Related Products Research Articles

Exploring the synergistic effect of chromium (Cr) tolerant Pseudomonas aeruginosa and nano zero valent iron (nZVI) for suppressing Cr uptake in Aloe Vera

Chromium (Cr) contamination of soil has substantially deteriorated soil health and has interfered with sustainable agricultural production worldwide and therefore, its remediation is inevitable. Inoculation of plant growth promoting rhizobacteria (PGPR) in association with nanotechnology has exerted broad based impacts in agriculture, and there is an urgent need to exploit their synergism in contaminated soils. Here, we investigated the effect of co-application of Cr-tolerant “Pseudomonas aeruginosa CKQ9” strain and nano zerovalent iron (nZVI) in improving the phytoremediation potential of aloe vera (Aloe barbadensis L.) under Cr contamination. Soil was contaminated by using potassium dichromate (K2Cr2O7) salt and 15 mg kg−1 contamination level in soil was maintained via spiking and exposure to Cr lasted throughout the duration of the experiment (120 days). We observed that the co-application alleviated the adverse impacts of Cr on aloe vera, and improved various plant attributes such as plant height, root area, number of leaves and gel contents by 51, 137, 67 and 49% respectively as compared to control treatment under Cr contamination. Similarly, significant boost in the activities of various antioxidants including catalase (124%), superoxide dismutase (87%), ascorbate peroxidase (36%), peroxidase (89%) and proline (34%) was pragmatic under contaminated soil conditions. In terms of soil Cr concentration and its plant uptake, co-application of P. aeruginosa and nZVI also reduced available Cr concentration in soil (50%), roots (77%) and leaves (84%), while simultaneously increasing the relative production index by 225% than un-inoculated control. Hence, integrating PGPR with nZVI can be an effective strategy for enhancing the phytoremediation potential of aloe vera.

Role of Microfinance Institutions in Ethiopian Economy: A Review

This work reviews the role of microfinance institutions in the Ethiopian economy, which was done by using a balanced scorecard (BSC) performance review approach that integrates both financial and nonfinancial metrics. The BSC framework of the review was developed using a total of performance indicators that were equally categorized under BSC perspectives (financial, customer, internal business processes, and learning and growth). The developed framework was applied to MFIs operating in Ethiopia, which have head offices in all regional capitals of the country and report to the Association of Ethiopian Microfinance Institutions (AEMFI) starting in 2010–2012 consecutively. The work of the review shows that based on their financial role, on average, the institutions reviewed are sustainable with high relative productivity and low profitability. The average non-financial performance is also high, indicating that the reviewed institutions are highly performing in both non-financial and financial measures. Beside the role performance, the work of this review confirmed the relationship assumption of BSC perspectives and it shows a positive correlation among them. The review concludes that comprehensive performance is observed when it is measured in a collective way. So, Ethiopian MFIs suggested paying attention to the use of BSC as a performance measurement tool and as a hub for specified role indicators that need enhancement.

Curriculum policies for brazilian high school education: the discursive production of the state education network of Mato Grosso do Sul (2012)

The analyses presented aim to problematize the discursive nuances (both political and curricular) of the identity constructed for high school education in the state of Mato Grosso do Sul. To this end, we examine the 2012 High School Curricular Reference Document (MATO GROSSO DO SUL, 2012) in its primary condition, that is, as an “official” text and, therefore, bearer of authorized language, product, process, and producer of interested power relations. Official discourses have the capacity not only to influence but also to regulate fundamental aspects of education, such as the production and distribution of legitimate pedagogical texts, the social relationships underlying the transmission and acquisition of knowledge, and the organization of educational contexts. In summary, given the complexity that the curriculum presents to the educational field, the analysis of official discourses becomes more than necessary; it becomes urgent. Contrary to what was initially hypothesized, the curricular proposal for the network was made, in the midst of a reform movement, as one of the “innovative” educational actions operationalized by the state agent. The organization of the document, which is part of the efforts to inaugurate and reformulate the curriculum, reaches different levels of power (from national to local) and is guided by principles from the economic field, especially those of a neoliberal matrix, which in the educational field assume specific contours, translated in the incorporation of Competence Theories.

Quantifying sodium hypochlorite content in hypochlorite-based disinfectants via phase-conversion headspace technique

In this work, a novel and efficient approach for sodium hypochlorite analysis is proposed via phase-conversion headspace technique, which is based on the gas chromatography (GC) detection of generated carbon dioxide (CO2) from the redox reaction of sodium hypochlorite with sodium oxalate. The data obtained by the proposed method suggest the high detecting precision and accuracy. In addition, the method has low detection limits (limit of quantification (LOQ) = 0.24 μg/mL), and the recoveries of added standard ranged from 98.33 to 101.27 %. The proposed phase-conversion headspace technique is efficient and automated, thereby offering an efficient strategy for highly efficient analysis of sodium hypochlorite and related products.

Diacylglycerol oil on metabolic syndrome: A Review

The metabolic syndrome is a trait of metabolic disorders that results from the increasing prevalence of obesity. Clinical manifestations include insulin resistance, hyperlipidemia, hyperuricemia, etc. Populations with high morbidity tend to be middle-aged and elder adults. With the advent of an ageing society, the incidence of metabolic syndrome will be higher. Since diacylglycerol (DAG) oil was first introduced in 1999, it has received extensive attention. DAG oils and related products have been distributed in markets in Japan, Europe, and the United States since 2001. This paper will review the effects of the new dietary oil, DAG, on the metabolic syndrome. It is hoped that DAG oil has the ability to replace traditional triacylglycerol (TAG) oil and control the morbidity of metabolic syndrome. This review article collected recent studies, and the results proved that dietary DAG is effective for reducing postprandial blood lipids and blood glucose, managing weight, and ameliorating insulin sensitivity.

The urge to splurge: Differentiating unplanned and impulse purchases

This research note addresses a significant gap in the literature regarding the underlying mechanisms of purchase decision-making that lead to unplanned and impulse purchases. Although several papers have highlighted the differences between the two purchase types, recent academic publications continue to use those terms interchangeably. Through a systematic literature review, this study identified six high-level constructs, in line the Theoretical Domains Framework, that effectively differentiate unplanned from impulse purchase types. Overall, impulse (vs. unplanned) purchases have a primary association with automatic (vs. reflective) motivation. With these findings, academic researchers can better define the types of purchase they are investigating, including the main constructs and underlying psychological mechanisms that are associated with these purchases. As a result, this study substantially improves the reliability of knowledge in this domain. Additionally, this study may encourage marketers to expand their existing toolkits with a broader set of activities that can drive these different purchase types. For instance, marketers could appeal to different underlying purchase decision-making mechanisms: for unplanned purchases, they could offer reminders of related products; for impulse purchases, they could focus on immediate gratification.

Behavior of endo-xylanases on wheat milling products in relation with variable solid loading conditions

To investigate the incubation conditions encountered by enzymes in cereal-based product transformation processes, this study aims to provide comprehensive information on the effect of low (18 %) to high (72 %) solid loading on the behavior of bacterial and fungal xylanases towards wheat grain fractions, i.e. white flour, ground whole grain and bran. Both enzymes are effective from 30 % water content. A water content of 50 % appears as the threshold for optimal arabinoxylan solubilisation. The specificity of enzymes was influenced by low hydration conditions, particularly in wheat bran, which contains arabinoxylan with diverse structures. Especially the bacterial xylanase became more tolerant to arabinose substitution as the water content decreased. Time Domain-NMR measurements revealed four water mobility domains in all the fractions. The water populations corresponding to 7.5 nm to 15 nm pores were found to be the most restrictive for enzyme activity. These results define the water content limits for the optimal xylanase action in cereal products.

Abrupt intensification of AMOC and monsoonal winds during mid-MIS4 (Heinrich Event 6) in the western Arabian Sea

In the Arabian Sea (AS), higher organic matter preservation and biological productivity are observed during the summer due to strong southwest monsoonal winds. Centennial and millennial-scale fluctuation in the geochemical and relative abundance of foraminifera species are widely used to study the past preservation and productivity variation reconstruction in the Western Arabian Sea (WAS). The sediment records from the AS also show similarities with the North Atlantic and Greenland mainly during Heinrich events (HEs) which is related to the atmospheric and oceanic teleconnections of the AS with the higher latitude climate perturbations. In this context, we used a sediment core VM3504-PC from the WAS to understand the long-term changes in productivity and organic matter preservation using Globigerina bulloides (G. bulloides) relative abundance, total organic carbon (TOC) content, and calcium carbonate (CaCO3) wt%. The TOC and G. bulloides shows a positive correlation, while significantly negative correlation is recorded in the TOC % and CaCO3 wt% datasets during interglacial periods (MIS5e-b, MIS3, and MIS1). Our results show evidence of CaCO3 dissolution and intense summer monsoon induced upwelling related productivity in core location during interglacial periods (MIS5e), based on higher relative abundance of G. bulloides (%), higher TOC content, and lower CaCO3 wt%. Interestingly, higher preservation of organic matter and increased productivity/nutrient concentration during mid-MIS4 suggesting stronger upwelling/winter convective mixing together with higher aeolian transport from adjacent landmasses. The abrupt weakening in the Atlantic Meridional Overturning Circulation (AMOC) synchronized with low productivity due to weak monsoon during HEs except for H6 and H4 in the tropical Indian Ocean. The H6 coincides with mid-MIS4 is showing abnormal preservation. Thus, AMOC and the summer monsoon significantly regulate primary productivity in the WAS. It is interesting to note that possibly well‑oxygenated deep-water masses do not penetrate up to surface water and/or ballistic effect (indicated by moderate sedimentation rate), preventing organic matter degradation on the seafloor during mid-MIS4.

A temperature-based model of biomass accumulation in humid forests of the world

Forests benefit humans in numerous ways. Many of these benefits are greater from forests with large trees and high biomass (i.e., above-ground biomass) than from young forests with small trees. Understanding how the biomass accumulation rate depends on climate is therefore important. According to a classic theory, the biomass accumulation rate first increases until canopy closure, as leaf area and gross primary productivity increase, and decreases thereafter because leaf area cannot increase further and maintaining larger biomass is energetically costlier as living tissue increases even though its proportion of all biomass decreases. We based our modeling on this classic theory and defined relative productivity, pr indicating productivity, and relative maintenance cost, cr, signaling the expense of sustaining a unit of biomass in humid climates of the world. The biomass accumulation rate of low biomass forests is determined by pr − cr and maximal biomass by pr/cr. We then compiled a global data set from the literature, with 3,177 records to fit a parameter for the efficiency of converting surplus carbon into accumulated biomass and another parameter determining biomass at canopy closure. Based on the parameterized models, a constant temperature of 22.3°C leads to the most rapid biomass accumulation in low biomass forests, whereas 16.4°C results in greatest maximal biomass. Our parameterized model can be applied to both climate change adaptation and mitigation by optimizing land use.

Potential Anti-Inflammatory Constituents from Aesculus wilsonii Seeds.

A chemical study of Aesculus wilsonii Rehd. (also called Suo Luo Zi) and the in vitro anti-inflammatory effects of the obtained compounds was conducted. Retrieving results through SciFinder showed that there were four unreported compounds, aeswilosides I-IV (1-4), along with fourteen known isolates (5-18). Their structures were elucidated by extensive spectroscopic methods such as UV, IR, NMR, [α]D, and MS spectra, as well as acid hydrolysis. Among the known ones, compounds 5, 6, 8-10, and 12-16 were obtained from the Aesculus genus for the first time; compounds 7, 11, 17, and 18 were first identified from this plant. The NMR data of 5 and 18 were reported first. The effects of 1-18 on the release of nitric oxide (NO) from lipopolysaccharide (LPS)-induced RAW264.7 cells were determined. The results showed that at concentrations of 10, 25, and 50 μM, the novel compounds, aeswilosides I (1) and IV (4), along with the known ones, 1-(2-methylbutyryl)phloroglucinyl-glucopyranoside (10) and pisuminic acid (15), displayed significant inhibitory effects on NO production in a concentration-dependent manner. It is worth mentioning that compound 10 showed the best NO inhibitory effect with a relative NO production of 88.1%, which was close to that of the positive drug dexamethasone. The Elisa experiment suggested that compounds 1, 4, 10, and 15 suppressed the release of TNF-α and IL-1β as well. In conclusion, this study enriches the spectra of compounds with potential anti-inflammatory effects in A. wilsonii and provides new references for the discovery of anti-inflammatory lead compounds, but further mechanistic research is still needed.

Clinical, Pathological and Epidemiological Aspects of Cephalopina titillator Larval, Exciter in Camelus dromedaris from the Rafsanjan Region, Iran

The camel nasal bot fly is an obligate parasite which its larvae causes nasopharyngeal myiasis and the 3rd generation of larvae may cause serious nasal mucosal damage. The present study was conducted on Camelus dromedaris to determine the clinical assessment, seasonal prevalence and also pathological adverse effect of Cephalopina titillator in Rafsanjan region (South east of Iran). Due to history and dental formula, camels were divided into four age groups: less than two years (62 cases), two to five years (86 cases), five to nine (42 cases) and more than nine years (10 cases), which positive cases confirmed in 12 (19.4%%), 31 (36%), 40 (95.2%) and 10 (100%) cases, respectively. The major clinical signs of naturally infected camel was categorized in three main parts; Respiratory signs, nervous behavior and general symptoms which the main ones were related to stridor and nasal discharge. Suspected larvae with average 14.83±4.35 was recovered from 93 infested camels and evaluated microscopically for determining the larval stage. Furthermore, the gross and histopathological findings were recorded by using tissue samples. These non sex related findings showed that with increasing the age, susceptibility to this specific parasite infestation increased as well (p<0.001). No significant seasonal changes were recorded, but the incidence rate was higher in March, April and September. Different larval stage were mostly found in nasal cavity, nasopharyngeal and laryngeal areas which was accompanied by local inflammation, regional edema and serosanguinous exudate. Microscopical findings were showed the epithelial damage along with lymphoid hyperplasia, accumulation of inflammatory cells and remnants of necrotic tissue. However, fibroblasts proliferation, connective tissue formation along with some degrees of atrophy and focal calcification were the significant findings of chronic infestation. These findings indicate the presence of heavy larval infestation in camel of Rafsanjan region which imposes severe economic losses and affect their health, growth and related productions. Therefore, it is recommended to carry out the necessary measures for the biological control of the camel nasal bot fly.

Script late injection: a framework to introduce JavaScript into web pages

Script injection is one type of fault present in web, which mostly utilizes user data to execute code without applying any type of filters. Script injection can impact both client and server making exposing them to vulnerabilities. Security and related products may need to execute logic on the client-side generally in a browser. In order to achieve this, proxy servers inject appropriate JavaScript code into the responses they proxy. Typically, the injection point is at the end of the body element. The framework introduced in this paper rather uses a stack-based approach to determine the injection point in the web page. Ten kilobytes from the end of a web page are given as a string input to the framework, after tokenization and construction of the vector of tokens. A stack is used to determine the injection point. Along with the position of the injection point, a warning flag is also estimated indicating the correctness of the injection point. Different types of web pages were considered for running the unit tests and fuzzy tests on the framework. These classes of pages are determined by crawling most used web pages. The injected scripts are executed once the body content is completely loaded. Hence, it can retrieve maximum information without affecting end-user performance. It also does the job at a low cost.

Liquid sheet formation and spray characterization of N-heptane spray jet from a swirl atomizer: Numerical analysis and validation

This paper analyzes the liquid atomization mechanisms of an N-heptane spray jet emerging from a swirl simplex atomizer using numerical and experimental techniques. In particular, a direct seamless coupled Volume of Fluid and Lagrangian Particle Tracking approach together with adaptive mesh refinement within the Large Eddy Simulation framework offers a suitable way to accurately simulate the complex behavior of spray atomization, spray evolution, and droplet dispersion as a whole while using manageable computational cost. The achieved simulation results are first presented in terms of qualitative properties, characteristics of liquid sheet, air core generation, flow recirculation zones, and vortex patterns. For validation purposes, the numerical results are then compared with detailed experimental data obtained by a two-component Phase Doppler Anemometry technique. The assessment includes especially droplet statistics which strongly determine subsequent possible spray combustion process and related product and species emissions. The overall reported agreement demonstrates the capability of the adopted methodology in predicting and comprehensively investigating the complex phenomena associated with a pressure swirl fuel atomizer. In particular, it is found out that the normalized number-based probability density function of droplet size fits well with a lognormal distribution.

Estimation of production rate distribution by overhaul periods of the wells

This article examines the issues of the distribution of production capacity over the actual intervals of the overhaul period of the wells under consideration. Production rates and overhaul intervals of wells are the main technical and economic indicators which are of great importance for increasing production and improving the efficiency of well stock operation in general, especially at the late stages of field development. On the basis of actual field data ranges of oil and water flow rates and values of overhaul period of wells of Balakhany-Sabunchu-Ramana field have been analyzed. Plots of distribution of flow rates and relative total production for all actual intervals of overhaul period were plotted. Mathematical models of distribution of production indicators by overhaul of wells have been obtained with the help of computer program. The results of the research allow to reveal regularities and to estimate production capacity of the considered well stock under the given operating conditions.

Gut microbiota dynamics and fecal SCFAs after colonoscopy: accelerating microbiome stabilization by Clostridium butyricum

BackgroundColonoscopy is a classic diagnostic method with possible complications including abdominal pain and diarrhoea. In this study, gut microbiota dynamics and related metabolic products during and after colonoscopy were explored to accelerate gut microbiome balance through probiotics.MethodsThe gut microbiota and fecal short-chain fatty acids (SCFAs) were analyzed in four healthy subjects before and after colonoscopy, along with seven individuals supplemented with Clostridium butyricum. We employed 16S rRNA sequencing and GC–MS to investigate these changes. We also conducted bioinformatic analysis to explore the buk gene, encoding butyrate kinase, across C. butyricum strains from the human gut.ResultsThe gut microbiota and fecal short-chain fatty acids (SCFAs) of four healthy subjects were recovered on the 7th day after colonoscopy. We found that Clostridium and other bacteria might have efficient butyric acid production through bioinformatic analysis of the buk and assessment of the transcriptional level of the buk. Supplementation of seven healthy subjects with Clostridium butyricum after colonoscopy resulted in a quicker recovery and stabilization of gut microbiota and fecal SCFAs on the third day.ConclusionWe suggest that supplementation of Clostridium butyricum after colonoscopy should be considered in future routine clinical practice.

Identification of mozambioside roasting products and their bitter taste receptor activation

Arabica coffee contains the bitter-tasting diterpene glycoside mozambioside, which degrades during coffee roasting, leading to yet unknown structurally related degradation products with possibly similar bitter-receptor-activating properties.The study aimed at the generation, isolation, and structure elucidation of individual pyrolysis products of mozambioside and characterization of bitter receptor activation by in vitro analysis in HEK 293T-Gα16gust44 cells.The new compounds 17-O-β-d-glucosyl-11-hydroxycafestol-2-on, 11-O-β-d-glucosyl-16-desoxycafestol-2-on, 11-O-β-d-glucosyl-(S)-16-desoxy-17-oxocafestol-2-on, 11-O-β-d-glucosyl-15,16-dehydrocafestol-2-on, and 11-O-β-d-glucosyl-(R)-16-desoxy-17-oxocafestol-2-on were isolated from pyrolyzed mozambioside by HPLC and identified by NMR and UHPLC-ToF-MS. Roasting products 11-O-β-d-glucosyl-(S)-16-desoxy-17-oxocafestol-2-on, 11-O-β-d-glucosyl-15,16-dehydrocafestol-2-on, and 11-O-β-d-glucosyl-(R)-16-desoxy-17-oxocafestol-2-on had lower bitter receptor activation thresholds compared to mozambioside.Molecular docking simulations revealed the binding modes of the compounds 11-O-β-d-glucosyl-15,16-dehydrocafestol-2-on and 11-O-β-d-glucosyl-(R)-16-desoxy-17-oxocafestol-2-on and their aglycone 11-hydroxycafestol-2-on in the two cognate receptors TAS2R43 and TAS2R46.The newly discovered roasting products 17-O-β-d-glucosyl-11-hydroxycafestol-2-on, 11-O-β-d-glucosyl-(S)-16-desoxy-17-oxocafestol-2-on, 11-O-β-d-glucosyl-15,16-dehydrocafestol-2-on, and 11-O-β-d-glucosyl-(R)-16-desoxy-17-oxocafestol-2-on were detected in authentic roast coffee brew by UHPLC-ToF-MS and could contribute to coffee's bitter taste impression.

A Theory of Architectural Production in a Geography of Change: Auguste Choisy in the Ottoman Empire

This article presents an expanded intellectual, historical and geographical context of Auguste Choisy’s history of architecture. Reading his history of Byzantine architecture along with his travelogue, L’Asie Mineure et les Turcs en 1875 (1876), the article situates Choisy’s notion of architectural production in relation to the background of the modernisation projects of the Ottoman Empire. It draws connections between Choisy’s historical and geographical thought at the end of the nineteenth century, articulating the notion of a material landscape composed of resources, work, and a sense of environment that suggested the ways in which a society transforms the earth to inhabit it. With environment in the background, Choisy’s history articulated architecture as an index of how a society makes use of its resources, organises work and allows for experimentation within its systems of knowledge.

전문대학의 상대적 효율성 분석과 생산성변화 연구

This study was conducted to measure the relative efficiency of 124 junior colleges in Korea. Data for three years from 2020 to 2022 were provided on the university information disclosure website, and the relative efficiency and productivity changes of junior colleges were analyzed using DEA and Malmquist techniques. As a result of the DEA analysis, it was analyzed that the efficiency of 23 junior colleges in 2020, 34 in 2021, and 26 in 2022 is determined by scale. As a result of the analysis of the Malmquist productivity index, a total of 33 junior colleges have generated technological progress, and 91 junior colleges have generated technological regression, which is about three times higher than the occurrence of technological progress. The average value of MPI-based productivity was analyzed to have decreased by about 4.8% over three years, and it was found to be affected by changes in efficiency. It was analyzed that 108 junior colleges were affected by efficiency by scale, excluding 16 junior colleges that were analyzed to have pure technological efficiency greater than efficiency of scale.

Protective effect of exosomes derived from bone marrow mesenchymal stem cells on hypoxia reperfusion injury of cardiomyocytes.

We aimed to investigate the cardiomyocyte-protective effects of bone marrow mesenchymal stem cells (BMSCs)-derived exosomes on ischemia/reperfusion (I/R)-injured rats and to explore the mechanisms. Cardiomyocytes were divided into control group, ischemia/reperfusion group (I/R group), ischemia/reperfusion+exosome group (I/R+Exo group) or ischemia/reperfusion+exosomes transfected with miR-101a-3p inhibitor group (I/R+Exo inhibitor group). MiR-101a-3p levels were lower in I/R and I/R+Exo inhibitor groups than in control and I/R+Exo groups. Apoptosis rate and cleaved caspase 3 expression were higher in I/R and I/R+Exo inhibitor groups. The levels of superoxide dismutase (SOD) in cardiomyocytes of I/R group and I/R+Exo inhibitor group were lower than those of control group and I/R+Exo group, and the levels of malondialdehyde (MDA) and the relative production of oxygen species clusters (ROS) in cardiomyocytes of I/R group and I/R+Exo inhibitor group were higher than those of control group and I/R+Exo group. The levels of interleukin-10 (IL-10), interleukin-6 (IL-6), tumour necrosis factor α (TNF-α), and nuclear factor κB (NF-κB) were higher in the I/R group and the I/R +Exo inhibitor group than in the control group and the I/R+Exo group. Bioinformatics analysis suggested that Pik3c3 is the most promising gene involved in miR-101a-3p-mediated apoptosis in cardiomyocytes, and in vitro experiments confirmed that low expression of miR-101a-3p significantly up-regulated the mRNA and protein expression levels of Pik3c3. BMSCs-derived exosomes have a protective effect on cardiomyocytes from I/R-injured rats, and the mechanism may be related to the inhibition of oxidative stress and inflammatory responses in cardiomyocytes by exosome-delivered miR-101a-3p.

A chemodynamical analysis of bright metal-poor stars from the HESP-GOMPA survey – indications of a non-prevailing site for light r-process elements

ABSTRACT We present a comprehensive analysis of the detailed chemical abundances for a sample of 11 metal-poor, very metal-poor, and extremely metal-poor stars ([Fe/H] = −1.65 to [Fe/H] = −3.0) as part of the HESP-GOMPA (Galactic survey Of Metal Poor stArs) survey. The abundance determinations encompass a range of elements, including C, Na, Mg, Al, Si, Ca, Sc, Ti, Cr, Mn, Fe, Co, Ni, Cu, Zn, Sr, and Ba, with a subset of the brighter objects allowing for the measurement of additional key elements. Notably, the abundance analysis of a relatively bright highly r-process-enhanced (r-II) star (SDSS J0019+3141) exhibits a predominantly main r-process signature and variations in the lighter r-process elements. Moreover, successful measurements of thorium in this star facilitate stellar age determinations. We find a consistent odd–even nucleosynthesis pattern in these stars, aligning with expectations for their respective metallicity levels, thus implicating Type II supernovae as potential progenitors. From the interplay between the light and heavy r-process elements, we infer a diminishing relative production of light r-process elements with increasing Type II supernova contributions, challenging the notion that Type II supernovae are the primary source of these light r-process elements in the early Milky Way. A chemodynamical analysis based on Gaia astrometric data and our derived abundances indicates that all but one of our program stars are likely to be of accreted origin. Additionally, our examination of α-poor stars underscores the occurrence of an early accretion event from a satellite on a prograde orbit, similar to that of the Galactic disc.