Rheological Effects Research Articles

A viscoelastic–plastic constitutive model incorporating creep initiation stress for surrounding rock in deep roadways and its practical application

AbstractWith the increasing depth of engineering in rock masses, the issue of significant rheological deformation becomes notably prominent. To accurately characterize the deformation and failure behavior of the surrounding rock near the goaf in deep small coal pillars, we have developed a viscoelastic–plastic constitutive model that takes into account the initial stress associated with creep. This model builds upon an existing viscoelastic–plastic constitutive framework and is implemented numerically using C++ in the FLAC3D. The Oedometer test method is used to check the creep components and the calculated parameter (η/G) ensure convergence of numerical operations. We conducted both pre‐improvement and post‐improvement tests of the constitutive model in a simple numerical analysis of roadways. The enhanced model demonstrates improved accuracy in deviational stress calculations and proves suitable for modeling deep, soft roadways. Furthermore, we applied the improved model to simulate actual working conditions at Zhaozhuang Mine, where mining operations near the working face induce a fracture zone of approximately 3 m in the small coal pillar located at the goaf's edge. The new model closely aligns with the observed results, further validating its suitability for tunneling along the goaf. Tunneling and mining activities result in significant deformation at various locations, including the shoulder socket of the working face, the top angle of the coal pillar, and the bottom angle of the floor. The crushing zone at the working face extends up to 4 m. Rheological effects transform the triangular elastic core, from its original high‐pressure elastic state to a fracture and plastic zone in the deep coal. Stress in deep coal is transmitted along the triangular elastic core. Numerical simulation results closely match the excavation profile of the tunneling, providing valuable insights into the impact of mining activities. This study can provide reference for deformation of similar geological conditions and engineering situation.

Rheological effects of montmorillonite and ethyl cellulose for Xanthoceras sorbifolium Bunge oil-based lubricants

Xanthoceras sorbifolium Bunge oil exhibits favorable characteristics such as excellent low temperature fluidity, high flash point, and degradability. However, it also suffers from drawbacks including low kinematic viscosity at low temperatures and significant loss of kinematic viscosity at high temperatures. In view of these characteristics of X. sorbifolium oil, it was modified in this work with a combination of ethyl cellulose (EC), montmorillonite (MMT), and cetyltrimethylammonium chloride (CTAB). The effects of temperature, time, and additive content on the rheological properties of lubricating oil were studied. The kinematic viscosity of the prepared lubricating oil reached up to 433 mm2/s at 40 °C and 51.1 mm2/s at 100 °C. The coagulation point could be reduced to -25 °C, the friction coefficient was 0.026, and the average wear spot diameter was 0.81 mm, The anti-friction performance was enhanced, and the anti-wear performance decreased somewhat. The prepared lubricating oil had the characteristics of high kinematic viscosity at high temperature and excellent rheological properties at low temperature. It also met the energy and environmental application requirements of a green, environmentally friendly, and biodegradable sustainable development strategy. This study greatly broadens the application range of lubricating oil.

Pickering emulsions for stimuli-responsive transdermal drug delivery: effect of rheology and microstructure on performance.

This work investigates the design of stimuli-responsive Pickering emulsions (PEs) for transdermal drug delivery applications, by exploring the impact of stabilising microgels size and interactions on their rheological and release properties. Temperature-responsive poly(N-isopropylacrylamide) microgels modified with 1-benzyl-3-vinylimidazolium bromide (pNIPAM-co-BVI) are synthesized in varying sizes and used to stabilise jojoba oil-in-water concentrated emulsions. The results reveals two distinct behaviours: for small microgels (∼300 nm), the PEs exhibit a smooth, uniform structure characterised by a mild yield stress, characteristic of soft glassy systems. Conversely, larger microgels (∼800 nm) induce droplet clustering, resulting in increased elasticity and a more complex yielding process. Interestingly, transdermal delivery tests demonstrate that microstructure, rather than bulk rheology, governs sustained drug release. The release process can be modelled as diffusion-controlled transport through a porous medium with random traps. At room temperature, the trap size corresponds to the droplet size, and the release time scales with the total dispersed phases volume fraction. However, at physiological temperature (37 °C), above the volume-phase transition temperature of the microgels, the release time increases significantly. The trap size approaches the microgel size, suggesting that microgel porosity becomes the dominant factor controlling drug release. Overall, the results highlight the critical role of microstructure design in optimising stimuli-responsive PEs for controlled transdermal drug delivery.

HYBRIDIZATION OF THE LINEAR VISCOELASTIC CONSTITUTIVE EQUATION AND A NONLINEAR MAXWELL-TYPE VISCOELASTOPLASTIC MODEL, AND ANALYSIS OF EVOLUTION SCENARIOS OF THE TRANSVERSE STRAIN COEFFICIENT UNDER CREEP

In this work, a generalization of a physically nonlinear Maxwell-type viscoelastoplastic constitutive equation with four material functions is formulated, whose general properties and range of applicability were discussed in a series of our previous studies. In order to expand the range of rheological effects and materials that can be described by the equation, it is proposed to add a third strain component expressed by a linear integral Boltzmann-Volterra operator with arbitrary functions of shear and volumetric creep. For generality and for the convenience of using the model, as well as for fitting the model to various materials and simulated effects, a weight factor (degree of nonlinearity) is introduced into the constitutive equation, which allows combining the original nonlinear equation and the linear viscoelastic operator in arbitrary proportions and controlling the degree of different effects simulated. Equations are derived for families of creep curves (volumetric, shear, longitudinal and transverse) induced by the proposed constitutive equation with six arbitrary material functions, and an expression is obtained for the transverse strain coefficient as a function of time. Their general properties and dependence on loading parameters and characteristics of all material functions are studied analytically and compared with the properties of similar relations generated by two combined constitutive equations separately. New qualitative effects are identified which can be described by the new constitutive equation in comparison with the original ones, and it is verified that the generalization eliminates some shortcomings of the Maxwell-type viscoelastoplastic constitutive equation, but retains its valuable features. It is confirmed that the proposed constitutive equation is capable of simulating sign alternation, monotonic and nonmonotonic changes in transverse deformation and transverse strain coefficient under constant stress, and their stabilization over time. Generally accurate estimates are obtained for the variation range, monotonicity and nonmonotonicity conditions of Poisson’s ratio, and its negativity criterion over a certain time interval. It is proven that neglecting volumetric creep (the postulate of volumetric elasticity), which simplifies the constitutive equation, greatly limits the range of possible evolution scenarios of the transverse strain coefficient in time: it increases and cannot have extremum and inflection points. The analysis shows that the proposed constitutive equation provides ample opportunities for describing various properties of creep and recovery curves of materials and various evolution scenarios of the transverse strain coefficient during creep. It can significantly expand the range of described rheological effects, the range of applicability of the Maxwell-type viscoelastoplastic equation, and deserves further research and application in modeling.

Rheological effects on purely-elastic flow asymmetries in the cross-slot geometry.

Viscoelastic flows in the cross-slot geometry can undergo a transition from a steady symmetric to a steady asymmetric flow state, ostensibly due to purely-elastic effects arising beyond a critical flow rate, or Weissenberg number Wi. However, some reports suggest that shear thinning of the fluid's viscosity may also play an important role in this transition. We employ a series of polymer solutions of varying rheological properties to investigate in detail how the interplay between fluid elasticity and shear thinning affects the onset and development of asymmetric flows in the cross-slot. Flow velocimetry is performed on each of the polymer solutions, and is used to assess the degree of flow asymmetry I in the cross-slot as a function of both Wi and a dimensionless parameter S quantifying the flow-rate-dependent extent of shear thinning. Typically, the flow field breaks symmetry as Wi is increased beyond a critical value, but the magnitude of I is found to also be dependent on S. For a few specific polymer solutions, the flow field recovers symmetry above a second, higher critical Wi as S becomes small. The experimental results are summarized in a flow state diagram in Wi-S space, showing the relationship between flow asymmetry and fluid rheology. Finally, to gain a deeper understanding of the effects of shear thinning, numerical simulations are performed using the linear simplified Phan-Thien-Tanner model. We demonstrate that the degree of both shear thinning and elasticity of the fluid, and their interplay, are important factors controlling elastic instabilities in the cross-slot geometry.

Numerical and experimental investigation on ball motion with oil rheology and thermal effect in high speed ball bearings

Dynamic behavior of rolling elements determines the performance including the extent of skidding and wear in ball bearings, which are influenced by many factors. A comprehensive investigation of dynamic behaviors of high speed ball bearings has been conducted both numerically and experimentally. The dynamic model of high speed ball bearings applicable to a wide range of shaft speeds has been developed, taking into account rheological behavior of lubricating oil, curvature effect, collision between balls and cage and thermal effect. Analyses of ball speeds and interaction forces, as well as sliding speed within ball-raceway contact ellipse have been carried out. The ball-to-race ratio (BRR) of speed has been studied specifically under various operating conditions to reflect the cage speed with high precision. A set of experiments have accordingly been performed on a test rig where optic fiber transducer was employed to obtain the orbital speed of ball. The increase of orbital speed of ball with shaft speed was observed in experiments under different axial load. Numerical results from dynamic simulations also agree with the experimental results based on the investigated ball bearing. The present model is versatile over a wide range of operating conditions.

The role of viscoplastic drop shape in impact

The impact of fluid drops on solid substrates is a cardinal fluid dynamics phenomenon intrinsically related to many fields. Although these impacting objects are very often non-spherical and non-Newtonian, previous studies have mainly focused on spherical Newtonian drops. As a result, both shape and rheological effects on the drop-spreading dynamics remain largely unexplored. In the present work we use a mixed approach combining experiments with multiphase three-dimensional numerical simulations to extend the work reported by Luu & Forterre (J. Fluid Mech., vol. 632, 2009, pp. 301–327) by highlighting the fundamental role of shape in the normal impact of viscoplastic drops. Such complex fluids are highly common in various industrial domains and ideally behave either like a rigid body or a shear-rate-dependent liquid, according to the stress solicitation. Spherical, prolate, cylindrical and prismatic drops are considered. The results show that, under negligible capillary effects, the impacting kinetic energy of the drop is dissipated through viscoplastic effects during the spreading process, giving rise to three flow regimes: (i) inertio-viscous, (ii) inertio-plastic, and (iii) mixed inertio-visco-plastic. These regimes are deeply affected by the drop initial aspect ratio, which in turn reveals the possibility of using drop shape to control spreading. The physical mechanisms driving the considered phenomenon are underlined by energy budget analyses and scaling laws. The results are summarised in a two-dimensional diagram linking the drop maximum spreading, minimum height and final shape with different spreading regimes through a single dimensionless parameter, here called the impact number.

Fibre alignment in fresh concrete with coarse aggregates and its visualization in transparent model concrete

Steel fibres distributed in concrete can greatly improve the mechanical performance of concrete, especially flexural and tensile behavior, if their orientations align to the direction of principal tensile stress. The study attempts to find diversified characters of fibre alignment in fresh concrete with consideration of adding coarse aggregates. A transparent concrete model, consisting of Carbopol gel, glass beads and crystals, is designed for the observation of fibre orientation. It shows good transparency and visibility, and can consider the effect of coarse aggregates since the volume fraction and particle size distribution of crystals are the same as coarse aggregates in real concrete mixture. The rheological properties of the model can be adjusted by the dosage of Carbopol and glass beads. Using this concrete model, the distribution and orientation of fibres can be directly observed and analyzed, considering the effect of aggregate sizes, concrete rheology and vibration time. The results show that coarse aggregates could limit the distribution space of fibres and lead to the decrease of fibre orientation coefficient. Fibre dispersion coefficient also decreases with the increase of aggregate sizes.

Geodetic slip rate partitioning in the central Anninghe and Daliangshan faults: Effects of fault geometry, elastic heterogeneity, and viscoelastic rheology

Geodetic measurements can be employed to estimate the secular slip rates and locking depths of crustal faults, two key parameters which influence assessment of long-term seismic hazard presented by a fault. However, this process requires making assumptions about the rheological properties of the Earth's crust and lithosphere, as well as the fault geometry at depth. Previous geodetic studies have inferred widely varying slip rates and locking depths for the central Xianshuihe-Xiaojiang Fault System, located along the southeastern margin of the Tibetan plateau. In this study, we use updated GNSS measurements, including 13 new velocities, to explore the effects of assumed rheology and fault geometry on the inferred slip rates and locking depths of the subparallel Anninghe (ANH) and Daliangshan (DLS) faults in this region. We demonstrate that only models taking into account the viscoelastic relaxation of the lower crust can resolve the apparent discrepancies. Models assuming a fully elastic rheology suggest very deep locking depths (∼35 km) and a lower slip rate on the ANH fault (∼5 mm/yr) than the DLS fault (∼7 mm/yr). Neither the relative slip rates nor the locking depths agree with seismic or geologic observations. We also consider models assuming a heterogeneous elastic rheology, but find they are indistinguishable from the homogeneous models. Modifying the fault geometry can impact the relative slip rates of the two faults but does not produce a reasonable locking depth either. In contrast, viscoelastic models accounting for seismic cycle effects indicate a faster ANH slip rate (∼5–7 mm/yr), a slower DLS rate (∼4–5 mm/yr), and a shallower locking depth for both faults (∼18 km), all of which are more consistent with independent seismic and geological observations. Our study suggests that steady long-term motion on these faults is modulated by long-lasting viscoelastic effects over a relatively broad region.

Effect of combined waste oils on the chemical, thermal, microscopic, and rheological properties of devulcanized waste tire rubber

This research investigates the influence of combined waste oils process variables, including the mass ratio of waste engine–cooking oil (WECO), medium reaction temperature for a constant reaction time, and waste tire rubber (WTR) mesh size, on the chemical properties, rheological properties, and thermal behavior of combined waste oil devulcanized WTR. The samples' chemical elements and bonding energy changes were characterized and their sol friction, thermal behavior, morphology, and rheological properties were analyzed. Different proportions of mixed WECO can devulcanize WTR under medium temperature. WECO with increased reaction temperature and waste engine oil improves WTR's devulcanization (mesh size: 80). The waste oil content significantly increased the WTR morphology quality and reduced its surface roughness. The de-crosslinked structure produced compound structural changeover. Thus, the rheological effects were significant. For devulcanized waste rubber engine–cooking oil, G* decreased gradually and δ° increased progressively, and its anti-fatigue performance increased as the fatigue factors decreased G* sin δ°.

Temperature dependance of 3D printed concrete produced with copper tailings

Abstract3D printed concrete is being applied in an increasing amount worldwide. While in theory, there are environmental and economic benefits associated with using this technology, in practice, the amount of cement in printable concrete is much higher than in a conventional one, leading to increased environmental and economic costs. Furthermore, cement's performance relies heavily on climate variables, specifically temperature. One way to solve this issue is to include local alternative low‐CO2 materials, such as processed mine tailings, as cement replacement. This paper presents an experimental approach to assess the use of copper tailings as cement replacement in printable concrete under different ambient temperatures. Three levels of cement volume replacement have been researched. The copper tailings' rheological effect has been measured using standard printability tests and a rheometer. Four mixtures have been printed in a controlled‐climate chamber to evaluate print‐ability, buildability and extrudability. The mechanical effect has been assessed with compressive and flexural strength tests of samples collected from the printed specimens. The results show that copper tailings are a promising alternative to cement in printable concrete in countries where this by‐product is abundant.

Doxorubicin/poly(caprolactone)/polyethylene glycol nanoparticles prepared by electrospray

AbstractThe development of sustainable drug delivery systems is very important in the field of pharmaceutical research and has many advantages over the usual methods of drug administration, including improving effectiveness, reducing side effects, and increasing patient compliance. Among various techniques, electrospraying as a voltage‐driven process has emerged as a promising technology for the fabrication of drug‐loaded nanoparticles. In recent years, the application of electrospray approach for drug release has been widely investigated. However, optimization of electrospray process parameters and development of mathematical models to predict drug release kinetics from microparticles are still challenging. To address these issues, a combination of Central Composite Design (CCD) and Response Surface Methodology (RSM) has been used. This paper focuses on the application of CCD‐RSM for modeling and optimization of doxorubicin (DOX)‐poly(caprolactone) (PCL)‐polyethylene glycol (PEG) microparticles prepared using electrospray method. Doxorubicin, a widely used anticancer drug, exhibits potent cytotoxicity against a wide range of cancers. PCL‐PEG microparticles are promising as drug carriers due to their biocompatibility, controlled release properties, and ability to protect the encapsulated drug from degradation. The CCD‐RSM approach allows systematic investigation and optimization of several formulation and process variables, including polymer concentration, PCL‐PEG weight ratio, and applied voltage on drug release behavior. In addition, the effect of rheology and electrical conductivity of polymer fluid on the size of particles obtained from electrospraying was investigated. The effect of adding folic acid and doxorubicin in the optimized sample of nanoparticles and the effect of different concentrations of doxorubicin were investigated, and SEM, DLS, and FTIR techniques were used to characterize the microparticles, and the MMT test was performed to evaluate their cytotoxicity. The results showed that the optimized formulation is effective for sustained drug release over a long period for drug delivery applications.

Vertical tearing of subducting plates controlled by geometry and rheology of oceanic plates

Lateral non-uniform subduction is impacted by continuous plate segmentation owing to vertical tearing of the subducting plate. However, the dynamics and physical controls of vertical tearing remain controversial. Here, we employed 3D numerical models to investigate the effects of trench geometry (offset by a transform boundary) and plate rheology (plate age and the magnitude of brittle/plastic strain weakening) on the evolution of shear stress-controlled vertical tearing within a homogenous subducting oceanic plate. Numerical results suggest that the trench offset geometry could result in self-sustained vertical tearing as a narrow shear zone within the intact subducting oceanic plate, and that this process of tearing could operate throughout the entire subduction process. Further, the critical trench offset length for the maturation of vertical tearing is impacted by plate rheology. Comparison between numerical modelling results and natural observations suggests that vertical tearing attributed to trench offset geometry is broadly developed in modern subduction and collision systems worldwide.

Calibration strategies for long-term strain forecasting in high-rise building columns

Concrete exhibits long-term time-dependent behavior due to creep and shrinkage that impacts the safety and serviceability of high-rise buildings. These rheological effects are difficult to predict due to their random nature, dependence on environmental conditions, and loading history. Current methods include the use of creep and shrinkage tests of structure-specific concrete samples to update compliance and shrinkage, and sophisticated numerical models for prediction of the long-term structural behavior. However, creep and shrinkage tests are time-consuming, and simulation requires reliable numerical models and often proprietary solvers that are not available to the structural health monitoring (SHM) practitioner. Further, uncertainty propagation in complex numerical models is rarely seen in the relevant literature. In contrast, data-driven prediction methods using SHM data and simplified analytical models have shown to be successful for prestressed concrete bridges. In this work, we investigate calibration strategies of creep and shrinkage models using SHM data toward data-driven forecasting of long-term time-dependent behavior of high-rise buildings. A calibration strategy is identified that enables significant and consistent improvement of forecasting of long-term time-dependent behavior. It is also shown that continuous calibration can provide good predictions at least 30 days ahead. First-order analytical uncertainty propagation formulas are also provided. The calibration strategies are evaluated on data from two residential high-rise buildings in Singapore. Recommendations to the SHM practitioners are also given.

Characteristics of temperature-dependent shear flow in an ultrasonicated ferrofluid

The rheological effect of manganese zinc (Mn-Zn) ferrite ferrofluid was studied and the impact of temperature on the magnetoviscosity and viscoelastic system of manganese-zinc ferrite ferrofluid generated by co-precipitation process is investigated. At 25 ◦C, a ferrofluid structure that is both hard and elastic is produced. As the temperature rises, the fluid structure loses its elasticity and becomes semi-rigid. When a low relaxation modulus is applied, the fluid behavior, which is temperature-dependent, exhibits the development of linear stress relaxation and steady state flow. When a greater relaxation modulus is used, non-steady state flow results. At a high temperature of 50 ◦C, steady state flow is quickly obtained, whereas at a low temperature, equilibrium or steady state is attained more slowly. At low temperatures, the fluid exhibits a solid-like structure, whereas at high temperatures, a liquid-like structure forms as the fluid’s viscosity decreases. With the creation of yield stress in the region with high shear rates, shear stress increases with temperature, and yield stress increases with temperature. The viscoelastic system is underdamped, and the amount of fluid deflected at 25 ◦C is small, which prevents the disruption of the fluid’s rheology. This develops as a result of the presence of a small deflection angle, which facilitates the development of high magnetoviscosity at low temperature. High viscous effect forms at low temperatures due to the creation of low shear stress and low deflection angle at temperature 25 ◦C. The sample has a single phase and FCC structure, which X-ray diffraction research has verified.

A model-based approach for evaluating the effects of sludge rheology on methane production during high solid anaerobic digestion: Focusing on mass transfer resistance

Mass transfer process is vital for biochemical reactions, which is related to sludge rheology. But this inherent interaction has not yet been established for sewage sludge anaerobic digestion (AD). This work investigated the role of sludge rheology in bio-kinetics of AD. AD of sodium acetate and microcrystalline cellulose under different total solids (TS of 6.29%, 7.63%, 9.02%, 11.06%) of digested sludge was set up to identify the role of sludge rheology. Results showed that rheological properties, e.g., viscosity and viscoelasticity, increased with the increase of TS content. These resulted in negative effect on methane production of sodium acetate with lag phase increased from 0.93 d to 1.57 d, but almost no effect was observed for microcrystalline cellulose. An extended ADM1 model was developed, which revealed that enhanced sludge rheological properties increased mass diffusion resistance and reduced uptake rate of acetate. This effect can be described explicitly by mass transfer coefficient (kla_Sac). However, from the original ADM1, this effect was indistinctly lumped in apparent half-saturation coefficient (ksac). Based on the role of sludge rheology in mass transfer and bio-kinetics, it is suggested that modeling the methane production based on TS contents and sludge rheology is possible, which should be considered in giving an insight into the micro-scale phenomena (e.g. mass transport, bio-kinetics) in high solid AD.

Viscos-elastic-plastic solution for deep buried tunnels considering tunnel face effect and sequential installation of double linings

Tunnels excavated in soft rock under high in situ stress are usually accompanied by large time-dependent deformation, slow convergence, and long periods of increased support load due to the strong rheological properties of the surrounding rock. This paper presents a time-dependent solution for deeply buried supported circular tunnels excavated in viscoelastic-plastic strain-softening rock masses, in which both the whole process of longitudinal excavation and the sequential installation of two elastic linings are considered. In the solution, the surrounding rock obeys a Burger-creep viscous elastic–plastic strain-softening model and two stages, referring to the “tunnel face influence stage” and the “creep stage”, are divided to derive the explicit expressions of the time-dependent tunnel convergences and support loads, in which the former stage accounts for the effect of stress release based on the elastic–plastic analysis, and the latter concentrates on the long-term response induced by the viscous behavior of the ground. To account for the different rock qualities, tunnel face advance rates, and lining tunnel support locations, the elastic–plastic strain-softening solution in the former stage is divided into three cases and the viscos-elastic–plastic solution in the creep stage includes two sub-solutions depending on the evolutions of stress paths being considered or not. For validation purposes, the provided analytical solutions are compared with the numerical results by finite-difference simulations and previous solutions. Following that, parametric studies are conducted to compare the stresses, deformations, and support loads under different stages and solutions. Finally, to further verify the applicability of the solutions in practical tunnels, the convergences, support loads and lining stresses of a typical tunnel cross-section in the Saint Martin La Porte access adit are successfully predicted. Overall, the proposed solutions in this study provide a profitable idea for deriving various viscoelastic-plastic or elasto-viscoplastic explicit solutions that can simultaneously account for both the rock rheology and tunnel face effect.

Electroconvective viscous fingering in a single polyelectrolyte fluid on a charge selective surface

When a low-viscosity fluid displaces into a higher-viscosity fluid, the liquid-liquid interface becomes unstable causing finger-like patterns. This viscous fingering instability has been widely observed in nature and engineering systems with two adjoined fluids. Here, we demonstrate a hitherto-unrealizable viscous fingering in a single fluid-solid interface. In a single polyelectrolyte fluid on a charge selective surface, selective ion rejection through the surface initiates i) stepwise ion concentration and viscosity gradient boundaries in the fluid and ii) electroconvective vortices on the surface. As the vortices grow, the viscosity gradient boundary pushes away from the surface, resulting viscous fingering. Comparable to conventional one with two fluids, i) a viscosity ratio (M) governs the onset of this electroconvective viscous fingering, and ii) the boundary properties (finger velocity and rheological effects) - represented by M, electric Rayleigh ({{Ra}}_{E}), Schmidt ({Sc}), and Deborah ({De}) numbers - determine finger shapes (straight v.s. ramified, the onset length of fingering, and relative finger width). With controllable onset and shape, the mechanism of electroconvective viscous fingering offers new possibilities for manipulating ion transport and dendritic instability in electrochemical systems.

Effect of fiber properties and orientation on the shear rheology and Poynting effect in meat and meat analogues

The development of plant-based meat analogues is an important aspect of the transition towards using more plant proteins. Production of such products with texture (and rheology) adequate for consumer acceptance like meats is a great challenge. However, there is a current lack in quantitative methods to compare whole cut meats and plant-based analogues that also consider its fibrous structures. We tackled this problem by combining non-linear shear rheology and shear-induced normal stress measurements on whole cut meats (beef and chicken) and plant-based fibrous model systems for meat analogues (soy and pea protein isolates combined with wheat gluten). We found different response in the linear viscoelastic regime for different samples, and the non-linear viscoelastic regime provided a deeper understanding into the role of structural components. Meat samples showed rearrangements at small strains and lower energy dissipation, higher intracycle strain stiffening, and a larger normal stress response at large strains than plant-based fibrous products, due to more elastic fibers. The plant-based fibrous products behave more solid-like until a larger strain, but the fibrous structures break down at large deformations resulting in higher energy dissipation, and show a lower normal stress response than meat. We therefore explore the importance of fiber properties and orientation on the nonlinear rheology of fibrous model systems for meat analogues, and provide a robust methodology to quantitatively compare different mechanical responses of meat and plant-based fibrous meat analogues. These results thereby allow comparison and tuning mechanical responses of plant-based meat analogue products towards real meat.

Dynamic performance of newly developed environmentally friendly greases containing polysaccharide gums in rolling bearing

The present study explores the performance of novel vegetable oil-based greases containing polysaccharide gums as additives. Two series of greases with varying concentrations of gum acacia (GA) and guar gum (GG) are evaluated in a rolling bearing at various speeds and loads. The vibrations and shock pulse measurements (SPM) quantified the tribo-dynamics of the developed greases against two commercial greases used as the benchmark. The vibration and SPM assessment suggest that the newly developed eco-friendly greases are at par with the commercial ones; the performance varies with the concentration and type of gum. Where a cumulative effect of rheology and gum size seems to influence the vibrations, the entrainment of gums in the contact zone governs the SPM carpet values. The developed greases show great prospects as a sustainable, potential, and commercial alternative to existing environmentally unfriendly greases.