Developing efficient photocatalysts that can degrade persistent antibiotics in water bodies and generate clean H2 through water splitting is crucial for environmental and energy sustainability. This study introduces an advanced hierarchical ZnIn2S4/TiO2/Ti3C2 (ZIS/TO/TC) heterocatalyst for the efficient removal of amoxicillin (AXC) from wastewater and the production of H2 through water reduction process under simulated solar illumination. The ZIS/TO/TC hybrids were fabricated via an in situ hydrothermal process, resulting in a hierarchical 3D structure that capitalizes on the complementary properties of each component. The design of the S-scheme heterojunction significantly enhances charge separation and transfer efficiency, offering improvements over traditional type-II or Z-scheme mechanisms. Notably, the optimized ZIS10/TO/TC hybrid catalyst demonstrated remarkable activity, achieving 100 % AXC degradation and excellent mineralization within 90 min, along with an H2 production rate of 4104 μmol h−1 g−1, significantly outperforming the individual components and exceeding previously reported efficiencies. The outstanding performance of the ZIS10/TO/TC hybrid is attributed to its enhanced light absorption properties, synergistic interactions among the ZIS, TO, and TC MXene, and the efficient S-scheme charge transfer mechanism, which facilitates effective charge separation and transfer while preserving the strong reducing and oxidizing capabilities of the components. Additionally, the ZIS10/TO/TC hybrid exhibited excellent stability over multiple photocatalytic tests, emphasizing its potential for practical applications. Therefore, this research demonstrates an advanced and highly efficient hybrid photocatalyst that offers a promising and sustainable solution for both integrated water treatment and renewable energy generation.
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