When designing ozone bubble columns, two major sources of uncertainties usually exist: (1) the measurement techniques and the estimation methods of the various operating parameters; and (2) the application of the pertinent design model. This paper presents a simple and easy-to-use, yet accurate and reliable design model for describing the performance of ozone bubble columns for water and wastewater treatment applications. This mode! is a modified non-isobaric steady-sate one-phase axial dispersion model (1P-ADM). The 1P-ADM is different from the complete axial dispersion model, or referred to as the two-phase axial dispersion model (2P-ADM), in its simple use for practical design and process control of full-scale contacting chambers. The 2P-ADM is represented by a system of two non-linear partial differential equations. In order to solve that system of equations, an elaborate numerical solving technique is needed. On the other hand, die 1P-ADM is composed of a single non-homogeneous linear second-order ordinary differential equation representing the liquid phase. Yet, this liquid-phase differential equation accounts for the countering effects of die gas bubbles' shrinkage and expansion caused by gas depletion and absorption and reduced liquid hydrostatic head. The differential equation was solved analytically by the method of variation of parameters. Expressing the 1P-ADM in terms of dimensionless operating parameters and with the available analytical solution of the differential equation, the model predictions of the dissolved and the gaseous ozone profiles along the column height were examined using a simple spreadsheet approach. Therefore, describing mat analytical solution in terms of a simple spreadsheet program facilitated obtaining the model predictions for any operating conditions represented by the model parameters entered into die spreadsheet program. Consequently, using die 1P-ADM for process design and/or on-line process control becomes very feasible. The 1P-ADM was initially tested to evaluate its predictions of the dissolved ozone profiles for water treatment conditions. The model provided excellent predictions of the dissolved ozone profiles along the bubble column for die counter-current and the co-current flow modes.
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