In this study, the dielectric properties were evaluated in the microwave region for a ZnNb2O6 (ZNO) matrix with added TiO2. X-ray diffraction analysis demonstrated that the addition of TiO2 to ZNO led to formation of the ZnTiNb2O8 (ZTNO) phase. Evaluation of the dielectric properties in the microwave region for the ZNO-ZTNO ceramic composites showed that the permittivity (εr) ranged between 23.08 and 26.19 and the dielectric loss (tan δ) was 7.20 × 10−5 to 3.25 × 10−4. The temperature coefficient of resonant frequency (τf) ranged from −97.64 ppm °C−1 to −62.93 ppm °C−1, thereby demonstrating that adding TiO2 increased the τf value. The ZNO-ZTNO composites were evaluated as dielectric resonator antennas and their far-field parameters obtained based on numerical simulations indicated a gain between 4.69 and 5.60 dBi, bandwidth of 125.00–164.00 MHz, and efficiency above 98%. These results demonstrate that the ceramics investigated in this study have great potential for application in devices that operate in the C-band.