The deployment of photovoltaic (PV) systems has increased globally to meet renewable energy targets. Intermittent PV power generated due to cloud-induced variability introduces reliability and grid stability issues at higher penetration levels. Variability in power generation can induce voltage fluctuations within the distribution system and cause adverse effects on power quality. Therefore, it is essential to quantify resource variability to mitigate an intermittent power supply. In this study, we propose a new scheme to classify the sky conditions that are based on two common variability metrices: daily clear-sky index and normalized aggregate ramp rates. The daily clear-sky index estimates the cloudiness in the sky, and ramp rates account for the variability introduced in the system generation due to sudden cloud movements. This classification scheme can identify clear-sky, highly variable, low intermittent, high intermittent and overcast days. By performing a Chi-square test on the training and test sets, we obtain Chi-square statistic values greater than 3 with p-value > 0.05. This indicates that the distribution of the training and test clusters are similar, indicating the robustness of the proposed sky classification scheme. We have demonstrated the applicability of the scheme with diverse datasets to show that the proposed classification scheme can be homogenously applied to any dataset globally despite their temporal resolution. Using various case studies, we demonstrate the potential applications of the scheme for understanding resource allocation, site selection, estimating future intermittency due to climate change, and cloud enhancement effects. The proposed sky classification scheme enhances the precision and reliability of solar energy forecasts, optimizing system performance and maximizing energy production efficiency. This improved accuracy is crucial for variability control and planning, ensuring optimal output from PV plants.