Humidity Range Research Articles

Enhancing the energy efficiency of land vehicles air conditioning units through a new evaporative membrane cooler

Led by the growing need for energy efficiency in the air conditioning systems on land vehicles, this paper proposes an original approach that integrates evaporative cooling technologies into the existing systems. In detail, the new evaporative membrane system adds to the traditional one an auxiliary kit composed of a water reserve, a circulation pump, a heat exchanger, and an innovative capillary crossflow membrane cooler. The evaporation process is used to both pre-cool the air flow to the condenser, thus lowering the refrigerant condensation temperature, and also to supply refreshed water for pre-chilling the renewal air. The proposed architecture is particularly feasible for vehicular applications where a water reservoir already exists or where it is possible to install and maintain one. The designed membrane cooler grants high mass transfer efficiency, compactness (membrane surface-to-volume ratio around 1000 m2/m3) and manages high air flow rates while minimizing pressure loss. It is composed by organized layers of polypropylene capillaries where water flows, and plastic spacers for the airflow.First, the vapor and heat transfer mechanisms involved are investigated and the cooler’s mathematical model is described. Numerical results show that a wet-bulb effectiveness exceeding 0.85 can be reached.Subsequently, an assessment of energy performance indicators for a motorhome application is conducted within the MATLAB© Simulink environment. This involves a comparative analysis between the proposed system and the conventional standalone one. The considered contactor has a total membrane area of 8.32 m2 and handles 1200 m3/h of air and 150 kg/h of water. Results indicate that the efficiency ratio and the energy savings of the two systems decrease as the external air humidity increases even though the average energy efficiency ratio of the new system remains significantly higher. Mechanical energy savings are very interesting and decrease as the external air humidity increases: they are about 36–38 % within the humidity range [40–50 %], 26–30 % within the range [50–60 %], and 17–21 % within the range [60–70 %]. The corresponding water consumptions are between 2 kg/h and 6.5 kg/h, and they increase as air humidity decreases.Due to its simple architecture and high performance, this system is very promising in applications for motorhome, city buses, trains, and trucks.

Ultra Responsive NO2 silicon nanowires gas sensor

Nitrogen dioxide (NO2) is a hazardous gas emitted primarily from burning fossil fuels. When inhaled, it can have severe health implications, particularly for individuals with respiratory conditions such as asthma. It contributes to ground-level ozone formation, which can cause reduced lung function and increased susceptibility to respiratory infections. When in contact with water moisture in the air, NO2 is easily oxidized into nitric acid (HNO3), causing acid rain. Detection of NO2 levels is therefore important for monitoring air quality and protecting public health. Among the possible technical solutions for gas sensing, silicon nanowires (SiNWs) have proven to be a promising candidate, partly due to their high sensitivity, low manufacturing cost, and ability to perform in various air qualities. This paper presents using SiNWs, fabricated by metal-assisted chemical etching, as a fast, accurate, sensitive, robust, and cost-effective NO2 gas sensor. Our SiNWs gas sensor can experimentally detect 20 parts per billion (ppb) of NO2 under a wide range of relative humidity. Our sensor shows ultra-high sensitivity with fast response and recovery time.

High-sensitivity, fast-response quartz crystal microbalance humidity sensors coated with nanodiamond/halloysite nanotube composites

This paper develops a composite mixture of halloysite nanotubes (HNTs) and nanodiamond (ND) as a humidity-sensitive material for a quartz crystal microbalance (QCM) to achieve a balance between rapid response/recovery times and high sensitivity. The ND-HNTs composite-integrated QCM sensor exhibited rapid response/recovery times of 2/1 and 4/2 s when transitioning from an environmental humidity of 55 % RH to both low (11.3 % RH) and high (97.3 % RH) humidity levels. Throughout the humidity range of 11.3 %∼97.3 % RH, the sensor demonstrated a sensitivity of up to 98.14 Hz/%RH and low humidity hysteresis of around 1.95 % RH, good repeatability and stability. Furthermore, a detailed analysis of the response mechanism for the ND-HNTs composite-integrated QCM humidity sensor was conducted by integrating a bimodal exponential kinetic adsorption model. This paper introduces a new approach for fabricating QCM humidity sensors that possess both heightened sensitivity and rapid response/recovery times.

Assessment of Climate Factors on Benthic Fauna in Jabi Lake Federal Capital Territory Abuja

Studies of climate factors on benthic fauna in Jabi Lake was conducted from November, 2016 to June, 2017 using combination of insitu and laboratory equipment. Three stations were selected to determine the climate characteristics based on activities in the various stations and proximity to terrestrial influence. The results of the climatic parameters showed that atmospheric temperature range 18.40 to 32.100C, rainfall from 1997-2016 range from 0.00 to 513.8mm, relative humidity range from 22.00 to 72.20%, wind speed range from 0.40 to 3.40m/s, variation with time in all the stations. There were significant differences (P<0.05) between these parameters, within the months, stations and seasons. A total of 1, 867 benthic fauna were collected and identified into 6 phyla, 27 families and 60 species. All the species identify were represented in all the stations. Faunistic composition and abundance of benthic fauna showed that Family Bithyniidae has the highest percentage composition 60% (1120) followed by Lymnaelidae and Nuculoidae with 4% each. Chironmidae has 3% while others has 2 to 1%. Similarity ratio computed by Jaccard’s similarities index (0.63) shows that the three stations has about 63% species similarities between them. The relationship between climatic variable and fauna in the CCA diagram shows only torant organisms on positive axis i.e. representative of Nematoda, Mollusca, Polifera and Annelida has affinity to variables while Crustacean and Arthropoda were senstive to environmental condition. The Shannon Weiner species diversity index is 0.96 which is quite high.

Bioinspired 1T-MoS2-based aerogel beads for efficient freshwater harvesting in harsh environments

Freshwater scarcity is one of the most critical issues worldwide, particularly in arid regions, stemming from population growth and climate change. Inspired by the hydrophilic bump structures of desert beetles, 1T-MoS2-based aerogel beads with porous structures and CaCl2-crystal loading (termed as MoAB-m@CaCl2-n) were prepared for freshwater harvesting. Metallic-phase MoS2 nanospheres exhibit excellent photothermal conversion abilities, facilitating solar-driven water desorption and evaporation. Owing to the synergistic effect of its localized surface features, hydrophilic groups, and dispersive CaCl2 particles, MoAB-2@CaCl2-2 efficiently harvests water from atmosphere with a superior moisture adsorption capacity (0.18–0.82 g g−1) at a wide range of relative humidity (10 %-70 %). Under one-sun illumination, MoAB-2@CaCl2-2 demonstrates an outstanding solar-driven water evaporation rate of 2.25 kg m-2h−1. The water evaporation rate from soil (water content = 20 %) is 1.19 kg m-2h−1, which is sufficient for sustainable freshwater generation from the soil in arid regions. More importantly, the multifunctional MoAB-2@CaCl2-2-based homemade freshwater generation prototype delivers a certain amount of water harvesting (0.99 g g−1 day−1) on a rainy day and provides an impressive daily freshwater yield (53.7 kg m−2) under natural sunlight. The integrated device exhibits excellent efficiency and practicality and offers a feasible method for freshwater harvesting in harsh environments.

Switchable Slippery Surfaces Controlled by a Humidity‐Induced Glass Transition of Polyelectrolyte‐Grafted Brushes

AbstractPolymer brushes have found extensive applications as nano‐scale surface coatings with responsive properties, particularly in achieving tunable friction in solvent environments. Here, a special property of hygroscopic polyelectrolyte‐grafted brushes, where the friction forces change by over two orders of magnitude within a narrow range in humidity is reported. Using mechanical measurements of nano‐scale modulus and water absorption coupled with friction and surface‐sensitive spectroscopy, this sharp change in friction is controlled by a humidity‐induced glass transition that abruptly shifts the mode of sliding is demonstrated. Contrary to expectations based on conventional thinking regarding brush lubrication, friction remains large and humidity‐independent below the glass transition even for systems that absorb as much as 30–40% water by volume. This results in an abrupt change in friction past the glass transition humidity. Tuning the chemistry of brushes and their humidity‐induced glass transition offers the tunability to control the on/off friction (or slipperiness) for nanoactuators, ratchets, and catheters, without the need for externally applied lubricating liquids.

Polydopamine-modified MXene/cellulose nanofibers composite film for self-powered humidity sensing and humidity actuating

Humidity sensors are of great significance in the domains of wearable electronic products, environmental and food quality monitoring, and human healthcare. In general, they necessitate an external power source in the form of a battery. Despite considerable efforts, developing self-powered sensing systems without reliance on an external power supply remains a major challenge. Herein, an electrochemical humidity sensor with primary battery structure based on redox reaction was designed, in which polydopamine (PDA)-modified MXene/TEMPO-oxidized cellulose nanofibers/LiCl (PDMM/TOCNFs/LiCl) composite film serves as electrolyte layer. The introduction of TOCNFs confers outstanding structural stability and superior tensile strength upon the composite film. Importantly, the hygroscopic and ionic conductivity properties of the PDMM/TOCNFs/LiCl electrolyte allow the sensor to generate spontaneous voltage over a wide relative humidity (RH) range of 11 – 91%. In addition, the developed sensor exhibits excellent humidity-sensing performances, including high voltage response, fast response/recovery time, and superior humidity-sensing stability. Moreover, mussel-inspired PDA improves the ambient stability of MXene by engineering interfacial interactions, which imparts the hygroscopic PDMM/TOCNFs/LiCl composite film with desirable stability for practical applications. Finally, the potential applications of the sensor and the composite film in human respiration, non-contact sensing, and humidity actuating are demonstrated. This work paves the way for the development of an innovative self-powered humidity sensing system.

Adsorption of DMMP and water vapor on granular activated carbon: An experimental and molecular simulation study

The adsorption behavior of Dimethyl methylphosphonate (DMMP), as a simulant of sarin nerve agent, especially in the presence of water vapor, is crucial for the design of efficient chemical protection equipment. Experimental results reveal DMMP's adsorption isotherm on granular activated carbon (GAC) as a typical type I. The adsorption process was a spontaneous and exothermic physical adsorption process, and the adsorption mechanism was in accordance with Dubinin's micropore filling theory. In the relative humidity range of 10 % ∼ 90 %, the isotherm remained I-type, and the effect of water vapor on the equilibrium adsorption capacity and apparent adsorption rate was weak. Molecular simulations also show that DMMP adsorption on GAC follows a type I isotherm, primarily driven by van der Waals forces of physical adsorption. The adsorption potential energy between DMMP and GAC surpasses that of water molecules, resulting in negligible effects from water vapor on DMMP adsorption equilibrium. Meanwhile, water molecules had minimal effect on the diffusion of DMMP molecules in the GAC pores, and the positional distribution of DMMP multilayer adsorption was consistent under different relative humidity conditions. Furthermore, the presence of polar functional groups such as hydroxyl groups significantly affects the adsorption equilibrium of DMMP.

Data Driven Type-2 Fuzzy Modeling and Control of Personalized Thermal Comfort

Since the room thermal comfort has high uncertainties, it is difficult but necessary to study the modeling and control of thermal comfort. This paper tries to solve the modeling and control problem for the room thermal comfort by utilizing the temperature and humidity data collected from the working or living room. Firstly, in order to discard the noisy data and to obtain the reasonable intervals for modeling the temperature and humidity, a statistic method based preprocessing strategy is presented. Secondly, the Gaussian interval type-2 fuzzy set models are constructed to depict the personalized temperature and humidity comfort by measuring the uncertainty degrees of the obtained intervals. Thirdly, a interval type-2 fuzzy method based control scheme is proposed to realize the personalized thermal comfort regulation. Finally, some experimental results are given. And, the results show that the proposed thermal comfort models and control scheme can not only recommend a reasonable temperature and humidity range, but also can realize the optimal thermal comfort control.

Hibernating female big brown bats (Eptesicus fuscus) adjust huddling and drinking behaviour, but not arousal frequency, in response to low humidity.

Many mammals hibernate during winter, reducing energy expenditure via bouts of torpor. The majority of a hibernator's energy reserves are used to fuel brief, but costly, arousals from torpor. Although arousals likely serve multiple functions, an important one is to restore water stores depleted during torpor. Many hibernating bat species require high humidity, presumably to reduce torpid water loss, but big brown bats (Eptesicus fuscus) appear tolerant of a wide humidity range. We tested the hypothesis that hibernating female E. fuscus use behavioural flexibility during torpor and arousals to maintain water balance and reduce energy expenditure. We predicted: (1) E. fuscus hibernating in dry conditions would exhibit more compact huddles during torpor and drink more frequently than bats in high humidity conditions; and (2) the frequency and duration of torpor bouts and arousals, and thus total loss of body mass would not differ between bats in the two environments. We housed hibernating E. fuscus in temperature- and humidity-controlled incubators at 50% or 98% relative humidity (8°C, 110 days). Bats in the dry environment maintained a more compact huddle during torpor and drank more frequently during arousals. Bats in the two environments had a similar number of arousals, but arousal duration was shorter in the dry environment. However, total loss of body mass over hibernation did not differ between treatments, indicating that the two groups used similar amounts of energy. Our results suggest that behavioural flexibility allows hibernating E. fuscus to maintain water balance and reduce energy costs across a wide range of hibernation humidities.

Mesoporous CoxWO4-sensing platform toward ethanol detection

We report for the first time using pure cobaltous tungstate (CoWO4) as an efficient ethanol sensor by controlling the Co3+-Co2+ redox couple in CoWO4. The prepared CoxWO4 has a flower-like structure self-assembled by a mesoporous microbelt. Moreover, the CoxWO4 sensor with a Co3+/Co2+ ratio of 38.9% exhibits a high response (42.9–100 ppm ethanol), fast response/recovery time (11/13 s), low detection limit (0.42 ppm), as well as remarkable short-term and long-term repeatability. Notably, the CoxWO4 sample maintains a constant response value over a wide range of humidity (30–90 RH%), manifesting its good anti-humidity properties. The outstanding sensing performance is owing to the Co3+-Co2+ redox couple, high surface area and moderate porosity of the obtained samples. The self-transforming of the Co3+-Co2+ redox couple contributes to the formation of absorbed oxygen (O2-), oxygen vacancies and the reduction of the band gap, which is a crucial factor in improving the sensing properties of CoxWO4.

The Effects of Ambient Temperature and Atmospheric Humidity on the Diffusion Dynamics of Hydrogen Fluoride Gas Leakage Based on the Computational Fluid Dynamics Method.

In order to investigate the impact of environmental temperature and atmospheric humidity on the leakage and diffusion of hydrogen fluoride (HF) gas, this study focused on the real scenario of an HF chemical industrial park. Based on the actual dispersion scenario of HF gas, a proportionally scaled-down experimental platform for HF gas leakage was established to validate the accuracy and feasibility of numerical simulations under complex conditions. Using the validated model, the study calculated the complex scenarios of HF leakage and diffusion within the temperature range of 293 K to 313 K and the humidity range of 0% to 100%. The simulation results indicated that different environmental temperatures had a relatively small impact on the hazardous areas (the lethal area, severe injury area, light injury area, and maximum allowable concentration (MAC) area) formed by HF gas leakage. At 600 s of dispersion, the fluctuation range of hazardous area sizes under different temperature conditions was between 3.11% and 13.07%. In contrast to environmental temperature, atmospheric relative humidity had a more significant impact on the dispersion trend of HF leakage. Different relative humidity levels mainly affected the areas of the lethal zone, light injury zone, and MAC zone. When HF continued to leak and disperse for 600 s, compared to 0% relative humidity, 100% relative humidity reduced the lethal area by 35.7%, while increasing the light injury area and MAC area by 27.26% and 111.6%, respectively. The impact on the severe injury area was relatively small, decreasing by 1.68%. The results of this study are crucial for understanding the dispersion patterns of HF gas under different temperature and humidity conditions.

The X-ray peak profiling, optical and dielectric properties of Ag@ZnFe2O4/rGO ternary nanocomposites: LED assisted photocatalysis and humidity sensing

Ag@ZnFe2O4/reduced graphene oxide (Ag@ZnFe2O4/rGO) ternary nanocomposites were successfully synthesized (NCs) via hydrothermal method and explored the LED assisted photocatalytic performance for the degradation of organic dyes as well as humidity sensing properties of the material. For comparison, bare ZnFe2O4, and ZnFe2O4/rGO also synthesized. The freshly prepared samples were investigated using XRD, TEM, UV–vis–NIR spectroscopy, VSM, Impedance analyzer, and particle size analyzer. The detailed structural parameters were calculated through X-ray peak profiling using Classical Scherrer, Modified Scherrer, Williumson-Hall, Halder-Wagner, Size Strain Plot methods along with Rietveld refinement. From UV–vis–DRS analysis, optical energy gaps were obtained in the range of 1.58–1.92 eV. Ag@ZnFe2O4/rGO NCs showed significant photocatalytic activity and exceptional adsorption capacities for the breakdown of methylene blue (MB) 95.7% and rhodamine B (RhB) 77.7% after 100 min. The synergistic interactions of Ag, ZnFe2O4, and rGO minimized NCs agglomeration and small particle size with higher surface area, resulting in a higher absorption in both UV and visible light. The photocatalysis mechanism was explored by scavenger test using ascorbic Acid, NaHCO3, and isopropyl alcohol. The magnetic studies revealed the paramagnetic nature of NCs. Frequency dependent dielectric data obey the modified Debye model with relaxation time of ∼10−4 s and spreading factor of 0.534 (±0.08). Complex impedance measurements support the grain-interior process that contributes to dielectric properties. The impedance-type humidity sensing characteristics of the fabricated sensor were investigated by exposing in a wide humidity range of 11–98% RH at ambient temperature. The Ag@ZnFe2O4/rGO sensor displayed an ultrahigh sensitivity when compared to traditional humidity sensors. On the basis of, Ag@ZnFe2O4/rGO NCs are exciting nanomaterials for outstanding photocatalytic activity for the degradation of organic dyes along with potent humidity sensor.

First Report of Pectobacterium aroidearum Causing Soft Rot of Pinellia ternata in China.

Pinelliae rhizoma is the dried tuber of Pinellia ternata (Thunb.) Breit., and has been used for thousand of years in traditional Chinese medicine as an antivomit, anticough, and analgesic (Ying et al. 2007). In September 2022, P. ternata planted in Bijie, Guizhou Province, showed severe soft rot symptoms with incidence of about 50%. The diseased plants showed water-soaked symptoms and produced a foul soft rot smell, and finally the whole plant collapsed. Lesions were first observed at the tip of a leaf or wound, and symptoms of the disease spread rapidly, with the entire plant collapsing and dying within a week. The tissue sections of six plants with typical symptoms from the diseased field were disinfected with 75% ethanol for 30 seconds and 0.3% NaClO for 3 minutes. The tissue sections were then washed with sterile water for three times. A small piece of tissue (5x5mm) was removed from the edge of the lesion and mashed in a 1.5 ml centrifuge tube containing 20 μl of sterile water. The tissue liquid was then diluted 100 times with prepared sterile water. The bacteria were streaked on LB (tryptone/yeast extract/NaCl) AGAR medium and cultured at 37°C for 48 h (Kravitz, 1962). Isolated colonies were streaked on Luria-Bertani (LB) AGAR medium to obtain single colonies for further identification. A total of 13 representative isolates were selected for PCR amplification using primers targeting the conserved region of the 16S rDNA gene, which were in turn analyzed via the BLASTn search engine on the NCBI website. The results of the analysis revealed that seven of the isolates were similar to P. aroidearum strain SCRI 109 (GenBank accession no. NR_159926), with strain BX13 exhibiting the highest similarity to P. aroidearum (99.93% similarity), and therefore, this strain was selected for further investigation. The strain BX13 was incubated on LB solid medium for 24 h at 37 °C, and the single colonies were creamy white, translucent and round, slightly elevated in the center, with smooth surfaces and neat edges (Figure S1 B1). Then,the Scanning Electron Microscope revealed that the thalli of strain BX13 were short rod-shaped and somewhat blunt round at both ends (Figure S1 B2). The steward genes (icdA, gapA, proA) of BX13 were amplified and sequenced for further identification. The sequences of the amplified fragments were all deposited in GenBank 16S rDNA (OQ874505,) icdA (OQ954122)，gapA (OQ954123), proA (OQ954124). Sequence analysis using the BLASTn program at the NCBI revealed gene icdA, gapA, and proA had 100% identity to P. aroidearum strain QJ002 (GenBank accession no. CP090597).. Meanwhile, a maximum likelihood phylogenetic tree was constructed based on multigene sequence analysis of BX13 16S rDNA and steward genes (gapA, icdA, proA) by MEGA X (Liang et al. 2022). Phylogenetic results also showed that BX13 and P. aroidearum strain QJ002 gathered in the same clade(Figure S2). Accordingly, the morphological and molecular characteristics of strain BX13 indicate that it is P. aroidearum. (Nabhan S., et al.2013,Xu et al. 2020). In order to confirm the pathogenicity of strain BX13, a bacterial suspension containing 107 CFU/ml (10 ml/ inoculation point) was injected into the base of a one-week-old P. ternata stems, control seedlings were inoculated with sterile water, inoculated and control seedlings (each of six plants) were kept in a growth chamber maintained at 26°C with a relative humidity range of 70% to 80%. Plants were watered as needed. After 3 days, the stem base of the plants inoculated with bacteria solution showed water-soaked necrosis and stems began to rot, while the plants inoculated with water did not show this symptom. The strains were then successfully re-isolated from the symptomatic P. ternata. Then the strain re-isolated was identified using the BLASTn program at the NCBI and found that it has the same 16S rDNA, icdA, gapA, and proA sequences as strain BX13, thus completing the Koch's postulates. To our knowledge, this is the first report of P. aroidearum causing P. ternata soft rot in China, which expands its known host range. Accordingly, this study provides essential information for the breeding of P. ternata resistant to bacterial soft rot and the development of control measures in China.

A Calibration Facility for Hot-Wire Anemometers in Extremely Low Speed with Air Temperature and Humidity Variable and Controllable

Aimed at addressing the difficult problems existing in extremely low speed calibration facilities for hot-wire anemometers, where calibration accuracy is often insufficient and vulnerable to the contamination from temperature and humidity discrepancies between the calibration environment and the application environment, a calibration rig with a velocity range from 0.10 m/s to 1.0 m/s, an air temperature range from ambient temperature to 60 °C, and a humidity range from 20%RH to 80%RH was designed, developed, and constructed. The overall layout arrangement and the mechanical structure of the facility are illustrated. The master control system, the motion control system, the temperature and humidity control system are designed, tested and adjusted. The adjustment results are demonstrated and discussed. The analysis of the results reveals that the maximum velocity control error is 0.000989 m/s, satisfying the design target of 0.003 m/s; the corresponding maximum relative error is 0.241%, which is less than the design target of 0.4%; the maximum temperature control error is 0.9 °C, meeting the design target accuracy of 1 °C; the maximum humidity control error is 2.9%RH, which is below the design target of 4%RH. When the facility is applied to the calibration of a hot-wire anemometer, the maximum error of the fitting curves in modified King’s law is 0.02236 m/s, while that in Van der Hegge Zijnen’s formula is 0.023217 m/s, both of which satisfy the design target accuracy of 0.03 m/s. The maximum relative errors of fitting curves using the two formulas are 5.214% and 8.527%, respectively. Analysis of calibration data reveals that the discrepancy in temperature and humidity between application site and calibration site may bring errors that can reach up to 1.2676% per unit relative humidity discrepancy, and 5.672% per degree Celsius of temperature deviation, respectively.

A highly sensitive flexible humidity sensor based on a wafer-level composite material of carbon-quantum-dots@nanofiber clusters

A novel composite material composed of carbon-quantum-dots@nanofiber clusters (CQDs@NFCs) is successfully developed in wafer level, taking it as a sensitive material, a flexible humidity sensor is also developed. Since the composite material is superhydrophilic and contains a super large number of nanopores of different sizes, capillary condensation is able to take place within the composite material at different relative humidity (RH) conditions. Taking advantage of the chemi-physisorption and the capillary condensation, such a sensing material helps to significantly improve sensitivity of the flexible sensor, especially at low RH conditions. Compared with the device adopting only nanofibers as the sensing material, this novel sensor offers a 4.3-time increament in sensitivity within a humidity range of 7%−59% RH, while maintains high sensitivity in the entire humidity range. This heightened sensitivity is crucial for monitoring low-level humidity with high accuracy, making the sensor highly promising for various applications.

Evaporative controls on Antarctic precipitation: an ECHAM6 model study using innovative water tracer diagnostics

Abstract. Improving our understanding of the controls on Antarctic precipitation is critical for gaining insights into past and future polar and global environmental changes. Here we develop innovative water tracing diagnostics in the atmospheric general circulation model ECHAM6. These tracers provide new detailed information on moisture source locations and properties of Antarctic precipitation. In the preindustrial simulation, annual mean Antarctic precipitation originating from the open ocean has a source latitude range of 49–35∘ S, a source sea surface temperature range of 9.8–16.3 ∘C, a source 2 m relative humidity range of 75.6 %–83.3 %, and a source 10 m wind velocity (vel10) range of 10.1 to 11.3 m s−1. These results are consistent with estimates from existing literature. Central Antarctic precipitation is sourced from more equatorward (distant) sources via elevated transport pathways compared to coastal Antarctic precipitation. This has been attributed to a moist isentropic framework; i.e. poleward vapour transport tends to follow constant equivalent potential temperature. However, we find notable deviations from this tendency especially in the lower troposphere, likely due to radiative cooling. Heavy precipitation is sourced by longer-range moisture transport: it comes from 2.9∘ (300 km, averaged over Antarctica) more equatorward (distant) sources compared to the rest of precipitation. Precipitation during negative phases of the Southern Annular Mode (SAM) also comes from more equatorward moisture sources (by 2.4∘, averaged over Antarctica) compared to precipitation during positive SAM phases, likely due to amplified planetary waves during negative SAM phases. Moreover, source vel10 of annual mean precipitation is on average 2.1 m s−1 higher than annual mean vel10 at moisture source locations from which the precipitation originates. This shows that the evaporation of moisture driving Antarctic precipitation occurs under windier conditions than average. We quantified this dynamic control of Southern Ocean surface wind on moisture availability for Antarctic precipitation. Overall, the innovative water tracing diagnostics enhance our understanding of the controlling factors of Antarctic precipitation.

Customizing Wettability of Defect-Rich CeO2/TiO2 Nanotube Arrays for Humidity-Resistant, Ultrafast, and Sensitive Ammonia Response.

In all their applications, gas sensors should satisfy several requirements, including low cost, reduced energy consumption, fast response/recovery, high sensitivity, and reliability in a broad humidity range. Unfortunately, the fast response/recovery and sensing reliability under high humidity conditions are often still missing, especially those working at room temperature. In this study, a humidity-resistant gas sensor with an ultrafast response/recovery rate was designed by integrating a defect-rich semiconducting sensing interface and a self-assembled monolayer (SAM) with controllable wettability. As a proof-of-concept application, ammonia (NH3), one of the atmospheric and indoor pollutants, was selected as the target gas. The decoration of interconnected defective CeO2 nanowires on spaced TiO2 nanotube arrays (NTAs) provided superior NH3 sensing performances. Moreover, we showed that manipulating the functional end group of SAMs is an efficient and simple method to adjust the wettability, by which 86% sensitivity retention with an ultrafast response (within 5 s) and a low limit of detection (45 ppb) were achieved even at 75% relative humidity and room temperature. This work provides a new route toward the comprehensive design and application of metal oxide semiconductors for trace gas monitoring under harsh conditions, such as those of agricultural, environmental, and industrial fields.

Bio-inspired polyionic membrane for long-lasting and repeatable electricity harvesting from moisture

Evaporation power generation (EPG), hailed as a promising clean power generation technology, has garnered significant attention. Nonetheless, achieving consistent and replicable performance of EPG remains a major challenge, hampering its practical application potential. Herein, we present the design of a tri-layered poly-ionic membrane (TL-PIM) inspired by transpiration processes in plants, that can not only continuously output electricity with an average voltage of ∼0.6 V for over 8 consecutive days with a maximum power density of 1.6 µW cm−2, but can also be reused for at least 70 cycles (> 350 h) with a stable voltage, demonstrating superior repeatability over most previous works. The excellent long-lasting and repeatable performance of EPG in the TL-PIM can be attributed to the stable nanochannels constructed by a hydrophilic polymer, 2D nanosheets, and poly-ionic liquids (PILs), where the bromide ions (Br-) in the PILs can shuttle back and forth selectively and efficiently during the power generation and discharge processes. More importantly, the TL-PIM can be integrated linearly to generate electricity within a wide range of temperatures and humidity, even outdoors, showcasing remarkable environmental adaptability. These findings on EPG indicate that the bio-inspired TL-PIM offers a promising venue for continuous and reproducible electricity generation by harnessing thermal energy from moisture, which holds significance for the sustainable utilization of EPG as a renewable energy source in the future.

Surface Hydroxyl and Oxygen Vacancies Engineering in ZnSnAl LDH: Synergistic Promotion of Photocatalytic Oxidation of Aromatic VOCs.

Photocatalytic oxidation has gained great interest in environmental remediation, but it is still limited by its low efficiency and catalytic deactivation in the degradation of aromatic VOCs. In this study, we concurrently regulated the surface hydroxyl and oxygen vacancies by introducing Al into ZnSn layered double hydroxide (LDH). The presence of distorted Al species induced local charge redistribution, leading to the remarkable formation of oxygen vacancies. These oxygen vacancies subsequently increased the amount of surface hydroxyl and elongated its bond length. The synergistic effects of surface hydroxyl and oxygen vacancies greatly enhanced reactant adsorption-activation and facilitated charge transfer to generate •OH, •O2-, and 1O2, resulting in highly efficient oxidation and ring-opening of various aromatic VOCs. Compared with commercial TiO2, the optimized ZnSnAl-50 catalyst exhibited about 2-fold activity for the toluene and styrene degradation and 10-fold activity for the chlorobenzene degradation. Moreover, ZnSnAl-50 demonstrated exceptional stability in the photocatalytic oxidation of toluene under a wide humidity range of 0-75%. This work marvelously improves the photocatalytic efficiency, stability, and adaptability through a novel strategy of surface hydroxyl and oxygen vacancies engineering.