Reservoir Conditions Research Articles

FEATURES OF WELL KILLING IN CONDITIONS OF CARBONATE RESERVOIR AND HIGH GOR

The article presents the results of studies on the use of well killing technology in fractured carbonate reservoirs of the Republic of Bashkortostan under conditions of loss of kill fluid and high GOR of the product. The geological and technical conditions of the Metelinskoye field are summarized, and the factors complicating well killing before routine and workover are described - reduced reservoir pressure during operation, previous large-volume salt-acid treatments, and the presence of hydrogen sulfide.The article substantiates the choice of invert-emulsion solutions (IER) for killing wells in the Metelinskoye field, taking into account the experience of using various killing technologies in the Volga-Ural oil and gas province. The authors have determined the physicochemical and rheological characteristics of kill compositions based on IER of various densities. An increase in the effective viscosity at high shear rates and the limit shear stress of the IER with an increase in the density of the composition was revealed. Taking into account the high risks of gas breakthrough during well killing in the Metelinskoye field, studies were also conducted to assess the gas-retaining capacity of the IER on an experimental installation by extruding the composition from a metal capillary. It has been shown that the gas holding capacity of these compositions with increasing density is described by an equation with a power function and a high degree of reliability. The effect of hydrogen sulfide neutralizer addition on IER properties was investigated. In order to increase the success of killing, the IER-based killing technology was selected and adapted to the existing conditions. The better blocking ability of higher density formulations has been confirmed. Successful well tests. To reduce the risks of using the IER and optimize the consumption of reagents during the further use of the technology, organizational and technical measures for killing and subsequent repair of wells were developed and implemented. The results of this work can be used in wells of the Ural-Volga region, Eastern Siberia and Timan-Pechora province with the presence of losses and a high gas factor, the repair of which is complicated by the lack of fluid circulation and the presence of excess pressure at the wellhead with signs of gas shows.

EXPERIMENTAL STUDY OF HYDRATE FORMATION PECULIARITIES FOR CONDITIONS OF THE TURNO AND CENOMANIAN DEPOSITS. Part I

This paper is the Part I of a study devoted to investigating the peculiarities of hydrate formation for the conditions of Turonian and Cenomanian reservoirs. The launch of new gas projects at the Turon and Senoman production facilities in Western Siberia provided a good opportunity to critically analyze the known methods of protecting production, gathering and transportation facilities of the gas field from the formation of solid gas hydrates. The paper presents the experience of implementing a program of laboratory studies of conditions of gas hydrate formation with their subsequent processing and in-depth analysis. The research program covered the area of thermobaric parameters typical for the conditions of Turon-Senoman deposits exploitation with localization of hydrate-hazardous areas in the conditions of technological regimes for full development. The description of laboratory studies is given, in which two gas compositions of Senoman and Turon objects, different variants of mineralization and ionic composition corresponding to formation and condensation water, as well as hydrate formation conditions under changing dosages of basic inhibitor on the basis of methanol were considered. The details of the experiment based on the method of swinging cells and the subsequent analysis of the results of the completed experiments to determine the thermobaric conditions of formation and decomposition of hydrates are given. The main features of the experiment are specified, estimates of the rate of change of the influencing parameters of the experiment on its quality are given. In the process of implementation of the experimental program, the optimal values of these parameters were selected, which allowed us to significantly reduce the variation of experimental results to determine the thermobaric conditions of hydrate formation. It is experimentally established that the temperature of hydrate decomposition is higher than the temperature of its formation at all investigated gas compositions and water mineralization.Based on the processing of an extensive matrix of experimental studies, the calculation dependences of thermobaric conditions of hydrate formation were specified, which allowed to significantly improve the efficiency of prediction and accuracy of calculation of optimal dosages of inhibitor for the Kharampurskoye gas field. In this part of the study, the characteristic thermobaric conditions of natural gas production and collection from Turonian-Cenomanian deposits are summarized, the component composition of the investigated gas and water is described, and the methodology of laboratory tests is described.

Frictional Properties of Feldspar‐Chlorite Gouges and Implications for Fault Reactivation in Hydrothermal Systems

AbstractAs a particularly common mineral in granites, the presence of feldspar and feldspar‐chlorite gouges at hydrothermal conditions has important implications in fault strength and reactivation. We present laboratory observations of frictional strength and stability of feldspar (K‐feldspar and albite) and feldspar‐chlorite gouges under conditions representative of deep geothermal reservoirs to evaluate the impact on fault stability. Velocity‐stepping experiments are performed at a confining stress of 95 MPa, pore pressures of 35–90 MPa, and temperatures of 120–400°C representative of in situ conditions for such reservoirs. Our experiment results indicate that the feldspar gouge exhibits strong friction (μ ∼ 0.71) at all experimental temperatures (∼120–400°C) but when T > 120°C, the frictional response transitions from velocity‐strengthening to slightly velocity‐weakening. At constant confining pressure and temperature, increasing the pore pressure increases the friction coefficient (∼0.70–0.85) and the gouge remains slightly velocity weakening. The presence of alteration‐sourced chlorite leads to a transition from velocity weakening to velocity strengthening in the mixed gouge at experimental temperatures and pore pressures. As a ubiquitous mineral in reservoir rocks, feldspar is shown to potentially contribute to unstable sliding over ranges in temperature and pressure typical in deep hydrothermal reservoirs. These findings emphasize that feldspar minerals may increase the potential for injection‐induced seismicity on pre‐existing faults if devoid of chloritization.

Experimental Constraints on the Storage Conditions and Differentiation of High-Ti Basalts from the Panzhihua and Hongge Layered Intrusions, SW China

Abstract High-Ti basalts are commonly believed to represent parental magmas leading to the formation of mafic-ultramafic layered intrusions, such as Late Permian Panzhihua and Hongge in the Emeishan Large Igneous Province (SW China). Consequently, elucidation of the crystallisation and crustal differentiation of high-Ti basalts is critical for our understanding of the petrogenesis of these layered intrusions and the associated oxide ore mineralisation. Here, we present the results of crystallisation experiments carried out in internally heated pressure vessels using a primitive high-Ti basaltic composition. The experiments were conducted at 100 and 300 MPa, in the temperature interval of 950–1200 °C and with water activities (aH2O) from 0 to 1. The oxygen fugacity (fO2) was controlled and varied from FMQ −1 to FMQ +3.3 log units (FMQ corresponds to fayalite-quartz-magnetite buffer). The main mineral phases are olivine, clinopyroxene and plagioclase, accompanied by Cr-Fe-Ti-oxides, orthopyroxene, apatite and amphibole, depending on the conditions. Redox conditions primarily influence the stability fields of Cr-Fe-Ti oxides. Clinopyroxene, orthopyroxene and amphibole are pressure-dependent and have larger stability fields under high pressure conditions. The olivine→orthopyroxene and olivine→amphibole peritectic reactions are observed. Comparisons of phase equilibria between this study and experiments conducted with parental magma of Skaergaard layered intrusion demonstrate the effect of bulk system composition. For instance, ilmenite crystallisation is determined not only by intrinsic parameters such as fO2 but also by additional compositional parameters (e.g. melt Ti, Fe, Al and Mg content). Although COMAGMAT and MELTS modelling results generally reproduce the crystallisation sequence, only the stability field of clinopyroxene and its composition are perfectly modelled. The comparison of experimental results with the rocks from the lowest units of Panzhihua and Hongge layered intrusions are applied to constrain storage conditions in the magma reservoirs. Compared to Hongge, we conclude that the Panzhihua magma chamber was probably located at a shallower depth (~3–6 km), that magma crystallisation started at lower temperatures (~1125–1100 °C), higher fO2 (~FMQ + 1 to FMQ + 2) and that its initial melt H2O content was lower (~0.5–1 wt. %).

Halide perovskite photovoltaics for in-sensor reservoir computing

As intelligent electronics get laden with multimodal sensors, the data transfer and computation increase their energy expenditure. Consequently, researchers aim to develop efficient computing paradigms or integrate energy harvesting from ambient sources. Halide perovskites possess unique photophysics and coupled ionic-electronic dynamics that actualise memory devices for brain-inspired computing. Synergising the computing capability with their conventional light harvesting efficacy could aptly address the aforementioned problem. In a novel approach, the transient open circuit voltage (VOC) of a methylammonium lead bromide-based solar cell was exploited to serve as a self-powered volatile short-term memory for optoelectronic in-sensor reservoir computing. The origin of the memory is attributed to the influence of mobile ions on the carrier generation and recombination in the device. The system's versatility and task specificity were shown by engineering the volatility of the memory. The benchmarking task of MNIST handwritten digit recognition was performed with the highly reproducible and robust transformation of optical inputs into unique reservoir states. To demonstrate the high nonlinearity, second-order time-series prediction (NARMA2) was performed. Finally, an exemplary cardiac health-monitoring application was showcased by monolithic reading and processing of a physiological time series known as photoplethysmography (PPG) to identify atrial fibrillation with increased computational efficiency.

Innovative approaches in enhanced oil recovery: A focus on gas injection synergies with other EOR methods

Enhanced Oil Recovery (EOR) techniques have become crucial in extending the productive life of mature oil fields and maximizing resource extraction. Among these, gas injection methods, particularly those involving CO₂, nitrogen, and hydrocarbon gases, have shown significant promise. This review focuses on the innovative synergies achieved by combining gas injection with other EOR methods to enhance recovery efficiency and economic viability. Gas injection techniques work by increasing reservoir pressure and reducing oil viscosity, facilitating easier flow and extraction. When integrated with other EOR methods such as thermal, chemical, and microbial techniques, the synergistic effects can lead to even greater enhancements in oil recovery. For instance, the combination of gas injection with thermal EOR, like steam injection, can improve the displacement of heavy oils by simultaneously reducing viscosity and enhancing thermal conductivity within the reservoir. Similarly, integrating gas injection with chemical EOR methods, such as polymer flooding, can optimize the sweep efficiency by leveraging the mobility control provided by polymers and the pressure maintenance by gases. Recent advancements in monitoring and simulation technologies have further improved the effectiveness of these combined approaches. Real-time reservoir simulation and 4D seismic monitoring allow for precise tracking of gas and fluid movements, enabling dynamic adjustments to injection parameters for optimal performance. Smart well technologies, equipped with advanced downhole sensors, provide continuous data on reservoir conditions, facilitating more responsive and adaptive EOR strategies. However, these innovative synergies are not without challenges. Economic feasibility remains a significant concern, particularly given the high costs associated with gas procurement and the integration of multiple EOR techniques. Additionally, managing the complex interactions between different EOR methods and heterogeneous reservoir conditions requires sophisticated modeling and robust operational protocols. In conclusion, the integration of gas injection with other EOR methods offers a promising pathway to enhance oil recovery rates and extend the lifespan of mature reservoirs. Continued research and development, coupled with cross-industry collaboration, are essential to overcoming the economic and technical challenges associated with these innovative approaches. This review underscores the potential for gas injection synergies to revolutionize EOR practices and drive sustainable growth in the oil and gas industry.

The Effectiveness of Generated Electrical Power Based on the Water Discharge of Reservoir

Renewable energy has an important role today, one of which is hydroelectric power plants which use water as the main resource. The operation of a hydroelectric power plant generally aims to maximize the water discharge available in the reservoir in order to obtain maximum energy generation. The main driver of hydropower development is the hydraulic turbines. It's a mechanical device that turns the potential energy of water into electrical energy. So researchers are interested in conducting research with the title analysis of the effectiveness of electrical energy based on reservoir conditions. The method used in this research is daily data collection in the form of reservoir elevation level data, outflow, and data on the electrical power generated by the generator. After that, calculate the water volume, hydraulic power, turbine mechanical power along with turbine efficiency, and the efficiency of the generator. Then analyze the values of hydraulic power, turbine mechanical power, electrical power based on water discharge over time. As well as analyzing the efficiency of the generator based on the electrical power that can be generated over a period of one year. Based on research, it is known that an increase in powerplant efficiency occurs after draining the reservoir with a value range of 70% - 72%, because mud deposits accumulate in the reservoir resulting in the reservoir water volume capacity not being optimal.

Correlations between Geomechanical Effects, SAGD Performance, and Reservoir Conditions in SAGD Operations in Alberta, Canada

Correlations between Geomechanical Effects, SAGD Performance, and Reservoir Conditions in SAGD Operations in Alberta, Canada

Dynamic response of Akcakoca RCC Dam including galleries

Dams are structures that demand a significant amount of concrete, making them costly constructions. Hence, various alternative methods are employed for dam construction, one of which is the use of Roller Compacted Concrete (RCC). This is a case study, which focuses on examining the behavior of RCC dams with and without galleries under seismic excitations, considering the Akçakoca RCC dam in Düzce Province. The seismic ground motion data from the 1999 Düzce earthquake were utilized. The impact of galleries inside the concrete dams was investigated through stress and displacement, considering both empty and full reservoir conditions. The Eulerian-Lagrangian coupled (CEL) approach was employed for two-dimensional fluid finite elements. This study revealed that reservoir water and galleries have a notable influence on the behavior of dams under seismic forces. In cases with reservoirs and galleries, stress and displacement values increased, and critical changes in stresses were observed around gallery areas. Therefore, careful design considerations are essential for dams with galleries under significant seismic forces.

Microscopic Mechanism and Percolation Model of Dynamic Deposition of Elemental Sulfur Particles in Acidic Gas Reservoirs.

The dissolution of elemental sulfur in acidic gas leads to its precipitation as gas pressure decreases, thereby causing potential damage to the formation due to the deposition of sulfur particles. Previous sulfur deposition prediction models often relied on the solubility of sulfur in acidic gas and the stress state of sulfur particles to determine the occurrence of deposition, thus establishing predictive models. However, in the presence of complex geological conditions, the multiphase flow through porous media and the adsorption of particles on pore throat walls can also influence sulfur particle deposition to some degree. It is well known that sulfur particle deposition during gas reservoir development exhibits instability, with multiple factors influencing the deposited sulfur particles. Particularly noteworthy is the influence of airflow velocity, which can resuspend sulfur particles that are physically adsorbed on pore throat surfaces, thereby reintegrating them into the gas phase. Additionally, the dynamic deposition of larger sulfur particles involves a dynamic process. This study elucidates the dynamic process of sulfur deposition by considering the diverse transport dynamics of sulfur particles. Physical adsorption and desorption behaviors of sulfur particles are determined based on variations in reservoir conditions. The desorption status of sulfur particles with different particle sizes within the formation is established by evaluating the equilibrium between the force exerted on the pore throat wall and the suspension force generated by gas flow. The critical conditions for sulfur deposition in Yuanba gas reservoir were obtained by substituting on-site parameters into calculations. Moreover, a mathematical model is proposed to describe the dynamic deposition and migration of sulfur particles, adopting principles from continuous porous media porous flow theory, fluid flow mass conservation, as well as sulfur particle desorption and migration. The formulated model is solved, and its resulting solution process and outcomes hold significant implications for numerical simulation and predictive assessment of the development impact on gas reservoirs, particularly in later stages.

Paleoclimatic and environmental conditions of the Lower-Middle Ordovician carbonate reservoir in the middle of Tarim Basin (NW China): Constrained by petrographic, geochemical, and carbon–oxygen isotopic characteristics

Breakthroughs have been made recently in the exploration of hydrocarbon in the middle of Tarim Basin, NW China. The complexity of the Lower-Middle Ordovician carbonate reservoir remains enigmatic and hinders the source, developmental mechanism of the calcite fills, and paleo-environmental conditions of the Yingshan and Yijianfang Formations have been unclear. Here we present the related paleoenvironmental settings and diagenetic history, using petrographic, geochemical, and carbon (13C) and oxygen (18O) isotopic characteristics of calcite fracture, cave, and fissure fillings of a Lower-Middle Ordovician carbonate reservoir. The results indicate that the limestone caves dominantly consist of CaO, FeO, and MgO, and minor quantities of TiO2 and MnO. Among the trace elements, Ni reported the highest values (with an average of 1162.16 ppm) and other trace elements such as Ba, V, and Ga occur in minor values (with an average of 71.03, 19.18, and 12.92 ppm) respectively. The enrichment of light rare earth elements (LREEs) over the heavy rare earth elements (HREEs), with positive and negative Ce, and negative Eu anomalies indicate the contexts of oxic and anoxic conditions in seawater and sediments interface. The variation in δ18OPDB values ranges from −4.72 to −14.48‰ (with an average of −10.12‰), indicating a setting of paleo-karstification by atmospheric freshwater dissolution. While the variation in δ13CPDB indicates relatively significant values, ranging between 0.82 to −3.80‰ (with an average of −1.07‰), suggests that the paleo-karstification in this region has experienced episodes of supergene and burial diagenesis. The paleo-temperature average value of 59.1 °C, and the paleo-salinity average (Z-value) of 120.07, indicating a relatively warm paleoclimatic environment during the development of calcite-filling deposits. The results suggest several paleo-environmental conditions when paleokarst occurred: a marine deposition environment, an atmospheric freshwater karstification environment, a shallow burial paleo-karstification environment, and a high-temperature deep-burial environment in Yingshan and Yijianfang Formation in the Shunbei area. This study serves as an analog for similar carbonate systems worldwide, providing valuable insights for understanding paleo-karstification processes in different tectonic and climatic settings. Comparative studies between the Shunbei area, Tarim Basin, and other carbonate platforms contribute to our knowledge of karst evolution and its implications for reservoir development and groundwater resources.

Characterization of supercritical CO2 heat transfer in microporous media under (T/p)-mutability and integrated random function

The thermophysical properties of supercritical carbon dioxide (sCO2) undergo drastic changes under reservoir conditions, which significantly affects transfer characteristics and the storage efficiency. The present work seeks to identity of the heat transfer response of a mutable sCO2 in porous micromodels with integrated Boolean stochastic models. An upgraded variant of Lattice Boltzmann model is used after a thorough validation with literature experiments. The injection conditions of sCO2 are ranged from 295 to 333 K and 8–10 MPa, with a mass flow rate of 0.05–0.20 kg/min. The thermodynamic instabilities are discussed through the joint bonds between temperature and density, local and overall heat transfer, and pressure drop coefficient, under a series of pore-throats dimension from 7.5 to 401.3 μm. The results showed: (i) the remarkable (T/p)-nature of heat transfer capacity of sCO2 to lead the transfer coefficients with a subordinate impact of thermal conductivity near the Widom line, as long as the convective mode primes with increased temperature and pressure; (ii) The heterogeneity of the microporous media promoted the decrease of the transfer capacity while adjusting the spatiotemporal density and the heat transfer orientations inside the pore bodies; (iii) the growth of the pressure drop under increasing temperature has revealed an equilibrium stage where, neither the mutability of sCO2 properties nor the injection intensity can significantly affect the heat transfer of the integrated microporous.

Porous media flow of polymeric nanofluids in multilayered formations: a simulation study

ABSTRACT The injection of viscoelastic fluids into the oil-bearing formations to push the bypassed and entrapped oil toward the producers is a widely accepted technique known for creating a stable displacement front and piston-like displacement, leading to Enhanced Oil Recovery (EOR). However, the sweep efficiency of such complex fluids in stratified formations is still a topic of debate in the literature and is problematic, particularly in harsh reservoir conditions. This research concerns how the inclusion of nanoparticles into the polymer solution could affect the porous media flow of polymeric fluids in multilayered reservoirs. Accordingly, validated core-scale numerical models for polymer flood and polymer nanohybrid flood were upscaled to develop a reservoir-scale model. Through numerical simulations using a compositional reservoir simulator, the simultaneous flow of crude oil and polymer nanohybrids in both low and high-permeable layers of the reservoir were scrutinized. The numerical outputs showed that, compared with polymer flood, the flow dynamics of the polymer nanohybrids in different layers of the reservoir are more favorable, which resulted in improved oil recovery of over 20% of Residual Oil In Place (ROIP). Additionally, our numerical findings indicated that the polymer nanohybrids could exhibit lower polymer adsorption and acceptable salt tolerance in porous media.

Study on seismic characterization and distribution characteristics of effective reservoirs of granite weathering crust in Dongying Sag, Bohai Bay Basin

To solve the problem of low resolution of seismic data from granite weathering crust and difficulty in predicting effective reservoir distribution. Based on the research idea of combining geology and seismology, seismic facies characteristics and effective reservoir distribution of granite weathering crust are studied by means of frequency division reconstruction processing, seismic facies analysis and sensitive attributes interpretation. This method consists of the following four main processes: (1) Using improved Morlet wavelet function for frequency division and reconstruction processing of seismic data; (2) From the perspective of geological evolution, analyzing the geological origin of seismic facies; (3) Based on the results of well- seismic combination, clarifying the types of effective reservoirs and predicting their distribution; (4) Comprehensive research indicating favorable reservoirs distribution. The results indicate that (1) a considerably improved resolution of seismic data processed by frequency division reconstruction is obtained based on the improved Morlet wavelet function. Thus, granite reservoirs then have clearer internal reflection characteristics. (2) Affected by differences in weathering, the seismic facies in granite weathering crusts can be classified as follows: Strong-amplitude facies with amplitudes of 23,700 − 32,800, corresponding to eluvium, represents the late stage of weathering crust evolution with high-intensity weathering. Medium-amplitude facies with amplitudes of 5,250 − 24,000, corresponding to dissolution layer, represents a middle stage of weathering crust evolution with moderate weathering. And weak-amplitude-blank facies with amplitudes of 0–5,330, corresponding to disintegration layer, represents an early stage of weathering crust evolution with weak weathering. (3) Effective reservoirs can be classified according to well-seismic calibrations and combined with reservoir spaces, porosities and permeabilities, and the logging and oil-bearing characteristics of the reservoirs. Type I effective reservoir comprises medium-amplitude facies, with favorable reservoir conditions and high-yield oil-bearing properties; this type is distributed in the western slopes, with an elevation of 1,300-2,500 m. Type II effective reservoir comprises strong-amplitude facies, with poor oil-bearing properties; this type is mainly distributed in the southeast and north slopes of the study area, with a relatively limited range, and the elevation is mostly below 1,500 m. Type III effective reservoir comprises weak-amplitude-blank facies, with poor reservoir conditions and poor oil-bearing properties; this type is widely distributed at various elevations. (4) The areas where medium-amplitude facies have developed are the most favorable reservoir exploration zones for granite in Dongying Sag, Bohai Bay Basin.

Charakterystyka złoża formacji Baharyia, pola naftowe Neag-1, 2 i 3, Pustynia Zachodnia, Egipt

An integration was achieved between different bore holes and laboratory measured data using several petrophysical parameters of the Baharyia Formation encountered in Neag-1,2&3 oil fields. It illustrates the key control factors affecting the Baharyia reservoir quality. The obtained petrophysical relationships could be used widely in both exploration geophysics and hydrocarbon reservoir production. It provides and demonstrates solutions for both geological and geophysical engineering problems. The measured porosity and permeability are ranging from 2.5 to 32 % and 0.005 to 874 mD respectively. The influence of diagenesis on both reservoir porosity and permeability has been investigated. Pore filling minerals has been classified into four classes by XRD- analysis technique. A reliable regression equation was reached between reservoir permeability and mineral pore fillings. Several relationships among rock permeability, porosity and density obtained from open hole logs were recognized. The pore throat distribution has been laboratory measured by use of MICP technique for some selected samples. The calculated reservoir storage and flow capacity indicate four major fluid flow types which are controlled by the variations in reservoir pore space framework. Formation resistivity factor – porosity relation was accomplished under reservoir conditions, while the Archie’s 2nd equation was outlined. The Archie’s parameters (a, m &n) were calculated for shaly and clean sandstones of the Baharyia Formation. Both cation exchange capacity (CEC), Mounce potential (MP) and mercury injection capillary pressure (MICP) were measured to distinguish reservoir facies.

The state of spawning grounds, a study of the biology and population dynamics of pacific salmon on Kunashir Island (Southern Kuril Islands) in 2023

The purpose: formation of scientific foundations for improving the efficiency of salmon management on Kunashir Island (South Kuril zone) to ensure the sustainable exploitation of the commercial stock of Pacific salmon, maintain the necessary level of their reproduction, preserve the habitat, as well as improve scientific approaches to forecasting commercial catches.Methods used: the work was carried out in accordance with the methods generally accepted in fisheries research.Result: information was obtained on the dynamics of Pacific salmon entry, the filling of spawning grounds and the state of reservoirs on Kunashir Island. The collection of materials characterizing the biological indicators of chum salmon producers was carried out. Statistical information was obtained on catches of chum salmon and artificial reproduction of salmon fish on Kunashir Island.Practical significance: information on the filling of the spawning grounds of Pacific salmon on Kunashir Island and the quality indicators of their producers will be used to substantiate fishing regulation measures. Data on the state of artificial and natural reproduction of Pacific salmon are intended to develop a strategy for the development of artificial reproduction on Kunashir Island.

Gas-phase reaction of CH4 and H2S – Evidence from pyrolysis experiments and case study from the Sichuan Basin

The application of routine geochemical analyses for identification of dry natural gas sources and post generation processes poses a challenge as its hydrocarbon composition is typically dominated by CH4 (∼≥99 %) while the presence of non-hydrocarbons may be limited. In particular, the possibility of dry gas interaction with H2S at reservoir conditions (low temperatures, high pressures, millions of years residence time) is not established as previous studies of this reaction focused on conditions typical for industrial reactors (high temperature, ambient pressure, residence time of seconds). To address these issues, we studied the molecular and isotopic (δ34S) composition of volatile organic sulfur compounds (VOSC) formed during pyrolysis experiments between CH4 and H2S at 360 °C (4–96 h), reaching %Ro equivalent of 0.80–1.25 which represents thermally mature oil and gas reservoirs. The results demonstrated that methanethiol (MeSH) is the main product of the reaction, while its δ34S value suggest equilibrium isotopic effect with its parent H2S. Subsequent analysis of the molecular and isotopic (δ13C, δ2H, δ34S) composition of thermogenic, H2S containing, dry natural gases from the Jiannan gas field in China revealed the presence of short thiols and sulfides dominated by MeSH. The δ34S of the VOSC identified suggests they all formed by gas-phase reaction of alkanes (mainly CH4) with the associated H2S.This study demonstrates the applicability of VOSC as a proxy for identification of interaction between H2S and dry gas and identification of H2S sources within a gas reservoir or a basin.

Optimization of CO2 flooding under dual goals of oil recovery and CO2 storage: Numerical case studies of the first-ever CCUS pilot in Changqing oilfield

CCUS (CO2 capture, utilization, and storage) is an important way to reduce carbon emissions and is increasingly applied in the development of hydrocarbon resources. It is crucial to develop proper engineering parameters to achieve the dual goals of enhanced oil recovery (EOR) and CO2 storage. This paper reports systematic numerical case studies of the first-ever CCUS pilot project at Changqing Oilfield to identify further improvement opportunities compared to the current development strategy. The targeted reservoir is located in the Huang 3 (H3) block and is characterized by ultra-low permeability (<1 mD), low oil production (<5 tons/day), and miscible and near-miscible flooding. A three-phase compositional reservoir model is established and a typical well group, consisting of one injector and eight producers, is selected to perform the numerical case studies. We investigate the influence and sensitivity analysis of engineering parameters on oil production and CO2 storage in ultra-low permeability sandstone reservoirs. The results indicate that the well pattern, the timing of switching to water-alternating-gas injection, the gas-water slug size ratio, and the injection rate are controlling factors to achieve favorable performance. The simulation results show that by using optimized engineering parameters, the oil recovery factor of the target reservoir is significantly increased by 25% and the CO2 storage efficiency is increased by 60%. Finally, an optimized development plan is obtained based on the actual conditions of the target reservoir. The reported case studies are supposed to provide insights into the optimal design and operation of CO2 utilization and storage in hydrocarbon reservoirs.

Delayed self-feedback echo state network for long-term dynamics of hyperchaotic systems.

Analyzing the long-term behavior of hyperchaotic systems poses formidable challenges in the field of nonlinear science. This paper proposes a data-driven model called the delayed self-feedback echo state network (self-ESN) specifically designed for the evolution behavior of hyperchaotic systems. Self-ESN incorporates a delayed self-feedback term into the dynamic equationof a reservoir to reflect the finite transmission speed of neuron signals. Delayed self-feedback establishes a connection between the current and previous m time steps of the reservoir state and provides an effective means to capture the dynamic characteristics of the system, thereby significantly improving memory performance. In addition, the concept of local echo state property (ESP) is introduced to relax the conventional ESP condition, and theoretical analysis is conducted on guiding the selection of feedback delay and gain to ensure the local ESP. The judicious selection of feedback gain and delay in self-ESN improves prediction accuracy and overcomes the challenges associated with obtaining optimal parameters of the reservoir in conventional ESN models. Numerical experiments are conducted to assess the long-term prediction capabilities of the self-ESN across various scenarios, including a 4D hyperchaotic system, a hyperchaotic network, and an infinite-dimensional delayed chaotic system. The experiments involve reconstructing bifurcation diagrams, predicting the chaotic synchronization, examining spatiotemporal evolution patterns, and uncovering the hidden attractors. The results underscore the capability of the proposed self-ESN as a strategy for long-term prediction and analysis of the complex systems.

Upper limit magnitudes for induced seismicity in energy industries

AbstractWe adopt extreme value theory to estimate the upper limit of the next record‐breaking magnitudes of induced seismic events. The methodology is based on order statistics and does not rely on knowledge of the state of the subsurface reservoir or injection strategy. The estimation depends on the history of record‐breaking events produced by the anthropogenic activities. We apply the methodology to three different types of industrial operations: natural gas production, saltwater disposal and hydraulic fracturing. We show that the upper limit estimate provides a reliable and realistic upper bound for magnitudes of the record‐breaking events in investigated datasets including 15 publicly available datasets. The predicted magnitudes do not overestimate the observed magnitudes by more than 1.0 magnitude unit and underestimation is rare, probably resulting from insufficient sampling of the statistical distribution of the induced seismicity. The richest dataset, sourced from downhole and surface monitoring of the Preston New Road hydraulic fracturing, provides reliable estimates of the magnitudes over three orders of magnitudes with only slight underprediction of the largest observed event. While the detection of weaker events improves the performance of the method, we show that it can be applied even with a few observed record‐breaking events to provide reliable estimates of magnitudes. However, care must be taken to ensure that event catalogues are estimated consistently across a range of magnitudes.