Resonance Line Research Articles

A nanogold sensor test for tire wear chemicals based on the plasmon ruler approach

The release of tire wear substances in the environment is raising concerns about potential impacts on aquatic ecosystems. The purpose of this study was to develop a quick and inexpensive screening test for the following tire wear substances: 6-phenylphenyldiamine quinone (6-PPD quinone), hexamethoxymethylmelamine (HMMM), 1–3-diphenylguanidine (1,3-DPG), and melamine. A dual strategy consisting of nanogold (nAu) signal intensity and the plasmonic ruler principle was used based on the spectral shift from the unaggregated free-form nAu from 525 nm to aggregated nAu at higher wavelengths. The shift in resonance corresponded to the relative sizes of the tire wear substances at the surface of nAu: 6-PPD (560 nm), HMMM (590 nm), 1,3-DPG (620 nm), and melamine (660 nm) in a concentration-dependent manner. When present in mixtures, a large indiscriminate band between 550 and 660 nm with a maximum corresponding to the mean intermolecular distance of 0.43 nm from the tested individual substances suggests that all compounds indiscriminately interacted at the surface of nAu. An internal calibration methodology was developed for mixtures and biological extracts from mussels and biofilms and revealed a proportional increase in absorbance at the corresponding resonance line for each test compound. Application of this simple and quick methodology revealed the increased presence of melamine and HMMM compounds in mussels and biofilms collected at urban sites (downstream city, road runoffs), respectively. The data also showed that treated municipal effluent decreased somewhat melamine levels in mussels.Graphical

Photonic bound states in the continuum governed by heating.

A photonic crystal microcavity with the liquid crystal resonant layer tunable by heating has been implemented. The multiple vanishing resonant lines corresponding to optical bound states in the continuum are observed. The abrupt change in the resonant linewidth near the vanishing point can be used for temperature sensing.

Use of rational approximations for phonon density of states in evaluation of neutron thermal scattering law

We propose and explore a new analytical formulation for evaluation of Thermal Scattering Law (TSL) using continuous phonon spectra for neutron inelastic scattering. It involves approximating Phonon Density of States (PDOS) in terms of rational approximations in energy transfer. Debye Waller coefficient calculated with these forms are in reasonable agreement with LEAPR calculated values. TSL can be expanded as a power series, each term of which can be integrated analytically. The method leads to TSL being a series of exponential cosine integrals which again have closed rational forms in energy transfer. Their shapes are analogous to asymmetric resonance line shapes and show maxima for certain values of energy transfer which could correspond to phonon emission or absorption. The series is shown to be convergent and easy to compute as it does not involve any numerical integration. The approach is applied to Beryllium metal and Graphite which have vastly different PDOS shapes, and is shown to be capable of giving most of the trends shown by TSL and cross section results from NJOY nuclear code processing system, even with smaller number of power series terms. Since TSL can be calculated for both negative and positive energy transfer with equal ease, one can easily check for the validity of the approximation obeying Principle of Detailed Balance (PDB). The results overall have shown promise of our formulation in making a case for rapid calculations of TSL and also for using the rational forms in energy transfer for analysis of experimental/calculated PDOS data.

Fröhlich resonance splitting in hybrid GaN nanowire-Ag nanoparticle structures

Plasmonic nanoparticles (NPs) have attracted significant attention due to their unique optical properties and broad optoelectronic and photonic applications. We investigate modifications of emission in hybrid structures formed by 60 nm silver NPs and GaN planar nanowires (NWs). Bare GaN NWs exhibit photoluminescence (PL) spectra dominated by broad bands peaking at ∼3.44 eV and ∼3.33 eV, attributed to basal plane stacking faults. In hybrids, two new narrow PL lines appear at 3.36 and 3.31 eV, resulting in PL enhancement at these energies. While the 3.36 eV line in hybrid structures can be explained using the Fröhlich resonance approximation based on the electric dipole concept, the appearance of two features at 3.36 and 3.31 eV indicates the splitting of resonance lines. This phenomenon is explained in framework of theoretical model based on the interaction of the dipole with its charge image, taking into account the quadrupole moment of the silver sphere and the quadrupole field of the charge image. A good agreement is obtained between the calculated Fröhlich resonance frequencies and the experimental PL lines in hybrid structures.

Magnetic resonance frequency shifts in quantum magnetometers based on the phenomenon of the optical orientation of atoms

Subject of study. Magnetic resonance frequency shifts caused by spin exchange collisions involving optically oriented alkali atoms in the ground state are studied. Aim of study. Spin-exchange collisions involving optically oriented pairs of alkali atoms of different types are theoretically studied to determine the shifts in the magnetic resonance line frequencies as a function of temperature for various pairs of alkali atoms under various optical orientation conditions in order to determine optimum constraints for the construction of quantum magnetometers with optical pumping using mixtures of alkali atoms. Method. Collisions between optically oriented alkali atoms are analyzed within the framework of quantum scattering theory, and data on the interaction potentials of alkali-atom dimers are used to calculate the scattering phases for collisions involving these potentials and the imaginary parts of the complex spin-exchange cross-section. The resulting cross sections as a function of energy were used to determine the magnetic resonance frequency shifts as a function of temperature. Main results. The magnetic resonance line frequency shifts for the following pairs of alkali atoms were obtained as a function of temperature: 39K−133Cs, 39K−85Rb, and 133Cs−85Rb. The shift in the magnetic resonance line involving the F=1 hyperfine state for a 39K−85Rb alkali-atom pair was found to pass through zero near temperature 480 K. Practical significance. The results obtained in this paper can be used to develop zero-spin-exchange-shift quantum electronic devices based on the optical orientation of atoms. In particular, it is possible to develop co-magnetometers based on the optical orientation of alkali atoms.

Hubble Space Telescope Images of SN 1987A: Evolution of the Ejecta and the Equatorial Ring from 2009 to 2022

Supernova (SN) 1987A offers a unique opportunity to study how a spatially resolved SN evolves into a young SN remnant. We present and analyze Hubble Space Telescope (HST) imaging observations of SN 1987A obtained in 2022 and compare them with HST observations from 2009 to 2021. These observations allow us to follow the evolution of the equatorial ring (ER), the rapidly expanding ejecta, and emission from the center over a wide range in wavelength from 2000 to 11,000 Å. The ER has continued to fade since it reached its maximum ∼8200 days after the explosion. In contrast, the ejecta brightened until day ∼11,000 before their emission levelled off; the west side brightened more than the east side, which we attribute to the stronger X-ray emission by the ER on that side. The asymmetric ejecta expand homologously in all filters, which are dominated by various emission lines from hydrogen, calcium, and iron. From this overall similarity, we infer the ejecta are chemically well mixed on large scales. The exception is the diffuse morphology observed in the UV filters dominated by emission from the Mg ii resonance lines that get scattered before escaping. The 2022 observations do not show any sign of the compact object that was inferred from highly ionized emission near the remnant’s center observed with JWST. We determine an upper limit on the flux from a compact central source in the [O iii] HST image. The nondetection of this line indicates that the S and Ar lines observed with JWST originate from the O free inner Si–S–Ar-rich zone and/or that the observed [O iii] flux is strongly affected by dust scattering.

Quantum calculation of the pressure broadening of H and K lines of Ca+ calcium ion in a gaz of ground-state He helium atoms

In this theoretical study, we have conducted calculations to investigate the pressure broadening of the H ( 4 s 2 S 1 / 2 − 4 p 2 P 1 / 2 ) and the K ( 4 s 2 S 1 / 2 − 4 p 2 P 3 / 2 ) lines of the Ca + calcium ion in a gas of ground-state He helium atoms. The focus of our work is to determine the profiles of the pressure-broadened resonance lines and analyse their behaviour under the influence of binary collisions between Ca + ions and He atoms. To achieve this, we constructed accurate potential energy curves for the ground X 2 Σ 1 / 2 + and the excited D 2 Π 1 / 2 , D 2 Π 3 / 2 and E 2 Σ 1 / 2 + states. Additionally, we constructed the corresponding transition dipole moments based on the data obtained through high-level ab initio methods, including SA-CASSCF, MRCI, and SO coupling, with Davidson and BSSE corrections. The study spans a range of temperatures from 4000 K to 12,000 K and wavelengths from 200 nm to 500 nm . The theoretical profile is characterised by dominant free-free transitions. In the vicinity of the 436 nm wavelength position, there is a satellite peak in the red wing, attributed to the contribution of D 2 Π 1 / 2 ⟵ X 2 Σ 1 / 2 + and D 2 Π 3 / 2 ⟵ X 2 Σ 1 / 2 + transitions. Our findings are in good agreement with previous theoretical results.

Motion of Two-Dimensional Excitons in Momentum Space Leads to Pseudospin Distribution Narrowing on the Bloch Sphere.

Motional narrowing implies narrowing induced by motion; for example, in nuclear magnetic resonance, the thermally induced random motion of the nuclei in an inhomogeneous environment leads to a counterintuitive narrowing of the resonance line. Similarly, the excitons in monolayer semiconductors experience magnetic inhomogeneity: the electron-hole spin-exchange interaction manifests as an in-plane pseudomagnetic field with a periodically varying orientation inside the exciton band. The excitons undergo random momentum scattering and pseudospin precession repeatedly in this inhomogeneous magnetic environment, typically resulting in fast exciton depolarization. On the contrary, we show that such magnetic inhomogeneity averages out at high scattering rates due to motional narrowing. Physically, a faster exciton scattering leads to a narrower pseudospin distribution on the Bloch sphere, implying a nontrivial improvement in exciton polarization. The in-plane nature of the pseudomagnetic field enforces a contrasting scattering dependence between the circularly and linearly polarized excitons, providing a spectroscopic way to gauge the sample quality.

Miniaturized Microstrip Dual-Channel Diplexer Based on Modified Meander Line Resonators for Wireless and Computer Communication Technologies

There has been a lot of interest in microstrip diplexers lately due to their potential use in numerous wireless and computer communication technologies, including radio broadcasts, mobile phones, broadband wireless, and satellite-based communication systems. It can do this because it has a communication channel that can combine two distinct filters into one. This article presents a narrow-band microstrip diplexer that uses a stepped impedance resonator, a uniform impedance resonator, tiny square patches, and a meander line resonator. The projected diplexer might be made smaller than its initial dimensions by utilizing the winding construction. To model the microstrip diplexer topology for WiMAX and WIFI/WLAN at 1.66 GHz and 2.52 GHz, the Advanced Wave Research (AWR) solver was employed. It exhibited an insertion loss of 3.2 dB and a return loss of 16 dB for the first channel, while the insertion loss and return loss were 2.88 dB and 21 dB, respectively, for the second channel. When both filters were simulated, the band isolation was 31 dB. The projected microstrip diplexer has been fabricated using an FR4 epoxy laminate with dimensions of 32 × 26 mm2. The simulated S-parameters phase and group delay closely matched the measurements.

Nanocrystalline Iron Oxides with Various Average Crystallite Size Investigated Using Magnetic Resonance Method

A series of nanocrystalline iron oxide samples (M1–M5) which differ from each other in average crystallite size (from 26 to 37 nm) was studied. The raw material was nanocrystalline iron with an average crystallite size equal to 21 nm promoted with hardly reducible oxides: Al2O3, CaO, K2O (in total, max. 10 wt%). Nanocrystalline iron was subjected to oxidation with water vapor to achieve different oxidation degrees (α = 0.16–1.00). Metallic iron remaining in the samples after the oxidizing step was removed by etching. Magnetic resonance spectra of all samples were obtained at room temperature. All resonance lines were asymmetric and intense. These spectra were fitted by Lorentzian and Gaussian functions. All spectral parameters depend on the preparation method of the nanoparticles. We suppose that the Lorentz fit gives us a spectrum from larger agglomerated sizes whereas the Gaussian fit comes from much smaller magnetic centers. For the nanocrystalline samples with the largest size of iron oxide nanocrystallites, the highest value of total integrated intensity was obtained, indicating that at smaller sizes, they are more mobile in reorientation processes resulting in more settings of anti-parallel magnetic moments. The magnetic anisotropy should also increase with the increase in size of nanocrystallites.

Radiative transfer of excitation: Lévy flights and self-similarity

The Green function of the Biberman–Holstein integral equation, both nonstationary (instantaneous point flash) and stationary (stationary point source) is studied. The point flash produces a self-similar spherical wave of excitation in homogenous gas medium. The transfer of excitation is due to the Lévy flights of resonance line photons. The properties of the wave – its shape, time evolution and propagation – are found for arbitrary line profile. The cases of Doppler, Lorentz and Voigt profiles are considered in some detail. For the Doppler broadened line, the structure of the self-similar wave is given by a rational function. The properties of the Green function of stationary Biberman–Holstein equation are reviewed. Some unexpected parallels with non-stationary case are found. The spherically-symmetric version of the longest flight approximation is discussed and the condition of its validity is formulated.

Tune optimization for alleviating space charge effects and suppressing beam instability at the RCS of CSNS

The design betatron tune of the Rapid Cycling Synchrotron (RCS) of China Spallation Neutron Source (CSNS) is (4.86, 4.80), which allows for incoherent tune shifts to avoid serious systematic betatron resonances. When the operational bare tune was set at the design value, serious beam instability in the horizontal plane and beam loss induced by half-integer resonance in the vertical plane under space charge detuning were observed. Simulations and experiments have shown that space charge-induced beam loss reduces as the tunes move up and away from half-integer resonance lines. However, experimental observations have shown that instability growth rates increase rapidly as the tune approaches integer from below. The tune requirements for reducing the beam loss caused by space charge effects and suppressing beam instability are different at the RCS of CSNS. The tunes over the whole acceleration process are optimized based on space charge effects and beam instability. The optimized tune pattern was able to well control the beam loss induced by space charge and beam instability. The beam power of CSNS achieved the design value of 100 kW with small beam loss.

Emission Line Intensity Ratios of Fe xxvi/ xxv/ xxiv in Solar Flares Observed by Hinotori

High-resolution spectra observed by the Solar X-ray spectrometer on board the Hinotori mission are revisited. Flat crystals slightly offset to the satellite spin axis produce automatic spectral scans for emission lines emerging from highly charged iron ions in solar flares every half-spin time period. All the downlinked data of the mission are converted to FITS format and major flare spectral data are revived as IDL save files in ISAS/DARTS. Based on these data sets, single-temperature fits are performed for the emission line complex of highly charged iron ions in the wavelength range of 1.75–1.95 Å and compared with theoretical predictions. Synthetic spectra with single electron temperatures estimated from j/w line-intensity ratios fit fairly well for Fe xxiv and Fe xxiii lines in the wavelength range of 1.85–1.88 Å, while intensity ratios of Fe xxv lines (x, y, z) and the inner-shell excitation line of Fe xxiv (q) to the Fe xxv resonance line (w) have systematic excesses. Empirical relations for the observed line ratios are derived. Ion fractions of Fe+25/Fe+24 estimated by intensity ratios of Lyα/w in the temperature range of log T e =7.25–7.45 are consistent with values in ionization equilibrium, and the remaining excesses of the Fe xxv line ratios may suggest problems with the atomic parameters or atomic modeling.

Improvement of rejection band with Defected Microstrip Line and Ground plane Resonators

In this paper first a dual band bandstop filter is proposed using a unique spiral defect at the signal plane for Wi-Fi communication and remote sensing applications. The spiral defects is studied, simulated and measured. Next proposed spiral defect is combined with the hexagonal head defected resonators at ground plane to improve the rejection band. In addition a study is also done to observe the effects of the proposed defects at both signal plane and ground plane. A comparison is done among the response of individual defects filters and combined defect filter. It is observed that later shows improved overall bandwidth with compactness. The proposed combined defect filter with improved stopband displays 92.6% FBW and 112.5 dB/GHz sharpness factor with very compact in size as 0.26 λ0 × 0.25 λ0. All measurement results are in good agreement with the simulated results.

14N NMR of magnetically oriented microcrystals

14N NMR of magnetically oriented microcrystals is reported. With a home-built 1H–13C–14N probe capable of modulating the rotation of the sample around the axis normal to the magnetic field, magnetically oriented microcrystal suspension (MOMS) of l-alanine is made. 14N NMR spectra acquired with various timings during intermittent rotation lead to a rotation pattern of the MOMS similar to that of a single crystal. The effect of orientational distribution of the microcrystals to broadening of the resonance line is discussed.

High-frequency suppression of inductive coupling between flux qubit and transmission line resonator

Abstract We perform theoretical calculations to investigate the naturally occurring high-frequency cutoff in a circuit comprising a flux qubit coupled inductively to a transmission line resonator (TLR). Specifically, a decoupling occurs between the qubit and the high-frequency modes. The coupling strength between the qubit and resonator modes increases with mode frequency ω as ω at low frequencies and decreases as 1 / ω at high frequencies. This result is similar to those of past studies that considered somewhat similar circuit designs. By avoiding the approximation of ignoring the qubit-TLR coupling in certain steps in the analysis, we obtain effects not captured in previous studies. In particular, we obtain a resonance effect that shifts the TLR mode frequencies close to qubit oscillation frequencies. We derive expressions for the TLR mode frequencies, qubit-TLR coupling strengths and qubit Lamb shift. We identify features in the spectrum of the system that can be used in future experiments to test and validate the theoretical model.

Anisotropic magnetoresistance probed by non-resonant microwave absorption in exchange-biased NiFe/IrMn structures

Sharp change of non-resonant microwave absorption was found in exchange-biased NiFe/IrMn and NiFe/Cu/IrMn structures possessing anisotropic magnetoresistance (AMR) and planar Hall effect (PHE). Angular dependence of the microwave detected AMR and contribution of the domain expansion to AMR microwave signal were analyzed. Decrease in the microwave absorption signal caused by Cu spacer between ferromagnetic NiFe and antiferromagnetic IrMn layers was observed, when NiFe and IrMn layers become exchange decoupled. Additional characterization of the electric transport was proved by asymmetry of resonant line. Sensitivity of the microwave AMR method is enough high to detect magnetic fields of microTesla level, that provides remote detection with a sensitivity corresponding to standard galvanic sensors. Developed technique is promising for wireless AMR sensor technology providing coordinate and angular field measurements through remote microwave absorption.

Low-cost microstrip sensor based on coupled step line (CSL) resonator for blood plasma glucose determination

In this paper, a microstrip sensor structure was designed and implemented to detect blood glucose levels (BGL) based on changes in resonant frequencies, achieved by creating couplings at sensitive regions. A coupled step line was used to create a sensitive region on the sensor suitable for BGL testing. Transmission matrix theory was employed for the mathematical analysis to obtain the resonant frequency. Received blood samples from 50 different patients were centrifuged, and their serums were extracted to study the performance of the microchip sensor. By placing individual serum samples (50 µl) at the sensitive region of the sensor, the scattering parameters of the sensor were measured to investigate the resonant frequency variation. In addition, the effects of basic blood parameters were analyzed based on the amount of frequency shift. High sensitivity, suitable quality (Q) factor, compact size, and acceptable reproducibility of the measured results are important features of the developed sensor.

3D non-LTE modeling of the stellar center-to-limb variation for transmission spectroscopy studies

Context. Transmission spectroscopy is one of the most powerful techniques used to characterize transiting exoplanets, since it allows for the abundance of the atomic and molecular species in the planetary atmosphere to be measured. However, stellar lines may bias the determination of such abundances if their center-to-limb variations (CLVs) are not properly accounted for. Aims. This paper aims to show that three-dimensional (3D) radiation hydrodynamic models and the assumption of non-local ther-modynamic equilibrium (non-LTE) line formation are required for an accurate modeling of the stellar CLV of the Na I D1 and K I resonance lines on transmission spectra. Methods. We modeled the CLV of the Na I D1 and K I resonance lines in the Sun with 3D non-LTE radiative transfer. The synthetic spectra were compared to solar observations with high spatial and spectral resolution, including new data collected with the CRISP instrument at the Swedish 1-m Solar Telescope between µ = 0.1 and µ = 1.0. Results. Our 3D non-LTE modeling of the Na I D1 resonance line at 5896 Å and the K I 7699 Å resonance line in the Sun is in good agreement with the observed CLV in the solar spectrum. Moreover, the simulated CLV curve for a Jupiter-Sun system inferred with a 3D non-LTE analysis shows significant differences from the one obtained from a 1D atmosphere. The latter does indeed tend to overestimate the amplitude of the transmission curve by a factor that is on the same order of magnitude as a planetary absorption depth (i.e., up to 0.2%). Conclusions. This work highlights the fact that to correctly characterize exoplanetary atmospheres, 3D non-LTE synthetic spectra ought to be used to estimate the stellar CLV effect in transmission spectra of solar-like planet hosts. Moreover, since different spectral lines show different CLV curves for the same geometry of the planet-star system, it is fundamental to model the CLV individually for each line of interest. The work will be extended to other lines and FGK-type stars, allowing for synthetic high-resolution spectra to mitigate the stellar contamination of low-resolution planetary spectra, for example, those drawn from JWST.

New theoretical study of potassium perturbed by He and a comparison to laboratory spectra

The visible and near-infrared spectra of late L- and T-type dwarf stars are dominated in large part by the resonance lines of neutral Na and K. It is the collision broadening of these atomic lines by H2 and He in the stellar atmosphere that determines the continuum from below 0.5 µm to above 0.9 µm in the spectrum. Their line profiles can be detected as far as 3000 cm−1 from the line center in T dwarfs and consequently an accurate and detailed determination of the complete profile, including the extreme far wing, is required to model the contribution of these strong alkali resonance lines to brown dwarf spectra. We report on our new calculations of unified line profiles of K perturbed by He using ab initio potential data for the conditions prevailing in cool substellar brown dwarfs and hot dense planetary atmospheres with temperatures from Teff = 500 to 3000 K. For such objects with atmospheres of H2 and He, conventional laboratory absorption spectroscopy can be used to examine the line wings and test the line shape theories and molecular potentials. We find that an analytical Lorentzian profile is useful for a few cm−1 from the line center, but not in the line wings, where the radiative transfer is a consequence of the K–He radiative collisions that are sensitive to the interaction potentials. Tables of the K–He absorption coefficients of the resonance lines allow accurate model atmospheres and synthetic spectra. For this purpose, we present new opacities from comprehensive line shape theory incorporating accurate ab initio potentials. Use of these new tables for the modeling of emergent spectra will be an improvement over previous line shape approximations based on incomplete or inaccurate potentials. We also present Lorentzian impact parameters obtained in the semi-classical and quantum theory for the K 4s − 4p resonance line centered at 0.77 µm specifically for the line core regime.