s core-level signal intensity and the surface excess derived from literature surface tension data with the offset being explained by the bulk contribution to the photoemission signal. The relative interfacial enhancement of the carboxylic acids over the carboxylates at the same bulk concentration was found to be highest (nearly 20) for propionic acid/propionate and still about 5 for formic acid/formate, also in fair agreement with surface tension measurements. This provides direct spectroscopic evidence for high carboxylic acid concentrations at aqueous solution-air interfaces that may be responsible for acid catalyzed chemistry under moderately acidic conditions with respect to their bulk aqueous phase acidity constant. By assessing the ratio of aliphatic to headgroup C 1s signal intensities XPS also provides information about the orientation of the molecules. The results indicate an increasing orientation of alcohols and neutral acids toward the surface normal as a function of chain length, along with increasing importance of lateral hydrophobic interactions at higher surface coverage. In turn, the carboxylate ions exhibit stronger orientation toward the surface normal than the corresponding neutral acids, likely caused by the stronger hydration of the charged headgroup.

Aerosol and monsoon climate interactions over Asia

AbstractThe increasing severity of droughts/floods and worsening air quality from increasing aerosols in Asia monsoon regions are the two gravest threats facing over 60% of the world population living in Asian monsoon regions. These dual threats have fueled a large body of research in the last decade on the roles of aerosols in impacting Asian monsoon weather and climate. This paper provides a comprehensive review of studies on Asian aerosols, monsoons, and their interactions. The Asian monsoon region is a primary source of emissions of diverse species of aerosols from both anthropogenic and natural origins. The distributions of aerosol loading are strongly influenced by distinct weather and climatic regimes, which are, in turn, modulated by aerosol effects. On a continental scale, aerosols reduce surface insolation and weaken the land‐ocean thermal contrast, thus inhibiting the development of monsoons. Locally, aerosol radiative effects alter the thermodynamic stability and convective potential of the lower atmosphere leading to reduced temperatures, increased atmospheric stability, and weakened wind and atmospheric circulations. The atmospheric thermodynamic state, which determines the formation of clouds, convection, and precipitation, may also be altered by aerosols serving as cloud condensation nuclei or ice nuclei. Absorbing aerosols such as black carbon and desert dust in Asian monsoon regions may also induce dynamical feedback processes, leading to a strengthening of the early monsoon and affecting the subsequent evolution of the monsoon. Many mechanisms have been put forth regarding how aerosols modulate the amplitude, frequency, intensity, and phase of different monsoon climate variables. A wide range of theoretical, observational, and modeling findings on the Asian monsoon, aerosols, and their interactions are synthesized. A new paradigm is proposed on investigating aerosol‐monsoon interactions, in which natural aerosols such as desert dust, black carbon from biomass burning, and biogenic aerosols from vegetation are considered integral components of an intrinsic aerosol‐monsoon climate system, subject to external forcing of global warming, anthropogenic aerosols, and land use and change. Future research on aerosol‐monsoon interactions calls for an integrated approach and international collaborations based on long‐term sustained observations, process measurements, and improved models, as well as using observations to constrain model simulations and projections.

Role of aerosols in modulating cloud properties during active–break cycle of Indian summer monsoon

In this study, the weather research and forecast model coupled with chemistry (WRF-Chem), is used to understand the impact of aerosol–cloud interaction during the active–break cycles of the Indian summer monsoon. Two sets of simulations are performed, one with a fixed aerosol concentration (ConstantAero) and the other with an observation-based prescription of the rate of change of aerosol concentration as a function of precipitation (VaryingAero). This prescription is derived based on satellite-retrieved daily rainrate and concurrent observations of aerosol optical depth from aerosol robotic network. The proposed modification is necessitated by the lack of realistic emission estimates over the Indian region as well as the presence of inherent biases in monsoon simulation in WRF-Chem. In the VaryingAero simulation, unlike in the ConstantAero run, we find that the break-to-active monsoon phase has more cloud liquid water (CLW) and less rain efficiency than in the active-to-break phase. This is primarily due to the indirect effect of increased aerosol loading in the break phase. This result is in accordance with the observed behaviour of CLW estimtes from microwave imager (TRMM 2A12) and radar reflectivity (TRMM precipitation radar). We also find that the proposed interactive aerosol loading results in higher spatial variability in CLW and enhances the likelihood of increased cloud cover via formation of larger clouds. The modification also alters the diurnal cycle of clouds in break and break-to-active phases as compared to other phases due to aerosol loading, with a stronger diurnal cycle of upper level clouds in these phases in the VaryingAero model as compared to ConstantAero model.

Study on Regional Variations of Aerosol Loading Using Long Term Satellite Data Over Indian Region

Satellite-based measurements of aerosols are one of the most effective ways to understand the role of aerosols in climate in terms of spatial and temporal variability. In the present study, we attempted to analyse spatial and temporal variations of satellite derived aerosol optical depth (AOD) over Indian region using moderate resolution imaging spectrometer over a period of 2001–2011. Due to its vast spatial extent, Indian region and adjacent oceanic regions are divided into different zones for analysis. The land mass is sub divided into five different zones such as Indo Gangetic Plain (IGP), Indian mainland, North Eastern India (NE), South India-1 (SI-1), South India-2 (SI-2). Oceanic areas are divided into Arabian Sea and Bay of Bengal. Arabian Sea is further divided as three zones viz. Northern AS (NAS), Central AS (CAS) and Eastern AS (EAS) zones. Bay of Bengal is divided as North BoB (NBoB), West BoB (WBoB), Central BoB (CBoB), and East BoB (EBoB). The study revealed that among all the land regions, IGP showed the highest peak AOD value (0.52 ± 0.17) while SI-2 showed the lower values of AOD in all the months compared to all India average. The maximum AOD is observed during premonsoon season for all regions. During the winter, average AOD levels were substantially lower than the summer averages. Peak of aerosol loading (0.35 ± 0.159) is observed in March over NE region, whereas in all other regions, peak is observed during May. Frequency distribution of long term AOD ( 0.5) shows a shift of frequency distribution of AOD from 0.5. Oceanic areas also shows seasonal variation of AOD. Over Arabian Sea, high AOD values with greater variations were observed in summer monsoon season while in Bay of Bengal it is observed during winter monsoon. This is due to the high wind speed prevailing in Arabian Sea during monsoon season which results in production of more sea salt aerosol. Highest AOD values are observed over NAS during monsoon season and over NBOB during winter season. Lowest AOD values with its lower variations observed in both the central region of Arabian Sea and Bay of Bengal.

Possible role of aerosols in the charge structure of isolated thunderstorms

The electric field and Maxwell current density measured below 32 small isolated thunderstorms over Pune (India) have been analyzed here. These data clearly show the presence of 10 out of 32 thunderstorms with inverted polarity charge structure. Values of Aerosol Optical Depth (AOD) on thunderstorm days taken from MODIS show that all the thunderstorms with inverted polarity occurred on days with significantly higher AOD compared to normal polarity thunderstorms. The peak flash rate did not show significant difference between normal polarity thunderstorms and inverted polarity thunderstorms. The dew point depression (DPD) during pre-monsoon thunderstorms shows good correlation with inverted polarity charge structure. Observations suggest that aerosol concentration plays an important role in the formation of inverted polarity charge structure in these thunderclouds. In presence of high aerosol concentration with adequate ice nuclei non-inductive charging mechanism can produce strong and wide spread positive charge region in the lower portion of cloud. However, observed good correlation of DPD with inverted polarity charge structure in the pre-monsoon period suggest that the effect of high cloud base height on inverted polarity charge structure as suggested by Williams et al. (2005) cannot be ruled out.

Viscosity and electric properties of water aerosols

The flow of water mist in a narrow duct has been studied experimentally. The profile of the velocity of drops has been measured, and the viscosity of the mist has been calculated using the Navier–Stokes equation. It has been found that at low gradients of the rate of shear the viscosity of the mist can exceed that of clean air by tens and even hundreds of times. The electric charge of the drops has been measured. It has been found that the viscosity of the mist differs from that of clean air at gradients of the rate of shear that are less than the frequency of the establishment of electric equilibrium between the drops. A comparative analysis of the viscosities of the mist and a drop cluster has been carried out, and the dependence of the viscosity of the water aerosol on the radius and the charge of the drops has been predicted. The possible role of aerosols that contain submicron drops in the known “clear air turbulence” problem has been shown.

Direct observations of shortwave aerosol radiative forcing at surface and its diurnal variation during the Asian dry season at southwest Indian peninsula

The Arabian Sea witnesses consistent occurrence of a large-scale aerosol plume transported by the northerlies from the Asian region during the dry season (December–April). This paper presents direct observations of the diurnal variation (and dependence on solar zenith angle, SZA) of instantaneous aerosol direct radiative forcing efficiency (IADRFE) and aerosol direct radiative forcing (ADRF) at surface during the period from December to March of 2010–2013 at Thiruvananthapuram (8.5°N, 77°E), an Indian peninsular station adjoining the Arabian Sea coast, which resides well within this aerosol plume. Magnitude of the IADRFE increases with SZA from −75 ± 20 W m−2τ500−1 at SZA of ~80° to attain a peak value of −170 ± 30 W m−2τ500−1 at SZA ~60° in March (~3 h before and after the local noon). Absolute magnitudes and SZA dependence of the observed seasonal mean IADRFE are in agreement (within 16 % of the absolute magnitudes) with those estimated using radiation transfer computations employing an aerosol model with visible band single-scattering albedo of ~0.90 ± 0.03. Observed values of the diurnal mean aerosol radiative forcing efficiency (ADRFE) averaged during the season (December–March) vary between −71 and −76.5 W m−2τ500−1, which is in agreement with the model estimate of −71 W m−2τ500−1. The present observations show that the seasonal mean ADRF at surface (−25 to −28 W m−2) is about 10 % of the diurnal mean downwelling shortwave flux reaching the surface (in the absence of aerosols) during dry season at this location, indicating the major role of aerosols in regulating surface energetics.