Replacement Percentage Research Articles

Enhancing the Mechanical Properties of Ultra-High-Performance Concrete (UHPC) Through Silica Sand Replacement with Steel Slag

In modern construction, increasing the sustainability of materials without sacrificing performance is crucial. Ultra-High-Performance Concrete (UHPC) is known for its exceptional strength and durability. However, incorporating waste and optimizing the mix is still a key focus. The main goal of this article is to evaluate the enhancement of the mechanical properties of UHPC by replacing silica sand with steel slag at various percentages (25%, 50%, 75%, and 100%). With this purpose, we measured the compressive, tensile, and flexural strengths, as well as relative density and water absorption. It was found that the best mechanical performance of UHPC occurs at 50% replacement, exhibiting a maximum compressive strength of 126 MPa (+13.5%), a bending strength of 11.6 MPa (+20.8%), and a tensile strength of 7.2 MPa (+6.5%). Moreover, for the same steel slag replacement, 5.1% decrease in the CO2 eq. emissions was found. However, exceeding the 50% threshold led to a deterioration of UHPC’s mechanical properties, and the SEM images revealed that this was mainly caused by the weakened bond between the cement matrix and the aggregates. Thus, it was concluded that the use of steel slag may significantly improve the structural integrity of UHPC when the adequate replacement percentage is adopted (around 50%), being a viable alternative to traditional aggregates that also has environmental advantages (e.g., reduced carbon emissions).

Assessing the Usage of Barytes Powder and Cuddapah Stone Dust as Supplementary Cementitious Materials in Concrete of Grade M30 and M35

This research studied the effects of using Barytes powder and Cuddapah stone waste as substitutes for cement in M30 and M35 grade concrete using OPC. Cement production is known to harm the environment and consume a lot of energy, making the search for alternative materials to replace cement in concrete important.In this study, different amounts of Barytes powder and Cuddapah stone waste were added to concrete mixes as partial replacements for cement. The resulting concrete was tested for compressive strength and compared to normal concrete. The experiment involved making concrete samples with varying percentages of cement replacement, ranging from 0% to 50%, using Barytes powder, Cuddapah stone waste and Combination. The samples underwent standard curing and testing according to Indian standards.The research analysed the results to find the optimum percentage of cement replacement that provided satisfactory mechanical properties. This study determined the feasibility and effectiveness of using Barytes powder and Cuddapah stone waste as partial replacements for cement in concrete production.

Mechanical and Microstructural Properties of Environmentally Friendly Concrete Partially Replacing Aggregates with Recycled Rubber and Recycled PET

Today, waste generation is a worldwide problem, where the major source of waste is generated by worn-out tires and Polyethylene Terephthalate (PET) bottles. Therefore, as a way to provide an ecological disposal and reduce the environmental impact, the feasibility of producing ecological concrete (EC) with recycled rubber (RB) and PET as substitutes for natural aggregates is explored, determining their physical, mechanical and microstructural properties. This experimental study considered the replacement of fine aggregate with RB at 1%, 4%, 7%, 10%, 20% and 30%, and the optimum content of coarse aggregate plus the replacement of coarse aggregate with PET at 1%, 5%, 10% and 15%. The results showed that the optimum percentage of RB was 1%, which, when combined with PET, resulted that the design with 1% RB+ 1% PET was the optimum replacement combination, increasing 10% in bending, 1% in compression and for tension it decreased by 11%, in turn with the XRD test quartz and different aluminosilicates were found, such as portlandite and by SEM-EDS it was possible to visualize polymer flakes embedded in the analyzed fragment. It is concluded that RB and PET can be viable for the production of EC only if low percentages of replacement by natural aggregates are used.

Mechanical and Microstructural Properties of Environmentally Friendly Concrete Partially Replacing Aggregates with Recycled Rubber and Recycled PET

Today, waste generation is a worldwide problem, where the major source of waste is generated by worn-out tires and Polyethylene Terephthalate (PET) bottles. Therefore, as a way to provide an ecological disposal and reduce the environmental impact, the feasibility of producing ecological concrete (EC) with recycled rubber (RB) and PET as substitutes for natural aggregates is explored, determining their physical, mechanical and microstructural properties. This experimental study considered the replacement of fine aggregate with RB at 1%, 4%, 7%, 10%, 20% and 30%, and the optimum content of coarse aggregate plus the replacement of coarse aggregate with PET at 1%, 5%, 10% and 15%. The results showed that the optimum percentage of RB was 1%, which, when combined with PET, resulted that the design with 1% RB+ 1% PET was the optimum replacement combination, increasing 10% in bending, 1% in compression and for tension it decreased by 11%, in turn with the XRD test quartz and different aluminosilicates were found, such as portlandite and by SEM-EDS it was possible to visualize polymer flakes embedded in the analyzed fragment. It is concluded that RB and PET can be viable for the production of EC only if low percentages of replacement by natural aggregates are used.

Performance evaluation of untreated sugarcane bagasse ash as partial replacement of cement on setting time and compressive strength of M15 concrete

Due to its escalating cost, cement, the primary component of concrete, has become a significant issue in Nigeria over time. The use of agricultural wastes such as cow bones, periwinkle shells, rice husks,and sugarcane bagasse as additives to partially replace cement has been made possible by scientific efforts to find alternative and effective materials from large deposits of agricultural wastes. This study examines how adding sugarcane bagasse ash (SCBA) to concrete affects its strength properties. Sugarcane bagasse ash was successfully included in various amounts (0, 2.5, 5.0, 7.5, and 10% by weight of cement). A mix design of 1:2:4 (M15) grade and a water-cement ratio of 0.5 was used to cast 60 concrete cubes measuring (150 x 150 x 150) mm. Concrete's workability and setting time were improved by adding sugarcane bagasse ash to the cement. The outcome revealed a reduction in concrete density with an increase in percentage replacement of sugarcane bagasse ash. Addition of sugarcane bagasse ash to cement increased the concrete's workability and speed of setting. The results showed that concrete density decreased as sugarcane bagasse ash replacement percentage increased. This is not unrelated to the fineness of sugarcane bagasse ash, which makes the cementitious matrix and aggregate interface more intense and lighter. Concrete's compressive strength was discovered to be decreased by the usage of sugarcane bagasse ash. Between 0, 2.5, 7.5, and 10% sugarcane bagasse ash, the average compressive strength measured at 28 days was found to be 25.93, 25.19, 23.70, 20.30, and 18.96 MPa, respectively. 10% sugarcane bagasse ash concentration was suggested as the optimal level to employ for improving concrete characteristics.

Can mussel shell waste optimize cement and air lime mortars hygrothermal performance?

Mussel shells used as aggregates for mortars have flaky and irregular particles, which significantly increases the pore volume. This leads to the identification the microstructure of mussel shell mortars as a light and porous composite, which could have good hygrothermal properties. In the present study, the density and thermal properties are assessed on cement and air lime mortars, each with three replacement percentages of replacement of conventional sand by mussel shell sand (25 %, 50 % and 75 %), are evaluated and compared with their respective baselines (0 % replacement). Thermal conductivity measurements are also carried out on different loose fractions of the mussel shell aggregate to understand the behaviour of this material without binder matrix. Finally, adsorption and desorption cycles at 80 % and 50 % relative humidity are carried out on loose aggregate fractions and on the eight mortars. The results are very positive for the mussel shell mortars, as it can be concluded that the use of mussel shell aggregates improves the thermal performance and the potential moisture buffering capacity of both cement and air-lime coating mortars.

Studying of Mechanical Behavior of Waste Materials Modified Cement Mortar

Large-scale environmental problems have been triggered by ceramic tiles from demolished buildings and animal bone waste. Therefore, optimizing their potential for reuse and recycling is an important goal of sustainable solid waste management. The primary objective of this study is to evaluate the feasibility of partial replacement of the fine aggregates in cement mortar with a combination of natural animal bone powder and industrial waste materials which is wall tiles ceramic powder. This study measures thermal and mechanical characteristics. Recycling construction waste is one of many ways to deny waste material from entering landfills and create new eco-friendly material that reduces energy consumption in buildings. Modified mortar cement specimens with 5% up to 25% mixtures were combined using a 1:3 ratio and a 0.5 W/C ratio to see how the ratios would affect the material’s properties. The addition of a superplasticizer boosted the cement mortar’s workability and compressive strength. The compressive strength, flexural strength, density, and thermal conductivity were evaluated for each mortar mixture ratio. Results showed that compared to regular cement mortar, cement mortar combined with 20% bone and ceramic powder wastes reached the optimal replacement percentage. Compressive strength increased by 54% and flexural strength by about 67%. At the 28-day mark, thermal insulation was lowered by 25%.It is concluded from this study that it is possible to use bone waste as a natural material with ceramic waste as an industrial material to modify the insulation and mechanical properties of cement mortar.

Drying Shrinkage Properties and Engineering Performance for Cement Mortar Containing Bamboo Biochar Powder (BCP)

Drying shrinkage, the reduction in volume as a material like cement mortar dries, can result in cracks and decreased durability. Bamboo biochar powder (BCP) serves as a substitute for cement in mortar, affecting its drying shrinkage characteristics. Research has shown that BCP in cement mortar can alleviate drying shrinkage by absorbing and retaining moisture. This study aims to assess the chemical and physical properties of BCP, determine the mechanical attributes of bamboo biochar mortar with varying percentages of cement replacement, and investigate the impact of BCP on mortar shrinkage in indoor and outdoor tropical conditions. BCP, derived from Gigantocholoa Abociliata species and sized at 75 µm, was used to replace cement rates of 0%, 5%, 10%, 15%, and 20%. Sixty cube samples (50x50x50mm) were employed for density, ultrasonic pulse velocity (upv), compressive strength, and water absorption tests. Additionally, thirty prism samples (100x100x400mm) were employed to assess drying shrinkage during outdoor and indoor exposure, spanning up to 150 days. The experimental data indicates a consistent trend as the percentage of cement replacement increases in the mortar mix, density, and compressive strength decrease, while UPV and water absorption increase. The lowest shrinkage strain was observed during indoor exposure with 5% cement replacement, attributed to BCP acting as a filler, creating strong bonding properties, and reducing shrinkage. Conversely, the highest strain was noted during outdoor exposure with 20% cement replacement, resulting from higher moisture loss. In summary, a 5% replacement of cement with BCP in mortar offers the most effective reduction in shrinkage strain.

Where do all the ewes go? Ewe culling and mortality in 34 sheep flocks in New Zealand

ABSTRACT Aims To describe rates of and reasons for culling and mortality of ewes between breeding and mid-lactation on New Zealand sheep farms; to investigate associations of these variables with farm demographic variables; and to describe rates of and reasons for culling of ewes at weaning. Methods Participants were a convenience sample of 34 farms from across New Zealand. Demographic data were initially collected for each farm via a questionnaire administered in-person to the flock owner or manager. During approximately 8 months from breeding to mid-lactation, ewe tally, culling and mortality data were collected and used to calculate various parameters related to flock performance and to investigate associations. During the main ewe-culling event at weaning, ewe-culling data were collected from 29/34 flocks participating in the study. Results There was considerable variation between flocks, but the between-flock mean replacement percentage was 29.2 (SD 5.0)%. Overall, a between-flock mean of 10.5 (SD 4.6)% of ewes presented for breeding were culled or dead/missing by mid-lactation and thus did not rear any lambs. Additionally, from 27 flocks that reported data on ewes’ success at rearing lambs, a between-flock mean of 3.9 (SD 2.5)% of ewes that remained alive at mid-lactation failed to rear any lambs, resulting in an overall between-flock mean loss of 23.1 (SD 6.3) potential lambs per 100 ewes. Two-thirds of ewe mortalities between breeding and mid-lactation occurred during the lambing period. Model results showed flocks with higher pregnancy scanning percentages had lower rates of culling and mortality between breeding and mid-lactation. However, apart from farm contour, from breeding to mid-lactation there were no associations for culling and mortality with farm size, flock size, number of ewes per labour unit, whether ewe hoggets (7–9 months of age) were presented for breeding, or duration of the breeding period. A between-flock mean of 16.5 (SD 8.3)% of ewes present at weaning were culled, and among mixed-age ewes, the most common reasons for culling at this time were age, incisor teeth defects and udder defects. Conclusions To reduce unnecessary ewe culling and mortality, attention should be focused on maximising conception rates, ensuring judicious culling decisions, optimising body condition score, and identifying farm-specific causes of death over the lambing period to facilitate targeted intervention strategies. Clinical relevance Identifying why and when ewes exit flocks, and comparing it with the data presented here, will facilitate the development of flock-specific interventions to reduce ewe culling and mortality. Abbreviations BCS: Body condition score; NI: North Island; SI: South Island

New Eco-Cements Made with Marabou Weed Biomass Ash

Biomass ash is currently attracting the attention of science and industry as an inexhaustible eco-friendly alternative to pozzolans traditionally used in commercial cement manufacture (fly ash, silica fume, natural/calcined pozzolan). This paper explores a new line of research into Marabou weed ash (MA), an alternative to better-known conventional agro-industry waste materials (rice husk, bagasse cane, bamboo, forest waste, etc.) produced in Cuba from an invasive plant harvested as biomass for bioenergy production. The study entailed full characterization of MA using a variety of instrumental techniques, analysis of pozzolanic reactivity in the pozzolan/lime system, and, finally its influence on the physical and mechanical properties of binary pastes and mortars containing 10% and 20% MA replacement content. The results indicate that MA has a very low acid oxide content and a high loss on ignition (30%) and K2O content (6.9%), which produces medium–low pozzolanic activity. Despite an observed increase in the blended mortars’ total and capillary water absorption capacity and electrical resistivity and a loss in mechanical strength approximately equivalent to the replacement percentage, the 10% and 20% MA blended cements meet the regulatory chemical, physical, and mechanical requirements specified. Marabou weed ash is therefore a viable future supplementary cementitious material.

The study on bond‐slip constitutive model of recycled concrete under different loading rates

AbstractIf recycled concrete is to be widely, reasonably, and safely applied in practical engineering, the study of bond‐slip performance between steel bars and concrete is crucial. In this paper, the central pull‐out test of recycled concrete under different loading rates was conducted. The characteristics of failure mode and crack directions of the specimens were observed and analyzed. The ultimate bond strength and slip displacement between rebar and concrete were analyzed. The effects of three parameters, namely concrete strength grades, replacement percentage of recycled coarse aggregate, and loading rates on the failure modes and bond‐slip mechanical properties of recycled concrete, were analyzed and summarized. The experimental results showed that there were significant differences in the influence trend and amplitude of the above three parameters on the ultimate bonding strength, slip amount, and slip curve. Based on the above experimental and theoretical analysis, a reasonable bond‐slip constitutive model was established in this paper and was in good agreement with the experimental results.

Bonding strength of steel and concrete containing Palm Oil Fuel Ash (POFA) and Expanded Polystyrene (EPS)

The usage of recycled materials in concrete has become popular recently. This paper focuses on a study related to the bonding between steel and concrete containing expanded polystyrene beads (EPS) and palm oil fuel ash (POFA) as replacement material. The EPS were used as fine aggregate replacement, and POFA was used as cement replacement. The replacement percentages for EPS and POFA in the concrete were limited to a range of 0-30% and 0-10%, respectively. Previous studies have identified the potential of POFA and EPS as concrete substances. The typical issue with EPS-containing concrete is its characteristic weakness, which leads to a compromised bond with steel. This occurs because EPS fails to effectively interact with cement, resulting in a weak bond and low compressive strength. Consequently, in this study, POFA is introduced as an addition to enhance the bond strength between EPS-containing concrete and steel. Pull-out tests in this study seem to represent the bonding performance between concrete and steel. The 10% of POFA in concrete seems might improve its performance in terms of compression strength, and bonding between concrete and steel.

Fresh and Hardened Properties of Alkali-Activated POFA-GGBFS Pastes Cured in Ambient Temperature – An Initial Mix Design

Weak soils are characterised by their high compressibility and low shear strength, which requires stabilisation to improve their compaction and strength characteristics before being used for construction projects. Recent trends in soil stabilisation show an increased interest in the application of waste-derived geopolymers as low-carbon materials to address the carbon emission problem related to cement production. This paper presents the preliminary findings of using Palm Oil Fuel Ash (POFA) and Ground Granulated Blast Furnace Slag (GGBFS) binary blends as geopolymer precursor materials. These binary waste material blends were activated using alkaline solutions, namely Sodium Hydroxide (NH) and Sodium Silicate (NS), to synthesise geopolymers at ambient temperatures. Three main factors were considered for the optimisation of the geopolymer mix design, as recommended by past research: alkali equivalent (8-11.5%), activator modulus (0-0.7), and slag replacement (fixed at 30%). Alkali equivalent and activator modulus parameters were varied and tested to establish its initial and final setting times, workability and strength properties, while the slag replacement percentage was set at 30%. This study aimed to determine the most influential parameters to produce the geopolymer material with the highest compressive strength and satisfactory setting times and workability. Single-source alkali activators (NH only) used on POFA-GGBFS produced specimens with smaller flow diameters, longer initial and final setting times, and lower compressive strength than specimens activated with NH and NS. Geopolymer specimens synthesised with NH and NS produce stiffer compounds possessing higher compressive strength values and explosive-type failure modes due to their higher silica content. At ambient temperatures, TM-Mix 2 (7% alkali equivalent and 0.7 activator modulus) produced the highest compressive strength value of 67.3 MPa at 28 days curing, flow diameter of 227 mm, with the initial and final setting time of 25 minutes and 45 minutes, respectively. Consequently, the results show that the preliminary POFA-GGBFS geopolymer mix design could produce sustainably sourced geopolymer compounds with adequate strength and acceptable setting time and workability. This study is part of a current investigation to further optimise the POFA-GGBFS mix design for the purpose of weak soil stabilisation.

Incorporating Crumb Rubber in Slag-Based Geopolymer: Experimental Work and Predictive Modelling

Crumb rubber (CR), a prevalent hazardous waste material, poses significant environmental challenges that necessitate innovative management strategies. Recent studies have focused on incorporating CR and ground granulated blast furnace slag (GGBS) into geopolymer concrete (GC) to address this challenge. This research presents a novel approach that combines experimental analysis with machine learning (ML) techniques to investigate the chemical effects of these materials on GC. Initially, compressive strength (CS) tests are conducted on rubberized geopolymer (RG) concrete, and the resulting data are further analyzed through ML algorithms to enhance the understanding of material behavior. Despite numerous attempts by researchers to integrate CR into geopolymer-based materials, the challenge of mitigating strength degradation persists. Therefore, it becomes imperative to construct a predictive model that relies on new variables influencing the strength characteristics. This research develops a predictive model to assess concrete compressive strength (CS). Key variables such as CR grade (particle size), incorporation percentage, and oxide ratio were analyzed for their impact on geopolymer strength. Employing ensemble techniques, namely Bagging (BA) and Gradient boosting (GB) with five learners (M5P, random forest (RF), random tree (RT), reduced error pruning tree (REPT), and support vector machine (SVM), the study found that M5P-GB models offered the most accurate CS predictions with the highest accuracy and lowest errors. Moreover, the dataset was checked via the k-fold cross-validation technique and confirmed the developed models' robustness, reliability, and effectiveness. Furthermore, uncertainty analysis revealed that GB-M5P-unpruned models-maintained uncertainty percentages of 14.769% at 7 days and 11.277% at 28 days, which was under the 35% threshold. Additionally, the sensitivity analysis identified the CR grade and replacement percentage by volume of crusher dust (CD) as the most critical factors affecting CS. These findings underscore the importance of considering predictive model development in decision-making processes related to RG concrete properties, providing valuable insights into optimizing the model's robustness and reliability for practical applications. However, the study's reliance on specific input parameters and controlled laboratory conditions may limit the generalizability of the predictive models, necessitating further validation under diverse real-world conditions and variations in CR source and environmental factors.

Importance of pumice amount in the design of self-compacting lightweight concrete

Although concrete has high compressive strength values, it has a heavy unit volume and low tensile strength. In this study, the normal-weight aggregate, which takes up the most space in concrete by volume and mass, was partially replaced with pumice aggregate, and macro steel fiber (30 mm) was also added to the mixtures. This experimental work aims to investigate the effect of pumice aggregate amount on the fresh and hardened properties, as well as the flexural performance of the self-compacting lightweight concrete (SCLC). The replacement proportions of pumice aggregate with crushed sand were arranged as 45%, 50%, and 55% of the entire aggregate by weight. Three mixtures, each with 1% macro steel fiber reinforcement and without fiber, were prepared for each mixture scenario. The mix design of these six mixtures was arranged to achieve the self-compacting ability and the workability tests recommended by EFNARC (slump-flow, T50, J-ring) were taken into account. To investigate the mechanical properties (compressive, splitting tensile, and flexural strengths) and flexural toughness of the samples, the specimens were cured in water at 23±2 °C for 28 days. As a result, the unit volume weights of the specimens produced from pumice-substituted mixtures decreased with the increase in the pumice dosage, while the compressive, splitting tensile, and flexural strengths decreased. However, it has been determined that all SCLC mixtures including pumice aggregate provided workability properties in general and had enough compressive strength to be used in the production of structural bearing elements, regardless of fiber content. As a result, the optimum pumice aggregate replacement percentage with crushed sand was found to be 45% and the best flexural performance values of the specimens having macro steel fiber were observed in the ones having 45% pumice aggregate substitution.

An Experimental Investigation on Nano-Enhanced Tertiary Blended Concrete Incorporating Industrial Wastes

Concrete is a crucial material in the construction industry; however, its production process releases carbon dioxide into the atmosphere. Undoubtedly, the building sector's increasing global interest unveils a challenge to its ability to withstand cement alternatives and manage the resulting outflows. Fly ash, GGBS (ground granulated blast furnace slag), Zeolite, rice husk, silica fume, metakaolin, and various industry by-products can typically replace cement. This research study aims to replace cement with multiple cementitious materials, individually and in combination, to evaluate the strength characteristics of blended concrete. The replacement percentages ranged from 0 to 30% for each substitute material, such as fly ash, GGBS, and Zeolite, and strength tests were done to assess the performance of the modified concrete after 7 and 28 days of water curing. Ordinary Portland Cement (OPC) is used to create M30 and M50 grades of concrete. Similarly, cement was replaced with fly ash, GGBS, and Zeolite in amounts ranging from 10 to 30% for M30 and M50 grades, and their strength was evaluated after 7 and 28 days of curing. The most efficient percentage of substitution for both the concrete grades is determined, and the corresponding replacement ratio is used to produce the blended concrete, which incorporates cement, fly ash, GGBS, and Zeolite. The overall findings reveal that the composite concrete, comprising four binding materials, demonstrated superior strength for the concrete grade compared to alternative substitutes. The optimal mixture ratios for M30 concrete after 28 days consist of 20% fly ash, 20% GGBS, and 10% zeolite. Moreover, different ratios of Zeolite-10%, Fly-Ash-30%, and GGBS-20% were used to produce M50 concrete.

Improved morphological and yield responses of green lettuce (Lactuca sativa L.) grown with seaweed extract as a hydroponic nutrient solution

Sargassum polycystum is among the seaweed species in the Philippines that are considered coastal waste after drifting on the shorelines. Although there has been a report on the potential of S. polycystum as a biostimulant for certain crops, its utilization as a hydroponic nutrient solution is not yet thoroughly analyzed. Thus, a study utilizes various ratios of S. polycystum seaweed extract (SE) mixed with commercial hydroponic nutrient solution (CHNS) to the growth and yield of green leaf lettuce grown under the Kratky method of hydroponic system. Treatments are 100% CHNS and percentage replacements of CHNS with SE (25%, 50%, and 75%, respectively). The result shows a 10.53% increase in lettuce plant height grown under 25% and 50% SE compared to 100% CHNS. A similar result is also observed in the lettuce leaf width (14.29%), leaf length (7.14%), and plant weight (22.41%). Regarding root length, replacing 50% SE resulted in longer root length (44.83%) and more leaves (10%) compared to lettuce plants grown under 100% CHNS. However, replacement of SE beyond 50% is detrimental to leaf length and comparable to all growth and yield parameters with 100% CHNS. Regarding the return on investment, 50% SE replacement has the highest return of 98.62% compared to 100% CHNS, with 49.87% only for a projected six cropping cycles. Hence, a 50% replacement of CHNS with SE from its recommended rate can be suggested for more profitable production of green leaf lettuce under a hydroponic system.

Pore-scale deformation characteristics of hydrate-bearing sediments with gas replacement

Gas replacement method enables the simultaneous exploitation of natural gas and the realization of carbon capture, utilization, and storage (CCUS). Safe exploitation of hydrate-bearing sediments (HBS) has garnered significant attention, particularly concerning the engineering geological risks involved. Understanding deformation characteristics during shear after the replacement of HBS is crucial for safe and efficient exploitation. This study employs microfocus computer tomography and digital volume correlation (DVC) to investigate the deformation characteristics of HBS samples with varying replacement percentages. Key findings include: 1. An increase in failure strength of HBS is observed with higher replacement percentages due to improved hydrate cementation and consolidation under confining pressure. 2. DVC analysis shows that narrower radial displacement ranges are associated with increased pore compression, while wider ranges indicate greater particle repositioning. Frequent large axial displacements suggest significant pore compaction, whereas smaller axial displacements indicate particle movement and pore-filling phenomena. 3. The gas replacement process enhances the cementation structure of HBS without altering hydrate saturation, resulting in thinner shear bands and accelerated strain softening with higher replacement percentages. 4. The DVC approach effectively captures volumetric strain and deformation behaviors, offering valuable insights into sediment responses under shear. This study provides a theoretical reference for geological safety evaluation during gas replacement exploitation.

Effect of accelerated carbonation on fine cement paste aggregates

Accelerated carbonation is suggested as a potential alternative for carbon dioxide sequestration, which also improves the microstructure of recycled concrete aggregates. In this study, the carbonation parameters of model aggregates derived from cement pastes with two different water/cement ratios (i.e., 0.5 and 0.7) were evaluated in order to maximize the benefits of the carbonation process on their density and absorption. For this purpose, in a first phase, the initial moisture content of the model aggregates and the reaction time were evaluated. Furthermore, in a second phase of mortar production, the fraction of fine natural aggregates was replaced, considering each type of unprocessed and carbonated model aggregate at volumetric replacement percentages of 50% and 100%, varying the amount of water in the mortar mix to maintain a similar workability in all the series. In this way, the properties of the eight series of mortars are evaluated in comparison with the control series made only with natural aggregates. The results indicate that the accelerated carbonation process positively influences density and absorption in the model aggregate. Regarding the parameters of the accelerated carbonation environment analyzed, for a higher w/c ratio in the original model aggregate, higher initial water content was necessary for the carbonation process to be efficient. As for the mechanical performance of the mortars with model aggregate, the series that incorporated model aggregate aggregates with a w/c ratio of 0.5 achieved better mechanical behavior compared to the series replacing model aggregate with a w/c ratio of 0.7; this was related to the formation of a more compact matrix in the mortar with model aggregate of cementitious pastes.

Analysis of the Impact of Superplasticizer on the Compressive Strength of Periwinkle Shell Concrete

This research project investigates the compressive strength characteristics of superplasticized concrete incorporating periwinkle shell (PS) as partial replacements for granite coarse aggregate. The study aims to assess the influence of superplasticizer content and curing age on the compressive strength development of the novel concrete mixtures. Comparative analysis with plain concrete (control specimen) reveals that superplasticized concrete with periwinkle shell partial replacement exhibits a slower strength development. Results indicate that the compressive strength of superplasticized PS concrete attains its maximum strength (22.07 kN/mm²) at 21 days with a 15% partial replacement and 0.5% superplasticizer content. The findings suggest that optimal strength development for PS partial replacement performs best at higher percentages (15%). Concerning the workability of fresh concrete, PS partial replacement exhibits a consistent increase in slump values with higher percentages of replacement and superplasticizer content, peaking at 55mm at 15% partial replacement and 1.5% superplasticizer content. This study contributes valuable insights into the optimization of compressive strength and workability of superplasticized concrete with PS partial replacements, offering a sustainable and resource-efficient alternative to conventional concrete mixtures