Resistance Measurements Research Articles

Thiol Coordination Softens Liquid Metal Particles To Improve On-Demand Conductivity.

Achieving tunable rupturing of eutectic gallium indium (EGaIn) particles holds great significance in flexible electronic applications, particularly pressure sensors. We tune the mechanosensitivity of EGaIn particles by preparing them in toluene with thiol surfactants and demonstrate an improvement over typical preparations in ethanol. We observe, across multiple length scales, that thiol surfactants and the nonpolar solvent synergistically reduce the applied stress requirements for electromechanical actuation. At the nanoscale, dodecanethiol and propanethiol in toluene suppress gallium oxide growth, as characterized by transmission electron microscopy and X-ray photoelectron spectroscopy. Quantitative AFM imaging produces force-indentation curves and height images, while conductive AFM measures current while probing individual EGaIn particles. As the applied force increases, thiolated particles demonstrate intensified softening, rupturing, and stress-induced electrical activation at forces 40% lower than those for bare particles in ethanol. To confirm that thiolation facilitates rupturing at the macroscale, a laser is used to ablate samples of EGaIn particles. Scanning electron microscopy and resistance measurements across macroscopic samples confirm that thiolated EGaIn particles coalesce to exhibit electrical activation at 0.1 W. Particles prepared in ethanol, however, require 3 times higher laser power to demonstrate a similar behavior. This unique collection of advanced techniques demonstrates that our particle synthesis conditions can facilitate on-demand functionality to benefit electronic applications.

Tunable magnetism in titanium-based kagome metals by rare-earth engineering and high pressure

Rare-earth engineering is an effective way to introduce and tune magnetism in topological kagome materials, which have been acting as a fertile platform to investigate the quantum interactions between geometry, topology, spin, and correlation. Here, we report the synthesis, structure, and physical properties of titanium-based kagome metals RETi3Bi4 (RE = Yb, Pr, and Nd) with various magnetic states. They all crystallize in the orthogonal space group Fmmm (No. 69), featuring distorted titanium kagome lattices and rare-earth zig-zag chains. By changing the rare earth atoms in the zig-zag chains, the magnetism can be tuned from nonmagnetic YbTi3Bi4 to short-range ordered PrTi3Bi4 (Tanomaly ~ 8.2 K), and finally to ferromagnetic NdTi3Bi4 (Tc ~ 8.5 K). In-situ resistance measurements of NdTi3Bi4 under high pressure further reveal a tunable ferromagnetic ordering temperature. These results highlight RETi3Bi4 as a promising family of kagome metals to explore nontrivial band topology and exotic phases.

Vandetanib as a prospective anti-inflammatory and anti-contractile agent in asthma

Background: Vandetanib is a small-molecule tyrosine kinase inhibitor. It exerts its therapeutic effects primarily in a range of lung cancers by inhibiting the vascular endothelial growth factor receptor 2. However, it remains unclear whether vandetanib has therapeutic benefits in other lung diseases, particularly asthma. The present study investigated the pioneering use of vandetanib in the treatment of asthma.Methods:In vivo experiments including establishment of an asthma model, measurement of airway resistance measurement and histological analysis were used primarily to confirm the anticontractile and anti-inflammatory effects of vandetanib, while in vitro experiments, including measurement of muscle tension and whole-cell patch-clamp recording, were used to explore the underlying molecular mechanism.Results:In vivo experiments in an asthmatic mouse model showed that vandetanib could significantly alleviate systemic inflammation and a range of airway pathological changes including hypersensitivity, hypersecretion and remodeling. Subsequent in vitro experiments showed that vandetanib was able to relax the precontracted rings of the mouse trachea via calcium mobilization which was regulated by specific ion channels including VDLCC, NSCC, NCX and K+ channels.Conclusions: Taken together, our study demonstrated that vandetanib has both anticontractile and anti-inflammatory properties in the treatment of asthma, which also suggests the feasibility of using vandetanib in the treatment of asthma by reducing abnormal airway contraction and systemic inflammation.

Depletion of Electrolyte Salt Upon Calendaric Aging of Lithium-Ion Batteries and its Effect on Cell Performance

Abstract The trend for increased nickel content in layered transition metal oxide cathode active materials and increasing charging cut-off voltages aggravates aging of lithium-ion battery cells at high state of charge (SOC). We investigate the calendaric aging behavior of large-format automotive prototype cells and laboratory single-layer pouch cells at high but realistic cell voltages/SOCs and demonstrate that electrolyte oxidation in combination with follow-up reactions can cause a significant loss of the LiPF6 salt in the electrolyte. For this, we analyze the LiPF6 concentration in aged cells, the generation of H2 upon storage, and the cell resistance for different aging conditions. We show that the LiPF6 loss is a critical aging phenomenon, as it cannot readily be detected by capacity fading measurements at low/medium C-rates or by cell resistance measurements, while it severely reduces rate and fast-charging capability. Under certain circumstances, LiPF6 loss can even lead to a temporary capacity increase due to conversion of the conducting salt in the electrolyte to cyclable lithium in the active material. Finally, we suggest a possible reaction mechanism and a simple accounting model to keep track of how different side reactions involved in LiPF6 loss change the cyclable lithium inventory of a lithium-ion cell.

In situ Electrical Resistance Measurement of Pure Titanium during Severe Plastic Deformation by High‐Pressure Sliding

This study presents in situ measurements of electrical resistance in pure Ti during severe plastic deformation (SPD) under high pressures. The process of high‐pressure sliding (HPS) is adopted for the SPD so that straining is feasible under various pressures covering α to ω allotropic phase transformation in pure Ti. Anvil surfaces are coated by a plasma‐sprayed alumina layer to maintain electrical insulation between the sample and the anvils during HPS operation. The electrical resistance increases continuously with straining by the HPS processing but the increase in the electrical resistance is more pronounced as the applied pressure increases, particularly when the ω phase formation occurs. The phase transformation is evidenced by X‐ray diffraction analysis as well as in situ static heating experiment. The continuous increase in the electrical resistance suggests that there is neither critical strain nor avalanche for the phase transformation to the ω phase.This article is protected by copyright. All rights reserved.

Laser-induced graphene formation on different wood species: Dependence of electronic performance on intrinsic features of certain types of wood

Conductive, 3D, porous graphene can be produced with a CO2 laser from a large variety of materials, including wood, at room temperature, and under inert atmosphere or after treatment for fire protection. Here, we investigated the suitability for direct conversion of 46 typical European and Asian woods into laser-induced graphene (LIG), without pre-treatment. The LIG was characterized by resistance measurements to determine if a conductive layer had formed, and via Raman spectroscopy. Here, we show, for the first time, that it is possible to produce LIG on certain woods under atmospheric conditions without additional fire protection treatment. We determined that the ability to produce LIG on untreated, natural wood under ambient atmosphere is favoured overall by a high density and a diffuse-porous xylem structure, as well as a high soluble lignin content. Some of these characteristics are similar to those required for high yields in char production. Problematic for the production of LIG-based electronics is the presence of pronounced growth rings, or other geometric wood features, with density variations, which can be reduced using specific cuts with minimized growth rings and absence of rays. This is the first time that untreated wood has been directly converted into LIG using a conventional CO2 laser and ambient atmosphere. Our results represent a further step towards the development of a new generation of sustainable electronics relying on natural materials.

Automatic in-situ measurement of thermal resistance for GaN HEMTs

An automatic in-situ technique for thermal resistance measurement based on an electrical method is proposed in this paper. In contrast to the conventional thermal resistance measurement circuits of the electrical method, this method involves direct measurement of the thermal resistance of GaN high-electron-mobility transistor (HEMT) devices in an operating circuit by introducing a well-matched radio-frequency switching circuit into the operating circuit. The advantage of this method is that the thermal resistance can be measured periodically on the in-situ device without changing the electrical characteristics of the device. Based on this result, the cooling curve of the HEMT device in the power amplifier (PA) circuit is collected and the thermal resistance characteristics of the HEMT are determined via the structure function method. The purpose of this paper is to successfully obtain the thermal resistance of in-situ devices through an automatic in-situ measurement circuit of thermal resistance, and to verify the feasibility of periodic detection of thermal resistance of in-situ devices.

A broadband pulse amplifier for Joule heating experiments in diamond anvil cells.

Decades of measurements of the thermophysical properties of hot metals show that pulsed Joule heating is an effective method to heat solid and liquid metals that are chemically reactive or difficult to contain. To extend such measurements to hundreds of GPa pressure, pulsed heating methods have recently been integrated with diamond anvil cells. The recent design used a low-side switch and active electrical sensing equipment that was prone to damage and measurement error. Here, we report the design and characterization of new electronics that use a high-side switch and robust, passive electrical sensing equipment. The new pulse amplifier can heat ∼5 to 50 μm diameter metal wires to thousands of kelvin at tens to hundreds of GPa using diamond anvil cells. Pulse durations and peak currents can each be varied over three orders of magnitude, from 5 µs to 10ms and from 0.2 to 200A. The pulse amplifier is integrated with a current probe. Two voltage probes attached to the body of a diamond anvil cell are used to measure voltage in a four-point probe geometry. The accuracy of four-point probe resistance measurements for a dummy sample with 0.1 Ω resistance is typically better than 5% at all times from 2 µs to 10ms after the beginning of the pulse.

Turn-to-Turn Contact Resistance Measurement of NI REBCO Double Pancake Coils

Turn-to-Turn Contact Resistance Measurement of NI REBCO Double Pancake Coils

Probing Intercalated Indium-Tin Oxide Films by Non-Local Resistance Measurements

Probing Intercalated Indium-Tin Oxide Films by Non-Local Resistance Measurements

Acoustic Wave-Induced FeRh Magnetic Phase Transition and Its Application in Antiferromagnetic Pattern Writing and Erasing.

We explore the FeRh magnetic phase transition (MPT) and magnetic phase domain (MPD) with the introduction of surface acoustic waves (SAWs). The effects of the SAW pulses with different pulse widths and powers on resistance-temperature loops are investigated, revealing that the SAW can reduce the thermal hysteresis. Meanwhile, the SAW-induced comb-like antiferromagnetic (AFM) phase domains are observed. By changing the pulse width and SAW frequency, we further realize a writing-erasing process of the different comb-like AFM phase domains in the mixed-phase regime of the cooling transition branch. Resistance measurements also display the repeated SAW writing-erasing and the nonvolatile characteristic clearly. MPT paths are measured to demonstrate that short SAW pulses induce isothermal MPT and write magnetic phase patterns via the dynamic strain, whereas long SAW pulses erase patterns via the acoustothermal effect. The Preisach model is introduced to model the FeRh MPT under the SAW pulses, and the calculated results correspond well with our experiments, which reveals the SAW-induced energy modulation promotes FeRh MPT. COMSOL simulations of the SAW strain field also support our results. Our study not only can be used to reduce the thermal hysteresis but also extends the application of the SAW as a tool to write and erase AFM patterns for spintronics and magnonics.

The barrier-protective effect of β-eudesmol against type 2-inflammatory cytokine-induced tight junction disassembly in airway epithelial cells.

Allergic inflammation, which is the pathogenesis of allergic rhinitis and asthma, is associated with disruption of the airway epithelial barrier due to the effects of type 2 inflammatory cytokines, i.e. interleukin-4 and interleukin-13 (IL-4/13). The anti-allergic inflammatory effect of β-eudesmol (BE) on the tight junction (TJ) of the airway epithelium has not previously been reported. Herein, the barrier protective effect of BE was determined by measurement of transepithelial electrical resistance and by paracellular permeability assay in an IL-4/13-treated 16HBE14o- monolayer. Pre-treatment of BE concentration- and time- dependently inhibited IL-4/13-induced TJ barrier disruption, with the most significant effect observed at 20 μM. Cytotoxicity analyses showed that BE, either alone or in combination with IL-4/13, had no effect on cell viability. Western blot and immunofluorescence analyses showed that BE inhibited IL-4/13-induced mislocalization of TJ components, including occludin and zonula occludens-1 (ZO-1), without affecting the expression of these two proteins. In addition, the mechanism of the TJ-protective effect of BE was mediated by inhibition of IL-4/13-induced STAT6 phosphorylation, in which BE might serve as an antagonist of cytokine receptors. In silico molecular docking analysis demonstrated that BE potentially interacted with the site I pocket of the type 2 IL-4 receptor, likely at Asn-126 and Tyr-127 amino acid residues. It can therefore be concluded that BE is able to prevent IL-4/13-induced TJ disassembly by interfering with cytokine-receptor interaction, leading to suppression of STAT6-induced mislocalization of occludin and ZO-1. BE is a promising candidate for a therapeutic intervention for inflammatory airway epithelial disorders driven by IL-4/13.

Indirect temperature protection of an asynchronous generator by stator winding resistance measurement with superimposition of high-frequency pulse signals

The article deals with the indirect methods for calculating the temperature of asynchronous generators with the introduction of a pulse component in the power supply circuit of the stator windings of asynchronous generators with squirrel-cage rotor. The relevance of this issue is determined by the need to improve asynchronous energy converters to increase their reliability and safety. The object of the study is an asynchronous generator with squirrel-cage rotor, which consume 40 % of the total electricity generated, and are the most affordable. One of the dangerous modes of asynchronous generators is their overheating as a result of increased currents and temperatures. The thermal protection of the stator winding of asynchronous generators relies primarily on measuring or determining the winding temperature. An indirect method for determining temperature based on measuring the resistance of the stator of an asynchronous generator with squirrel-cage rotor is proposed. The method is based on superimposing pulse signals of small amplitude and high frequency of 600 Hz on an alternating sinusoidal voltage with a frequency of 50 Hz. A simulation model for a 3 kW asynchronous generator has been developed. There were given the simulation results. The estimated values of the active resistances of the stator can be used to indirectly determine the temperature of the windings in thermal protection devices of asynchronous generators, as well as for control, monitoring and diagnostics of the technical condition. The research results confirm the possibility of indirect temperature determination and the creation of a thermal protection system for asynchronous energy converters based on the use of estimation methods.

From Insulator to Superconductor: A Series of Pressure-Driven Transitions in Quasi-One-Dimensional TiS3 Nanoribbons.

Transition metal trichalcogenides (TMTCs) offer remarkable opportunities for tuning electronic states through modifications in chemical composition, temperature, and pressure. Despite considerable interest in TMTCs, there remain significant knowledge gaps concerning the evolution of their electronic properties under compression. In this study, we employ experimental and theoretical approaches to comprehensively explore the high-pressure behavior of the electronic properties of TiS3, a quasi-one-dimensional (Q1D) semiconductor, across various temperature ranges. Through high-pressure electrical resistance and magnetic measurements at elevated pressures, we uncover a distinctive sequence of phase transitions within TiS3, encompassing a transformation from an insulating state at ambient pressure to the emergence of an incipient superconducting state above 70 GPa. Our findings provide compelling evidence that superconductivity at low temperatures of ∼2.9 K is a fundamental characteristic of TiS3, shedding new light on the intriguing high-pressure electronic properties of TiS3 and underscoring the broader implications of our discoveries for TMTCs in general.

A three-probe method for accurate nanoscale thermal transport measurements

Measurements of transport phenomena are constantly plagued by contact resistance, prohibiting the sample's intrinsic electrical or thermal conductivity from being accurately determined. This predicament is particularly severe in thermal transport measurements due to the inability to meet similar impedance requirements for a four-probe method used in electrical resistance measurements. Here, we invent a three-probe measurement method that makes an accurate determination of thermal conductivity possible for nanomaterials. Incorporating electron beam heating provided by a scanning electron microscope (SEM) on a diffusive thermal conductor not only quantifies the thermal contact resistance, which may introduce an error of more than 270% to a sample's thermal conductivity, but also eliminates several device uncertainties that may contribute an additional 17% error in a measurement. The method also enables local temperature measurements, revealing nanoscale structural variations unfound by SEM. The high accuracy of the technique would make standardization of nanoscale thermal transport measurement possible.

Fragility crossover mediated by covalent-like electronic interactions in metallic liquids

Abstract Fragility is one of the central concepts in glass and liquid sciences, as it characterizes the extent of deviation of viscosity from Arrhenius behavior and is linked to a range of glass properties. However, the intervention of crystallization often prevents the assessment of fragility in poor glass-formers, such as supercooled metallic liquids. Hence experimental data on their compositional dependence are scarce, let alone fundamentally understood. In this work, we use fast scanning calorimetry to overcome this obstacle and systematically study the fragility in a ternary La-Ni-Al system, over previously inaccessible composition space. We observe fragility dropped in a small range with the Al alloying, indicating an alloying-induced fragility crossover. We use x-ray photoelectron spectroscopy, resistance measurements, electronic structure calculations, and DFT-based deep-learning atomic simulations to investigate the cause of this fragility drop. These results show that the fragility crossover can be fundamentally ascribed to the electronic covalency associated with the unique Al-Al interactions. Our findings provide insight into the origin of fragility in metallic liquids from an electronic structure perspective and pave a new way for the design of metallic glasses.

Estimation of Lithium-Ion Battery Health in Electric Bicycles Using Internal Resistance Measurement Method

This study evaluates the performance of a 36 Volt 10 Ah battery in an electric bicycle with a 350-Watt Brushless DC (BLDC) motor as an environmentally friendly alternative to overcome the negative impacts of motorized vehicle use in Indonesia. In addition, this study measured the State of Health battery’s value of internal resistance, which is different from other studies that use capacity fading. With a focus on maximum travel distance and travel time, experiments were conducted without load and with a 70kg load. The no-load test was conducted only once, resulting in a travel time of 600 minutes and a distance of 330.1 Km. Although the battery was not discharged, the results were not in line with expectations, so the no-load test was only conducted once. In the 70kg load test, six trials were conducted with variable measurements of distance, battery voltage, and battery resistance. Results showed variations in distance between 50.7 km and 53.1 km, and travel time between 151 and 160 minutes. The battery voltage varied from 31.316 Volts to 31.850 Volts. The resistance in the battery also showed an increase of about 0.0001 ohms from 0.1132 ohms to 0.1139 ohms. Overall, the results from the study showed that as time and usage progressed, the battery voltage and internal resistance values tended to increase, while the distance and travel time tended to decrease. The internal resistance measurement method proved to be effective in assessing battery health as the State of Health value decreased throughout the experiment.

Cryopreservation and Rapid Recovery of Differentiated Intestinal Epithelial Barrier Cells at Complex Transwell Interfaces Is Enabled by Chemically Induced Ice Nucleation.

Cell-based models, such as organ-on-chips, can replace and inform in vivo (animal) studies for drug discovery, toxicology, and biomedical science, but most cannot be banked "ready to use" as they do not survive conventional cryopreservation with DMSO alone. Here, we demonstrate how macromolecular ice nucleators enable the successful cryopreservation of epithelial intestinal models supported upon the interface of transwells, allowing recovery of function in just 7 days post-thaw directly from the freezer, compared to 21 days from conventional suspension cryopreservation. Caco-2 cells and Caco-2/HT29-MTX cocultures are cryopreserved on transwell inserts, with chemically induced ice nucleation at warmer temperatures resulting in increased cell viability but crucially retaining the complex cellular adhesion on the transwell insert interfaces, which other cryoprotectants do not. Trans-epithelial electrical resistance measurements, confocal microscopy, histology, and whole-cell proteomics demonstrated the rapid recovery of differentiated cell function, including the formation of tight junctions. Lucifer yellow permeability assays confirmed that the barrier functions of the cells were intact. This work will help solve the long-standing problem of transwell tissue barrier model storage, facilitating access to advanced predictive cellular models. This is underpinned by precise control of the nucleation temperature, addressing a crucial biophysical mode of damage.

A design of gas diffusion media for polymer electrolyte membrane fuel cell: Characterization and water management investigation

Higher power density is a key technological goal for the deployment of polymer electrolyte membrane fuel cells (PEMFCs) in vehicles. Water production is proportional to current density and at high current densities water flooding in catalyst layers can result in significant mass transport limitations. A novel perfluoropolymers material, Teflon™ AF, is introduced as a hydrophobic agent to fabricate microporous layers (MPLs). The MPL ink with varying proportions of Teflon™ AF and Vulcan XC-72 carbon black is prepared and used to coat MPLs into the gas diffusion layers. X-ray computed tomography and mercury intrusion porosimetry are used to characterize the physical properties of the penetrated GDM. The performance of cells with the homemade MPLs are compared with commercial GDM cells under dry and wet operating conditions using varying backpressures. The results at high relative humidity and high backpressure show that the cells with homemade MPLs have less flooding than that with commercial GDM. Oxygen transport resistance measurements using the limiting current method show that the penetration of the MPL into the substrate has an undesirable effect of increasing oxygen transport resistance. The results are of benefit to understanding the water management and gas transport mechanism of MPL for fuel cells operating at both dry and wet conditions.

Correlation of CPT measurements and relative density of LEAP-2017 and LEAP-2020 centrifuge models

Miniature cone penetration tests (CPTs) were conducted during the LEAP 2017 and LEAP 2020 centrifuge experiments to characterize and quantify the soil deposit properties. A total of 43 CPTs were obtained for deposits with varying relative densities. All experiments were performed using Ottawa F-65 Sand and used the same CPT tool model. A comprehensive study was undertaken to assess the quality and consistency of the CPT data. Outlier and regression analyses were used to develop an empirical relation to evaluate the relative density of Ottawa sand (centrifuge) deposits from measurements of the CPT tip resistance. This relation provides an estimate of the mean relative density profile, and associated standard deviation to quantify uncertainty. The relation accounts for the overburden pressure influence and the potential effects of container width (when the used container is narrow). The experimental results were found to have a good consistency with a regression R2 equal to 0.85.