The analysis of network interactions among dynamical units and the impact of the coupling on self-organized structures is a challenging task with implications in many biological and engineered systems. We explore the coupling topology that arises through the potential drops in a flow channel in a lab-on-chip device that accommodates chemical reactions on electrode arrays. The networks are revealed by analysis of the synchronization patterns with the use of an oscillatory chemical reaction (nickel electrodissolution) and are further confirmed by direct decoding using phase model analysis. In dual electrode configuration, a variety coupling schemes, (uni- or bidirectional positive or negative) were identified depending on the relative placement of the reference and counter electrodes (e.g., placed at the same or the opposite ends of the ow channel). With three electrodes, the network consists of a superposition of a localized (upstream) and global (all-to-all) coupling. The synchronization patterns and the network configuration are compared for the linear and the branched channel configurations. The networked, electrode potential (current) spike generating electrochemical reactions hold potential for construction of an in-situ information processing unit to be used in electrochemical devices in sensors and batteries.