The implementation of some energy-saving and emission reduction measures can effectively offset the energy consumption and carbon emissions in the wastewater treatment process. Integrated policy-making information on carbon-energy-economy of these technologies is not clear in national wastewater treatment industry. This study investigated energy self-sufficiency, carbon neutralization potential and economic performance of wastewater treatment industry, as well as related synergy effect among the three aspects using the proposed approach. Then the approach was used to investigate energy-saving and carbon emission reduction potential of the three technologies (photovoltaic power (PV), combined heat and power (CHP) and water source heat pump (WSHP)) and technological combinations as well as related economic performance in urban wastewater treatment of Chinese different provinces in 2021. The results showed that (1) The national energy self-sufficiency is 95%; therein, 13 provinces have the potential to achieve or exceed energy self-sufficiency of 100%, and the top 3 provinces are Heilongjiang, Yunnan and Hunan. (2) The national carbon neutral potential is 87%; therein, 9 provinces have the potential to achieve or surpass carbon neutralization of 100%, and the top 3 provinces include Beijing, Hunan and Shaanxi. (3) these technologies or their combinations are potentially economically viable (net economic benefit ratio >1), and the top three provinces are Beijing, Shaanxi, and Inner Mongolia. (4) Generally, there are 13 provinces with synergy effect >1 in the country; the top three provinces are Liaoning, Heilongjiang and Hunan. Finally, targeted policy suggestions are provided for Chinese urban wastewater treatment. The proposed approach can also act as one of decision-making tools for wastewater treatment industry in other countries or areas in the world.