Removal Of Tetracycline Antibiotics Research Articles

Atomic H* mediated fast decontamination of antibiotics by bubble-propelled magnetic iron-manganese oxides core-shell micromotors

Wastewater remediation using micro/nanomotors is a hot topic, and MnO2 based materials have become fascinating alternatives to rare noble metal-based micro/nanomotors. Herein, we demonstrate facile and large-scale synthesis of Fe-MnO2 core-shell micromotors for antibiotic pollutant removal. Heat-treatment results in a phase transformation of MnO2 with formation of iron oxides and partially exfoliates the MnO2 nanoplate shell structure to promote mobility. The iron-manganese oxide micromotors exhibit an efficient removal of tetracycline antibiotics via a combination of catalytic degradation and adsorptive bubble separation. For the first time, atomic H* was found to participate in the micromotor-assisted degradation process, resulting in optimal Fenton reaction in neutral conditions with a good decontamination performance. Owing to the merits of abundance, magnetic recovery, facile fabrication, good motion, and environmental friendliness, as well as decontamination performance in a wide pH range, these core-shell micromotors demonstrate a promising candidate in practical wastewater treatment.

Removal of Tetracycline Antibiotic from Aqueous Solution Using Zeolite-X Modified by Pyridium Bromide Cationic Surfactant: A Laboratory Study

Removal of Tetracycline Antibiotic from Aqueous Solution Using Zeolite-X Modified by Pyridium Bromide Cationic Surfactant: A Laboratory Study

Optimization and Modeling of Tetracycline Antibiotic Removal Using TiO2/N/S Nanocatalyst in the Presence of Visible Light in Aqueous Solutions

Optimization and Modeling of Tetracycline Antibiotic Removal Using TiO2/N/S Nanocatalyst in the Presence of Visible Light in Aqueous Solutions

Fabrication of carbon dots@hierarchical mesoporous ZIF-8 for simultaneous ratiometric fluorescence detection and removal of tetracycline antibiotics

Excessive residues of tetracycline antibiotics (TCs) are very harmful to the ecosystems and human health, thus it is urgent to establish an effective method for both detection and removal of TCs. Herein, the blue luminescent carbon dots (CDs) were synthesized and modified into a hierarchical mesoporous zeolitic imidazolate framework-8 (HZIF-8) which prepared using hydrogel as template to form CDs@HZIF-8 complex. The blue fluorescence of CDs@HZIF-8 at 440 nm was quenched by TCs through internal filtering effect (IFE), meanwhile, the interaction between TCs and Zn2+ led to a significant conformational change of TCs, which enhanced the fluorescence at 536 nm. Based on the reverse change of two fluorescence signals (F536/F440), a ratiometric fluorescence sensor was constructed for the detection of TCs. It is worth mentioning that, thanks to the hierarchical porous structure of CDs@HZIF-8, sufficient space is provided for TCs enrichment in the pores and full contact with the skeleton, which improves the adsorption capacity of TCs and significantly enhances the sensitivity of TCs detection. The detection limits of tetracycline (TC), oxytetracycline (OTC) and doxycycline (DOX) were 6.56 nM, 29.46 nM, and 30.58 nM, respectively. Additionally, the rational design method was successfully applied to detect TCs in milk samples.

N self-doped hierarchically porous carbon derived from biomass as an efficient adsorbent for the removal of tetracycline antibiotics

In this study, we developed a simple strategy to synthesize a N self-doped hierarchically porous carbon adsorbent (LPC-NC) derived from biomass using potassium oxalate monohydrate and calcium carbonate and remove tetracyclines that are major antibiotics frequently measured in surface water. In the pyrolysis process, the N-enriching lotus seed pots biomass decomposed and formed a porous carbon matrix with self-doped N. The LPC-NC displayed high adsorption amount (506.6 mg/g for tetracycline (TTC) and 445.3 mg/g for oxytetracycline (OTC)), short equilibrium time (30 min) and stable reusability (the decline efficiency<8.0% after five cycles). Batch adsorption experimental and theoretical studies showed that the high adsorption capacity of LPC-NC for tetracyclines was mainly ascribed to the self-doped pyridinic-N species and the adsorption capacity of pyridinic-N species at the edge location was better than that of pyridinic-N species at the vacancy location. Importantly, we believe that the high adsorption performance of LPC-NC for tetracyclines is due to the activation of carbon π electrons by destroying the integrity of conjugation on LPC-NC, thus enhancing the π-π interaction between LPC-NC and tetracyclines. In addition, the results of solid-state nuclear magnetic resonance (NMR) confirmed that the hierarchically porous structure of LPC-NC was conducive to the adsorption of tetracyclines. These insights provide new ideas for the rational design of N-doped carbon-based adsorbents for the efficient removal of tetracyclines.

Insight into the significant contribution of intrinsic defects of carbon-based materials for the efficient removal of tetracycline antibiotics

Due to their high adsorption capacity and low cost, carbon-based materials have experienced great progress in the removal of tetracyclines. Unfortunately, the nature of the adsorption site is far from clarified. Especially, it is still a great challenge to systematically explore the impact of intrinsic defects of carbon-based adsorbents on the adsorption of tetracyclines. Herein, carbon-based adsorbents with different defects were designed and prepared, and their adsorption properties of tetracyclines were systematically studied. From microscopic characterization of carbon-based adsorbents and batch adsorption experiments, the intrinsic defects of carbon-based adsorbents facilitated the adsorption performance of tetracyclines. The best adsorbent (SSG-C) had a very high adsorption capacity (526.9 mg/g for tetracycline (TTC); 360.9 mg/g for oxytetracycline (OTC)). Additionally, density functional theory simulation results show that the ring defects of sp2 species promoted the adsorption performance more than sp3 edge defects, and the adsorption performance increased with increasing ring defect of sp2 species. Based on the above analysis, we proposed that intrinsic carbon defects activate the π electrons of sp2 carbon and facilitate π-π interaction between carbon-based adsorbents and tetracyclines, particularly the ring defects of sp2 species. This study provides a decisive contribution to better understanding of the role of intrinsic defects in carbon-based adsorbents for removal of tetracyclines.

Efficient adsorption and removal of tetracycline antibiotics from aqueous solutions onto nickel oxide nanoparticles via organometallic chelate

Efficient adsorption and removal of tetracycline antibiotics from aqueous solutions onto nickel oxide nanoparticles via organometallic chelate

Removal of tetracycline antibiotic from aqueous solution using biosorbent

Removal of tetracycline antibiotic from aqueous solution using biosorbent

A reusable ratiometric fluorescent probe for the detection and removal of doxycycline antibiotic demonstrated by environmental sample investigations

Tetracycline antibiotic residues have attracted worldwide attention due to the serious damage to human health and the environment. However, most of the reported fluorescent probes were based on a single fluorescence channel-based response, which often suffered from signal fluctuation-induced poor reproducibility. Herein, by taking advantage of the unique properties of zeolitic imidazolate frameworks (ZIFs), a novel europium-doped ZIF nanocomposite (ZIF-Eu) was reported for the detection of doxycycline (DOX) in a ratiometric fluorescence manner. The synthesized probe only showed blue fluorescence at 420 nm since the fluorescence of Eu was quenched by the coordinated water molecules. However, due to the strong coordination ability of DOX to Eu atoms, the probe solution demonstrated an obvious fluorescence enhancement at 615 nm in the presence of DOX, while the blue fluorescence signal remained unchanged, realizing a ratiometric fluorescence response to DOX with a good linear range from 1 to 9 μM and a detection limit of 49 nM. Interestingly, it is found that DOX could be discriminated from other tetracycline antibiotics using this ratiometric fluorescent probe. In addition, direct detection of DOX in soil samples, the DOX removal efficiency and the reusability of the proposed ZIF-Eu nanocomposite were demonstrated to evaluate its potential in environmental remediation application.

Application of magnetic activated carbon coated with CuS nanoparticles as a new adsorbent for the removal of tetracycline antibiotic from aqueous solutions (isotherm, kinetic and thermodynamic study)

Application of magnetic activated carbon coated with CuS nanoparticles as a new adsorbent for the removal of tetracycline antibiotic from aqueous solutions (isotherm, kinetic and thermodynamic study)

0D/2D/2D ZnFe2O4/Bi2O2CO3/BiOBr double Z-scheme heterojunctions for the removal of tetracycline antibiotics by permonosulfate activation: Photocatalytic and non-photocatalytic mechanisms, radical and non-radical pathways

• Efficient removal of TCs was achieved by the catalyst/sunlight/PMS systems. • The double Z-scheme heterojunction structure was proved by multiple characterizations and DFT calculation. • 1 O 2 was the dominant species for TCs degradation rather than SO 4 ·− or ·OH. • Photocatalytic and non-photocatalytic processes were distinguished. • Radical and non-radical pathways were also elucidated. A series of environmental-friendly and cost-effective 0D/2D/2D ZnFe 2 O 4 /Bi 2 O 2 CO 3 /BiOBr double Z-scheme heterojunctions (abbreviated as xZnCB) were fabricated by a hydrothermal method using an electrostatic self-assembly strategy. The removal efficiencies toward tetracycline (TC), oxytetracycline (OTC), and doxycycline (DOX) were 93%, 90.1%, and 89.4% in 10ZnCB/sunlight/permonosulfate (PMS) systems within 20 min, and the degradation rate constants of 10ZnCB were 5.7–8.2 times higher than those of ZnFe 2 O 4 and 2.6–2.9 times higher than those of Bi 2 O 2 CO 3 /BiOBr (CB) under the same conditions. XPS valence band spectra, quenching experiments, EPR measurements, and density functional theory (DFT) calculations demonstrated the existence of the double Z-scheme heterojunctions. The coexistence of radical and non-radical pathways caused by photocatalytic and non-photocatalytic degradation mechanisms was also elucidated. PMS was effectively activated by a photoinduced e − , · O 2 − , and Fe(II)/Fe(III) pathway, and active species including · O 2 − , 1 O 2 , SO 4 · − , · OH, and h + participated in the catalytic processes. Unexpectedly, 1 O 2 , and · OH were determined to be the primary species during the degradation processes instead of SO 4 · − . Recycling experiments, metal leaching measurements, and TC degradation experiments in the secondary effluent demonstrated the excellent catalytic and structural properties of these xZnCB hybrid materials.

Designing Oxygen Vacancy Mediated Bi2moo6/C3n5 S-Scheme Heterojunctions for Boosted Photocatalytic Removal of Tetracycline Antibiotic and Cr(Vi): Intermediate Toxicity and Mechanism Insight

Designing Oxygen Vacancy Mediated Bi2moo6/C3n5 S-Scheme Heterojunctions for Boosted Photocatalytic Removal of Tetracycline Antibiotic and Cr(Vi): Intermediate Toxicity and Mechanism Insight

A Bifunctional Nitrogen-Doped Hierarchical Porous Graphite Carbon for Adsorption and Catalytic Removal of Tetracycline Antibiotics: Performance and Nonradical Mechanism

A Bifunctional Nitrogen-Doped Hierarchical Porous Graphite Carbon for Adsorption and Catalytic Removal of Tetracycline Antibiotics: Performance and Nonradical Mechanism

Photocatalytic MIL101(Fe)/ZnO chitosan composites for adsorptive removal of tetracycline antibiotics from the aqueous stream

Antibiotics are widely used to treat bacterial infections in humans and animals. Among different classes of antibiotics, tetracycline (TC) is the most used, and its elimination from the environment has become a serious concern. The present study focused on the facile synthesis of zinc oxide (ZnO) nanoflowers, Matériaux de l' Institut Lavoisier 101 (MIL-101(Fe)) and MIL101(Fe)/ZnO chitosan composite beads for the adsorptive removal and photocatalytic degradation of TC. The effect of various operational parameters such as adsorbent dosage, TC concentration, pH and time was investigated. The MIL101(Fe)/ZnO chitosan composite beads were characterized by XRD, TGA, SEM, BET surface area and FT-IR. The MIL101(Fe)/ZnO chitosan composite beads showed high thermal stability up to 250 °C and the highest adsorption capacity of 31.12 mg g−1. The PSO adsorption kinetics and Langmuir adsorption isotherm were found the best fit. The adsorption of TC on the MIL101(Fe)/ZnO chitosan composites was attributed to the π -π interaction between the aromatic rings of TC and the adsorbent. The adsorption of the TC was confirmed using the SEM and FT-IR; the TC was visible on the bead's surface that showed the affinity of the synthesized beads towards the adsorption of the TC. The beads were regenerated with high efficiency in the presence of sunlight. The photo-excitation was due to MIL101(Fe) and ZnO, which created the electrons (e−) and holes (h+) in the structure. The beads showed a removal efficiency of more than 90% up to 5 cycles. Therefore, the MIL101(Fe)/ZnO chitosan composite beads can be used and reused for a long period.

The Effect of Exogenous Oxytetracycline on High-Temperature Anaerobic Digestion of Elements in Swine Wastewater

Tetracycline antibiotics (TCs) are a common type of antibiotic found in swine wastewater. Oxytetracycline (OTC) is a significant type of TC. This study mainly examined the influence of OTC on high-temperature anaerobic digestion by adding OTC to collections of swine wastewater at different times during the digestion process. The results showed that high-temperature anaerobic digestion was suitable for the removal of TCs, with an 87% OTC removal efficiency achieved by day 20. Additionally, OTC added from external sources was found to inhibit the chlortetracycline degradation process and affect the first-order degradation kinetic model of TCs. Complexation reactions were the main ways in which OTC affected the heavy metal content of the water. The exogenous addition of OTC was found to inhibit the activity of some digester microbial strains, reduce the proportion of dominant strains, such as MBA03, and kill certain specific strains. This performance alteration was most obvious when OTC was added in the middle of the reaction.

Biosynthesis of SiO2 nanoparticles using extract of Nerium oleander leaves for the removal of tetracycline antibiotic

Tetracycline (TC) is one of the antibiotics that is found in wastewaters. TC is toxic, carcinogenic, and teratogenic. In this study, the tetracycline was removed from water by adsorption using dioxide silicon nanoparticles (SiO2 NPs) biosynthesized from the extract of Nerium oleander leaves. These nanoparticles were characterized using SEM-EDX, BET-BJH, FTIR-ATR, TEM, and XRD. The influences of various factors such as pH solution, SiO2 NPs dose, adsorption process time, initial TC concentration, and ionic strength on adsorption behaviour of TC onto SiO2 NPs were investigated. TC adsorption on SiO2 NPs could be well described in the pseudo-second-order kinetic model and followed the Langmuir isotherm model with a maximum adsorption capacity was 552.48 mg/g. At optimal conditions, the experimental adsorption results indicated that the SiO2 NPs adsorbed 98.62% of TC. The removal of TC using SiO2 NPs was 99.56% at conditions (SiO2 NPs dose = 0.25 g/L, C0 = 25 mg/L, and t = 40 min) based on Box–Behnken design (BBD) combined with response surface methodology (RSM) modelling. Electrostatic interaction governs the adsorption mechanism is attributed. The reusability of SiO2 NPs was tested, and the performance adsorption was 85.36% after the five cycles. The synthesized SiO2 NPs as promising adsorbent has a potential application for antibiotics removal from wastewaters.

Fabrication of zirconium-based metal-organic frameworks@tungsten trioxide (UiO-66-NH2@WO3) heterostructure on carbon cloth for efficient photocatalytic removal of tetracycline antibiotic under visible light

Designing recyclable photocatalysts with high activity and stability has drawn considerable attention in the fields of sewage treatment. Herein, a series of heterojunctions constructed by zirconium-based metal–organic frameworks (UiO-66-NH2) and tungsten trioxide (WO3) is immobilized on carbon cloth via a facile solvothermal method, resulting in highly recyclable photocatalysts. Multiple characterization techniques, such as X-ray diffraction, scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, and Fourier-transform infrared spectroscopy, verify the successful synthesis of UiO-66-NH2 nanospheres on the surface of needlelike WO3 modified carbon cloth. Results show that the optimal heterojunction photocatalyst exhibits excellent photocatalytic degradation efficiency for the removal of tetracycline (TC) from water, for which nearly 100% of TC is degraded within 60 min under visible light. Trapping experiments and electron spin resonance (ESR) spectra analyses demonstrate that the superoxide radicals O2– and photogenerated hole h+ play a dominant role in the degradation process. Excellent photocatalytic activity is dominantly attributed to the effective separation of photoinduced carriers in this type-Ⅱ heterostructure system. Moreover, the possible photocatalytic oxidation degradation pathway is confirmed by analyzing intermediates using liquid chromatography mass spectrometry (LC-MS). This study offers a highly efficient strategy to design recyclable heterojunction photocatalysts for the degradation of refractory antibiotics in sewage.

Effective removal of tetracycline antibiotics from wastewater using practically applicable iron(III)-loaded cellulose nanofibres.

The non-toxic and completely biodegradable cellulose within bamboo is one of the most abundant agricultural polysaccharide wastes worldwide, and can be processed into cellulose nanofibres (CNFs). Iron(III)-loaded CNFs (Fe(III)@CNFs) derived from bamboo were prepared to improve the adsorption of tetracycline (TC), chlortetracycline (CTC) and oxytetracycline (OTC) from an aqueous solution. The preparation conditions of Fe(III)@CNFs suitable for the simultaneous adsorption of three tetracycline antibiotics (TCs) were investigated. Various analyses proved the abundance of oxygen-containing functional groups and the existence of Fe(III) active metal sites in Fe(III)@CNFs. In batch experiments, Fe(III)@CNFs were applied under a wide pH range and the maximum adsorption capacities were 294.12, 232.56 and 500.00 mg g−1 (for TC, CTC and OTC, respectively). In addition, different concentrations and types of coexisting anions have a weak effect on TCs adsorption. The original TCs adsorption capacities of Fe(III)@CNFs remained stable (greater than 92%) after five cycles when UV + H2O2 was used as the regeneration method. Four adsorption mechanisms (surface complexation, hydrogen bonding, electrostatic interaction and van der Waals force) were obtained for the endothermic adsorption of TCs, among which surface complexation between Fe(III) and TCs always dominates. The practically applicable Fe(III)@CNFs adsorbents are promising for TCs enrichment and remediation in engineering applications.

Reducing tetracycline antibiotics residues in aqueous environments using Tet(X) degrading enzymes expressed in Pichia pastoris

Tetracycline antibiotics (TCs) are massively produced and consumed in various industries resulting in large quantities of residuals in the environment. In this study, to achieve safe and efficient removal of residual TCs, a Pichia pastoris (P. pastoris) was gained to stably express glycosylated TCs degrading enzyme Tet(X) followed codon and expression parameter optimization of tet(X4). As expected, glycosylated Tet(X) still maintains efficient capacity of degrading TCs. The expressed Tet(X) maintained efficient TCs degrading ability over a pH range of 6.5 – 9.5 and temperature range of 17 – 47 °C. We tested this recombinant protein for its ability to degrade tetracycline in pond water and sewage models of tetracycline removal at starting levels of 10 mg/L substrate. 80.5 ± 3.8% and 26.2 ± 2.6% of tetracycline was degraded within 15 min in the presence of 0.2 μM Tet(X) and 50 μM NADPH, respectively. More importantly, the direct use of a Tet(X) degrading enzymes reduces the risk of gene transmission during degradation. Thus, the Tet(X) degrading enzyme expressed by P. pastoris is an effective and safe method for treating intractable TCs residues.

An Eu-doped Zr-metal-organic framework for simultaneous detection and removal of antibiotic tetracycline

Due to the widespread use of tetracycline (TC), there is an increasing demand for rapid detection as well as effective removal of residual tetracycline for environment and food safety. Herein, we report an Eu/Zr-MOF material that combines the high adsorption performance of water-stable Zr-MOF and the unique emission characteristics of Eu3+, which enables both sensing and adsorption functions for TC. Eu/Zr-MOF can be achieved facilely by doping Eu3+ into Zr-MOF via the traditional hydrothermal method. In aqueous medium, the Eu3+ preferentially coordinate with TC molecules, which in turn acts as an antenna for UV–Vis absorbance to enhance the characteristic fluorescence of Eu3+. In such way, TC can be specifically detected in a wide dynamic range (0.001–0.5 µg/mL) with a low detection limit (0.00092 µg/mL). Moreover, by taking advantage of the unsaturated character of ZrO centers, the Eu/Zr-MOF has a TC loading capacity as high as 289 mg g-1. As a consequence, based on the Eu/Zr-MOF, rapid detection and efficient removal of TC from food and environment was realized at once. The principle of design proposed in this work may find more applications to synthesize new platforms for simultaneous sensing and removal of specific pollutants.