Remediation Techniques Research Articles

Critical roles of soil composition and pollutant properties on the degradation of PPCPs during ferrous/persulfate processes

Pharmaceuticals and personal care products (PPCPs) are widely used worldwide and cause potential soil pollution. Fe2+-activated persulfate (PS) processes (Fe-PAPs) are promising techniques for soil remediation. However, a knowledge gap exists in the mechanistic insights into the dominant factors affecting the degradation of different PPCPs in varied soil types. This study systematically investigated the roles of soil components and pollutant properties in the degradation of three PPCPs (triclosan (TCS), triclocarban (TCC), and naproxen (NPS)) in the nine soils in the Fe2+/PS system. The degradation efficiencies of TCS and NPS ranged from 10.92 % to 91.62 % and 46.59 % to 99.81 %, respectively, whereas nearly no degradation was observed for TCC. PPCPs with high water solubility, high energies of the highest occupied molecular orbital (EHOMO), low pKa values, low energy gap (ΔE), or low vertical ionization potential (VIP) were more favorable for degradation. XPS analysis suggested that aliphatic carbon (Ali–C–C(H)), ether or alcohol carbon (C–O), and aldehyde or ketonic carbon (CO) on SOM significantly inhibited TCS degradation. The results of ROS quenching experiments showed that SO4•− and 1O2 played major roles in TCS and NPS degradation in the six soils, with the relative contributions ranged from 24.82 % to 99.14 % and 0.15 % to 73.40 %, respectively. The interaction between soil components, active species, and pollutants resulted in the distinct intermediates of TCS and NPS in different soils. Our findings provide in-depth insights into the role of soil composition and pollutant properties on the remediation of PPCP-contaminated soils in Fe-PAPs.

A facile green synthesis of gold nanoparticles using Canthium parviflorum extract sustainable and energy efficient photocatalytic degradation of organic pollutants for environmental remediation

Organic dye and nitrophenol pollution from textiles and other industries present a substantial risk to people and aquatic life. One of the most essential remediation techniques is photocatalysis, which uses the strength of visible light to decolorize water. The present study reports Canthium Parviflorum (CNP) leaf extract utilization as an effective bio-reductant for green synthesis of Au NPs. A simple, eco-friendly process with low reaction time and temperature was adopted to synthesize CNP extract-mediated Au-NPs (CNP-AuNPs). The prepared AuNPs characterization involving X-ray diffraction (XRD), Fourier-transform infrared spectroscopy (FT-IR), energy-dispersive X-ray spectroscopy (EDX), scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray photoelectron microscopy (XPS) surface area analysis, ultraviolet–visible spectroscopy (UV–Vis). XRD results showed that the cubic-structured AuNPs had a crystallite size of 14.12 nm. Assessment of organic dyes performance in degrading brilliant green (BTG) and amido black 10B (AMB) under visible light irradiation highlights an impressive 83.25% and 86% degradation efficiency within 120 min, accompanied by a kinetic rate constant dyes was found to be 0.0828 min⁻1, BTG, and 0.0123 min⁻1, Furthermore, the reduction of 4-nitrophenol by NaBH4 using CNP-AuNPs as a catalyst demonstrated good catalytic performance and rapid degradation at 89.4%. and rate constant 0.099 min−1 followed pseudo-first-order. The LC-MS analysis identified various intermediates during the degradation of the CR dye. Radical trapping experiments suggest that photogenerated free electrons and hydroxyl radicals are crucial for degrading the amido black 10B dye The AuNPs influenced the significant factors responsible for the photocatalytic activity, such as the increase in range of absorbance, increased e− and h+ pair separation, improvement in the charge transfer process, and active site formation, which significantly enhanced the process of degradation. We found that the CNP-AuNPs could effectively remove dyes and nitrophenol from industrial wastewater.

Synergistic Remediation of Cd-Contaminated Soil with Pure Natural Adsorption Material and Hyperaccumulator Plant

In recent years, cadmium (Cd) contamination in agricultural soil has emerged as a significant global environmental issue, posing irreversible harm to crops and human health. As a result, efficient soil remediation techniques are urgently needed. For this issue, synergistic remediation by material and plant is an effective approach. In this study, a natural and green adsorption material (starch/montmorillonite composite, SMC) of Cd was prepared, which was further employed in synergistic remediation toward soil Cd contamination with the cadmium hyperaccumulator plant Bidens bipinnata. The results of the pot experiment demonstrated that an available Cd removal rate of 77.92 could be obtained, and the results of the field experiments demonstrate that the concentrations of Cd in contaminated soil could be reduced below the risk-screening values for agricultural land. Further analyses, including a microbial community diversity study, changes in soil BCR fraction components, and a TCLP toxicity leaching experiment, unequivocally elucidated that the synergy of SMC and Bidens bipinnata enhanced the remediation efficiency of Cd in contaminated soil. This study confirmed the application potential of the synergy of SMC and Bidens bipinnata toward Cd-contaminated soil.

Enhancing biodegradation of vegetable oil-contaminated soil with soybean texturized waste, spent mushroom substrate, and stabilized poultry litter in microcosm systems.

Industrial activities contribute to environmental pollution, particularly through unregulated effluent discharges, causing adverse effects on ecosystems. Vegetable oils, as insoluble substances, exacerbate this pollution, forming impermeable films and affecting the oxygen transfer, leading to serious habitat disruption. Organic wastes, such as soybean texturized waste, spent mushroom substrate, and stabilized poultry litter, were assessed for their efficacy in enhancing the degradation of vegetable oil in contaminated soil. For this purpose, contaminated soil was amended with each of the wastes (10% w/w) using microcosm systems, which were monitored physico-chemically, microbiologically and toxicologically. Results indicate that the wastes promoted significant oil degradation, achieving 83.1, 90.7, and 86.2% removal for soybean texturized waste, spent mushroom substrate, and stabilized poultry litter, respectively, within a 90-day period. Additionally, they positively influenced soil microbial activity, as evidenced by increased levels of culturable microorganisms and hydrolytic microbial activity. While bioassays indicated no phytotoxicity in most cases, soybean texturized waste exhibited inhibitory effects on seed germination and root elongation of Lactuca sativa. This study significantly enhances our comprehension of remediation techniques for sites tainted with vegetable oils, highlighting the critical role of organic waste as eco-friendly agents in soil restoration. Emphasizing the practical implications of these findings is imperative to underscore the relevance and urgency of addressing vegetable oil contamination in soil. Moving forward, tailored strategies considering both contaminant characteristics and soil ecosystem traits are vital for ensuring effective and sustainable soil remediation.

Permeable Reactive Barrier Remediation Technique Using Carbonized Food Waste in Ground Contaminated with Combined Cu and Pb

In recent years, with the escalation of food waste generation, stringent legal constraints on landfill usage and incineration have necessitated the exploration of alternative disposal methods, augmenting interest in diverse recycling strategies. Notably, carbonized food waste (CFW), a byproduct of food waste carbonization, has emerged as an efficacious adsorbent for pollutant removal. This study focuses on the application of in situ remediation techniques, specifically electrokinetic (EK) remediation combined with enhancers, to decontaminate soil afflicted with single or multiple heavy metals. The utilization of a permeable reactive barrier (PRB) infused with CFW aims to mitigate secondary environmental repercussions, including the propagation of contaminants in soil and groundwater. Experiments were conducted on clay samples contaminated with copper, lead, or a combination thereof. Observations revealed that the current density peaked during the initial 1–2 days of the experiment, experienced a resurgence post-electrode exchange, and subsequently diminished. The efficacy of metal removal was predominantly pronounced for copper, with remediation rates ranging from 85% to 92% in singly contaminated samples and 75% to 89% in dually contaminated samples after a 10-day treatment period, incorporating an electrode exchange on the eighth day. Conversely, the efficacy of lead removal was markedly lower, with rates of 0.6% to 33% in singly contaminated samples and 14% to 25% in combined contamination scenarios, suggesting the necessity for extended treatment durations. The post-experimental moisture content indicated successful enhancer injection. Additionally, pH measurements affirmed that heavy metals migrated effectively within the sample matrix, facilitated by the EK phenomenon after the electrode exchange. This study highlights the potential of CFW within PRBs for the remediation of heavy metal-contaminated soils, although the removal efficiencies between different metals is variable, emphasizing the need for tailored approaches in the treatment of lead-contaminated environments.

Assessment of Possibly Toxic Elements in Landfill Soils and Their Impacts on the Ecosystem in Alice, South Africa

Soil contamination by metallic components is an obscure, detrimental, protracted, and irreparable predicament. Dumping of waste containing heavy metals into landfills, fertilizer and pesticide application, and coal combustion results in high toxicity of metallic elements, and their continuous accumulation in soil pollutes the environment, which, in turn, poses a threat to human health. The specimens were subsequently dehydrated, processed for mineralization, and carefully examined microscopically by scanning electron microscopy and energy-dispersive X-ray spectroscopy (SEM/EDX), which examined their mineral substance, crystalline configuration, and chemical composition. Thirteen (13) elements were detected, and only eight (8) metals were discovered (K, Mg, Na, Ca, Al, Fe, Au, Ba), including non-metals (C, O, Cl, P) and a metalloid (Si). The concentrations of possibly toxic elements obtained showed no consistent succession, as they fluctuated across the examined sites. The Al concentration ranged from 3.78 ± 0.23 wt% to 10.23 ± 0.31 wt%, while the Fe concentration fluctuated from 4.14 ± 0.40 wt% to 13.13 ± 1.07 wt%. Na and Mg levels were present in all samples, but their availability was minimal, at less than 2.0 wt%, ranging between 1.44 ± 0.20 wt% and 0.31 ± 0.08 wt%. The concentrations of Ca and K were low in all soil samples, ranging from 0.91 ± 0.14 wt% to 5.56 ± 0.47 wt% for Ca and from 1.32 ± 0.25 wt% to 4.87 ± 0.18 wt% for K. During the investigation at the designated and control areas, it was discovered that the concentrations of potentially hazardous metals exceeded the accepted limits established by the World Health Organization (WHO) > 100 ppm. The findings provide proof of metallic contaminants in the study region, which calls for proper monitoring, management, and remedial measures of metal-tainted sites, since the residents of this locality are at a significantly elevated risk of experiencing adverse effects due to their heightened exposure to these elements. As a result of that, there is an imperative need to monitor and regulate this area regularly and appropriately. The study recommends sustainable farming practices, where farmers could use natural fertilizers and compost, as well as, the implementation of proper waste management, effective recycling techniques, and proper disposal of substances containing heavy metals as byproducts. Further implement remediation techniques that effectively and safely restore soils contaminated by metals in an environmentally sustainable and economically efficient manner.

Recent advancements in encapsulation of poly aromatic hydrocarbons via macrocyclic host-guest chemistry

Polyaromatic hydrocarbons (PAHs) pose a significant threat to ecosystems and human health due to their widespread presence and persistence in the environment. Conventional remediation techniques often fall short in both efficiency and environmental impact. However, recent advancements in utilizing organic macrocyclic host molecules show considerable promise for effectively sequestering and eliminating PAHs across diverse media. These macrocyclic host molecules play a central role in host–guest chemistry and supramolecular chemistry. It offers distinct advantages by virtue of their precisely tailored cavities and customizable functionalities, greatly enhancing their selective recognition abilities towards guest PAHs. The pursuit of designing and synthesizing novel functional macrocycles has captivated the attention of researchers, driven by the quest to address various challenges in supramolecular research. Over decades of dedicated exploration in host–guest chemistry and supramolecular chemistry, an expansive array of macrocyclic host molecules, constructed from diverse building blocks, have emerged as pivotal tools for encapsulating PAHs. This review presents an overview of the recent progress in the design, synthesis, and application of purely organic macrocyclic molecules in the encapsulation of PAHs. It elucidates the underlying principles that govern their ability to recognise PAHs, such as host–guest interactions, shape complementarity, and π-π stacking interactions. Furthermore, the review discusses various experimental methodologies, such as spectroscopic analyses, chromatography, and computational modelling, employed to assess the efficiency of organic cage molecules in PAH trapping. Additionally, considerations regarding the scalability and environmental implications of organic cage-based PAH trapping systems are addressed. The insights gleaned from this research provide valuable guidance for the development of robust strategies to combat PAH pollution in diverse environmental contexts.

An Overview of the Degradation and Removal of Pesticide Residues from Water and Agricultural Runoff using Nanoparticles and Nanocomposites

: A high percentage of the applied chemicals on farmlands find their way into the water bodies and groundwater through agricultural runoff and leaching/percolation. Therefore, multiple remediation techniques need to be employed to deter the menace of pesticide residue contamination. Therefore, this review aimed to compute the most suitable degradation conditions for the removal of pesticide residue from water and agricultural runoff using nanomaterials. The review touches on the aspect of adsorption and photocatalytic degradation methods using nanomaterials and the most prominent factors that affect the degradation process. Information from recently published articles, book chapters, and conference proceedings were carefully studied and analyzed. It was revealed that heterogeneous photocatalysis shows the capability of complete mineralization of organic pollutants under optimum experimental conditions. Moreover, it is crucial to consider experimental conditions that could be applicable in the field to achieve a better result. It has been observed that integrating nanoremediation with other degradation methods to create a hybrid technique may play a crucial role in removing pesticide residues from agricultural runoff. However, the detrimental effects of the nanomaterials if any on the environmental matrices need to be taken under consideration to avoid the menace similar to plastic pollution as a result of extensive production and application of nanomaterials.

Experimental study of copper contamination in mechanical properties of residual soil under different concentration

Abstract Industrialization in modern society comes along with soil degradation and heavy metal pollution. The presence of heavy metals changes the geotechnical properties of soils, risking the sites with the possibility of contaminated soil. Heavy metal contaminants might alter the mechanical properties and soil behaviour leading to the effects on the structural integrity. The purpose of this research is to evaluate the mechanical properties of residual soil samples contaminated with different concentrations of copper. Disturbed residual soils were induced with copper in controlled environment. Six samples were prepared, including a control sample consisting of a CuSO4 solution with a spectrum of concentrations ranging from 0 mg/L to 4000 mg/L, with interval 500 mg/L. The results of the experiment revealed that increasing the concentration led to an increase in the maximum dry density, while the optimum moisture content showed an opposite response. The increase in copper concentration resulted in a dynamic shift in the plastic limit, a decrease in the liquid limit and pH, making the soil naturally acidic. The output shows aid in the development of appropriate soil management strategies and remediation techniques to mitigate the adverse effects of copper contamination on soil quality and environmental sustainability.

Sustainable remediation of cadmium-contaminated soils: capture by Fe3O4/polyaniline and removal by magnetic separation

Cadmium (Cd) contamination of soil is a global environmental issue. Traditional remediation techniques such as immobilization, leaching and phytoextraction have numerous shortcomings, which has led to growing interest in the development of low cost, high-efficiency, and environmentally friendly agents for removing Cd from soil. In this study, Fe3O4/polyaniline (Fe3O4/PANI) was developed as a remediation agent with magnetic separation and regeneration capabilities. Its Cd adsorption isotherms showed a better fit to Langmuir model, exhibiting a high Cd adsorption capacity of 47.62 mg·g-1 at 25°C. In bench-scale experiments, Fe3O4/PANI was first attempted to remediating four typical Chinese soils with Cd concentration of 180 mg·kg-1: black, brown, cinnamon, and red. Results showed that the total Cd removal efficiency was satisfactory at 25.25%–38.91% and that the exchangeable Cd removal efficiency was 36.03% on average. In addition, the soil basic properties did not show major changes after remediation. Regarding the regeneration performance, after the first regeneration cycle, a better total Cd removal efficiency was achieved, i.e., 27.89%–44.96%. After two regeneration cycles, it decreased but still remained above 95% of the initial performance. Fe3O4/PANI has a simple and cost-effective synthetic process, and it combines high Cd removal efficiency with easy recovery and recyclability. It is a promising solution for the sustainable and efficient remediation of Cd-contaminated soils, especially for the reclamation of highly contaminated development land.

An Experimental Investigation on Mechanical Properties of Bacterial Concrete Using Bacillus Subtilis

Abstract: This Concrete is susceptible to micro crack formation and has pores which are highly undesirable because they provide an open pathway for the ingress of water and other deleterious substances. The use of concrete surface treatments with water proofing materials to prevent the access of aggressive substances is a common way of contributing to concrete durability. However, the most common surface treatments use organic polymers (epoxy, acrylics and polyurethanes) all of which have some degree of toxicity. Bio inspired materials can lead to a more sustainable construction industry, especially when providing new low toxic solutions. Hence, there is an urgent need to pay more attention for improving the properties of concrete with respect to strength and durability, especially in aggressive environments. One effective remedy for closure of cracks is the Bacterial Concrete (BC) which will continuously deposit calcite in concrete. This, phenomenon is called as Microbiologically Induced Calcite Precipitation (MICP). The urease enzyme enables the deposition of calcium carbonate (CaCO3) with the help of bacteria. The bacterial remediation technique surpasses other techniques as it is bio-based, eco-friendly and durable. Bacteria need to offer resistance to withstand high pH of concrete and mechanical stresses during mixing. In these present investigations bacterial sample name Bacillus Subtilis (BS) is considered in concentrations of 104 , 105 and 106 cells/ml of mixing of water. investigations are carried out on strength-related properties such as compressive strength, splitting tensile strength and flexural strength to assess the quality of concrete. The optimum dosage of cell concentration of bacteria is found to be 105 cells/ml for BS based on compressive strength results. M25 grade concrete is designed and used for embedding Bacillus subtilis bacteria.

Impact of Photo-remediation on Anthracene PAHs in treated wastewater using ZnO/TiO2/H2O2 Catalysis

The remediation of carcinogenic Polycyclic Aromatic Hydrocarbons )PAHs( such as Anthracene (3 Rings) in different sources of wastewater was examined using a mix of Zink Oxide, Titanium Oxide, and Hydrogen peroxide (ZnO/ TiO2/H2O2). Eleven wastewater sources were collected from different industrial wastewater and treated wastewater (5 Farms, Main treatment plant, Tanning factory treated wastewater, Tanning factory non-treated wastewater, Carton factories, Factories Lake, and Grease refining plants. Anthracene was extracted by QuEChERS methodology and Analyzed by GCMSMS/TQD. Remediation techniques were applied by using different UV wavelengths irradiation on photolysis of PAHs under two wavelengths (254 and 306 nm) UV irradiation with ZnO + TiO2+ H2O2catalysts for 10 h. Also, the influence of remediation time and several parameters on Anthracene photolysis have been studied. The results indicate that Tanning factory non-treated wastewater had the highest concentration of Anthracene PAHs. The average recovery of Anthracene ranged from 92-96% and Detection Limit (DL) was 5 µg/l. The results of Anthracene concentration in tested wastewater ranged from 21.09 -223.69 µg/l. Also, the results show the anthracene was not detected after 5, 8, and 10h after the remediation using UV 254nm ZnO + TiO2+ H2O2. On the other side, the Anthracene was not detected after 3, 5, and 8h after the remediation using UV 254nm/ZnO + TiO2+ H2O2. Generally, the results of Photoremediation were effective and sufficient for the Anthracen. The impact of photocatalytic illumination of ZnO + TiO2 + H2O2yields valence band holes and conduction band electrons, which interact with the surface adsorbed molecular oxygen to give superoxide radical anions, and finally, the water produces radicals of HO•. These radicals oxidize the target molecule (Anthracene) to Anthraquinone.

A Review of Remediation Strategies for Diphenyl Ether Herbicide Contamination.

In agriculture, diphenyl ether herbicides are a broad-spectrum family of pesticides mainly used to control annual weeds in agriculture. Although diphenyl ether herbicides have a long-lasting effect in weed control, they can also be harmful to succeeding crops, as well as to the water and soil environment. Residual herbicides can also harm a large number of non-target organisms, leading to the death of pest predators and other beneficial organisms. Therefore, it is of great significance to control and remediate the contamination caused by diphenyl ether herbicide residues for the sake of environmental, nutritional, and biological safety. This review provides an overview of the techniques used for remediating diphenyl ether herbicide contamination, including biological, physical, and chemical remediation. Among these techniques, bioremediation, particularly microbial biodegradation technology, is extensively employed. The mechanisms and influencing factors of different remediation techniques in eliminating diphenyl ether herbicide contamination are discussed, together with a prospect for future development directions. This review serves as a scientific reference for the efficient remediation of residual contamination from diphenyl ether herbicides.

Phytobial remediation advances and application of omics and artificial intelligence: a review.

Industrialization and urbanization increased the use of chemicals in agriculture, vehicular emissions, etc., and spoiled all environmental sectors. It causes various problems among living beings at multiple levels and concentrations. Phytoremediation and microbial association are emerging as a potential method for removing heavy metals and other contaminants from soil. The treatment uses plant physiology and metabolism to remove or clean up various soil contaminants efficiently. In recent years, omics and artificial intelligence have been seen as powerful techniques for phytobial remediation. Recently, AI and modeling are used to analyze large data generated by omics technologies. Machine learning algorithms can be used to develop predictive models that can help guide the selection of the most appropriate plant and plant growth-promoting rhizobacteria combination that is most effective at remediation. In this review, emphasis is given to the phytoremediation techniques being explored worldwide in soil contamination.

A Review of Chromium Behavior in Soil and its Remediation Techniques

A Review of Chromium Behavior in Soil and its Remediation Techniques

Qualitative and quantitative simulation of best management practices (BMPs) for contaminated megasite remediation using the SiteWise™ tool

Remediation activities, particularly in megasites, may induce substantial secondary environmental impacts that must be addressed for green and sustainable remediation (GSR) practices. Only limited studies are available quantitatively assessing the environmental footprint and environmental benefits of implementing Best Management Practices (BMPs) in megasite remediation. This study used the SiteWise™ tool, a quantitative environmental footprint assessment for scenario simulation and benefit quantification of BMPs, on a contaminated megasite in Hebei Province, China. We observed a considerable environmental footprint and energy from the remediation. Taking the final implementation alternative (Alt 1) as an example, which is characterized by combining multiple remediation techniques, the greenhouse gas (GHG) emissions reached 113,474 t, the energy used was 2,082,841 million metric British thermal units (MMBTU), and other air pollutant emissions (NOx, SOx, and PM10) amounted to 856 t. Further BMP analyses highlighted the benefits of substituting the conventional solidification/stabilization agent with willow woodchip-based biochar, which could reduce GHG emissions by 50,806 t and energy used by 926,648 MMBTU. The overall environmental benefits of implementing all applicable BMPs in the remediation were significant, with a 66.85%, 50.15%, and 56.05% reduction in GHG emissions, energy used, and other air pollutants, respectively. Our study provides insights into quantifying the environmental footprint and exploring emission reduction pathways for contaminated megasite remediation. It also offers a feasible path for quantifying the environmental benefits of BMPs, promoting the development of GSR of contaminated sites.

Selective Isolation and Identification of Microorganisms with Dual Capabilities: Leather Biodegradation and Heavy Metal Resistance for Industrial Applications.

Tanning, crucial for leather production, relies heavily on chromium yet poses risks due to chromium's oxidative conversion, leading to significant wastewater and solid waste generation. Physico-chemical methods are typically used for heavy metal removal, but they have drawbacks, prompting interest in eco-friendly biological remediation techniques like biosorption, bioaccumulation, and biotransformation. The EU Directive (2018/850) mandates alternatives to landfilling or incineration for industrial textile waste management, highlighting the importance of environmentally conscious practices for leather products' end-of-life management, with composting being the most researched and viable option. This study aimed to isolate microorganisms from tannery wastewater and identify those responsible for different types of tanned leather biodegradation. Bacterial shifts during leather biodegradation were observed using a leather biodegradation assay (ISO 20136) with tannery and municipal wastewater as the inoculum. Over 10,000 bacterial species were identified in all analysed samples, with 7 bacterial strains isolated from tannery wastewaters. Identification of bacterial genera like Acinetobacter, Brevundimonas, and Mycolicibacterium provides insights into potential microbial candidates for enhancing leather biodegradability, wastewater treatment, and heavy metal bioremediation in industrial applications.

Optimizing solar powered electrokinetic remediation of chromium contaminated groundwater: One step closer to a sustainable solution

Electrokinetic remediation (EKR) presents a promising solution for addressing soil and groundwater contamination challenges. However, practical viability is hindered by significant energy consumption and related expenses, necessitating a comprehensive sustainability approach beyond solely adopting renewable energy and low-carbon sources. This study aims to merge innovative solar-powered systems with a risk-based evaluation strategy for tackling chromium-contaminated groundwater, providing valuable insights into EKR economically viable and applicable approaches. Through the integration of environmental and electrical engineering expertise, this study introduces the Continuous Solar-powered Electrokinetic Remediation (CSER) system and risk-based energy efficiency (REF) evaluation approach, addressing intermittency issues while optimizing energy generation and minimizing costs. Experimental results demonstrate removal efficiencies ranging from 29.85% to 84.26%, highlighting the impact of intermittent current, voltage boosters, and electrolyte selection on risk reduction and energy consumption. While intermittent current intensifies the focusing phenomenon and reduces contaminant migration, it may offer promising results in specific cases, such as observed in the EK2 experiment. Conversely, the EK3 results reveal that the integration of conventional solar power with a voltage booster may enhance removal rates but often leads to unfavorable outcomes in risk reduction considering related higher energy consumption. However, CSER, with its utilization of constant current, proves more efficient in power generation, risk reduction, and energy usage compared to other systems. Integration of such a system with cost-effective and environmentally friendly chemical agents could significantly increase the REF index while minimizing related costs, thereby shifting EKR remediation techniques towards sustainable solutions for contaminated groundwater worldwide.

Reviewing Soil Contaminant Remediation Techniques

Harmful contaminants generating from industry, agricultural and human activity are causing the degradation of soil health, along with detrimental effects on human and the environment. It is imperative to safeguard the soil from these dangerous pollutants by using soil remediation techniques that may be effective breakdown these dangerous toxins. A sustainable approach to remediate the soil from different contaminants is bioremediation. Bioremediation is a method where microbes are used to alleviate soil pollution effectively. Natural microorganisms like fungus, bacteria, and algae are employed in the bioremediation process to break down heavy metal (lead, arsenic, chromium etc.) or organic based. chemical contaminants. This study examines the use of microorganisms and various bioremediation methods, including genetic engineering, nanotechnology, and electro bioremediation, for recovering polluted soil. This investigation clarified the challenges associated with applying these bioremediation technologies and microorganisms, as well as their effects on the ecosystem and inherent soil microbial population. The goal of this current study is to illustrate the various technologies which are more effective in this remediation process.

Micronutrient Deficiency in Indian Diet

Micronutrient deficiency in the Indian diet poses a significant health challenge, impacting millions across the nation. The inadequate intake of essential vitamins and minerals, such as iron, zinc, vitamin A, and iodine, can lead to severe health issues, including anaemia, impaired cognitive development, and compromised immune function. One crucial factor contributing to micronutrient deficiency is soil pollution, which directly affects the nutritional content of vegetables and fruits. Soil pollution results from the presence of contaminants like heavy metals, pesticides, and industrial waste, negatively impacting soil health and composition. As plants absorb nutrients from the soil, polluted soil leads to diminished nutrient uptake by crops, exacerbating the micronutrient deficiency in the food chain. The contamination of soil with heavy metals, such as lead and cadmium, can inhibit the absorption of essential minerals by plant roots. Consequently, vegetables and fruits grown in polluted soil may exhibit lower concentrations of vital micronutrients, even if individuals consume the same quantity of produce. This compromised nutritional quality directly contributes to the prevalence of micronutrient deficiencies in the Indian population. Addressing this issue necessitates a multi-faceted approach. Implementing sustainable agricultural practices, such as organic farming and soil remediation techniques, can help reduce soil pollution and enhance soil fertility. Additionally, promoting awareness about the importance of diversified diets and dietary supplements can empower communities to combat micronutrient deficiencies. Government initiatives, research collaborations, and public-private partnerships are essential to developing and implementing strategies that tackle both soil pollution and micronutrient deficiency in the Indian context, fostering a healthier and more resilient population. Keywords: Nutrients, Micronutrients, Indian diet, Vitamins, Supplements.