Resistance Values Research Articles

Improving optical and electrical stabilities of fluorine-doped tin oxide films in sweat solutions with O2 addition in plasma

Abstract Recently, the use of wearable smart devices has significantly increased; however, sweat can corrode the outer-layer films, thereby decreasing their transmittance, conductivity, and overall functionality. In this study, fluorine-doped tin oxide (FTO) films for wearable smart devices were prepared via magnetron sputtering. The effects and mechanism of O2 gas flow in plasma on the properties of the fabricated films were investigated. Minor changes were observed in the film morphologies, with the preferred orientations shifting from polar (101) to nonpolar (110) and standard positions. As the O2 flow rate increased from 0 to 2 sccm, the transmittance of the film within the visible spectrum increased from 83% to 89%, with sheet resistance values in the order of 102–106 Ω·sq–1. Following immersion in an acidic sweat solution, the film without O2 peeled off, whereas several corrosion pits were observed in the films with 1 or 2 sccm O2. Conversely, following immersion in an alkaline sweat solution, several pits were observed in the films without O2, while the other films exhibited excellent corrosion resistance. The transmittance of the films immersed in different solutions did not significantly differ. Notably, the sheet resistances of the films treated with 1 sccm O2 met the industrial requirement of 3000 Ω. Moreover, the coexistence of polar and nonpolar planes provided transparency and conductive stability to the FTO films treated with 1 sccm O2. Our study aimed to not only enhance the transmittance and sweat-corrosion resistance but maintain the conductivity of the outer screen layer of a wearable smart electronic device.

Detection of shallow underground targets using electrical resistivity tomography and the implications in civil/environmental engineering

Applying the electrical resistivity tomography (ERT) technique in detecting very near-surface targets is quite challenging in geophysical investigation, especially in civil and environmental engineering for adequate planning and designing of structural foundations, contributing to the overall safety and efficiency of construction projects. However, locating the exact position and depth of underground targets such as faults, underground utilities, and contaminants is more challenging. Therefore, this study is aimed at examining the geophysical response of various buried targets and evaluating the ability of ERT to detect buried targets in terms of locations and depths of occurrence in the context of engineering investigation and environmental studies. A laboratory test was conducted on the targets to determine their electrical conductivity and resistivity before burial. The two-dimensional (2D) ERT survey was performed on thirteen targets buried at the site using both Wenner and dipole–dipole (DD) arrays. Both arrays captured the metallic targets with a low electrical resistivity contrast (< 0.1 Ωm) corresponding to the laboratory results. In comparison, the positions of the non-metallic buried targets were found to have a high resistivity contrast greater than 3000 Ωm, matching the laboratory results. The modelled pipes and the car engine block captured by both DD and Wenner arrays on 1.0 m electrode spacing were relatively smeared and poorly resolved in shapes, sizes and geometries, while some were not captured. The electrode spacing of 0.25 m and 0.50 m was explored on undetected targets, which provide a better resolution with sizes and depths compared to 1.0 m spacing but did not produce satisfactory results in some cases. The success and failure of ERT to detect a few targets were discussed alongside the environmental and engineering implications. The effectiveness of both arrays was assessed by their sensitivity in mapping the change in subsurface resistivity values. The DD array shows sensitivity to horizontal variations in resistivity values with low signal. In contrast, the Wenner array shows a good signal strength with a good change in the horizontal and vertical resistivity values. In addition, both arrays show capacity in mapping the geophysical signature of the buried targets and subsurface structures, which has significant application in engineering and environmental investigations.

Experimental Investigation of Heat Dissipation of Lithium–Ion Cells and Its Correlation with Internal Resistance

Power loss is a limiting factor for batteries and individual cells. The resulting heat generation due to the power loss leads to reduced battery performance and, thus, lower efficiency. These losses are largely due to the internal resistance of the cells. Therefore, it is important to accurately determine the value of the internal resistance of lithium–ion cells. From the literature, it was found that there are three widely used internal resistance-measurement methods (current step method, direct-energy-loss method, and calorimeter measurement), with negligible research on their comparison demonstrating the most efficient method. Henceforth, to find the most optimal method, this research adopts all three methods on a variety of cell chemistries, including Lithium-ion Manganese Oxide (LMO), Lithium Iron Phosphate (LFP), Nickel Manganese Cobalt (NMC), and Lithium Titanium-Oxide (LTO) for different c-rates (1 C, 2 C, and 3 C), with a wide temperature range (from 0 °C to 40 °C).

A flexible solid-state asymmetric supercapacitor device comprising cobalt hydroxide and biomass-derived porous carbon.

Development in the field of alternative and renewable energy sources is becoming necessary considering the current energy demands of the growing technologies. The main challenge associated with the produced energy is to store it for future use, such that it can be used when needed. Supercapacitors are among the electrochemical energy storage systems that provides higher power density, faster charging-discharging, high specific capacitance (C S), and long cycling life. Herein, the fabrication of a flexible solid-state asymmetric supercapacitor (ASC) device is reported, where Co(OH)2 hollow spheres and biomass-derived porous carbon (PC) are the cathode and anode, respectively. Co(OH)2 is a highly redox active material, whereas PC is an electric double-layer capacitive (EDLC) material. In this device, aqueous KOH solution (electrolyte) encapsulated in PVA gel (separator) was used to bind the electrodes. This Co(OH)2//PC ASC device exhibited a high C S of 260 F g-1 (at 2 A g-1). It retained ∼91% of the initial C S value (at 6 A g-1) till ∼5000 cycles. Electrochemical impedance spectroscopy (EIS) study confirmed low internal resistance (0.95 Ω) and charge transfer resistance (1.41 Ω) values of Co(OH)2//PC. These results indicate that the high electron transfer process in the electrode-electrolyte interface during the electrochemical reaction, which is responsible for the excellent performance of this ASC device. The high-performance Co(OH)2//PC ASC device exhibited an energy density of 76.7 W h kg-1 at a power density of 1416.9 W kg-1. To demonstrate its practical use, LED lights were illuminated using this Co(OH)2//PC ASC device.

Prediction of Contact Resistance of 4H–SiC by Machine Learning Using Optical Microscope Images after Laser Doping

In this study, machine learning (ML) was employed to predict the electrical properties of finished devices, specifically focusing on the state of the contacts at the electrodes. The predictions are based on optical microscope images of the surface conditions, which were captured immediately following the laser doping of nitrogen atoms into 4H-SiC. The laser doping process involved varying the laser fluence from 0.4 to 4.0 J/cm2 and using number of laser irradiation to 5, 10, 20, and 100 shots. The ML prediction was carried out in two steps. In STEP1, we classified the contact status into three types.: 1) Schottky junctions (insufficient doping), 2) Ohmic contact (good contact), and 3) Not ohmic (damage caused by laser irradiation). In STEP2, contact resistance prediction (numerical regression) was performed using the dataset predicted as an ohmic contact. As a result, we found that the three classifications in STEP1 could be predicted with a high accuracy of over 88%. Furthermore, the contact resistance prediction in STEP2 could be made with an accuracy (RMSPE: root mean square percent error) of 27.2%. Visualizing the prediction basis of numerical regression using modulus-reweighted grad-regression activation mapping (MoRAM) revealed that the ML model focused on the inside of the laser-irradiated area in the optical microscope image. The results of the scanning electron microscopy observation of the laser-irradiated area showed that ablation and residuals were generated during laser doping in that area. Consequently, it was concluded that our ML model predicted the contact resistance of the finished device taking into consideration these surface conditions. Even highly-skilled laser doping technicians have difficulty predicting the resistance values arising from the ablation and residue conditions. Based on above results, we conclude that our ML model is capable of predicting the electrical characteristics of a finished device, a task that is often considered challenging for humans.

Selective and reversible carbon mono oxide gas detection using silver doped octahedral molecular sieves (OMS-2) nanorods

In this work a potable, resistive sensor is fabricated for the selective detection of CO gas using nanorods of Ag doped octahedral molecular sieves-2 (Ag-OMS-2). During exposure to carbon monoxide (CO) gas at room temperature, resistance of Ag-OMS-2 film was dropped from 557 kΩ to 352 kΩ in just 18 sec. However, exposed sample regained its initial resistance value in 25 sec when CO gas source was removed. Both sensing and recovery processes were carried out at room temperature. The sensor film showed excellent reproducibility during several cycles of CO gas exposure. Swift activation of oxygen molecules for the oxidation of CO by the silver present in the tunnel of manganese oxide network is supposed to be responsible for sensing activity of Ag-OMS-2 towards carbon monoxide gas.

The freeze-drying performance under pressures from 1.325 to 101.325 kPa

The low drying rate is the main limitation of atmospheric freeze drying. The drying rate depends on the balance between heat and mass transfer. Among the process variables, air pressure changes have the opposite effects on heat and mass transfer simultaneously. The increase in pressure favors heat transfer but hinders mass transfer. Therefore, a conjugate model was proposed and validated to quantitatively investigate the heat and mass transport characteristics of lamellar products during freeze-drying in a tunnel under different pressures (1.325–101.325 kPa). To describe the effects of air pressure, the Navier-Stokes equations of the external fluid were coupled with the adsorption-sublimation model. Results show the regulation of transfer resistance values and drying rate with moisture content during the drying process, indicating that freeze-drying is the external heat transfer control at first, then the internal mass transfer control, and eventually, the heat transfer promotion can accelerate the process. The optimal constant pressure value was found to be 5.325 kPa, with the shortest drying time (17.3 h). It has been demonstrated that freeze drying employing a specific laddering-controlled strategy, offers the benefit of reducing drying time in comparison to the use of optimal constant pressure; however, the impact was not remarkable.

Facile synthesis of NiCo2O4 nanosheets efficient for electrocatalysis of water

Effective regulation of transition metal spinel morphology is crucial for stable bifunctional catalysts in the electrocatalysis of water. In this work, we crafted a fine NiCo2O4 (F-NCO) microflower structure assembled by nanosheet arrays, which exhibited highly efficient hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), outperforming most of the previous transition metal catalysts. Electronic microscope analysis revealed that the thickness of the F-NCO catalyst was only 1.6 nm, much smaller than that (58.8 nm) of bulk NiCo2O4 (B-NCO), and the ultrathin lamellar structure facilitated the exposure of active sites and improved the reaction kinetics. Compared with the B-NCO catalyst, the overpotential of the F-NCO catalyst in HER and OER was reduced by 36 and 82 mV, the active surface area increased by 2.68 and 4.16 times, and the charge transfer resistance values were reduced by 0.42 and 0.61 times, respectively. In the assembled cell, F-NCO/CFP(+)||F-NCO/CFP(−) electrolyzer was able to achieve 10 mA cm−2 at a low cell voltage of 1.74 V, which was much lower than B-NCO/CFP(+)||B-NCO/CFP(−) electrolyzer. In the 12-hour stability test, the potentiometric time dropped by only 30 mV, lower than 70 mV of the B-NCO catalyst. This work presents a facile strategy for developing a bifunctional catalyst for the electrocatalysis of water.

ESTIMATING THE GOLD MINERALIZATION ZONE BY INDUCED POLARIZATION AND RESISTIVITY METHOD IN X VILLAGE, SUMATERA, INDONESIA

This paper identifies the gold mineralization zone in X Village using the Induced Polarization and resistivity geoelectric method. The measurements were performed using the Wenner arrangement on six tracks, each separated by a distance of 235 meters and spaced 5 meters apart. The distribution of chargeability values was determined using the Induced Polarization method, while the distribution of resistivity values was determined using the resistivity geoelectric method at the research site. The identification results indicate that the suspected gold mineralization zone is on tracks 2 and 6. On track 2, the zone of suspected gold mineralization is suspected to be located 70-75 meters away from the starting point of measurement (point A). On track 6, it is located 65-75 meters away. The gold deposits are found in phyllite rocks that have undergone alteration, specifically philic, argillic, and silicified rock.

Comparative study of Ti/Al and Ti/Al/Ti/Au ohmic contacts to AlGaN/GaN heterostructures

We investigated the electrical properties and the ohmic contact formation considering Ti/Al and Ti/Al/Ti/Au ohmic contact metallization schemes on AlGaN/GaN heterostructures. The specific contact resistance of contacts was determined by characterizing the current–voltage relation from TLM measurement. The lowest value for the specific contact resistivity was obtained using Ti/Al/Ti/Au metallization. An interfacial TiN layer was monitored at the contact-AlGaN interface. TiN phases were found at both contacts, but the thickness in the Ti/Al/Ti/Au contact reached 8 nm, while the thickness in Ti/Al was thinner and discontinuous. The surface roughness of the Ti/Al/Ti/Au contact was determined as 8.17 nm and that of the Ti/Al contact as 36.23 nm. It was found that the spesific contact resistance depends on the atomic structure of the metal–semiconductor interface and composition and structure of the ohmic contact layers. These results showed that it is possible to achieve higher reliability and uniformity as well as lower contact resistance in AlGaN/GaN HEMTs with Ti/Al/Ti/Au contact compared to Ti/Al contact.

Enhanced photodiode performance: Au/boron-dipyrromethene/n-Si/Ag structure unveiling high photosensitivity and efficiency

In this study, the classical boron-dipyrromethene (4,4- difuoro-4-borata-3a-azonia-4a-aza-s-indacene, BODIPY) unit (C1), its halogenated derivative (C2), and disytryl derivative (C3), which are known for their absorption properties in the near-infrared (NIR) region, were synthesized. Chemical and photophysical investigations were carried out to reveal the complex features of the molecules using a range of spectroscopic techniques and their energies were calculated by Density Functional Theory (DFT) with the same basis set. The BODIPY thin films were coated on n-Si substrates using a spin coater to examine the effect of interlayer on photodiode/photovoltaic properties and Au/BODIPY (C1, C2, C3)/n-Si/Ag photodiodes having rectifying behavior were fabricated. The thermionic emission theory (TET) and modified Norde’s functions were utilized to determine the rectification ratio, ideality factor, series resistance, and barrier height values of diodes. The values of barrier height, ideality factor, and rectification ratio at ± 2 V were calculated as 0.81 eV, 1.83 and 2.47x103 for the Au/C1/n-Si/Ag diode, 0.83 eV, 1.63, and 7.06 x103 for the Au/C2/n-Si/Ag diode and 0.84 eV, 1.51 and 2.14x104 for the Au/C3/n-Si/Ag diode in the dark from the TET, respectively. The values of FF (%) and efficiency were calculated as 38 and 1.51 for the Au/C1/n-Si/Ag diode, 47 and 2.03 for the Au/C2/n-Si/Ag diode, and 56 and 3.68 for the Au/C3/n-Si/Ag diode under 100 mW/cm2 illumination, respectively. With remarkable electrical properties, the Au/C3/n-Si/Ag photodiode stood out among the others, performing better in both dark and light conditions. Therefore, the produced diodes based on the BODIPY thin film can be employed as photodiodes/photovoltaics in optoelectronic applications.

Impact of Intra-Phenotypic Nasal Vestibular Variation on Local Airflow Dynamics.

Many individuals with healthy normal nasal anatomy and function exhibit a prominent notch indentation at the junction of the ala and sidewall, specifically around the anterior-superior region of the unilateral nasal vestibule up to the internal nasal valve. This study evaluates the influence of various sizes of notched indentations at the anterior nasal airway on local airflow pattern. A retrospective study involving 25 healthy individuals, each exhibiting at least one unilateral notched indentation (40 total airways). Each individual's notched indentation was quantified after subject-specific three-dimensional nasal airway reconstruction from radiographic images. Computational fluid dynamics modeling was used to simulate nasal inspiratory airflow in each nasal airway at 15 L/min. Localized airflow distributions passing through the inferior, middle, and superior regions were calculated at 15 cross sections. Notched indentation size ranged 1.75-86.84 mm2 (average = 22.37 mm2). At the anterior airway, notched size significantly correlated with inferior airflow volume (R = 0.32, p = 0.04) but not in the middle (R = 0.21, p = 0.20) or superior (R = 0.06, p = 0.70) regions, whereas middle and superior regional resistance values were significantly correlated with notched size (middle: R = 0.54, p < 0.001; superior: R = 0.41, p = 0.009). Medially, resistance at the middle region significantly correlated with notched size (R = 0.56, p < 0.001). At the posterior airway, airflow distributions through the inferior, middle, and superior regions demonstrated weak correlation with notched size (inferior: R = 0.24, p = 0.14, middle: R = 0.24, p = 0.13; superior:R = 0.03, p = 0.83), whereas resistance was significantly correlated in the middle and inferior regions (middle: R = 0.56, p < 0.001;inferior: R = 0.43, p = 0.006). Anterior nasal airway notched indentation size had significantly stronger influence on localized airflow volume through the anterior-inferior airway than other regions of the nasal passage. N/A Laryngoscope, 2024.

Bioelectrical Impedance Vectors Analysis of Sarcopenic Older Adults Submitted to a Resistance Training Program.

The objective of the present study is to analyze the changes in bioimpedance vector analysis (BIVA) and phase angle (PhA) in sarcopenic older people submitted to a 12-week resistance training (RT) program according to classic and specific analyses. To this end, 20 sarcopenic older adults of both sexes, invited through media, underwent bioimpedance analysis before and after the RT carried out three times a week, for 12 weeks. The mean impedance vectors of the groups established for the confidence ellipses (95% of the confidence ellipse) are compared using Hotelling's T2 test. The distance D from Mahalanobis is also calculated. Classic and Specific BIVA are presented. The resistance values for the classical analyses (R/H) decreased across all groups (whole group, women and men, p < 0.05), with approximate decreases ranging from 9.4% to 10%, while the classic reactance (Xc/H) decreased (p < 0.05) only for the whole group (5.9%) and men (7.7%). For the specific BIVA, trends are verified for the whole sample, with a decrease in resistance (R.sp) and an increase in reactance (Xc.sp). In conclusion, the RT program in sarcopenic individuals promoted a reduction in resistance values in classical analyses, indicating a possible increase in hydration status and, consequently, musculoskeletal mass.

Influence of the Addition of Palm (Borassus Aethiopum Mart.) Fibers on the Durability of Compressed Earth Blocks

This study aims to determine the influence of the content and length of the palm (borassus aethiopum mart.) fibers on the physical, mechanical and thermal properties of Compressed Earth Blocks (CEB). Three fiber contents (0.2%, 0.4% and 0.8%) of different lengths (10 mm, 20 mm, or 40 mm) were used to make CEB. CEB with 0% fiber content were manufactured to serve as control samples. CEB specimens stabilized with palm fibers or not were subjected to various tests according to standard XP P 13-901 for the determination of the following properties: dry density, water absorption, dry compressive strength, abrasion resistance and thermal conductivity. The results show that the dry density of CEB decreases from 4% to 7% when the content and length of the fibers increase respectively from 0.2% and 10 mm in length to 0.8% and 40 mm in length. The water absorption of fiber-containing CEBs ranges from 14% to 22% with increasing fiber content and length. The results also indicate that the mechanical and thermal properties are improved for well-chosen fiber contents. Thus, the dry compressive strength of the fibers increases by more than 13% for a fiber content of 0.2% and a length of 10 mm compared to CEB with 0% fibers. On the other hand, the optimal abrasion resistance values are obtained for a fiber content of 0.4% and a length of 40 mm. For all CEBs, the thermal conductivity values vary from 0.51 W/mK to 0.38 W/mK when the fiber content varies from 0.2% to 0.8%. Overall, palm fiber content has a greater influence on the measured physical, mechanical and thermal characteristics than fiber length.

IDENTIFICATION OF HYDROTHERMAL DISTRIBUTIONS USING THE WENNER-SCHLUMBERGER CONFIGURATION GEOELECTRIC METHOD IN LEMEU VILLAGE, LEBONG REGENCY, BENGKULU

The hot spring pool, Lemeu Village, Lebong Regency, is one of the geothermal fields. This research aims to identify the study area's geothermal potential and lithology. This is illustrated by the correlation method of resistivity and electrical conductivity values of rocks based on geoelectric measurements. This research uses the Wenner-Schlumberger configuration geoelectric method, as many as four tracks spread around the hot spring hill with a length of 480 meters, which are used to see variations in resistivity values that can indicate the presence of hydrothermal potential. The result is a 2D Resistivity model processed with Res2DinvX32 software. Based on the interpretation results, the subsurface rock lithology in each track is relatively similar in color, texture, grain size, and composition because it is around the hill. The Hulusimpang formation consists of clay, silty sand, tuff, andesite, basalt, and granite. Hydrothermal is found on lines 2 and 4 with resistivity values of 7.3 and 10.1 Ωm at a depth of 26 meters. Geothermal potential in the research area is divided into several temperature categories; some have low, medium, and high temperatures. In the research area, tracks 1 and 3 have low temperatures.

THE COMPOSITION OF IMPURITIES AND DEFECTS IN Cd1-XMgXTe:In, NECESSARY TO ENSURE STABLE DETECTOR PROPERTIES

A model study of the promising new material Cd0.92Mg0.08Te:In, intended for X-ray and gamma radiation detectors operating at room temperature, was carried out. The paper highlights the results of quantitative studies of the influence of the content of impurities and structural defects on the electrophysical and detector properties of Cd0.92Mg0.08Te:In. An analysis of the calculated values of resistivity ρ and concentrations of free charge carriers, life time of non-equilibrium electrons τn, and holes τp, charge collection efficiency η with different composition of impurities and defects in this material at temperature T = 298 K was carried out. The optimal ranges of energy and concentration of alloying deep donor, which ensure a stable high-resistive state and acceptable values of η, are established. Compensation of cadmium vacancies with indium admixture was studied. Assumption was made regarding possibility of increasing the operating time of the detector having semi-insulating properties and great charge collection efficiency. A direction for further research has been formulated in order to clarify the nature of a suitable doping deep donor that ensures stable properties of the detector.

Polarization insensitive and wideband terahertz absorber using high-impedance resistive material of RuO2

This paper introduces a novel, cost-effective solution designed to achieve large absorption bandwidth within the THz spectrum employing a miniaturized, single-layer metamaterial structure. The designed structure features a single circular ring composed of an ohmic resistive sheet with notably higher sheet resistance than traditional metallic resonators. This distinctive design is implemented on a lossy dielectric polyimide substrate with a backing of metallic gold. Our developed absorbing structure demonstrates the capability to achieve a substantial absorption bandwidth ranging from 3.78 to 4.25 THz, maintaining a consistent absorption rate of over 90%. Moreover, we conducted an analysis to assess its absorption performance under various sheet resistance values within the top layer. Additionally, we characterized its angular stability and polarization insensitivity through oblique incident and polarization angle analysis. Finally, an RLC circuital and interference theory approach is adopted to justify its simulated results. The proposed absorber shows potential for a broad spectrum of applications, encompassing communication, imaging, and diverse integrated circuits operating within the THz band.

Research on the Measurement and Estimation Method of Wheel Resistance on a Soil Runway

In view of the fact that there is no suitable measurement method for tire driving resistance during the operation of a transporter on soil pavement, this paper proposes a simple measurement and estimation method for driving resistance on a soil runway based on the Bekker settlement model. In this paper, using the driving resistance equation based on the Bekker model, a simplified equation of driving resistance related to mass is proposed. Using the principle of kinematics, a simple test device for driving resistance was developed, and the test data of the test device were used to determine the parameters of the driving resistance estimation equation of the road surface. The driving resistance of the wheel running state was tested by the simulated aircraft load loading vehicle through the mechanical sensor, and the consistency between the theoretical value and the actual value of the driving resistance value under 8T, 10T, and 12T loads was verified. This research shows that the test method and estimation method have low cost and good accuracy and are suitable for wide promotion. The results of this paper provide a new idea and method for estimating the driving resistance of a wheel when a transporter runs on a soil road and also provide a reference for designing the length of a soil runway.

Response Surface Modelling Nafion-117 Sorption of Tetraammineplatinum(II) Chloride in the Electroless Plating of IPMCs.

This work looks at the effects of a varying concentration, soak time, pH and temperature on the sorption of tetraammineplatinum(II) chloride (Pt-Ammine) in Nafion-117 films in the context of the electroless plating of ionic polymer-metal composites (IPMCs). Sorption is characterised by atomic absorption spectroscopy. A definitive screening design carried out determined all four factors to be significant for further analysis using response surface modelling. A duplicated central composite design (CCD) was utilised to characterise how the four factors affect the sorption amount and efficiency. Regression models for both responses were of poor fit. Nevertheless, key insights were obtained on the effects of the process parameters on sorption behaviour. The results indicate that above 0.5 g/L Pt-Ammine sorption, the platinisation of 10 × 50 mm IPMC samples through sodium borohydride reduction becomes redundant by the surface resistance metric. IPMCs with surface resistance values of approximately 2.5 Ω/square were obtained through only one round of chemical reduction. Varying surface morphologies and electrode thicknesses were analysed under a scanning electron microscope. The CCD parameter settings were validated. Recommended settings for optimised Pt-Ammine sorption in 10 × 50 mm Nafion-117 films were identified as follows: 1.0 g/L Pt-Ammine concentration, 24 h soak time, pH of 3 and temperature of 20 °C.

Fabrication and properties of conductive films based on bacterial cellulose and poly-N-isopropylacrylamide-modified graphene oxide

A conductive film (PNIPAM-rGO/BC) was fabricated combining bacterial cellulose (BC) with poly-N-isopropylacrylamide-modified graphene oxide (PNIPAM-GO) through vacuum filtration and steam reduction techniques. The conductivity and performance of PNIPAM-GO composite and the resulting conductive film were studied. The key findings revealed that PNIPAM-GO composite exhibited a reversible temperature-sensitive behavior. Specifically, the lower critical solution temperature (LCST) increased upon the introduction of graphene oxide (GO). Detailed analyses confirmed uniform dispersion of GO nanosheets within the BC matrix. The incorporation of 10.0 % PNIPAM-GO (containing 7.0 % GO) led to a remarkable 19.6 % increase in tensile strength and approximately 37.0 % enhancement in elongation at break for the conductive film (PNIPAM-rGO/BC) compared to BC. After steam reduction, the electrical conductivity of PNIPAM-rGO/BC exhibited significant improvement over BC. Furthermore, the conductive film demonstrated temperature-dependent conductivity, with a resistivity value approximately 5.2 ± 0.2 KΩ at 25 °C. As the test temperature above the LCST of PNIPAM-GO composite, the resistance decreased. These intriguing temperature-sensitive conductive properties position PNIPAM-rGO/BC as a promising material for smart switches.