Robust Quantum Research Articles

Bound-State Relativistic Quantum Electrodynamics: A Perspective for Precision Physics with Atoms and Molecules.

Precision physics aims to use atoms and molecules to test and develop the fundamental theory of matter, possibly beyond the Standard Model. Most of the atomic and molecular phenomena are described by the quantum electrodynamics (QED) sector of the Standard Model. Do we have the computational tools, algorithms, and practical equations for the most possible complete computation of atoms and molecules within the QED sector? What is the fundamental equation to start with? Is it still Schrödinger's wave equation for molecular matter, or is there anything beyond that? This paper provides a concise overview of the relativistic QED framework and recent numerical developments targeting precision physics and spectroscopy applications with common features of the robust and successful relativistic quantum chemistry methodology.

Realization of robust quantum noise characterization in the presence of coherent errors

Complex quantum systems and their various applications are susceptible to noise of coherent and incoherent nature. Characterization of noise and its sources is an open, key challenge in quantum technology applications, especially in terms of distinguishing between inherent incoherent noise and systematic coherent errors. In this paper, we study a scheme of repeated sequential measurements that enables the characterization of incoherent errors by reducing the effects of coherent errors. We demonstrate this approach using a coherently controlled nitrogen vacancy in diamond, coupled to both a natural nuclear spin bath (non-Markovian) and to experimentally controlled relaxation through an optical pumping process (nearly Markovian). Our results show mitigation of coherent errors both for Markovian and non-Markovian incoherent noise profiles. We apply this scheme to the estimation of the dephasing time (T2*) due to incoherent noise. We observe an improved robustness against coherent errors in the estimation of dephasing time (T2*) compared to the standard (Ramsey) measurement.

Fourier transform noise spectroscopy

Spectral characterization of noise environments that lead to the decoherence of qubits is critical to developing robust quantum technologies. While dynamical decoupling offers one of the most successful approaches to characterize noise spectra, it necessitates applying large sequences of π pulses that increase the complexity and cost of the method. Here, we introduce a noise spectroscopy method that utilizes only the Fourier transform of free induction decay or spin echo measurements, thus removing the need for the application many π pulses. We show that our method faithfully recovers the correct noise spectra for a variety of different environments (including 1/f-type noise) and outperforms previous dynamical decoupling schemes while significantly reducing their experimental overhead. We also discuss the experimental feasibility of our proposal and demonstrate its robustness in the presence of statistical measurement error. Our method is applicable to a wide range of quantum platforms and provides a simpler path toward a more accurate spectral characterization of quantum devices, thus offering possibilities for tailored decoherence mitigation.

A fast and robust quantum random number generator with a self-contained integrated photonic randomness core

A fast and robust quantum random number generator with a self-contained integrated photonic randomness core

Non-Hermitian CHSH* Game with a Single Trapped-Ion Qubit

Abstract The Clauser–Horne–Shimony–Holt (CHSH) game provides a captivating illustration of the advantages of quantum strategies over classical ones. In a recent study, a variant of the CHSH game leveraging a single qubit system, referred to as the CHSH* game, has been identified. We demonstrate that this mapping relationship between these two games remains effective even for a non-unitary gate. Here we delve into the breach of Tsirelson’s bound in a non-Hermitian system, predicting changes in the upper and lower bounds of the player’s winning probability when employing quantum strategies in a single dissipative qubit system. We experimentally explore the impact of the CHSH* game on the player’s winning probability in a single trapped-ion dissipative system, demonstrating a violation of Tsirelson’s bound under the influence of parity-time ( P T ) symmetry. These results contribute to a deeper understanding of the influence of non-Hermitian systems on quantum games and the behavior of quantum systems under P T symmetry, which is crucial for designing more robust and efficient quantum protocols.

Engineering the Kitaev Spin Liquid in a Quantum Dot System.

The Kitaev model on a honeycomb lattice may provide a robust topological quantum memory platform, but finding a material that realizes the unique spin-liquid phase remains a considerable challenge. We demonstrate that an effective Kitaev Hamiltonian can arise from a half-filled Fermi-Hubbard Hamiltonian where each site can experience a magnetic field in a different direction. As such, we provide a method for realizing the Kitaev spin liquid on a single hexagonal plaquette made up of 12 quantum dots. Despite the small system size, there are clear signatures of the Kitaev spin-liquid ground state, and there is a range of parameters where these signatures are predicted, allowing a potential platform where Kitaev spin-liquid physics can be explored experimentally in quantum dot plaquettes.

Universal and robust quantum coherent control based on a chirped-pulse driving protocol

Universal and robust quantum coherent control based on a chirped-pulse driving protocol

Topologically protected subradiant cavity polaritons through linewidth narrowing enabled by dissipationless edge states

Cavity polaritons derived from strong light–matter interaction provide a basis for efficient manipulation of quantum states via cavity field. Polaritons with narrow linewidth and long lifetime are appealing in applications, such as quantum sensing and storage. Here, we propose a prototypical arrangement to implement a whispering-gallery-mode resonator with one-dimensional topological atom mirror, which allows to boost the lifetime of cavity polaritons over an order of magnitude. This considerable enhancement attributes to the coupling of polaritonic states to dissipationless edge states protected by the topological bandgap of atom mirror that suppresses the leakage of cavity modes. When exceeding the width of Rabi splitting, topological bandgap can further reduce the dissipation from polaritonic states to bulk states, giving arise to subradiant cavity polaritons with extremely sharp linewidth. The resultant Rabi oscillation experiences decay rate lower than the free-space decay of a single quantum emitter. Inheriting from the topologically protected properties of edge states, the subradiance of cavity polaritons can be preserved in disordered atom mirror with moderate perturbations involving the atomic frequency, interaction strengths and location fluctuations. Our work opens up a new paradigm of topology-engineered quantum states with robust quantum coherence for future applications in quantum computing and network.

Topological protection of dual-polarization biphoton states in photonic crystals

Polarization control is a major issue in topological quantum optics that limits reliable generation and transmission of quantum states. This study presents what we believe to be a novel topological photonic crystal design that provides topological protection for biphoton pairs for both TE and TM polarization. By well-designed cell configurations within the lattice, two topological boundaries emerge that can accommodate TM and TE modes at the same time. By adjusting the dispersion curves, we can further design nonlinear four-wave mixing processes within the topological photonic crystals and provide theoretical explanations for the entanglement of the dual-polarization biphoton states. Numerical results confirm the robust transport of entangled photon pairs, even when subjected to sharp bending. Moreover, combining the dual-polarization topological photonic crystal with a polarization beam splitter enables the preparation of polarization-encoded maximally entangled states. Our work exhibits significant potential for applications in robust optical quantum information processing and quantum secure communication.

Photoactivated Circularly Polarized Luminescent Organic Radicals in Doped Amorphous Polymer

AbstractLuminescent organic radicals, especially those with photoactivated circularly polarized luminescence (CPL) features, hold great significance for cutting‐edge optoelectronic applications, but their development still remains a challenge. In this study, we propose a novel strategy to achieve photoactivated CPL radicals by bonding two phosphine centers within an axial chiral system, yielding a compound of R/S‐5,5‐bis(diphenylphosphino)‐4,4′‐bibenzo[d][1,3]dioxole (R/S‐BDP). The photoactivated R/S‐BDP molecules in polymer matrix display a robust quantum yield of 19.8 % and a dissymmetry factor (glum) of 1.2×10−4, marking this work as the first example of photoactivated CPL radicals. Furthermore, the glum is improved to 1.0×10−2 by using a liquid crystal as host. Experimental and theoretical analyses reveal that R/S‐BDP molecules, endowed with double phosphine cores in axial chirality, offer a direct way for intramolecular electron transfer upon photoirradiation. This leads to the generation of radical ionic pairs, which subsequently trigger the donor‐acceptor arrangement through intermolecular electron transfer, thereby resulting in stable radical emission. The extended photoactivated BDP‐F exhibits a remarkably high quantum efficiency of 57.8%. Ultimately, the distinctive photo‐responsive CPL radical luminescence has been successfully used for information displays and anti‐counterfeiting.

Photoactivated Circularly Polarized Luminescent Organic Radicals in Doped Amorphous Polymer.

Luminescent organic radicals, especially those with photoactivated circularly polarized luminescence (CPL) features, hold great significance for cutting-edge optoelectronic applications, but their development still remains a challenge. In this study, we propose a novel strategy to achieve photoactivated CPL radicals by bonding two phosphine centers within an axial chiral system, yielding a compound of R/S-5,5-bis(diphenylphosphino)-4,4'-bibenzo[d][1,3]dioxole (R/S-BDP). The photoactivated R/S-BDP molecules in polymer matrix display a robust quantum yield of 19.8 % and a dissymmetry factor (glum) of 1.2×10-4, marking this work as the first example of photoactivated CPL radicals. Furthermore, the glum is improved to 1.0×10-2 by using a liquid crystal as host. Experimental and theoretical analyses reveal that R/S-BDP molecules, endowed with double phosphine cores in axial chirality, offer a direct way for intramolecular electron transfer upon photoirradiation. This leads to the generation of radical ionic pairs, which subsequently trigger the donor-acceptor arrangement through intermolecular electron transfer, thereby resulting in stable radical emission. The extended photoactivated BDP-F exhibits a remarkably high quantum efficiency of 57.8%. Ultimately, the distinctive photo-responsive CPL radical luminescence has been successfully used for information displays and anti-counterfeiting.

Topologically Protected Quantum Logic Gates with Valley-Hall Photonic Crystals.

Topological photonics provide a promising way to realize more robust optical devices against some defects and environmental perturbations. Quantum logic gates are fundamental units of quantum computers, which are widely used in future quantum information processing. Thus, constructing robust universal quantum logic gates is an important way forward to practical quantum computing. However, the most important problem to be solved is how to construct the quantum-logic-gate-required 2×2 beam splitter with topological protection. Here, the experimental realization of the topologically protected contradirectional coupler is reported, which can be employed to realize the quantum logic gates, including control-NOT and Hadamard gates, on the silicon photonic platform. These quantum gates not only have high experimental fidelities but also exhibit a certain degree of tolerances against certain types of defects. This work paves the way for the development of practical optical quantum computations and signal processing.

Multiple classical noise mitigation by multiobjective robust quantum optimal control

Multiple classical noise mitigation by multiobjective robust quantum optimal control

Robust Classical and Quantum Polarimetry with a Single Nanostructured Metagrating.

We formulate a new conceptual approach for one-shot complete polarization state measurement with nanostructured metasurfaces applicable to classical light and multiphoton quantum states by drawing on the principles of generalized quantum measurements based on positive operator-valued measures. Accurate polarization reconstruction from a combination of photon counts or correlations from several diffraction orders is robust with respect to even strong fabrication inaccuracies, requiring only a single classical calibration of the metasurface transmission. Furthermore, this approach operates with a single metagrating without interleaving, allowing for a reduction in metasurface size while preserving high transmission efficiency and output beam quality. We theoretically obtained original metasurface designs, fabricated the metasurface from amorphous silicon nanostructures deposited on glass, and experimentally confirmed accurate polarization reconstruction of laser beams. We also anticipate robust operation under changes in environmental conditions, opening new possibilities for space-based imaging and satellite optics.

High-fidelity and Robust Stimulated Raman Transition with Parameter-modulated Optimal Control

High-fidelity and robust quantum control is essential for large-scale quantum information processing. The stimulated Raman transition that utilizes second-order coupling effect is a valuable and conventional technique for manipulating states in multi-level quantum systems, but its accuracy is limited by the driving-induced Stark shift. Here, we propose a new parameter-modulated method to effectively compensate the Stark-shift effect, so that we are able to realize high-fidelity and robust stimulated Raman transition with optimal control. Additionally, its robustness against different systematic errors can be further improved via optimization its average fidelity under these specific errors. Besides, our method has potential applications for high-fidelity and robust quantum control in high-order coupling scenarios.

De Broglie-Bohm analysis of a nonlinear membrane: From quantum to classical chaos.

Within the de Broglie-Bohm theory, we numerically study a generic two-dimensional anharmonic oscillator including cubic and quartic interactions in addition to a bilinear coupling term. Our analysis of the quantum velocity fields and trajectories reveals the emergence of dynamical vortices. In their vicinity, fingerprints of chaotic behavior such as unpredictability and sensitivity to initial conditions are detected. The simultaneous presence of the off-diagonal -kxy and nonlinear terms leads to robust quantum chaos very analogous to its classical version.

Rapid Synthesis of Chiral Figure‐Eight Macrocycles Using a Preorganized Natural Product‐Based Scaffold

AbstractChiral D2‐symmetric figure‐eight shaped macrocycles are promising scaffolds for amplifying the chiroptical properties of π‐conjugated systems. By harnessing the inherent and adaptable conformational dynamics of a chiral C2‐symmetric bispyrrolidinoindoline (BPI) manifold, we developed an enantio‐divergent modular synthetic platform to rapidly generate a diverse range of chiral macrocycles, spanning from 14‐ to 66‐membered rings, eliminating the need for optical resolution. Notably, a 32‐membered figure‐eight macrocycle showed excellent circularly polarized luminescence (CPL: |glum|=1.1×10−2) complemented by a robust emission quantum yield (Φfl=0.74), to achieve outstanding CPL brightness (BCPL: ϵ×Φfl×|glum|/2=480). Using quadruple Sonogashira couplings, this versatile synthetic platform enables precise adjustments of the angle, distance, and length among intersecting π‐conjugated chromophores. Our synthetic strategy offers a streamlined and systematic approach to significantly enhance BCPL values for a variety of chiral D2‐symmetric figure‐eight macrocycles.

Rapid Synthesis of Chiral Figure-Eight Macrocycles Using a Preorganized Natural Product-Based Scaffold.

Chiral D2 -symmetric figure-eight shaped macrocycles are promising scaffolds for amplifying the chiroptical properties of π-conjugated systems. By harnessing the inherent and adaptable conformational dynamics of a chiral C2 -symmetric bispyrrolidinoindoline (BPI) manifold, we developed an enantio-divergent modular synthetic platform to rapidly generate a diverse range of chiral macrocycles, spanning from 14- to 66-membered rings, eliminating the need for optical resolution. Notably, a 32-membered figure-eight macrocycle showed excellent circularly polarized luminescence (CPL: |glum |=1.1×10-2 ) complemented by a robust emission quantum yield (Φfl =0.74), to achieve outstanding CPL brightness (BCPL : ϵ×Φfl ×|glum |/2=480). Using quadruple Sonogashira couplings, this versatile synthetic platform enables precise adjustments of the angle, distance, and length among intersecting π-conjugated chromophores. Our synthetic strategy offers a streamlined and systematic approach to significantly enhance BCPL values for a variety of chiral D2 -symmetric figure-eight macrocycles.

Terahertz linear/non-linear anomalous Hall conductivity of moiré TMD hetero-nanoribbons as topological valleytronics materials

Twisted moiré van der Waals heterostructures hold promise to provide a robust quantum simulation platform for strongly correlated materials and realize elusive states of matter such as topological states in the laboratory. We demonstrated that the moiré bands of twisted transition metal dichalcogenide (TMD) hetero-nanoribbons exhibit non-trivial topological order due to the tendency of valence and conduction band states in K valleys to form giant band gaps when spin-orbit coupling (SOC) is taken into account. Among the features of twisted WS2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document}/MoS2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document} and WSe2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document}/MoSe2\\documentclass[12pt]{minimal} \\usepackage{amsmath} \\usepackage{wasysym} \\usepackage{amsfonts} \\usepackage{amssymb} \\usepackage{amsbsy} \\usepackage{mathrsfs} \\usepackage{upgreek} \\setlength{\\oddsidemargin}{-69pt} \\begin{document}$$_2$$\\end{document}, we found that the heavy fermions associated with the topological flat bands and the presence of strongly correlated states, enhance anomalous Hall conductivity (AHC) away from the magic angle. By band analysis, we showed that the topmost conduction bands from the ± K-valleys are perfectly flat and carry a spin/valley Chern number. Moreover, we showed that the non-linear anomalous Hall effect in moiré TMD hetero-nanoribbons can be used to manipulate terahertz (THz) radiation. Our findings establish twisted heterostructures of group-VI TMD nanoribbons as a tunable platform for engineering topological valley quantum phases and THz non-linear Hall conductivity.

Quantum Financial Modeling on Noisy Intermediate-Scale Quantum Hardware: Random Walks Using Approximate Quantum Counting

Quantum computers are expected to contribute more efficient and accurate ways of modeling economic processes. Quantum hardware is currently available at a relatively small scale, but effective algorithms are limited by the number of logic gates that can be used, before noise from gate inaccuracies tends to dominate results. Some theoretical algorithms that have been proposed and studied for years do not perform well yet on quantum hardware in practice. This encourages the development of suitable alternative algorithms that play similar roles in limited contexts. This paper implements this strategy in the case of quantum counting, which is used as a component for keeping track of position in a quantum walk, which is used as a model for simulating asset prices over time. We introduce quantum approximate counting circuits that use far fewer 2-qubit entangling gates than traditional quantum counting that relies on binary positional encoding. The robustness of these circuits to noise is demonstrated. While this paper is mainly about robust simplified quantum circuit designs, we compare some aspects of the results with price change distributions from stock indices, and compare the behavior of circuits with and without mid-measurement to trends in the housing market.