Resistant Materials Research Articles

Ballistic characteristics of ceramic core sandwich structures

The ceramic core sandwich structure (CCSS) is a lightweight material with advantages of high anti-ballistic impact performance, high energy absorption and high specific strength. The ballistic performances of the CCSS with metal face plates hit vertically by projectiles with the nose shapes of conical, flat, and hemispherical are studied analytically and numerically in this paper. Based on the principle of energy conservation, an analytical model of ballistic characteristics of the sandwich ceramic core structure is developed. Numerical calculations are conducted, and the numerical model has been verified by experimental results from references by others. In addition, the analytical results agree well with finite element results. The effects of shape of projectile head, the thickness ratio of three plates of CCSS, and the ratio of shear strength of ceramic core to yield strength of metal face plates on the ballistic characteristics of the CCSS are discussed. It is shown that the conical-nosed projectile achieved the highest ballistic limit velocity (BLV) and the sharper nose increases the normal stress at the impact area thereby enhancing the BLV. The thickness of the ceramic core significantly influences the resistance of the CCSS and the thicker ceramic core enhances the ability of CCSS to absorb kinetic energy from the projectile. Furthermore, an appropriate increase in the yield strength of face plates can enhance the anti-ballistic impact performance of the CCSS. These insights have practical implications for the design of protective systems in military and civilian applications, where optimizing materials for impact resistance is crucial.

Selective Extraction of Terbium Using Functionalized Metal–Organic Framework-Based Solvent-Impregnated Mixed-Matrix Membranes

Advancements in membrane separation techniques will expand the applications and requirements for highly specialized, inventive, efficient, and resistant separation materials. The selective separation of rare earth elements (REEs) is one of the expanding applications of membrane-based techniques, as their use is becoming more widespread. Membrane techniques are becoming increasingly desired as environmentally friendly, straightforward methods for treating wastewater and separating metals. For the separation of REEs, an innovative impregnated mixed-matrix membrane (IMMM) technique was developed in this study. It provides a selective, efficient, and reusable method that is suitable for industrial applications. Terbium was selectively adsorbed from other REEs using organophosphorus IMMM with a loading capacity of 113.2 mg/g in 3 h and was reused three times without destroying the initial membrane. Solvent impregnation is thought to offer specific chelation sites that are selective for terbium separation.

Machine Learning Enabled High‐Throughput Screening of 2D Ultrawide Bandgap Semiconductors for Flexible Resistive Materials

AbstractThe 2D ultrawide bandgap (UWBG) semiconductors have attracted great attentions for the next generation of electronics and optoelectronics, owing to their superiority on material flexibility, device stability, and power consumption. However, few 2D UWBG semiconductors have been discovered, impeding their prosperous developments and widespread applications. Here, a high‐throughput workflow is constructed to screen 2D UWBG semiconductors assisted by machine learning, and 507 potential candidates are obtained. Moreover, by learning, predicting, and screening Young's modulus and Poisson's ratio, 31 flexible 2D UWBG semiconductors are identified. Then the generation and the diffusion of anion vacancies, as well as the corresponding electronic properties are investigated by using the first‐principles calculations, and 3 of them are demonstrated as the most promising candidates for the flexible resistive materials. The facile interface tunneling and the increased material conductance caused by the anion vacancies will contribute to the transition from high resistive state to low resistive state. This work provides an efficient high‐throughput screening protocol to enrich the family of 2D UWBG semiconductors and is expected to foster their practical applications.

Experimental study on effect of elastic-rigid composite boundary on shockwave from cavitation bubble collapse

Understanding the mechanisms behind the cavitation erosion resistance of elastic materials is the basis for the development of new cavitation erosion resistance materials. This paper employs underwater low-voltage discharge to induce cavitation bubble, combined with high-speed photography, shadowgraph methods, and transient pressure measurement systems to experimentally investigate the evolution and intensity of shockwave from bubble collapse near elastic-rigid composite boundary. Under the condition of constant elastic material thickness, with the bubble–wall distance increasing, shockwave shape evolves from multi-layers to single-layer. The peak pressure of the shockwave shows a trend of decreasing, then increasing, and finally stabilizing with increase in the bubble–wall distance. Furthermore, it was found that the elastic-rigid composite boundary causes the shockwave to reflect twice. As the material thickness increases, the intensity of the first reflected shockwave from the elastic surface decreases initially, then increases, and eventually stabilizes. However, that of the second reflected shockwave decreases. The total energy of the two reflections at the elastic interface is less than 4% of the mechanical energy of the bubble at its maximum volume. Finally, after the energy dissipation by the two reflections and material deformation, the elastic layer substrate withstands over 70% of the total mechanical energy of the cavitation bubble. There is an optimal elastic material thickness to minimize the shockwave load on the elastic layer substrate under the condition that the elastic-rigid composite boundary does not affect the evolution of cavitation bubble shape. These findings are significant for understanding bubble dynamics near elastic-rigid composite boundaries and provide theoretical support for developing cavitation erosion-resistant materials in engineering.

Tunable impact resistant materials: Synergistic enhancement of paraffin/MRP/re-entrant structures

In the realm of safety protection, there is a critical demand for materials capable of superior energy absorption and adaptability across diverse application scenarios. Here, this study presents integrated two-phase negative Poisson’s ratio (NPR) composites with adjustable mechanical properties sensitive to magnetic field, temperature and impact load. It is achieved by substituting the vacancy of re-entrant structures (frame phase) with soft paraffin/magnetorheological plastomer (MRP) fillers (matrix phase). The paraffin/MRP exhibits temperature-sensitive properties, enhanced magnetorheological (MR) effect (up to 4178%) and shear thickening (ST) effect (up to 2365%). Through quasi-static compression and dynamic impact tests, the composites demonstrate remarkable adaptability in impact resistance. Specifically, the first peak force exhibits responsiveness to changes in magnetic flux density, temperature, and impact velocity, with respective variations of 80.6%, 68.2%, and 30.3%. The design strategy paves the way for tunable impact resistant materials with potential for extreme environment buffering applications.

PERBANDINGAN KINERJA STRUKTUR KOLOM BULAT DAN KOLOM PERSEGI BETON BERTULANG TERHADAP BEBAN GEMPA DENGAN ANALISIS PUSHOVER

Column is a vertical structural element that functions to absorb axial loads and transfer them to the foundation. The structure of this column consists of reinforcement and concrete which is a combination of tensile and compression resistant materials. The column carries a combination of axial loads and ultimate moments simultaneously. The column must have strength where the strength of the column must exceed the working load. The purpose of this study was to obtain differences in the performance of reinforced concrete building structures using circular and square columns due to earthquake loads. The research method used is a quantitative method with the help of SAP2000 software with nonlinear Pushover analysis. There are two models in this study, namely Model M1 is a square column model and model M2 is a circular column model. The results of the analysis show that the behavior of the structure for lateral deformation in the X direction of the square column is stiffer than the round column, while the lateral deformation in the Y direction of the circular column is stiffer than the square column. This is influenced by the inertia of the cross-section and the number of columns in each direction is different. The forces in the square column are 1% greater, the shear force is 62% smaller and the axial force is 24% greater than the circular column. The square column model with IO performance level has the ability to accept lateral loads and deformations on a larger capacity curve compared to circular columns for X and Y direction earthquakes.

Test and simulation of high temperature resistant polyamide composite with single lap single bolt connection

The advancement of next-generation aerospace vehicles has presented new requirements and challenges for ensuring the structural integrity of aircraft components in extreme environments. Consequently, the utilization of high temperature resistant polyamide composite materials has become pivotal in the manufacturing of aerospace vehicle parts that operate under high temperatures (250 °C). As a critical connection technology for these materials, the mechanical behavior of bolted connection structures under high temperatures requires further investigation. In this paper, a combination of experimental and numerical simulation is used to investigate the load carrying capacity and failure mechanism of T700/BMP316 composite bolted joints at room temperature and 250 °C. The experimental results show that the ultimate load carrying capacity of the structure at 250 °C is only 13.1 % lower than that of the room temperature environment, indicating that the temperature softening effect of such composites is not significant. Scanning electron microscope (SEM) and computed tomography (CT) results indicate that the structural damage modes were the crushing of the hole edge fibers and matrix due to the extrusion by the bolts, as well as the interlaminar delamination damage. Temperature effects were taken into account for the composite principal structure and finite element modeling was performed using a combination of Pinho criterion and Cohesive model. Numerical simulations allow accurate prediction of the load-displacement response and damage pattern throughout the damage evolution phase. The high temperature test results and the developed finite element model involved in this study can support the design of new-generation aerospace vehicles.

Photothermally‐Induced Reversible Rigidity of Nacre‐Mimetic Composites Toward Semi‐Active Personal Safeguard

AbstractThe capacity to withstand challenges posed by complex environments is crucial for developing advanced high‐performance protective materials with mechanically adjustable nature. By constructing long‐range hierarchical network of shear‐stiffening gel‐carbon nanotube‐cellulose nanofiber (SCC) embedded within epoxy resin (ER), this work engineers a nacre‐inspired variable‐stiffness SCC‐ER composite (SCCE). Lightweight SCC scaffold attenuates falling impact force from 2.23 to 0.46 kN, and reaches 60 °C within 20 s under 1 sun exposure. Additionally, owing to the rigid ER matrix, SCCE exhibits 4.03 GPa elastic modulus, outperforming numerous conventional engineering materials in puncture resistance. Specific energy absorption of nacre‐mimetic SCCE presents 1.91 MJ m−3 while that of random structural SCCE is only 0.50 MJ m−3. More importantly, SCCE features representative photothermal‐induced reversible rigidity whose storage modulus varies from 9.85 MPa at 30 °C to 11.61 kPa at 116 °C under light stimulation. It also presents shape‐programmability, capable of adhering complex structural surfaces for protection. Eventually, SCCE‐based semi‐active adjustable protectors are constructed that leverage contactless photothermal effect to modulate rigidity. 5 mm‐thick smart SCCE‐protectors resist 163.93 m s−1 ballistic impact while 15‐mm commercial kneepads are penetrated at lower speed of 136.98 m s−1. This bio‐inspired semi‐active strategy proposes a promising avenue for enhancing personal protective equipment.

SuFEx‐based Transparent Polysulfates and their Applications in Tunable Resistant Electrical Memory Materials

AbstractVisibly transparent electron devices are current research highlights, which are found at the “neotype” stage of technical development for the usage in the next generation “see‐through” electronic devices. However, less attention is paid to transparent semiconductor memory devices, and hence, achieving such “see‐through” electronic devices are still partially limited by lacking the easily achievable and cost‐effective transparent memory materials. Herein, three visible light transparent polysulfate‐based memory devices are reported, e.g. ITO/P‐BPS/Al, ITO/P‐TPA/Al, and ITO/P‐TPABPS/Al, that displayed DRAM, WORM, and FLASH effects, respectively. The mechanisms of the observed memory behavior of each memory material are proposed on the basis of computational simulation. Remarkably, these polysulfates‐based memory materials are obtained by simply using different main‐chain repeating units, suggesting a wide application potential of polysulfate as functionalized materials.

Upcycling polyethylene into closed-loop recyclable polymers through titanosilicate catalyzed C-H oxidation and in-chain heteroatom insertion

Polyolefins are the most widely produced type of plastics owing to their low production cost and favorable properties. Their polymer backbone consists solely of inert C-C bonds, making them resistant and durable materials. Although this is an extremely useful attribute during their use phase, it complicates chemical recycling. In this work, different types of polyethylenes (PEs) are converted into ketone-functionalized PEs with up to 3.4% functionalized carbon atoms, in mild conditions (≤100 °C), using a titanosilicate catalyst and tert-butyl hydroperoxide as the oxidant. Subsequently, the introduced ketones are exploited as sites for heteroatom insertion. Through Baeyer-Villiger oxidation, in-chain esters are produced with yields up to 73%. Alternatively, the ketones can be converted into the corresponding oxime, which can undergo a Beckmann rearrangement to obtain in-chain amides, with yields up to 75%. These transformations allow access to polymers that are amenable to solvolysis, thereby enhancing their potential for chemical recycling.

Analyses of Wheat Resistance to Fusarium Head Blight Using Different Inoculation Methods

Fusarium head blight is a devastating wheat disease that causes yield reduction and mycotoxins contamination, leading to multiple negative consequences for the economy, health, and food safety. Despite the tremendous efforts that have been undertaken over the last several decades to harness the disease, the problem remains a challenging issue. Due to global warming, its impact has become increasingly severe in Baltic and Nordic countries. The improvement of wheat resistance is hampered by complicated genetic inheritance, the scarcity of adapted resistant breeding materials, and difficulties in obtaining accurate and reproducible data due to the high interaction and dependency of the disease development on the environment. In this study, the resistance of 335 genotypes, 9 of which were of exotic origin and the remainder of which were adapted to the environments of Lithuania, Latvia, Estonia, or Norway, was studied in 8 trials using spray and point inoculation with spore suspensions and grain spawn inoculation under field and/or greenhouse conditions. The best linear unbiased estimates (BLUEs) of each genotype within the individual trials and the adjusted means across the trials were determined to reduce the environmental effects. Genotypes that exhibited excellent Type I or Type II resistance and overall resistance were identified.

Ultra-broadband and large angle metamaterial absorber based on 3D anisotropic resistive structure and magnetic material

Ultra-broadband and large angle metamaterial absorber based on 3D anisotropic resistive structure and magnetic material

Emergent Research Trends on the Structural Relaxation Dynamics of Molecular Clusters: From Structure-Property Relationship to New Function Prediction.

ConspectusMolecular clusters (MCs) are monodispersed, precisely defined ensembles of atom collections featured with shape-persistent architectures that can deliver certain functions independently. Their molecular compositions and surface functionalities can be tailored feasibly in a predefined manner, and they can be applied as basic structural units to be engineered into materials with desirable hierarchical structures and enriched functions. The chemical systems also offer great opportunities for the design and fabrication of soft structural materials without the chain topologies of polymers. The bulks of MC assemblies demonstrate viscoelasticity that is used to be considered as the unique feature of polymers, while the MC systems are distinct from polymers since their elasticities are resilient even at temperatures 100 K above their glass transition temperatures. The understanding of their anomalous viscoelasticity and the extended studies of general structure-property relationships are desired for the development of new chemical systems for emergent functions and the possibilities to resolve the intrinsic trade-offs of traditional materials.Meanwhile, general macroscopic functions or properties of materials are related to the transportation of mass, momentum, and/or energy, and they are basically realized or directed by the motions of structural units at different length scales. Structural relaxation dynamics research is critical in quantifying motions ranging from fast bond deformation, bond break/formation, and diffusion of ions and particles to the cooperative motions of structure units. Due to the advancement of measurement technology for relaxation dynamics (e.g., quasi-elastic scattering and broadband dielectric spectroscopy), the structural relaxation dynamics of MC materials have been probed for the first time, and their multiple relaxation modes across several temporal scales were systematically studied to bridge the correlation between molecular structures and macroscopic functions. The fingerprint information from dynamics studies, e.g., the temperature dependence of relaxation time and certain property, e.g., ion conductivity, was proposed to quantify the structure-property relationship, and the microscopic mechanism on the mechanical properties, ion conduction, and gas absorption and separation of MC materials can be fully understood.In this Account, to elucidate the uniqueness of MC materials, especially in comparison with polymers, four topics are mainly summarized: structural features, relaxation dynamics characterization techniques, relaxation dynamics characteristics, and quantified understanding of the structure-property relationship. The capability for new function prediction from relaxation dynamics studies is also introduced, and the typical example in impact resistant materials is provided. The Account aims to prove the significance of relaxation dynamics characterization for material innovation, while it also confirms the potential of MCs for functional material fabrications.

Estimating best nanomaterial for energy harvesting through reinforcement learning DQN coupled with fuzzy PROMETHEE under road-based conditions

Energy harvesters based on nanomaterials are getting more and more popular, but on their way to commercial availability, some crucial issues still need to be solved. The objective of the study is to select an appropriate nanomaterial. Using features of the Reinforcement Deep Q-Network (DQN) in conjunction with Fuzzy PROMETHEE, the proposed model, we present in this work a hybrid fuzzy approach to selecting appropriate materials for a vehicle-environmental-hazardous substance (EHS) combination that operates in roadways and under traffic conditions. The DQN is able to accumulate useful experience of operating in a dynamic traffic environment, accordingly selecting materials that deliver the highest energy output but at the same time bring consideration to factors such as durability, cost, and environmental impact. Fuzzy PROMETHEE allows the participation of human experts during the decision-making process, going beyond the quantitative data typically learned by DQN through the inclusion of qualitative preferences. Instead, this hybrid method unites the strength of individual approaches, as a result providing highly resistant and adjustable material selection to real EHS. The result of the study pointed out materials that can give high energy efficiency with reference to years of service, price, and environmental effects. The proposed model provides 95% accuracy with a computational efficiency of 300 s, and the application of hypothesis and practical testing on the chosen materials showed the high efficiency of the selected materials to harvest energy under fluctuating traffic conditions and proved the concept of a hybrid approach in True Vehicle Environmental High-risk Substance scenarios.

The capacity of disclinated non-equilibrium GBs to accommodate point defects in tungsten

Experimental observations reveal that disclinated non-equilibrium grain boundaries (GBs) exist extensively in polycrystalline metals; however, the interaction between these GBs and irradiation-induced point defects is rarely reported. In the present work, Molecular statics simulation was used to evaluate the capacity of disclinated non-equilibrium GBs to accommodate point defects in tungsten. Simulation results showed that disclinated non-equilibrium GBs are more efficient sinks for point defects than their equilibrium counterparts because of long-range stress field around them. Continuous segregation of point defects will change the structure of the disclinated non-equilibrium GBs and leads to the GBs tending to relax to equilibrium state. According to theoretical calculation, the disclinated non-equilibrium GBs can absorb a large number of point defects before transforming into equilibrium state; therefore, disclinated non-equilibrium GBs have very strong capacity to accommodate point defects and can be used as strong defect sinks for developing radiation resistance materials.

‘HARDNESS TESTS IN DENTISTRY’- AN EPIGRAMMATIC REVIEW

In the field of dentistry, several types of hardness tests are used to assess the mechanical properties of dental materials. These tests provide valuable information about a material's resistance to indentation, wear, and deformation. Hardness tests help dental professionals select appropriate materials for specific applications, ensuring that the chosen materials can withstand the functional demands of the oral environment. The hardness of dental materials often correlates with their wear resistance, strength, and overall performance, making hardness testing an essential part of material evaluation. There are many tests are in practice to test the hardness of various dental materials. Few of the tests are using in very regular practice to test the hardness. Hence this terse review aimed to discuss various commonly using hardness tests in dentistry, their indications, advantages and disadvantages.

Effect of SiCN thin film interlayer for ZnO-based RRAM.

This study investigates the effect of silicon carbon nitride (SiCN) as an interlayer for ZnO-based resistive random access memory (RRAM). SiCN was deposited using plasma-enhanced chemical vapor deposition (PECVD) with controlled carbon content, achieved by varying the partial pressure of tetramethylsilane (4MS). Our results indicate that increasing the carbon concentration enhances the endurance of RRAM devices but reduces the on/off ratio. Devices with SiCN exhibited lower operating voltages and more uniform resistive switching behavior. Oxygen migration from ZnO to SiCN is examined by X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) analyses, promoting the formation of conductive filaments (CFs) and lowering set voltages. Additionally, we examined the impact of top electrode oxidation on RRAM performance. The oxidation of the Ti top electrode was found to reduce endurance and increase low resistive state (LRS) resistance, potentially leading to device failure through the formation of an insulating layer between the electrode and resistive switching material. The oxygen storage capability of SiCN was further confirmed through high-temperature stress tests, demonstrating its potential as an oxygen reservoir. Devices with a 20 nm SiCN interlayer showed significantly improved endurance, with over 500 switching cycles, compared to 62 cycles in those with a 5 nm SiCN layer. However, the thicker SiCN layer resulted in a notably lower on/off ratio due to reduced capacitance. These findings suggest that SiCN interlayers can effectively enhance the performance and endurance of ZnO-based RRAM devices by acting as an oxygen reservoir and mitigating the top electrode oxidation effect.

Study on cementitious grout for scour protection of offshore wind turbine foundations

To study scour-resistant applicability, 6–10% mass ratio of polyurethane (PU) was added to sulphoaluminate cement (SAC) and ordinary Portland cement (OPC) grouts to generate OPCPU and SACPU. Sodium silicate (SS) with slurry volume ratio of 1:1–5:1 was added to SAC and OPC grouts to generate OPCSS and SACSS. The water-cement ratio (w/c) of grout was 0.8–1.5. Fresh-state properties and mechanical properties were investigated. Hydrated minerals and microstructures were analyzed, scouring tests were conducted considering key formulations. The results indicated that SACSS and OPCSS have a shorter setting time and higher strength, which makes them suitable as scour resistance materials. At the w/c of 1.0, OPCSS with a volume ratio of 3:1 and SACPU with 6% PU were selected for scour resistance tests. It showed that maximum scour depths and sediment transports were 7.0–12.2 and 1.1–1.2% as those without reinforcing conditions. The critical shear stress on the seabed under reinforcement is ∼103 times greater than the bed shear stress. This inhibits the occurrence of scouring. The study evaluated the applicability of cementitious reinforcement for scour resistance. This study analyzed material and mechanical properties, hydrated minerals, and microstructures, and conducted scour tests to optimize grouting material ratios for seabed scour protection, providing references for soil reinforcement and grouting protection.

Relaxation behaviour, conductive grains and resistive boundaries of bismuth-based double perovskite Bi2-xLaₓFeGaO₆

The successful synthesis of the ceramic Bi2-xLaxFeGaO6 powder ceramic sample with varying La content (x = 0.01, 0.03, 0.07, 0.10) were synthesized via the solid-state method. Analysis using X-ray diffraction at room temperature was carried out to examine its structure, revealing a crystallite size of approximately 22.07–50.84 nm. This size indicates the potential applications in microwave technology due to its small grain size, which has the capability to enhance microwave absorption properties. The dielectric constant of the material shows an increase with the frequency applied, in accordance with the behaviour anticipated by the dielectric HN model and Debye model. This model proposes that the material's dielectric response can be manipulated by modifying the applied frequency, making it a valuable tool in the material design for specific purposes. The full width at half maximum (FWHM) curve of the electrical modulus displayed variability, suggesting the existence of a non-Debye relaxation mechanism in the material. This indicates that the material could possess distinct electrical properties that might be beneficial for certain applications. The outcomes demonstrated a negative temperature coefficient resistance (NTCR), indicating a decrease in the material's resistance with increasing temperature. Such behaviour can be advantageous in situations where temperature variations require monitoring or regulation. The Cole-Cole plot illustrated that the grains exhibit conductive behaviour at lower frequencies, a crucial insight for comprehending the material's electrical properties. In conclusion, these results indicate that the ceramic Bi2-xLaxFeGaO6 for x = 0.01, 0.03, 0.07, 0.1) showcases promising attributes for various applications, particularly in microwave technology and electrical conductivity.

Effect of V-Ti multi-microalloying on enhancing hydrogen embrittlement resistance in hot-stamping steel

Hydrogen embrittlement (HE) has become a significant concern that limits the usage of ultra-high strength hot-stamping steel. In this work, the utilization of a novel approach employing V-Ti multi-microalloying has yielded substantial improvements in the resistance of hot-stamping steel to HE. The experimental findings demonstrate that V-Ti multi-microalloying effectively restrained the coarsening of precipitates, leading to the generation of high-density nanosized (V, Ti) C complex precipitates. The first principle calculation results indicate that V-Ti multi-microalloying improved the hydrogen trapping capacity of (V, Ti) C compared with TiC. Additionally, this approach refined the prior austenite grain size, fortifying the material's resistance to hydrogen-induced cracking.