The packed bed energy storage system can solve the mismatch between solar energy supply and demand at a low cost. The physical properties of storage materials have a decisive impact on the performance of storage systems. Different scenarios may require different storage materials. Studying the impact of storage materials on storage characteristics is crucial. However, the comparative analysis and research on different TES materials are focused on characterization and numerical simulation but less on packed bed TES experiments. This paper evaluates the thermal durabilities of three materials, including sintered ore particles, alumina balls, and rock particles, through thermal cycling tests. Through packed bed heat storage experiments, the energy storage characteristics and thermocline evolution characteristics of three beds under different operating conditions are compared and analyzed. The results indicate that all materials exhibit excellent thermal durabilities. A larger bed voidage and smaller bed heat capacity are beneficial for thermal diffusion in the bed. When reverse charging, the natural convection of air in the bed enhances the convective heat transfer effect, resulting in a higher charging power. The existence of natural convection promotes the mixing of cold air and hot air in the tank, increases the irreversibility of the process, and leads to a significantly lower efficiency in reverse flow compared to that in forward flow. When changing the airflow direction, the system overall exergy efficiencies of SOP, alumina, and rock bed decrease from 74.1 %, 72.4 %, and 77.2 % to 47.0 %, 39.9 %, and 45.8 %, respectively. Regardless of the airflow direction, the smaller the bed voidage and the larger the bed heat capacity, the better the maintenance characteristics of the thermocline.