Mass Ratio Research Articles

Retardation theory of eleven galaxies

Abstract The missing mass problem has been with us since the 1970s, as Newtonian gravity using baryonic mass cannot account for various observations. We investigate the viability of retardation theory, an alternative to the Dark Matter paradigm (DM) which does not seek to modify the General Principal of Relativity but to improve solutions within it by exploring its weak field approximation to solve the said problem in a galactic context. This approach have yielded satisfactory results, with respect to galactic rotation curves, the Tully-Fisher relation and missing mass derived from gravitational lensing. Recently it was able to introduce a necessary correction to the virial theorem explaining mass excess in clusters of galaxies. The current work presents eleven rotation curves calculated using Retardation Theory. The calculated rotation curves are compared with observed rotation curves. Values for the change in mass flux to mass ratio are extracted from the fitting process as a free fitting parameter. Those quantities are interpreted here and in previous works using galactic processes. Retardation Theory was able to successfully reproduce rotation curves and a preliminary correlation with star birthrate index is seen, suggesting a possible link between galactic winds and observed rotation curves. Retardation Theory shows promising results within current observations. More research is needed to elucidate the suggested mechanism and the processes which contribute to it. Galactic mass outflows carried by galactic winds may affect rotation curves.

Edible Coating from Breadfruit Starch and Chitosan for Food Packaging

Lectures that encompass Education for Sustainable Development (ESD) can encourage awareness about sustainable development by integrating current issues, such as the potential of breadfruit starch and chitosan for making edible coatings for food packaging. This work aimed to study the development of edible coating from breadfruit starch (BS) and chitosan (CH) for food packaging based on SDGs aspects and as preliminary research to develop worksheets for prospective chemistry teacher students. BS-CH edible film developed by solvent evaporation method, thickness measurement, and physical properties for application on chili, carrot, and sweet potato which. The results showed that the optimal comprehensive properties of the film were obtained when the mass ratio of 3% AS to 1% CH was 7:3. The solubility test results show that the addition of CH ratio increases the swelling of the film before the dissolution process. The tensile strength and elongation of the film increased with the addition of CH until the optimum condition with tensile strength values of 3.01 MPa and 58.26%. The optimum mass ratio was applied through the coating of carrot, chili, and sweet potato which can prevent mass weight and mushroom. Apart from that, student opinion data was generated in the form of potential edible coating topics in the theme of ESD issues. In addition, student opinion data was generated in the form of expectations of edible coatings topics in ESD-laden chemistry learning, including understanding and applying ESD principles and the context of edible coatings and introducing the potential of edible coatings in society so that it is expected to improve 21st-century skills. The results of this research show the need to integrate the topic of edible coating of breadfruit starch and chitosan in worksheets for prospective chemistry teacher students.

Enhanced CO2 capture and reverse water gas shift reaction using CaO in NaCl-CaCl2 molten salt medium

This study introduces an Integrated Carbon Capture and Utilisation-Reverse Water Gas Shift (ICCU-RWGS) approach, a novel method for in situ CO2 adsorption and conversion, leveraging the synergistic effects of CaO within a NaCl-CaCl2 molten salt blend to enhance CO2 capture and conversion efficiency. Building upon this foundation, we optimize CaO concentration and operating temperature to maximize CO2 uptake and conversion performance. The research focuses on integrating CaO with a NaCl-CaCl2 molten salt blend (mass ratio 4:6) to improve CO2 sorption and conversion performance. Findings show significant enhancements in CO2 uptake and CO yield with the presence of molten salt compared to systems without it. The optimal operating temperature and CaO concentration are identified for maximum CO yield. Characterisation techniques like in-situ infrared spectroscopy, XRD, and SEM provide insights into the behavior of CaO in the molten salt, revealing the solubility of the partial carbonate formed from CO2 and CaO, dispersion of CaO particles, and their morphological characteristics. Overall, the study demonstrates the potential of CaO-molten salt integration in improving ICCU-RWGS process efficiency and contributes to the development of more effective and sustainable ICCU technologies.

Effective photocatalytic degradation of sulfamethoxazole using Pan/Srtio3 nanofibers

Freshwater scarcity driven by pollution and climate change necessitates the development of effective water purification methods. There is an urgent need for innovative solutions that can efficiently remove contaminants from water sources. A effective material for the photocatalytic degradation of organic sulfonamide antibiotics from water was developed in this study. A composite of electrospun strontium titanate (SrTiO3) and carbon fibers polyacrylonitrile/strontium titanate (PAN/SrTiO3) was employed for the photocatalytic degradation of sulfamethoxazole (SMX). Scanning Electron Microscopy/Energy Dispersive Spectroscopy (SEM-EDS), Transmission electron microscopy (TEM), X-ray diffraction (XRD), and X-ray photoelectron spectroscopy (XPS) were used to characterise the composite. The fibers had a thickness of ~250 nm and uniformly dispersed PAN and SrTiO3 particles. A PAN/SrTiO3 composite with a 1:1 mass ratio (20 mg) demonstrated excellent performance, achieving over 90 % degradation at pH 7 and a contaminant concentration of 5 mg/L under ultraviolet (UV) light irradiation during 60 min. The composite was tested for the photodegradation of the major organic pollutant (SMX) in distilled and river water. In river water, the degradation efficiency exceeded 80 % at pH 7 because of the formation of secondary radicals involved in antibiotic degradation. SMX degradation was described using a pseudo-first order kinetic equation using the Langmuir-Hinshelwood model. These results underscore the novelty and significance of the PAN/SrTiO3 composite and demonstrate its high efficiency and potential for large-scale water purification applications.

The enhanced degradation of trichloroethylene in the bioelectrochemical system integrated with iron‑carbon micro-electrolysis

Trichloroethylene (TCE) is one of the most abundant volatile chlorinated hydrocarbons in groundwater which threatens human health and the environment. Utilizing a bioelectrochemical system (BES) to treat TCE is a promising strategy; however, as the ionic strength of the groundwater is low and the extracellular electron transfer of BES is limited, BES degradation of TCE is impeded. In this research, iron and graphite were added to the cathode chamber to form a micro-electrolysis to enhance the degradation of TCE synergistically. The results showed that when the iron and carbon mixture dosage was 70 g/L with the mass ratio (Fe/C) of 1:2 and the initial TCE concentration of 100 mg/L, the degradation efficiency of BES reached 97.8 % at the cathodic potential of −0.3 V (vs.SHE). This was 1.31 times, 1.94 times, and 2.74 times that of Fe/C + open-circuit BES, Fe/C micro-electrolysis, and conventional BES without Fe/C, respectively, which implied that iron‑carbon mediated BES colligated the advantages of microbial degradation and micro-electrolysis, and iron‑carbon provided more electrons and accelerated electron transfer to improve the degradation of TCE significantly. Moreover, through the analysis of the microorganisms of Fe/C + BES, the highest abundances of microorganisms at phylum, class, and genus levels were Proteobacteria, Alphaproteobacteria, and Acetobacterium, respectively. By comparing Fe/C + BES with conventional BES, the addition of iron‑carbon enhanced the microbial diversity and species richness and improved the abundances of Pseudomonas and Geobacter at the genus level. In all, iron‑carbon micro-electrolysis can be integrated with BES to treat TCE and facilitate BES application in the volatile chlorinated hydrocarbon-contaminated sites.

Numerical study on the impact of needle and dryness fraction on two-phase ejector performance under fixed/varied operating pressure

This study investigates the effects of varying needle block degree (blockage area ratio of the primary nozzle throat) and dryness fraction (the ratio of gas mass to mass of two-phase mixture) within the primary and secondary flow on the performance of a two-phase ejector, employing CFD numerical simulations under both fixed and varied conditions. The findings reveal the following: (1) Dryness fraction has a significant impact on the performance of the ejector. ER decreases with the decrease of X1 and increases with the decrease of X2, when X1=1 and X2=0.4, the ejector performance can be improved by 253.3% under the optimal area ratio; (2) A higher primary flow dryness fraction and a lower secondary flow dryness fraction are more favorable for enhancing the ejector's performance; (3) When P1 changes, the ejector is most sensitive to changes in P1, slightly less sensitive to changes in An, and least sensitive to changes in dryness fraction; When P2 changes, the ejector is most sensitive to changes in dryness fraction, slightly less sensitive to changes in P2, and least sensitive to changes in An; (4) When varying P1 and P2, the ejector performance is optimal at X1=1 and X2=0.8 (An); (5) Regardless of changes in AR or operating conditions, the adjustable ejector with the needle can effectively enhance the ejector's performance under certain conditions.

Synergy of oxygen reduction for H2O2 production and Electro-Fenton induced by atomic hydrogen over a bifunctional cathode towards water purification

In the Electro-Fenton (EF) process, hydrogen peroxide (H2O2) is produced in situ by a two-electron oxygen reduction reaction (2e ORR), which is further activated by electrocatalysts to generate reactive oxygen specieces (ROS). However, the selectivity of 2e transfer from catalysts to O2 is still unsatisfactory, resulting in the insufficient H2O2 availability. Carbon based materials with abundant oxygen-containing functional groups have been used as excellent 2e ORR electrocatalysts, and atomic hydrogen (H*) can quickly transfer one electron to H2O2 in a wide pH range and avoiding the restrict of traditional Fenton reaction. Herein, nickel nanoparticles growth on oxidized carbon deposited on modified carbon felt (Ni/Co@CFAO) was prepared as a bifunctional catalytic electrode coupling 2e ORR to form H2O2 with H* reducing H2O2 to produce ROS for highly efficient degradation of antibiotics. Electrochemical oxidation and thermal treatment were used to modulate the structure of carbon substrates for increasing the electro-generation of H2O2, while H* was produced over Ni sites through H2O/H+ reduction constructing an in-situ EF system. The experimental results indicated that 2e ORR and H* induced EF processes could promote each other mutually. The optimized Ni/Co@CFAO with a Ni:C mass ratio of 1:9 exhibited a high 2e selectivity and H2O2 yield of 49 mg L−1. As a result, the designed Ni/Co@CFAO exhibited excellent electrocatalytic ability to degrade tetracycline (TC) under different aqueous environmental conditions, and achieved 98.5% TC removal efficiency within 60 min. H2O2 and H* were generated simultaneously at the bifunctional cathode and react to form strong oxidizing free radicals •OH. At the same time, O2 gained an electron to form •O2−, which could react with •OH and H2O to form 1O2, which had relatively long life (10−6∼10−3 s), further promoting the efficient removal of antibiotics in water.

Effective Waste Management through Co-Pyrolysis of EFB and Tire Waste: Mechanistic and Synergism Analysis

Driven by the need for solutions to address the global issue of waste accumulation from human activities and industries, this study investigates the thermal behaviors of empty fruit bunch (EFB), tyre waste (TW), and their blends during co-pyrolysis, exploring a potential method to convert waste into usable products. The kinetics mechanism and thermodynamics properties of EFB and TW co-pyrolysis were analysed through thermogravimetric analysis (TGA). The rate of mass loss for the blend of EFB:TW at a 1:3 mass ratio shows an increase of around 20% due to synergism. However, the blend’s average activation energy is higher (298.64 kJ/mol) when compared with single feedstock pyrolysis (EFB=257.29 kJ/mol and TW=252.92 kJ/mol). The combination of EFB:TW at a 3:1 ratio does not result in synergistic effects on mass loss. However, a lower activation energy is reported, indicating the decomposition process can be initiated at a lower energy requirement. The reaction model that best describes the pyrolysis of EFB, TW and their blends can be categorised into the diffusion and power model categories. An equal mixture of EFB and TW was the preferred combination for co-management because of the synergistic effect, which significantly impacts the co-pyrolysis process. The mass loss rate experiences an inhibitive effect at an earlier stage (320 °C), followed by a promotional impact at the later stage (380 °C). The activation energy needed for a balanced mixture is the least compared to all tested feedstocks, even lower than the pyrolysis of a single feedstock. The study revealed the potential for increasing decomposition rates using lower energy input through the co-pyrolysis of both feedstocks. These findings evidenced that co-pyrolysis is a promising waste management and valorisation pathway to deal with overwhelming waste accumulation. Future works can be conducted at a larger scale to affirm the feasibility of EFB and TW co-management.

Luffa Vines-Derived N, O Doped Porous Carbon with High Surface Area for Supercapacitors

Considerable attention has been devoted to creating porous carbons with exceptional surface area and porosity from biomass waste for energy storage devices. Herein, we employed a straightforward high-temperature carbonization and KOH activation method to synthesize nitrogen (N) and oxygen (O) co-doped porous activated carbons derived from luffa vines (LVACs). The impact of varying KOH concentrations on the morphology, structure, and electrochemical properties of LVACs was thoroughly investigated. The optimal mass ratio of KOH to LVACs at 1:6 achieved the maximum specific surface area of 3369 m2 g-1. At a current density of 1Ag-1, the LASC-6 electrode exhibits an impressive specific capacitance of 348.5Fg-1. It also demonstrates exceptional rate performance, retaining 70.6% of its capacitance at a current density of 20Ag-1. The electrode possesses robust cycling stability, retaining 90% of the initial capacitance after 5000 cycles. We assessed the practicality of LVAC-6 by constructing symmetric supercapacitors (SSCs) using KOH and [BMIM]BF4 electrolytes. The KOH and [BMIM]BF4 SSCs achieved specific capacitances of 86.75 and 50.31Fg-1, respectively, at a current density of 0.25Ag-1. Moreover, the [BMIM]BF4 SSC exhibited an impressive energy density of 51.05Whkg-1 at a power density of 346.15Wkg-1. Therefore, we propose a simple and cost-effective strategy to produce porous carbon materials with excellent electrochemical performance from discarded biomass waste, facilitating the preparation of environmentally friendly electrode materials for high-performance supercapacitors.

Efficiency of black hole formation via collisions in stellar systems

Context. This paper explores the theoretical relation between star clusters and black holes within them, focusing on the potential role of nuclear star clusters (NSCS), globular clusters (GCS), and ultra-compact dwarf galaxies (UCDS) as environments that allow for black hole formation via stellar collisions. Aims. This study aims to identify the optimal conditions for stellar collisions across a range of stellar systems, leading to the formation of very massive stars that subsequently collapse into black holes. We analyze data from numerical simulations and observations of diverse stellar systems, encompassing various initial conditions, initial mass functions, and evolution scenarios. Methods. We computed a critical mass, determined by the interplay of the collision time, system age, and initial properties of the star cluster. The efficiency of black hole formation (ϵBH) is defined as the ratio of initial stellar mass divided by the critical mass. Results. We find that stellar systems with a ratio of initial stellar mass over critical mass above 1 exhibit a high efficiency in terms of black hole formation, ranging from 30 − 100%. While there is some scatter, potentially attributed to complex system histories and the presence of gas, the results highlight the potential for achieving high efficiencies via a purely collisional channel in black hole formation. Conclusions. In conclusion, this theoretical exploration elucidates the connection between star clusters and black hole formation. The study underscores the significance of UCDS, GCS, and NSCS as environments conducive to the black hole formation scenario via stellar collisions. The defined black hole formation efficiency (ϵBH) is shown to be influenced by the ratio of the initial stellar mass to the critical mass.

Variational Vibrational States of Methanol (12D).

Full-dimensional (12D) vibrational states of the methanol molecule (CH3OH) have been computed using the GENIUSH-Smolyak approach and the potential energy surface from Qu and Bowman (2013). All vibrational energies are converged better than 0.5 cm-1 with respect to the basis and grid size up to the first overtone of the CO stretch, ca. 2000 cm-1 beyond the zero-point vibrational energy. About 70 torsion-vibration states are reported and assigned. The computed vibrational energies agree with the available experimental data within less than a few cm-1 in most cases, which confirms the good accuracy of the potential energy surface. The computations are carried out using curvilinear normal coordinates with the option of path-following coefficients, which minimize the coupling of the small- and large-amplitude motions. It is important to ensure tight numerical fulfillment of the C3v(M) molecular symmetry for every geometry and coefficient set used to define the curvilinear normal coordinates along the torsional coordinate to obtain a faithful description of degeneracy in this floppy system. The reported values may provide a computational reference for fundamental spectroscopy, astrochemistry, and for the search of the proton-to-electron mass ratio variation using the methanol molecule.

Detection of Two Totally Eclipsing B-type Binaries with Extremely Low Mass Ratios

The detection of O- and B-type stars with extremely low-mass companions is very important for understanding the formation and evolution of binary stars. However, finding them remains a challenge because the low-mass components in such systems contribute such small flux to the total. During our search for pulsations among O- and B-type stars using the Transiting Exoplanet Survey Satellite (TESS) data, we found two short-period and B-type (B9) eclipsing binaries with orbital periods of 1.61613 and 2.37857 days. Photometric solutions of the two close binaries were derived by analyzing the TESS light curves with the Wilson–Devinney method. It is discovered that both of them are detached binaries with extremely low mass ratios of 0.067(2) for TIC 260342097 and 0.140(3) for TIC 209148631. The determined mass ratio indicates that TIC 260342097 is one of the lowest mass ratios among known B-type binary systems. We showed that the two systems have total eclipses with a broad and flat secondary minimum, suggesting that the photometric parameters could be derived reliably. The absolute parameters of the two binaries are estimated and it is found that the secondary components in the two systems are overluminous and oversize when compared with the normal low-mass and cool main-sequence (MS) stars. These findings may imply that the two systems are composed of a B-type MS primary and a cool pre-MS secondary with orbital periods shorter than 2.5 days. They are valuable targets to test theories of binary star formation and evolution.

Preparation and performance control of ultra-low near-infrared reflectivity coatings with super-hydrophobic and outstanding mechanical properties.

The development of ultra-low near-infrared reflectivity coatings with outstanding engineering properties remains a challenge in laser stealth materials research. Herein, we reported a laser stealth coating with outstanding mechanical properties, super-hydrophobicity, and an ultra-low near-infrared reflectivity for 1.06μm wavelength. The effects of the mass ratio of graphene to nano-SiO2, the proportion of total filler, the addition of KH560, the mass ratio of Polydimethylsiloxane (PDMS) to acrylic-modified polyurethane (APU), and the addition of dioctyl phthalate (DOP) on the coating properties were thoroughly discussed. The coating can achieve a low reflectivity of 9.3% at 1.06μm and a high water contact angle of 152° at a mass ratio of 7:3 for PDMS to APU and 6:4 for graphene to nano-SiO2 with a total filler amount of 40wt%. KH560 can play a bridging role between the blended resin matrix and nano-SiO2, which can significantly improve the impact strength of the coating. The DOP, which contains a polar ester group and a non-polar carbon chain structure, can be inserted between the molecular chains of the resin to weaken the intermolecular force of the resin, so that the flexibility of the coating can be significantly improved. Adding KH560 at 4wt% and DOP at 1wt%, resulted in a coating with ultra-low near-infrared reflectivity of 1.06μm (9.3%), super-hydrophobic properties, outstanding adhesion strength (grade 2), flexibility (2mm), and impact strength (50kgcm). The above super-hydrophobic ultra-low near-infrared reflectivity coating has significant potential for use in the field of laser stealth equipment, and it can serve as a useful reference for optimizing the mechanical properties of super-hydrophobic functional coatings.

The Significance of Body Surface Area to Mass Ratio for Thermal Responses to a Standardized Exercise-Heat Stress Test.

To evaluate the significance of body surface area-to-mass ratio (BSA/mass) on the heat-tolerance test (HTT) results. We hypothesized that individuals defined as heat tolerant (HT) would have on average higher BSA/mass compared to heat intolerant (HI) individuals. A retrospective reanalysis of the HTT results of 517 soldiers (age: 18-38 yrs., M/F: 96/4%), who were tested by the Israel Defense Forces (IDF) HTT protocol. The criterion for heat tolerance in the current analysis was a rectal temperature (Tre) plateau during the second hour of the test. A logistic regression analysis to evaluate the predictive power of BSA/mass for heat intolerance was performed; the spline model was applied to show the odds for heat intolerance across BSA/mass. In men BSA/mass of HI individuals was lower than HT individuals (248 ± 19 vs. 262 ± 18 cm2/kg, p < 0.01, d = 0.76). In women a similar trend was noted but with no statistical significance between HT and HI groups. The odd ratio for heat intolerance for every unit increase in BSA/mass was 0.97 (CI 95% 0.95-0.99). The spline model plateaued above BSA/mass of 270 cm2/kg. The results imply that body-core temperature responses to a standard exercise-heat stress (fixed external work rate and climatic conditions) are influenced by BSA/mass. More specifically, lack of a steady state in Tre (indicating heat intolerance) was more likely to occur with every unit decrease in BSA/mass. These findings contribute to a better understanding of the role of body anthropometry in the response to a standard exercise-heat task that might have an implication on clinical decision-making about return to duty/play of soldiers, athletes and others who deemed to be identified as HI.

Adiabatic Mass Loss in Binary Stars. IV. Low- and Intermediate-mass Helium Binary Stars

The unstable mass transfer situation in binary systems will asymptotically cause the adiabatic expansion of the donor star and finally lead to the common envelope phase. This process could happen in helium binary systems once the helium donor star fills its Roche-lobe. We have calculated the adiabatic mass-loss model of naked helium stars with a mass range of 0.35 M ⊙–10 M ⊙, and every mass sequence evolved from the helium-zero-age main sequence to the cooling track of white dwarf or carbon ignition. In consideration of the influence of stellar wind, massive helium stars are not considered in this paper. Comparing the stellar radius with the evolution of the Roche-lobe under the assumption of conservative mass transfer, we give the critical mass ratio q crit = M He/M accretor as the binary stability criteria of low- and intermediate-mass helium binary stars. On the helium main sequence, the result shows 1.0 < q crit < 2.6, which is more unstable than the classical result of polytropic model q crit = 3. After the early helium Hertzsprung Gap, the q crit quickly increases even larger than 10 (more stable compared with the widely used result of q crit = 4), which is dominated by the expansion of the radiative envelope. Our result could be useful for these quick mass transfer binary systems such as AM CVns, ultra-compact X-ray binaries, and helium novae, and it could guide the binary population synthesis for the formation of special objects such as type Ia supernova and gravitational wave sources.

Thermal Performance Improvement of Composite Phase-Change Storage Material of Octanoic Acid–Tetradecanol by Modified Expanded Graphite

Phase-change cold storage technology is recommended as a solution for energy conservation and carbon neutrality in air conditioning systems of buildings. This study focuses on the development of binary composite phase-change materials comprising octanoic acid–tetradecanol (OA-TD). To enhance its thermal conductivity, expanded graphite (EG) was employed as an additive carrier, and the surface modification of EG particles using hexadecyltrimethoxysilane (HDTMOS) was attempted to make up for the instability and further to improve the performance of OA-TD/EG CPCMs. The OA-TD/EG-HDTMOS CPCMs were synthesized by EG mixed with EG-HDTMOS at a 1:1 mass ratio. The thermal performance and stability of the OA-TD/EG-HDTMOS CPCMs were thoroughly evaluated by multi-cycle melting–solidification and thermal conductivity measurements. The results revealed that the OA-TD mixture, when at a mass ratio of 77:23, exhibited a phase-transition temperature of 11.4 °C and a latent heat ranging from 150 to 155 J/g. Then, the OA-TD/EG-HDTMOS composite material, at a 12:1 mass ratio of OA-TD to EG-HDTMOS, solidified and melted at temperatures of 9.2 °C and 11.2 °C, with a latent heat ranging from 138 to 143 J/g, and significantly improved the thermal conductivity to 0.7 W/(m·K), representing a remarkable 133% increase compared to that of OA-TD alone. Even after undergoing 100 melting–solidification cycles, the OA-TD/EG-HDTMOS maintained superior phase-change thermal performance and stability, making it suitable for cold storage and energy conservation in air conditioning.

From Halos to Galaxies. IX. Estimate of Halo Assembly History for SDSS Galaxy Groups

The properties of the galaxies are tightly connected to their host halo mass and halo assembly history. Accurate measurement of the halo assembly history in observation is challenging but crucial to the understanding of galaxy formation and evolution. The stellar-to-halo mass ratio (M */M h) for the centrals has often been used to indicate the halo assembly time t h,50 of the group, where t h,50 is the lookback time at which a halo has assembled half of its present-day virial mass. Using mock data from the semi-analytic models, we find that M */M h shows a significant scatter with t h,50, with a strong systematic difference between the group with a star-forming central (blue group) and passive central (red group). To improve the accuracy, we develop machine learning models to estimate t h,50 for galaxy groups using only observable quantities in the mocks. Since star formation quenching will decouple the co-growth of the dark matter and baryon, we train our models separately for blue and red groups. Our models have successfully recovered t h,50, within an accuracy of ∼1.09 Gyr. With careful calibrations of individual observable quantities in the mocks with Sloan Digital Sky Survey (SDSS) observations, we apply the trained models to the SDSS Yang et al. groups and derive the t h,50 for each group for the first time. The derived SDSS t h,50 distributions are in good agreement with that in the mocks, in particular for blue groups. The derived halo assembly history, together with the halo mass, make an important step forward in studying the halo–galaxy connections in observation.

Rheology and buildability of sustainable 3D printed magnesium potassium phosphate cement composites incorporating MgO-SiO2-K2HPO4

MKPCs with unique advantage of superior strength, excellent durability and high thixotropy provides alternative binder for 3D printing. The acid-base reaction between dead burnt MgO and K2HPO4 is intense and the retarding effect is limited in practical cases. This paper presents the investigation of MKPCs incorporating MgO-SiO2-K2HPO4 binders prepared with dead burnt MgO, soluble phosphate (K2HPO4•3 H2O) and silica fume (SF). The effects of magnesium-to-phosphate (M/P) mass ratio, SF and slag ratios on rheological properties and the printability were tailored and setting time reached to 50 min by increasing the alkaline environment of the solution. In addition, the pozzolanic activity of SF and slag were synergistically motivated and thus promoted the precipitation of K-struvite, MgSiO3 and C-(A)-S-H hydrates. Two-stage Athix values were calculated to describe the structuration rate. It is confirmed excellent thixotropy was dominated by early-age physical re-flocculation and later-age cement hydration. Although the structure deformation increased significantly as SF content increased, the beneficial effect of SF content on the increase of strength is significantly important than that of adverse effect on the buildability. Slag powder and fine aggregate were incorporated to make the binders more “printable”. A cylinder with 16 layers on optimum mixture was printed without deformation.

The Cytoprotective Effect of C60 Derivatives in the Self-Microemulsifying Drug Delivery System against Triptolide-Induced Cytotoxicity In Vitro

Objective: The aim of this study was to optimize the formulation of a C60-modified self-microemulsifying drug delivery system loaded with triptolide (C60-SMEDDS/TP) and evaluate the cytoprotective effect of the C60-SMEDDS/TP on normal human cells. Results: The C60-SMEDDS/TP exhibited rapid emulsification, an optimal particle size distribution of 50 ± 0.19 nm (PDI 0.211 ± 0.049), and a near-neutral zeta potential of −1.60 mV. The release kinetics of TP from the C60-SMEDDS/TP exhibited a sustained release profile and followed pseudo-first-order release kinetics. Cellular proliferation and apoptosis analysis indicated that the C60-SMEDDS/TP (with a mass ratio of TP: DSPE-PEG-C60 = 1:10) exhibited lower toxicity towards L02 and GES-1 cells. This was demonstrated by a higher IC50 (40.88 nM on L02 cells and 17.22 nM on GES-1 cells) compared to free TP (21.3 nM and 11.1 nM), and a lower apoptosis rate (20.8% on L02 cells and 26.3% on GES-1 cells, respectively) compared to free TP (50.5% and 47.0%) at a concentration of 50 nM. In comparison to the free TP group, L02 cells and GES-1 cells exposed to the C60-SMEDDS/TP exhibited a significant decrease in intracellular ROS and an increase in mitochondrial membrane potential (ΔψM). On the other hand, the C60-SMEDDS/TP demonstrated a similar inhibitory effect on BEL-7402 cells (IC50 = 28.9 nM) and HepG2 cells (IC50 = 107.6 nM), comparable to that of the free TP (27.2 nM and 90.4 nM). The C60-SMEDDS/TP group also exhibited a similar intracellular level of ROS and mitochondrial membrane potential compared to the SMEDDS/TP and free TP groups. Method: Fullerenol-Grafted Distearoyl Phosphatidylethanolamine-Polyethylene Glycol (DSPE-PEG-C60) was synthesized and applied in the self-microemulsifying drug delivery system. The C60-SMEDDS/TP was formulated using Cremophor EL, medium-chain triglycerides (MCT), PEG-400, and DSPE-PEG-C60, and loaded with triptolide (TP). The toxicity and bioactivity of the C60-SMEDDS/TP were assessed using normal human liver cell lines (L02 cells), normal human gastric mucosal epithelial cell lines (GES-1 cells), and liver cancer cell lines (BEL-7402 cells and HepG2 cells). The production of reactive oxygen species (ROS) after the C60-SMEDDS/TP treatment was assessed using 2′,7′-dichlorofluorescein diacetate (DCFDA) staining. The alterations in mitochondrial membrane potential (ΔψM) were assessed by measuring JC-1 fluorescence. Conclusions: The cytoprotection provided by the C60-SMEDDS/TP favored normal cells (L02 and GES-1) over tumor cells (BEL-7402 and HepG2 cells) in vitro. This suggests a promising approach for the safe and effective treatment of TP.

Retrofit of a Marine Engine to Dual-Fuel Methane–Diesel: Experimental Analysis of Performance and Exhaust Emission with Continuous and Phased Methane Injection Systems

Shipping is a highly energy-intensive sector, and fleet decarbonization initiatives can significantly reduce greenhouse gas emissions. In the short-to-medium term, internal combustion engines will continue to be used for propulsion or as electricity generators onboard ships. Natural gas is an effective solution which can be used to mitigate greenhouse gas emissions from the marine sector. Considered to be a transitional fuel, it can provide a potential reduction in CO2 emissions of around 20–30%, compared with conventional marine fuels. This work investigated the influence of diesel-injection strategies on the performance and emissions of a single-cylinder prototype compression-ignition engine for marine applications, retrofitted to run as a Low-Pressure Dual-Fuel Engine using natural gas. Two different injection systems were used: a mass flow controller enabling continuous-mode gas feeding, and a Solenoid-Operated Gas Admission Valve for marine applications, the latter allowing phased natural-gas injection. Experimental tests were focused on partial-load conditions, which are critical for dual-fuel engines, with a natural gas/diesel mass ratio of 4:1. Phased injection resulted in reductions in fuel consumption, compared to continuous mode, of up to 11%. Further experiments demonstrated reductions in fuel consumption of up to 20.7% (in equivalent diesel); on the other hand, the unburned hydrocarbon emissions which resulted were an order of magnitude larger than the reference values for full diesel, reducing the benefits in terms of greenhouse gas emissions, with a reduction in Global Warming Potential of only 3% compared to full diesel.