Raw Water Research Articles

Predicting energy performance of the drinking water treatment process and its determinants

ABSTRACT Within the global climate change framework, enhancing energy efficiency presents a significant challenge for water utilities. Drinking water treatment is energy-intensive, involving several physicochemical processes to remove multiple pollutants from raw water. This study employs artificial neural networks (ANNs) and decision tree methods to gain a deeper understanding of the water–energy nexus in drinking water treatment processes. The energy efficiency of a sample of Chilean drinking water treatment plants (DWTPs) was estimated, resulting in an average score of 0.343. This indicates that on average, DWTPs could potentially save 65.7% of their current energy consumption if they were operating at an efficient level while producing the same quantity and quality of drinking water. The main source of raw water and the technology for treating water have been identified as critical factors influencing energy efficiency. Specifically, using surface water for producing drinking water–-energy efficiency can increase to 0.514, whereas using groundwater would regress energy efficiency to 0.240. The use of predictive tools such as ANNs provides relevant information to support decision-making processes for a transition toward a sustainable urban water cycle.

Land-Use Pattern-Based Spatial Variation of Physicochemical Parameters and Efficacy of Safe Drinking Water Supply along the Mahaweli River, Sri Lanka

Exploration of the pollution status of river-based water sources is important to ensure quality and safe drinking water supply for the public. The present study investigated physicochemical parameters of surface water in the upper segment of River Mahaweli, which provides drinking water to the Nuwara Eliya and Kandy districts of Sri Lanka. River surface water from 15 intakes and treated water from 14 Water Treatment Plants (WTPs) were tested for pH, water temperature, turbidity, EC, COD, 6 anions, 21 cations, 3 pesticides, and 30 antibiotics once every 3 months from June 2022 to July 2023. Except for turbidity and iron concentrations, all other parameters were within the permissible range as per the Sri Lanka Standard Specification for Potable Water (SLS 614:2013). The uppermost Kotagala WTP raw water had a high concentration of iron due to runoff from areas with abundant iron-bearing minerals. Turbidity increased as the river flowed downstream, reaching its highest value of 13.43 NTU at the lowermost Haragama. Four intakes had raw surface water suitable for drinking as per the Water Quality Index (WQI). Pollution increased gradually towards downstream mainly due to agricultural runoff, industrial effluents, and urbanization. Poor water quality at the upstream Thalawakale-Nanuoya intake was due to highly contaminated effluent water coming from Lake Gregory in Nuwara Eliya. Cluster analysis categorized WTP locations in the river segment into 3 clusters as low, moderate, and high based on contaminations. Principal component analysis revealed that the significance of the 41.56% variance of the raw water was due to the pH and the presence of heavy metals V, Cr, Ni, Rb, Co, Sr, and As. All treated water from 15 WTPs had very good to excellent quality. In general, heavy metal contamination was low as indicated by the heavy metal pollution index (HPI) and heavy metal evaluation index (HEI). The treatment process could remove up to 94.7% of the turbidity. This is the first attempt to cluster the river catchment of the Mahaweli River based on physicochemical parameters of river water. We present here the land-use pattern-based pollution of the river and efficacy of the water treatment process using the Mahaweli River Basin as a case study. Regular monitoring and treatment adjustments at identified points are recommended to maintain the delivery of safe drinking water.

Time Series Analysis to Estimate the Volume of Drinking Water Consumption in the City of Meoqui, Chihuahua, Mexico

Water is a vital resource for sustaining life and for numerous processes within the transformation industry. It is a finite resource, albeit one that can be renewed, and thus sustainable management is imperative. To achieve this objective, it is necessary to have the appropriate tools to assist with the planning policies for its management. This paper presents a time series analysis approach to measure and predict the pattern of water consumption by humans throughout subsectors (domestic, commercial, public sector, education, industry, and raw water) and total water consumption in Meoqui, Chihuahua, Mexico with data from 2011 to 2023, applying calibration model techniques to measure uncertainty in the forecasting. The municipality of Meoqui encompasses an area of 342 km2. The climate is semi-arid, with an average annual rainfall of 272 mm and average temperatures of 26.4 °C in summer and 9.7 °C in winter. The municipal seat, which has a population of 23,140, is supplied with water from ten wells, with an average consumption of 20 ± 579 m3 per user. The consumption of the general population indicates the existence of a seasonal autoregressive integrated moving average (SARIMA) (0,1,2)(0,0,2)12 model. (Sen’s Slope = 682.7, p < 0.001). The domestic sector exhibited the highest overall consumption, with a total volume of 17,169,009 m3 (13 ± 93). A SARIMA (2,1,0)(2,0,0)12 model was estimated, with a Sen’s slope of 221.65 and a p-value of less than 0.001. The second-largest consumer of total water was the “raw water” sector, which consumed 5,124,795 (30,146 ± 35,841) m3 and exhibited an SARIMA (0,1,1)(2,0,0)12 model with no statistically significant trend. The resulting models will facilitate the company’s ability to define water resource management strategies in a sustainable manner, in alignment with projected consumption trends.

Impact of variable hydrostatic pressure and intermittent operation on filtration performance and biofouling layer in gravity-driven membrane system for practical decentralized water supply

The gravity-driven membrane (GDM) systems offer a promising solution for decentralized drinking water supply due to its low maintenance and energy consumption. However, research on the practical application of GDM under variable hydrostatic pressure (variable load) and intermittent operation conditions, particularly in response to high-turbidity water, remains limited. This study investigates the long-term performance and characteristics of the biofouling layer of GDM under ultra-low variable hydrostatic pressure (20–60 mbar) and intermittent operation (8–12 h) conditions in practical decentralized water supply. The results indicate that the membrane flux (1.9–6.0 L∙m−2∙h−1, LMH) remained relatively stable despite variations in gravity-driven pressure (ΔP). Long-term operation of GDM can stably remove turbidity and potential pathogens from raw water. The total protein/polysaccharide ratios of extracellular polymeric substances (EPS) in the biofouling layer were below 0.50, reducing contaminant adhesion on the membrane surface. The 0.2–0.4 μm transparent exopolymer particles (TEP) fraction might be crucial for biofouling layer formation. The key species, belong to Proteobacteria and Patescibacteria, significantly alleviated membrane fouling by degrading polysaccharide and proteins in biofouling layer. Comammox Nitrospira were significantly enriched, contributing to efficient nitrification. GDM with variable load maintained a stable flux of 2.2–5.2 LMH under high-turbidity water conditions (300–1200 NTU), and simple forward flushing combined with sludge discharge can quickly restore ΔP. Overall, the variable load GDM system effectively manages membrane fouling and maintains stable filtration performance through the combined effects of variable load and intermittent operation, ensuring long-term and low-maintenance operation for decentralized water supply.

Dehardening of carbon dioxide: A highly efficient chemical precipitant used for the dehardening of deep coalbed methane produced water

The greenhouse gas CO2 is used as a precipitant to deharden the deep coalbed methane produced water (PW), allowing it to meet the reuse requirements. The pH of PW is the key factor affecting the absorption and dissolution of CO2. High raw water pH leads to higher CO2 absorption, callback pH, and CO32− release. The aeration rate and aeration time determine how quickly and how much CO2 is absorbed and dissolved. Increasing temperature enhances the removal effect. Smaller CO2 bubble facilitates more rapid CO2 absorption, and high CO2 gas pressure increases the final CO2 dissolution. Under normal temperature and pressure, the pH of raw water is adjusted to 11, with an aeration rate of 200 mL/min for 16 min. In addition, the callback pH is equal to 12.80, resulting in a final dehardening effect of 99.77 %, making the treated PW suitable for reuse. Mechanistic studies have shown that at the first level of dehardness, CO2 is not dissolved enough under constant pressure, causing some Ca2+ to precipitate as Ca(OH)2, which enhances hardness removal. To improve the dehardening effect, excessive callback pH can be used, and multi-stage dehardening ensures that Ca2+ precipitates as CaCO3. Meanwhile, Mg2+ is predominantly removed as Mg(OH)2 in the first stage. Dehardening can produce small CaCO3 microsphere by-products, which can be considered for further recycling. The cost of CO2 as a dehardening agent is 23.83 % better than Na2CO3, which not only achieves the dehardening of deep coalbed methane PW at a low cost, but also provides a feasibility reference for the early realization of the “dual carbon” target to a certain extent.

Synthesis, performance and application of environmental protection scale inhibitorβ-CD-MA-SSS copolymer——in electric power industry

The issue of water scaling in the treatment of cooling water has become an imperative problem that should be solved urgently for the sake of safe operation in large-scale flexible DC converter stations. However, the coexistence of Ca2+ and Mg2+ in high content in this sort of pending raw water is quite hard to tackle. β-CD-MA-SSS, an eco-friendly ternary co-polymer antiscalant with good performance of inhibiting the formation of scale, was applied to address this conundrum in this paper. The efficacy of the antiscalant β-CD-MA-SSS was investigated in cooling water systems under the conditions of low hardness, low alkalinity, a temperature not exceeding 80 °C, and a pH range of 6–8. After optimization, this reagent dem onstrated an excellent scale inhibition rate up to 80% for both calcium carbonate and calcium-magnesium mixed scales. Scanning electron microscopy (SEM) analysis revealed a noticeable reduction in the size of CaCO3 particles when subjected to the action of β-CD-MA-SSS. It was postulated from FTIR analysis that nanoinpurity and chelation effects mainly contributed to the mixed scale inhibition. Further, the effect of β-CD-MA-SSS on the actual production wastewater was comprehensively evaluated from the technical, economic and environmental aspects.

Triple strategies for process salt reduction in industrial wastewater treatment: The case of coking wastewater

Human activities introduce nutrient elements into wastewater, yet the saline byproducts from treatment are poorly managed. Selecting a low-salt process, without compromising treatment efficacy, is essential for reaching the zero-discharge goal in water treatment. Based on the engineering treatment process of coking wastewater, the source and reduction strategy of salts were studied. The results showed that 73.21 % of the residual salt originated from raw coal, 10.87 % from raw water, and 15.92 % from chemicals, respectively. Triple strategies for process salt reduction (PSR): load salt reduction, technology salt reduction and cyclic salt reduction can bring 0.411 mS/cm·m3, 0.217 mS/cm·m3 and −0.070 mS/cm·m3 salt reduction, and also bring 1.455 CNY/m3, 0.836 CNY/m3 and 0.360 CNY/m3 net present value, respectively. Meanwhile, PSR is also a low-carbon strategy, which will bring about carbon emission reduction of 1.6948 kg CO2-eq/m3, 0.4898 kg CO2-eq/m3 and 1.4082 kg CO2-eq/m3 respectively. The Resource/Carbon source Management-Oxic − Hydrolytic & Denitrification − Oxic (A-OHO) process, incorporating PSR, cuts costs by 27.83–31.66 % and carbon emissions by 18.68–19.54 % compared to conventional wastewater treatment methods. It can be predicted that the PSR in the standard treatment stage can provide a guarantee for the subsequent water reuse and desalination process to reduce project investment and operating costs, and at the same time benefit the macro environment from the aspects of carbon emission reduction and sludge reduction.

Uncovering the performance and intrinsic mechanism of different hydrolyzed AlTi species in polystyrene nanoplastics coagulation

Hydrolyzed AlTi species are essential metal-based coagulants in a coagulation process to remove nanoplastics (NPs). Understanding the molecular interactions between hydrolyzed AlTi species and NPs is key to promoting coagulation efficiency. In this study, the coagulation performance and intrinsic mechanism of different AlTi species (including monomeric AlTi and polymeric AlTi species-Al13Ti13) for NPs removal were systematically investigated. We found that the polymeric AlTi species exhibited higher turbidity removal (95.0 %) and lower residual Al content (20.67 μg/L) at a low dosage over monomeric AlTi species. Al13 and Al13Ti13 formed by in situ hydrolysis were the dominant species to destabilize and aggregate NPs at pH 6. Main coagulation mechanisms were dominated by charge neutralization, complexation between the aliphatic CH of NPs and Al/Ti-OH, and cation-π interaction between polycations and the aromatic structure of NPs. The preformed Al13Ti13 showed multiple positive charge binding sites assisting its easy adsorption on NPs by electrostatic attraction, and then formed microscale aggregates through charge neutralization or intermolecular interaction. The preformed Al13Ti13 demonstrated a high stability and coagulation performance with respect to pH changes in raw water, whereas the promotion of μ-OH bridges dissociation by OH− and the presence of electrostatic repulsion significantly decreased the NPs removal by monomeric AlTi at high pH. This study provides valuable theoretical insights into the interaction between NPs and various hydrolyzed AlTi species.

The importance of institutional capacity in drinking water supply system governance: A policy evaluation from border area

In most developing countries, the equal access to clean and potable water is a major challenge faced by many communities. This research aims to evaluate water supply system governance policies as well as potential springs, constraints and problems related to the water needs of border communities. This research is a descriptive study using a qualitative approach. The qualitative approach looks at policies, institutions, conflicts, and problems faced, as well as looking at data on water sources, socio-economic challenges, culture, and local wisdom. The research location was in Belu Regency, on the Indonesia-Leste Timor border. Research informants were representatives of local government, academics and the community. The problems faced are the underdevelopment of piped networks due to budget constraints, low capacity and quality of human resources, and the absence of specific regulations governing the Drinking Water Supply System (SPAM). The study area has springs spread across 11 subdistricts, with raw water potential ranging from 0.5 to 250 liters per second. Most of these water sources are good for community consumption, but some have not been optimally utilized so that they cannot be fully utilized to meet the needs of the population. The results show that SPAM management policies can be implemented to a certain extent, but have not yet run optimally because they still require capacity building and competence of the apparatus and local communities and an increase in the role of local governments to help implement central government policies in relation to assistance tasks and as a tool for deconcentration of the central government. In conclusion, the potential of raw water sources has not been fully utilized due to the challenges of infrastructure development and the limited capacity of human resources and budgets. Without good management and institutional support, communities will continue to face problems related to access to clean water.

Study of a new biocoagulant/bioflocculant mixture based on Boscia senegalensis seeds powder and Aloe vera leaves extract for the treatment of raw water intended for human consumption in rural areas of Sub-Saharan Africa

Study of a new biocoagulant/bioflocculant mixture based on Boscia senegalensis seeds powder and Aloe vera leaves extract for the treatment of raw water intended for human consumption in rural areas of Sub-Saharan Africa

An Analysis Of Energy And Nutrient Content In High Energy Natural Isotonic Drink (Isopower)

Isotonic drink is the carbonated or non-carbonated drink product used to subtitute the fluid lost in the body. Lack of fluid in the body can cause muscle fatigue until causing the performance decrease in athlete. Isotonic drink can accelerate the return of body fluid compared to water. The purpose of this research was to analyze the content of energy, sodium, potassium, and Vitamin C in isotonic drink with raw material coconut water, pure coconut oil, bee bread, palm vinegar, and honey as high energy natural istotonic drink. The research design used was descriptive observation based laboratory test. The data analysis employed SPSS 22 programs namely by carrying out descriptive test until obtained the average for each isotonic namely 247,491 kkla, sodium 77,085 mg.kg, potassium 1000,785 mg/kg and Vitamin C 2,112 mg. This research concluded that the energy drink content has fulfilled the quality specification of isotonic drink, while the sodium and potassium level do not fulfill the quality specification of isotonic drink yet. Likewise with the Vitamin C content which also does not fulfill the Referrence of Nutrition Label namely 10%.

Occurrence and characterization of microplastics in bottled drinking water

Microplastics (MPs) have been identified in diverse settings, including drinking water, freshwater, food, air, and marine environments. This study employed stereomicroscopic and µ-Raman techniques to analyze water samples from ten widely consumed bottled water brands, aiming to detect and characterize MPs. Additionally, the oral consumption of MPs per capita was estimated. The average abundance of MPs ranged from 9 ± 1.00 MPs/L to 3 ± 1.73 MPs/L across all brands. Various MPs shapes were observed, including fibers, fragments, films, and pellets, with fibers being predominant (58.928%). MPs were categorized by color into five groups (red, blue, black, yellow, and transparent), with red comprising approximately 35.714% of the total count. All identified MPs were less than 500 µm in size. µ-Raman analysis validated the presence of eight different polymer types in the samples, namely Polypropylene (PP) (37.5%), Polymethyl methacrylate (PMMA) (3.571%), polystyrene (PS) (33.928%), polycarbonate (PC) (3.571%), polybutylene1 (PB1) (14.2%), Isotactic polypropylene (iPP) (7.142), Nylone 6-α polymorph (αNY6) (5.357%), and polyvinyl alcohol (PVOH) (1.785%). The estimated daily intake of MPs per person was determined to be 0.42 MPs, translating to an annual intake of 153.3 MPs per person. The origin of MPs in bottled water was likely attributed to both raw water sources and packaging materials, underscoring the need for further investigation. Given the potential health implications of human exposure to drinking water MPs, careful consideration should be given to the use of plastic packaging for potable water.

Assessment of poly(diallyl dimethyl ammonium chloride) and lime for surface water treatment (pond, river, and canal water): seasonal variations and correlation analyses.

The present study deals with the assessment of different physicochemical parameters (pH, electrical conductivity (E.C.), turbidity, total dissolved solids (TDS), and dissolved oxygen) in different surface water such as pond, river, and canal water in four different seasons, viz. March, June, September, and December 2023. The research endeavors to assess the impact of a cationic polyelectrolyte, specifically poly(diallyl dimethyl ammonium chloride) (PDADMAC), utilized as a coagulation aid in conjunction with lime for water treatment. Employing a conventional jar test apparatus, turbidity removal from diverse water samples is examined. Furthermore, the samples undergo characterization utilizing X-ray diffraction (XRD) and scanning electron microscopy (SEM) techniques. The study also conducts correlation analyses on various parameters such as electrical conductivity (EC), pH, total dissolved solids (TDS), turbidity of raw water, polyelectrolyte dosage, and percentage of turbidity removal across different water sources. Utilizing the Statistical Package for Social Science (SPSS) software, these analyses aim to establish robust relationships among initial turbidity, temperature, percentage of turbidity removal, dosage of coagulant aid, electrical conductivity, and total dissolved solids (TDS) in pond water, river water, and canal water. A strong positive correlation could be found between the percentage of turbidity removal and the value of initial turbidity of all surface water. However, a negative correlation could be observed between the polyelectrolyte dosage and raw water's turbidity. By elucidating these correlations, the study contributes to a deeper understanding of the effectiveness of PDADMAC and lime in water treatment processes across diverse environmental conditions. This research enhances our comprehension of surface water treatment methodologies and provides valuable insights for optimizing water treatment strategies to address the challenges posed by varying water sources and seasonal fluctuations.

Pharmaceuticals in raw and treated water from drinking water treatment plants nationwide: Insights into their sources and exposure risk assessment

Due to the large amounts of pharmaceuticals and personal care products (PPCPs) currently being consumed and released into the environment, this study provides a comprehensive analysis of pharmaceutical pollution in both raw and treated water from full-scale drinking water treatment plants nationwide. Our investigation revealed that 30 out of 37 PPCPs were present in raw water with mean concentrations ranging from 0.01–131 ng/L. The raw water sources, surface water (ND – 147 ng/L), subsurface water (ND – 123 ng/L) and reservoir sources (ND – 135 ng/L) exhibited higher mean concentration levels of pharmaceutical residues compared to groundwater sources (ND – 1.89 ng/L). Meanwhile, in treated water, 17 of the 37 analyzed PPCPs were present with carbamazepine, clarithromycin, fluconazole, telmisartan, valsartan, and cotinine being the most common (detection frequency > 40 %), and having mean concentrations of 1.22, 0.12, 3.48, 40.1, 6.36, and 3.73 ng/L, respectively. These findings highlight that, while water treatment processes are effective, there are some persistent compounds that prove challenging to fully eliminate. Using Monte Carlo simulations, risk assessment indicated that most of these compounds are likely to have negligible impact on human health, except for the antihypertensives. Telmisartan was identified as posing the highest ecological risk (RQ > 1), warranting further investigation, and monitoring. The study concludes by prioritizing specific 14 pharmaceuticals, including telmisartan, clarithromycin, lamotrigine, cotinine, lidocaine, tramadol, and others, for future monitoring to safeguard both ecological and human health.

Microplastics in urban water cycles: Looking for a more scientific approach for sampling and characterization in wastewater and drinking water treatment plants

Specific campaigns to detect microplastics (MPs) in the urban water cycle were carried out in three drinking water plants and two wastewater treatment plants. A self-designed sampler for MPs detection in water matrices was in this study preliminary validated and then tested in long term campaigns sampling up to 1000 L. Raw drinking water and wastewater show microplastics (MPs) concentrations of 2–11 and of 480–801 MPs/m3, respectively, and MPs removals of 47–78 % and of 84–98 %, correspondingly. Specific roles of chemical and physical conventional processes in microplastics removals were investigated. Solid-liquid separation, flotation and filtration are the main processes for achieving high microplastics removal. Regarding concentrated matrices, MPs concentrations in sludge samples varied in the range of 5000–500,000 MPs/m3. Finally, shapes, size classes and polymers' typologies were investigated in the extracted MPs. The detected sizes are mainly 0.5–0.1 mm in drinking waters while 5–1 mm in wastewaters. Wastewaters were predominated by synthetic fibers (polyester type), while drinking waters were mainly characterized by fragments and the fibers were mostly of natural origin. Finally, the results of this study supported best practices and guidelines for a representative assessment of MPs in water (sampling methods, extraction procedures, characterization and quantification).

Physical-chemical characterisation of an alum-based water treatment sludge in different raw water turbidity scenarios

Characterisation of the water treatment sludge (WTS) generated in drinking water treatment plants (DWTPs) is crucial to define alternatives for its adequate management, including potential reuse options. To define these alternatives, it is necessary to evaluate rainfall seasonality effect on WTS production and its physical and chemical characteristics. This study assessed the production and characterisation of four types of alum-based WTS. The WTS was generated in a pilot-scale system from different raw water turbidities (i.e., low: <5 NTU, medium: 5–10 NTU, high: ≥10 NTU, and very high turbidity: ∼300 NTU) and coagulant doses. To estimate WTS production, mathematical models based on variables such as raw water turbidity, coagulant dosage, and organic matter removed were used. The WTS characterisations included physical (solids and particle size distribution), chemical (metallic oxides, pH, mineral phases), and surface properties (functional groups and zero-charge point pH). The modified Kawamura model presented the best fit (R2 = 1.0, RMSE = 0.1062 and the lower Akaike Information Criterion) for the estimation of WTS production, indicating that at the DWTPs, it is possible to make sludge production projections using only two simple variables: coagulant dose and the raw water turbidity. The four types of WTS consist mainly of amorphous materials (45–65 %), featuring some mineral phases and exhibiting high contents of Al (Al2O3: 30–34 %), Si (SiO2: 21–26 %) and Fe (Fe2O3: 11–13 %). Nevertheless, very high turbidity WTS shows variations in its characteristics, notably a heightened content of clays. As a result of the high concentrations of Al and Fe, the WTS has the potential to be used as coagulants or for the recovery of coagulants, especially low turbidity WTS, which is produced from water with low turbidity and organic matter. The presence of aluminium–silicate clays and the surface functional groups of the silica network suggest that WTS, particularly very high turbidity WTS, also has the potential to be raw materials for generating adsorbents. The potential applications of WTS in coagulation and adsorption can be leveraged in wastewater treatment, promoting the circular economy in the water sector.

Seasonal natural organic matter removal and implications for disinfection by-product formation at the Koka water treatment plant: Upper Awash, Ethiopia

ABSTRACT This study evaluated the seasonal performance of the Koka water treatment plant in removing natural organic matter (NOM) and the implications for disinfection by-product (DBP) formation potential. Raw and treated water samples were collected during the dry and wet seasons and analyzed using physicochemical parameters and fluorescence spectroscopy. The results revealed significant seasonal variations in raw water (RW) quality, with higher turbidity, pH, temperature, conductivity, total organic carbon (TOC), dissolved organic carbon (DOC), and UV254 absorbance during both seasons and across treatment processes. The NOM removal efficiency of the treatment plant was poor, with mean TOC removal of 46 and 43% and DOC removal of 15.8 and 15.2% during dry and wet seasons, respectively. The sedimentation unit demonstrated negative TOC removal, indicating NOM accumulation likely due to biochemical reactions in the unit. Fluorescence analysis and the correlation between specific ultraviolet absorbance (SUVA) and DBP formation potential suggest a higher risk of DBP formation in chlorinated drinking water. These findings highlight the influence of seasonal variations, RW quality, and the treatment process dynamics on the plant's performance in removing NOM. There is a need to implement adaptable strategies to enhance NOM removal, accounting for seasonal fluctuations in RW quality.

Understanding and classifying the raw water transfer invasion pathway

Understanding and classifying the raw water transfer invasion pathway

The Potential of Spring Water Analysis for Drinking Water at Ujung Gagak Village, Kampung Laut Subdistrict, Cilacap Regency

Limited clean water is the main problem in Ujung Gagak Village. The community can use no groundwater because the water is brackish and salty, which is unsuitable for daily activities. This study aims to analyze the potential of the Karang Cave spring to be used as drinking water. This spring plays an important role in the life of the people of Ujung Gagak Village when the dry season arrives. Using the grab sampling method, raw water sampling at the Karang Cave spring. Pollution Status Index (IP) quality of 5.08 is included in the moderately polluted category. Then, raw water samples are taken and processed in the Reverse Osmosis (RO) system. Parameters that exceeded the quality standard were total coliform of &gt; 24,000 CFU/100ml, salinity parameter of 0.33‰, turbidity of 1.98 NTU, and hardness of 320 mg/L. However, treating it in an RO system for drinking water is necessary. Laboratory test results for water quality after processing, several parameters experienced a significant decrease, for the parameter salinity to 0‰, turbidity to 0.74 NTU, and hardness to 99 mg/L, total coliform decreased by 108 CFU /100ml. The results showed that the RO system succeeded in removing salt up to 99.5% and reducing the Concentration of turbidity, hardness, and total coliform. It is suitable for drinking water, but if you want to drink it immediately, you can cook it first, considering that the total coliform is still above the required quality standard.

Occurrence, persistence, and removal of contaminants of emerging concern through drinking water treatment processes – A case study in South Africa

The presence of contaminants of emerging concern (CECs) in drinking water is a global issue of concern. Evidence galore of the potential impacts of CECs on human health, yet there are no concrete guidelines or regulatory oversight to effectively tackle CECs exposure from drinking water. As a result, CECs concentrations can be well-above the suggested thresholds, particularly in low and middle-income countries (LMICs) due to undeveloped or underdeveloped (waste)water treatment infrastructure and/or substandard treatment practices. Yet, CECs occurrence and particularly their persistence during drinking water treatment is not well-documented in such settings. For this reason, here, the occurrence of 19 CECs was monitored across the different treatment steps (coagulation, sedimentation, sand filtration, and chlorination) of a typical water treatment plant in South Africa using UPLC-MS/MS. The most dominant CEC was, by and large, efavirenz (1103.9 ± 743.1 ng/L in raw water) tracing back to antiretroviral treatment for the human immunodeficiency virus (HIV) and revealing unpleasant realities about the HIV epidemic crisis in Sub-Sahara Africa (Global South) and possible drug abuse for illicit drug (whoonga/nyaope) manufacturing. For the other examined CECs, their concentrations in drinking water were, from higher to lower score: 1,7 dimethylxanthine (403.3 ± 244.2 ng/L) ≥ emtricitabine (358.4 ± 250.8 ng/L) ≥ atrazine (227.0 ± 61.0 ng/L) ≥ caffeine (194.1 ± 216.5 ng/L) ≥ tramadol (189.5 ± 112.4 ng/L) ≥ carbamazepine (122.9 ± 24.5 ng/L) ≥ sulfamethoxazole (107.8 ± 55.1 ng/L) ≥ methaqualone (72.2 ± 20.5 ng/L) ≥ benzotriazole (61.2 ± 18.8 ng/L) ≥ trimethoprim (59.1 ± 30.4 ng/L) ≥ cetirizine (33.7 ± 19.6 ng/L) ≥ codeine (26.7 ± 57.2 ng/L) ≥ naproxen (25.7 ± 11.3 ng/L) ≥ venlafaxine (21.6 ± 16.3 ng/L) ≥ acetaminophen (17.7 ± 25.8 ng/L) ≥ benzoylecgonine (9.6 ± 5.1 ng/L) ≥ methamphetamine (8.6 ± 6.4 ng/L) ≥ diclofenac (5.2 ± 7.9 ng/L). The large standard deviations indicate the high temporal variations in CECs releases in freshwater. The silver lining is that in the final drinking water, CECs concentrations are greatly reduced, with percentage removals in the range of 9 % (diclofenac) to 75 % (efavirenz). Nonetheless, in LMICs tangible limits and regulatory frameworks for the effective removal of CECs from drinking water, along with more robust polishing techniques such as activated carbon treatment, are missing and should be introduced to avoid the worst effects of CECs exposure.