Stripping Rate Research Articles

Investigation of Improving Stability in Desulfurized-Rubber-Modified Asphalt Using Cerium-Stearate Incorporation

To enhance the compatibility of high-content desulfurized-rubber-modified asphalt (DRMA), the innovative selection of cerium hard acid is employed in this study to investigate its impact on the compatibility of DRMA. The results indicate that when the optimal content of cerium stearate is 1%, the compatibility of the modified asphalt is improved. On the microscopic level, it is observed that the total heat absorption of the modified asphalt decreases and thermal storage stability is enhanced as measured by differential scanning calorimetry. On the macroscopic level, it gives the smallest difference in softening point, optimal storage stability, and best compatibility of the modified asphalt. Additionally, dissolution tests and adhesion tests demonstrate that the inclusion of cerium stearate increases the solubility of desulfurized rubber in asphalt and reduces the stripping rate of desulfurized-rubber particles on the asphalt surface, thereby decreasing phase separation and promoting the compatibility of DRMA. Furthermore, rheological tests indicate that cerium stearate improves both high-temperature and low-temperature performance of the modified asphalt. The addition of cerium stearate increases the dynamic shear modulus of the modified asphalt, maintaining good stability and elasticity under shear loading, with minimal change in low-temperature rheological properties and lower temperature sensitivity, indicating the best compatibility at this point. Finally, molecular-dynamics simulation data indicate that the addition of cerium stearate decreases the parameter difference in the dissolution of modified asphalt and enhances the binding energy of the modified asphalt, demonstrating the feasibility of cerium stearate in promoting the compatibility of modified asphalt.

High‐frequency (470 kHz) ultrasonics‐assisted room temperature CO2 stripping and fate of Sono exposed solvent

AbstractBACKGROUNDThe conventional CO2 stripping process in solvent‐based postcombustion CO2 capture (PCCC) process uses heating to strip the CO2 (~120 °C). However, the challenges associated with this method are high energy consumption in degassing the CO2 from solvent, solvent loss and degradation resulting from the high –temperatures, resulting in high energy consumption typical of solvent‐based PCCC. The present study demonstrates the use of bath‐type sonication (470 kHz frequency) to remove CO2 from CO2 loaded 30 wt% Monoethanolamine under controlled temperature conditions. Solvent performance was evaluated following exposure to 2 h conventional heating and 75 h sonication.RESULTSIn a batch sono‐assisted process, CO2 stripping became possible at 17.5 °C compared to 102.2 °C using the conventional method. Increasing the sonication time led decreased carbon loading and increased stripping efficiency. The stripping rate was high at the initial stages of treatment. Evaluation of sono‐exposed solvents exhibited decreased pH during CO2 loading and decreased absorption capacity of the conventionally heated sample.CONCLUSIONThe sono‐assisted method consumes 3.57‐foldless energy than conventional heating. Its CO2 stripping rate was found to be higher within 5 min of sonication. Notably, the maximum temperature reached for the 1 h intervening mode of sonication at 470 kHz was 49.49 °C. The reduction in absorption capacity per hour of conventional heating was 24.5%, whereas for sonication it was <0.4% and solvent loss was 19.7% lower than conventional. There was no significant change in the color, pH and density of the sample. A 20.4% higher surface tension than that of the virgin sample was observed. © 2024 Society of Chemical Industry (SCI).

High extraction efficiency of N,N,N′,N′-tetracyclohexyldiglycolamide for Sr(II): An experimental and crystal structure study

To improve the ability of diglycolamide extractants for the extraction of Sr(II) from high-level waste liquid, N,N,N′,N′-tetracyclohexyl-diglycolamide (TCHDGA) was proposed and studied to extract Sr(II) from nitrate media. TCHDGA was prepared and characterized by 1H Nuclear Magnetic Resonance Spectroscopy (NMR), 13C NMR, and Fourier Transform Infrared Spectroscopy (FT-IR). Various factors affecting extraction were studied systematically. In just 20 s, the extraction rate can reach approximately 98.2 %. The extraction capacity of cyclohexyl-substituted extractant TCHDGA is tens of times higher than that with linear or branched chain alkyl. The chemical structure of the complex has been demonstrated to be [Sr 3TCHDGA]·(NO3)2, based on FT-IR, X-ray Photoelectron Spectroscopy (XPS), and crystal structure analysis. The crystal belongs to the monoclinic system, space group P21, and a strontium ion coordinates with nine oxygen atoms, all of which contribute from TCHDGA. The stripping rate can reach over 99 % when using distilled water or 0.50 mol·L−1 oxalic acid as stripping agents.

It’s a Breeze: The Circumgalactic Medium of a Dwarf Galaxy Is Easy to Strip

The circumgalactic medium (CGM) of star-forming dwarf galaxies plays a key role in regulating the galactic baryonic cycle. We investigate how susceptible the CGM of dwarf satellite galaxies is to ram pressure stripping in Milky Way–like environments. In a suite of hydrodynamical wind tunnel simulations, we model an intermediate-mass dwarf satellite galaxy (M * = 107.2 M ⊙) with a multiphase interstellar medium (ISM; M ISM = 107.9 M ⊙) and CGM (M CGM,vir = 108.5 M ⊙) along two first-infall orbits to more than 500 Myr past pericenter of a Milky Way–like host. The spatial resolution is ∼79 pc in the star-forming ISM and 316−632 pc in the CGM. Our simulations show that the dwarf satellite CGM removal is fast and effective: more than 95% of the CGM mass is ram pressure stripped within a few hundred megayears, even under a weak ram pressure orbit where the ISM stripping is negligible. The conditions for CGM survival are consistent with the analytical halo gas stripping predictions in McCarthy et al. We also find that including the satellite CGM does not effectively shield its galaxy, and therefore the ISM stripping rate is unaffected. Our results imply that a dwarf galaxy CGM is unlikely to be detected in satellite galaxies; and that the star formation of gaseous dwarf satellites is likely devoid of replenishment from a CGM.

An improvement for enrichment and purification of germanium using carbonyl acid extractants

Germanium is a strategic metal that is challenging to enrich and purify without any side effects, especially stability and selectivity. Here the role of carbonyl acid in selective separation of germanium from complex industrial liquids was highlighted. Integrating theoretical and experimental analyses, carbonyl acids exhibit strong binding ability and high selectivity to germanium was demonstrated. The first set of carbonyl acid extractant (CAE) for germanium extraction was successfully synthesized with a solubility of less than 50 mg/L at pH = 0. The process analysis exhibits the extraction rate of germanium in a single stage by CAEs exceeds 99.9 %, while the separation factor surpasses 103, far beyond 101 of hydroxamic acids. Furthermore, the stripping rate for germanium in a single stage exceeds 83.0 %, with germanium accounting for over 99.9 % of the total metal content in the stripping solution. The CAE extraction process is straightforward and characterized by high germanium separation efficiency. The development of CAE not only realises the stable, green, low-carbon, and high-efficiency purification of germanium, but also the universality and inspiration of CAE make it highly significant and valuable in both theoretical research and practical applications.

A multiscale model to understand the interface chemistry, contacts, and dynamics during lithium stripping

A reversible Li-metal electrode, paired with a solid electrolyte, is critical for attaining higher energy density and safer batteries beyond the current lithium-ion cells. A stable stripping process may be even harder to attain as the stripping process will remove Li-atoms from the surface, and naturally reduce surface contact area, if not self-corrected by other mechanisms, such as diffusion and plastic deformation under an applied external stack pressure. Here, we capture these mechanisms occurring at multiple length- and time- scales, i.e., interface interactions, vacancy hopping, and plastic deformation, by integrating density functional theory (DFT) simulations, kinetic Monte Carlo (KMC), and continuum finite element method (FEM). By assuming the self-affine nature of multiscale contacts, we predict the steady-state contact area as a function of stripping current density, interface wettability, and stack pressure. We further estimate the exponential increase of overpotential due to contact area loss to maintain the same stripping current density. We demonstrate that a lithiophilic interface requires less stack pressure to reach the same steady-state contact area fraction than a lithiophobic interface. A “tolerable steady-state” contact area loss for maintaining stable stripping is estimated at 20 %, corresponding to a 10 % increase in overpotential. To constrain contact loss within the tolerance, the required stack pressure is 0.1, 0.5, and 2 times the yield strength of lithium metal for three distinct interfaces, lithiophilic Li/lithium oxide(Li2O), Li/lithium lanthanum zirconium oxide(LLZO), and lithiophoblic Li/lithium fluoride(LiF), respectively. The modeling results agree with experiments on the impact of the stack pressure quantitatively, while the discrepancy in stripping rate sensitivity is attributed to the simplifying interface interaction in our simulations. Overall, this multiscale simulation framework demonstrates the importance of electrochemical-mechanical coupling in understanding the dynamics of the Li/SE interface during stripping.

Influences of Weizmannia coagulans PR06 Fermentation on Texture, Cooking Quality and Starch Digestibility of Oolong Tea-Fortified Rice Noodles.

Weizmannia coagulans is increasingly employed in food processing owing to its health benefits. Our previous research developed Oolong tea-fortified rice noodles with unique flavor and potent antioxidant activity; however, their texture still requires improvement. In this study, Oolong tea-fortified rice noodles were fermented using W. coagulans PR06 at inoculation amounts of 1%, 3%, and 5% (v/v), and assessed for cooking quality, texture, and starch digestibility. The results indicated that fermentation with 3% and 5% W. coagulans PR06 altered the amylopectin length distribution in the rice noodles and increased the degree of starch short-range order. Furthermore, the fermentation process increased the storage modulus (G') and loss modulus (G″) values, decreased the tan δ value, and strengthened the interactions among tea polyphenols, proteins, and starch in the rice flour gel. Consequently, this process increased the hardness and chewiness of the rice noodles, decreased their broken strip rate and cooking loss, and significantly reduced their in vitro starch digestibility. Overall, fermentation with W. coagulans PR06 markedly improved the texture and cooking quality of Oolong tea-fortified rice noodles while effectively delaying starch digestion. This study highlights the potential application of W. coagulans PR06 in developing diverse and functional rice noodle products.

Corrosion evolution and quantitative corrosion monitoring of Q355 steel for offshore wind turbines in multiple marine corrosion zones

Offshore wind turbines operating in harsh marine environments are at risk of corrosion. Thickness loss and perforation caused by corrosion can lead to component failure or structure collapse. An environmental test setup was constructed to simulate various marine corrosion zones. Several experimental studies were conducted on Q355 steel, commonly used in offshore wind turbines. The mass loss and electrochemical properties of the steel specimens were analyzed, including electrochemical impedance spectra and polarization curves. The results indicate that corrosion remains stable in the immersion and tidal zones, whereas corrosion in the splash zone is the most severe, with a corrosion rate as high as 0.70 mm/a. A significant macroscopic corrosion cell effect was observed on the vertical steel strip, accelerating corrosion in the splash zone and at the low tide line. The corrosion product compositions and corrosion morphology of each corrosion zone were characterized and analyzed. Furthermore, a corrosion monitoring sensor based on electromechanical impedance was proposed. A prediction model for the mass loss rate of vertical steel strips was developed based on the conductance peak frequency. This study elucidates the corrosion evolution of wind turbine structural steel and proposes a comprehensive steel corrosion monitoring solution.

Synthesizing LiFePO4 by phosphate & iron recovered from sludge-incinerated ash and Li extracted from concentrated brines

Phosphorus (P) recovered from sludge-incinerated ash (SIA) could be applied to synthesize highly added-value products (FePO4 and LiFePO4) with in situ Fe in SIA. Indeed, LiFePO4 is a future of rechargeable batteries, which makes lithium (Li) highly needed. Alternatively, Li could also be extracted from concentrated brines to face a potential crisis of Li depletion on lands. Based on H3PO4 and Fe3+ co-extracted from the acidic leachate of SIA by tributyl phosphate (TBP), FePO4 (31.2 wt% Fe, 17.6 wt% P and the molar ratio of Fe/P = 0.98) was easily formed only adjusting pH of the stripping solution to 1.6. Interestingly, the organic phase from the first-stage co-extraction process of Fe3+ and H3PO4 could be utilized for Li-extraction from salt-lake brine, based on the TBP-FeCl3-kerosene system, and a good performance (78.7%) of Li-extraction and separation factors (β) (186.0–217.4) were obtained. Furthermore, the compounds with Li-extraction are complex, possibly LiFeCl4∙2TBP, in which Li+ could be stripped to form Li2CO3 by 4.0 M HCl (with a stripping rate up to 83%). Besides, Li2CO3 could also be obtained from desalinated brine by adsorption with manganese oxide ion sieve (HMO) and desorption with HCl. In the two cases, almost pure Li2CO3 products were obtained, up to 99.7 and 99.5 wt% Li2CO3 respectively, after further purification and concentration. Finally, recovered FePO4 and extracted Li2CO3 were synthesized for producing LiFePO4 that had a similar electrochemical property (69.5 and 77.8 mAh/g of the initial discharge capacity) to those synthesized from commercial raw materials.

Numerical Modeling of a Low-Cobalt All-Solid-State Cell with Ceramic Electrolyte Using a Deformable Geometry

All-solid-state batteries with a lithium negative electrode and a ceramic electrolyte are key toward high energy density. To ensure a safe, fast, accurate, and cost-effective development of this technology, the experimental methodology must be supported by the numerical modeling approach. This work proposes and describes an electrochemical model of a Li7La3Zr2O12 (LLZO) and Ni-rich NMC-based lithium cell with a deformable lithium negative electrode. Simulations were computed using the finite element method at different operating conditions to demonstrate the scope of the modeling work. Discharge rate tests, deformation tracking, geometric defect investigation, and polarization decomposition are described. Theoretical validation of the mass balance, the stripping rate, the ohmic polarization, and the mesh deformation demonstrated the consistency of the volumetric deformation strategy. We demonstrated in this study a deformable modeling strategy, which was found to be useful for the electrostripping analysis of anodic geometry defects during discharge. Non-uniformity in the lithium stripping rate was found along the anodic interface with defects, and this non-uniformity was accentuated with a higher discharge rate. The cell’s discharge potential was decomposed by considering the equilibrium potential and the polarizations of the main components of the cell. This post-processing was found to be useful for the understanding of the cell’s behavior.

Solid-state fermentation of Limosilactobacillus fermentum and lysine addition to improve the cooking and eating quality of high-fiber rice noodles

The incorporation of polysaccharides can effectively lower the glycemic index (GI) of rice noodles but may also negatively impact their cooking and eating quality. This study explores the use of solid-state fermentation with Limosilactobacillus fermentum and the addition of lysine to enhance the cooking and eating quality of high-fiber rice noodles (HFRN). Optimal fermentation conditions—10% Limosilactobacillus fermentum inoculum, 30 °C fermentation temperature, and 72-h fermentation time—along with a 3% lysine addition, were identified. The results revealed a significant increase in cooking quality and sensory characteristics of the rice noodles under these conditions. Compared to the control, the treated rice noodles exhibited higher sensory scores (increased by 17%), lower broken strip rates (reduced by 77.99%), and superior textural properties. Further analysis using Fourier Transform Infrared Spectroscopy (FTIR), rapid viscometer analyzer (RVA), and differential scanning calorimetry (DSC) demonstrated that fermentation and lysine addition inhibited starch granule swelling, leading to decreased pasting properties (viscosity drop of 22.77–29.94% in all stages). Additionally, the retrogradation rates were reduced, and thermal stability was markedly increased (ΔH increased by 190.90%). These findings suggest that solid-state fermentation combined with lysine supplementation offers a promising strategy for enhancing the cooking and eating quality of HFRN.

Investigating the mechanism of Au(III) transport using a polymer inclusion membrane with dibutyl carbitol as a carrier

In this article, firstly, the separation and transfer of Au(III) from gold chloride solution was investigated using a polymer inclusion membrane (PIM) system containing dibutyl carbitol (DBC) as carrier molecules, dioctyl phthalate (DOP), bis(2-ethyl hexyl) adipate (dioctyl adipate) (DOA) and tris (2-ethyl hexyl) phosphate (T2EHP) as plasticizers and high molecular weight polyvinyl chloride (PVC) as the base polymer. Fourier transform infrared spectroscopy (FT-IR), and scanning electron microscope (SEM) were used to identify PIMs. Kinetic studies featuring a two-step reaction, with the first step being reversible, were conducted across various sections to investigate the processes of extraction, stripping, and transport. The effects of different stripping agents such as water, HCl, thiourea, sodium thiosulfate, and oxalic acid was investigated, and the best results were obtained with thiourea. Also, the mechanisms of Au(III) extraction and transport were studied. Under the conditions of source solution, tetrachloroaurate anionic complex AuCl4− with protonated DBC (ROR2OHM+) was extracted by ion solvation mechanism. The validity of the proposed extraction mechanism was confirmed through the use of nuclear magnetic resonance (1H NMR) spectroscopy. In order to make the membrane with the best composition and the highest efficiency, the effect of weight percentage of the carrier and plasticizer was investigated. There was an optimal value for the weight percentage of plasticizer (10–20% by weight) and carrier (40%), in which the highest flux and permeability in the membrane occurred. The effect of the viscosity of different plasticizers (DOP, DOA, and T2EHP) on the Au(III) flux was also investigated. It was found that the flux increases linearly with the reduction of plasticizer viscosity. Effect of membrane thickness on the permeability, initial flux, and efficiency of Au(III) transfer, were conducted with thickness of 120, 80, 45, and 30 μm. By reducing the thickness of the membrane, the transfer flux, permeability and percent of Au(III) transport, were improved from 12.9 × 10−3mh−1, 45.3 × 10−7molm−2s−1 and 18.2% to 26.4 × 10−3mh−1, 83.5 × 10−7molm−2s−1 and 37.3%, respectively. According to the results, a membrane with a combination of PVC:DBC:D2EHP with a weight percentage ratio of 50:40:10 with a thickness of 30 μm was suggested. Optimized results with the proposed membrane were obtained to be: extraction rate constant of 1.43 h−1, extraction percent of 99.1%, stripping rate constant of 37.5 × 10−4h−1, stripping percent of 40.9%, and permeability of 27.0 × 10−3mh−1, initial flux of 82.1 × 10−7molm−2s−1.

Mathematical Modelling and Optimisation in Multibeam Bathymetry: A Study of Coverage Width, Overlap Rate and Course Optimisation

This paper focuses on the field of multibeam bathymetry, firstly, a two-dimensional mathematical model with coverage width, overlap rate, and seawater depth as the objectives is established by using the trigonometric properties, the terrain slope factor and the effect of different survey line distances from the centre on multibeam bathymetry. Matlab software was used to solve the model, and the expressions for the coverage width and the overlap rate of adjacent strips were obtained. Secondly, for the multibeam bathymetry along a certain direction, based on the three-dimensional geometric seawater depth model, the coverage width model corresponding to different survey line directions was obtained by using the classification discussion method. Finally, through the optimisation model and traversal algorithm, the optimisation model that meets the requirement of the overlap rate of adjacent strips is established with the objective of minimising the total routes, and solved by the cyclic traversal idea. This study provides a comprehensive mathematical model and optimisation method for multibeam bathymetry, and lays a theoretical foundation for practical applications in related fields.

Quantitative characterization and fracture morphology in reservoirs with various lithologies: An experimental investigation

Accurately quantifying the development of hydraulic fractures is pivotal for further elucidating the relationship between reservoir physical properties and hydraulic fracture propagation. In this research, we centered on reservoirs featuring diverse lithologies, procured downhole full-diameter cores, conducted triaxial hydraulic fracturing experiments, and employed CT scanning and electron microscopy to characterize fracture morphology. The primary findings are summarized as follows: sandstones specimens typically exhibit bi-wing fractures inclined at a certain angle to σH, with internal microfractures predominantly comprised of corrugated shear fractures traversing mineral grains. Conversely, conglomerate specimens display a higher prevalence of branching fractures, with fracture zones forming in areas of gravel densities and weak heterogeneous matrices, along with the development of multiple microfractures. Volcanic rock specimens fractures primarily propagate via deflection following NF activation, showcasing two modes of microfracture propagation: through and alongside the NF. Quantitative parameters of fracture morphology indicate that the fractal dimension ranges from 2.02 to 2.08 for sandstone fractures, 2.19 to 2.22 for conglomerate fractures, and 2.11 to 2.13 for volcanic rock fractures. Notably, the NF filler in volcanic rock undergoes erosion by fracturing fluid, accumulating non-uniformly on the surface of rock crystals, thereby augmenting fracture tortuosity. Additionally, the fracture surface area of conglomerates surpasses that of sandstones and volcanic rocks by 1.3 times, with the stripping rate of conglomerate fracture surfaces exceeding 10%. Furthermore, the average normal width of conglomerate fractures surpasses 2 mm, whereas volcanic rock and sandstone measure 1.6 mm and 1.1 mm, respectively. Notably, sandstone fractures exhibit uniform normal width distribution, while conglomerate fractures, especially those around gravels and eroded by fracturing fluid, manifest larger widths. Moreover, NF influenced volcanic rock fractures also exhibit wider widths. Elucidating the quantitative attributes of fracture morphology in lithologically diverse reservoirs holds significant implications for formulating hydraulic fracturing and targeted optimization strategies aimed at enhancing fracturing efficacy.

Ammonia stripping by in situ biogas self-circulation to upgrade continuous thermophilic and mesophilic digestion of hydrothermal high-solid sludge

High-solid anaerobic digestion of hydrothermal sewage sludge has been developed. In order to upgrade the process by focusing on ammonia inhibition, a simply-equipped stripping system without additional alkali or heat supply was introduced by in situ biogas self-circulation. As the determined limit of total ammonia nitrogen at 1500 mg/L and 1000 mg/L for the mesophilic (MAD) and thermophilic anaerobic digestion (TAD) respectively and stripping rate at 5 L/min, continuous MAD and TAD was conducted in parallel. The stripping system successfully polished up the ammonia inhibition, and methanogenic capability of the TAD was promoted to approximately 90.0 % of the potential. Intermittent stripping mode proved usable. More frequent stripping was inevitable for the TAD as compared to the MAD. Hydraulic retention time below 20 d resulted in failure of the stripping mode due to rapid ammonia generation. Overall, this technology was practical in upgrading high-solid sludge digestion by effective ammonia control.

Research on Multibeam Bathymetric System Based on Greedy Algorithm and Variable Step Size Traversal Algorithm

Multi-beam bathymetry system is an advanced technology to measure the seabed based on single-beam bathymetry. In this paper, the greedy algorithm and variable step traversal method will be used to establish the mathematical models of coverage width and overlapping rate of adjacent strips of multi-beam sounding, and the best scheme of survey line layout will be designed by establishing the optimization model. According to the established mathematical model of overlap rate, the mathematical model of coverage width of multi-beam sounding in three-dimensional rectangular waters is optimized. Finally, according to the real life, with the overlapping rate of adjacent strips within 10% to 20% as the limiting condition and the minimum total length of survey lines as the objective function, a single-objective optimization model is established. Then, Python is used to solve the problem through greedy algorithm and variable step-size traversal algorithm, and it is found that the included angle of survey line direction in the optimal scheme is 90, and the minimum total length of survey line is 68 nautical miles. Stability analysis is carried out by changing the constraint range of overlap rate.

Development of a colloidal gold immunochromatographic strip for rapid detection of ribavirin in pig urine

ABSTRACT A specific and sensitive monoclonal antibody (mAb) for ribavirin (RBV) was generated by immunizing BALB/c mice with RBV – bovine serum albumin. Using the mAb, a highly sensitive indirect competitive enzyme-linked immunosorbent assay (ic-ELISA) and a colloidal gold immunochromatographic (CGI) test strip were developed for detecting RBV in pig urine. Under optimum assay conditions, IC50 was 0.08 ng/mL in 0.05 M phosphate-buffered saline and the recovery rate in real-world samples ranged between 77.3% and 99%. The cut-off limit of the CGI test strip for RBV was 5 ng/mL in pig urine. The cross-reactivity rate of the test strip to the tested antiviral drugs including acyclovir and moroxydine hydrochloride and the metabolites 1,2,4-triazole-3-carboxamide and 1-β-D-ribofuranosyl-1,2,4-triazole-3-carboxylic acid was below 0.1%. The results indicate that ic-ELISA and the CGI test strip have high sensitivity and specificity and that these methods are suitable for the rapid detection of RBV in pig urine.

Potential–Dependent BDAC Adsorption on Zinc Enabling Selective Suppression of Zinc Corrosion for Energy Storage Applications

Utility-scale zinc (Zn) batteries are a promising solution to address the problem of intermittency of renewable energy sources; however, Zn-metal anodes in these batteries suffer from capacity loss due to spontaneous corrosion of the Zn especially when high-surface area anode configurations are employed. Additionally, Zn dendrites are known to form during battery charging limiting the cycle-life of these batteries. Electrolyte additives have been explored that prevent aforementioned issues, but these too come at a cost, i.e., surface-blocking additives polarize the electrode surface leading to loss in the voltaic and energy efficiencies of the battery. In this contribution, a novel electrolyte additive, benzyldimethylhexadecylammonium chloride (BDAC), is investigated for its ability to suppresses corrosion of Zn in an acidic (pH = 3) electrolyte. An attribute of BDAC distinct from previously studied additives is that it selectively suppresses electrochemical activity when the Zn electrode is at its corrosion potential; however, during high-rate Zn deposition (charging) or stripping (discharging), BDAC is essentially deactivated and thus it does not appreciably polarize the electrode surface, thus minimizing voltaic efficiency losses. This selective corrosion suppression behavior is explored using slow-scan voltammetry, which reveals hysteresis implying a potential- or current-dependent BDAC adsorption mechanism in which BDAC reaches higher surface coverages when the partial currents at the Zn surface are low (e.g., at or near the corrosion potential), but BDAC coverage is reduced considerably when the Zn deposition or stripping rates are increased. Numerical simulations of the BDAC diffusion-adsorption process corroborate this mechanism. Ramifications of our approach to the selective suppression of Zn dendrites are discussed.

Fine sediment and the insecticide chlorantraniliprole inhibit organic‐matter decomposition in streams through different pathways

Abstract Intensive agriculture drives an ongoing deterioration of stream biodiversity and ecosystem functioning across the planet. Key agricultural stressors include increased deposited fine sediment and insecticides flushed from adjacent land into streams. The individual and combined effects on aquatic biota are increasingly studied, but the functional consequences of biodiversity loss associated with agricultural stressors remain poorly understood. We addressed this knowledge gap by examining the effects of fine sediment and different concentrations of the insecticide chlorantraniliprole on organic‐matter decomposition. We conducted an outdoor stream mesocosm experiment. Mesocosms contained a standardised organic‐matter assay (the cotton‐strip assay), which was used to assess organic‐matter decomposition rates (as tensile‐strength loss of the fabric) and microbial respiration of the cotton strips. The decomposition rate of strips buried under fine sediment was inhibited, a result we attribute to the limited accessibility for invertebrate feeding and microbial activities, as well as the limited nutrient and dissolved oxygen exchange. The insecticide also inhibited decay rates, a finding we relate to reduced invertebrate grazing and associated excessive algal growth. In contrast to decomposition rates, we did not observe stressor effects on microbial respiration. An interaction between fine sediment and chlorantraniliprole was not identified. Our results suggest that stressors induced by agriculture affect functions of stream ecosystems through a variety of pathways and operate by modifying habitats and biotic interactions. By examining a combination of stressors and responses that have not been addressed before, this study gives important insights into the effects of agricultural practices on streams. Understanding the effects of chlorantraniliprole is especially important since it is likely to become more widely used in future agricultural practice due to the increasing ban on neonicotinoid insecticides. Furthermore, most experimental studies address multiple stressor effects on biota. For a comprehensive understanding of complex stressor effects on ecosystems, ecosystem functions also need to be studied, such as the organic‐matter decomposition within streams.

Improving the Quality of Ceramic Products by Removing the Defective Surface Layer

The surface of ceramic products manufactured using diamond grinding is replete with shallow scratches, deep grooves and other defects. The thickness of the defective layer amounts to 3–4 µm and it must be removed to increase wear resistance of the products when exposed to intense thermomechanical loads. In this study, removal of the defective layers from samples made of ZrO2, Al2O3 and Si3N4 with a beam of fast argon atoms was carried out with a stripping rate of up to 5 µm/h. To prevent contamination of the source of fast argon atoms by the sputtered dielectric material, the beam was compressed and passed to the sample through a small hole in a wide screen. Due to the removal of the defective layer, abrasive wear decreased by an order of magnitude and the adhesion of coatings deposited on the cleaned ceramic surfaces improved significantly.