Frequency Range Research Articles

Advanced, Real-Time Programmable FPGA-Based Digital Filtering Unit for IR Detection Modules

This paper presents a programmable digital filtering unit dedicated to operating with signals from infrared (IR) detection modules. The designed device is quite useful for increasing the signal-to-noise ratio due to the reduction in noise and interference from detector–amplifier circuits or external radiation sources. Moreover, the developed device is flexible due to the possibility of programming the desired filter types and their responses. In the circuit, an advanced field-programmable gate array FPGA chip was used to ensure an adequate number of resources that are necessary to implement an effective filtration process. The proposed circuity was assisted by a 32-bit microcontroller to perform controlling functions and could operate at frequency sampling of up to 40 MSa/s with 16-bit resolution. In addition, in our application, the sampling frequency decimation enabled obtaining relatively narrow passband characteristics also in the low frequency range. The filtered signal was available in real time at the digital-to-analog converter output. In the paper, we showed results of simulations and real measurements of filters implementation in the FPGA device. Moreover, we also presented a practical application of the proposed circuit in cooperation with an InAsSb mid-IR detector module, where its self-noise was effectively reduced. The presented device can be regarded as an attractive alternative to the lock-in technique, artificial intelligence algorithms, or wavelet transform in applications where their use is impossible or problematic. Comparing the presented device with the previous proposal, a higher signal-to-noise ratio improvement and wider bandwidth of operation were obtained.

Influence of Voice Focus on Auditory Feedback Control of Speech Using Long-Term Average Spectrum, Phon Spectrum, and Accelerometry.

This study investigates the effect of voice-focus adjustments on oronasal balance and auditory feedback control of speech via analyzing spectral distribution, perceived loudness, and nasal vibrations during sustained phonation and passage reading. Twenty-five speech-language pathologists sustained /a/ and read passages with forward, backward, and natural voice focuses in quiet and noisy conditions. The low-frequency power (LFP) below 3 Hz of vocal fundamental frequency was analyzed to access audio-vocal feedback control. Long-term average spectra of speech were converted to phon spectra based on equal-loudness contours ISO 226:2003 to estimate perceived loudness of self-voice across different conditions. Nasal vibrations were also recorded using a digital accelerometer to measure oronasal coupling. Forward-focused voice enhanced the nasal acceleration and reduced LFP, suggesting that increasing the degree of oronasal coupling can improve audio-vocal feedback control compared to natural and backward-focused voices. Voice-focus adjustments were most related to average power and phon values in the 0.2- to 0.3-kHz band. In noise, perceived loudness in the 0.5- to 2.3-kHz band effectively predicted LFP, outperforming the average spectral power of the same band. Voice-focus adjustments significantly impact both the acoustic transfer function of the vocal tract and the spontaneous fine-tuning of audio-vocal integration. This influence becomes particularly pronounced when sound intensity or perceived loudness is changed within the frequency range of 0.2-2.3 kHz, depending on the voice focus selected by the speakers. https://doi.org/10.23641/asha.27183483.

Wind tunnel and flight testing of a lamb wave-based ice accretion sensor

Abstract Severe icing conditions are still a risk in aviation. Heavy ice accretion on aircraft can affect mass and aerodynamic performance in a way, that a catastrophic loss of control may occur. Detecting icing conditions and the extent of ice accretion is therefore essential to react instantly and to assess the severity. This eases the decision to either activate ice protection systems and continue the flight or to leave the icing conditions immediately. These functions can be provided by an icing sensor. Within the EU funded SENS4ICE project, several ice sensors have been developed. One of them is the so-called local ice layer detector (LILD). It uses lamb waves which are guided by the aircraft structure. If an ice accretion happens, the wave guide behavior is affected changing amplitude and lag time of the lamb wave pulses. This can be measured. If the sensor is mounted to a surface on the aircraft which is prone to icing, e.g. the leading edge of the wing, ice can be detected where it is relevant for the aerodynamic performance. Within the project, the sensor hard- and software have been developed to create and measure lamb wave pulses in a wide frequency range. To investigate the influence of ice accretion on the lamb waves, wind tunnel tests were undertaken. Finally, the sensor was investigated in a flight test. In this paper, an overview about the function of the sensor as well as the general signal behavior are given. The results of the wind tunnel test and some preliminary results from the flight tests will be shown. In both tests, the sensor was able to detect even very thin ice layers with minimum delay from the beginning of the ice accretion.

A Sinusoidal Current Generator IC with 0.04% THD for Bio-Impedance Spectroscopy Using a Digital ΔΣ Modulator and FIR Filter

This paper presents a highly efficient, low-power, compact mixed-signal sinusoidal current generator (CG) integrated circuit (IC) designed for bioelectrical impedance spectroscopy (BIS) with low total harmonic distortion (THD). The proposed system employs a 9-bit sine wave lookup table (LUT) which is simplified to a 4-bit data stream through a third-order digital delta–sigma modulator (ΔΣM). Unlike conventional analog low-pass filters (LPF), which statically limit bandwidth, the finite impulse response (FIR) filter attenuates high-frequency noise according to the operating frequency, allowing the frequency range of the sinusoidal signal to vary. Additionally, the output of the FIR filter is applied to a 6-bit capacitive digital-to-analog converter (CDAC) with data-weighted averaging (DWA), enabling dynamic capacitor matching and seamless interfacing. The sinusoidal CG IC, fabricated using a 65 nm CMOS process, produces a 5 μA amplitude and operates over a wide frequency range of 0.6 to 20 kHz. This highly synthesizable CG achieves a THD of 0.04%, consumes 19.2 μW of power, and occupies an area of 0.0798 mm2. These attributes make the CG IC highly suitable for compact, low-power bio-impedance applications.

Design of a CPW-based SSPP band-pass filter with reflectionless notch

Abstract This work proposes a band-pass filter (BPF) with a reflectionless notch based on spoof surface plasmon polaritons (SSPPs), utilizing interdigital coupling structures and novel transmission line unit cells. This filter efficiently transmits signals within the 0.67 GHz −4.06 GHz frequency range. By analyzing the equivalent LC circuit of the novel transmission line unit cell, its dispersion relation is derived using microwave network theory, with a cutoff frequency of 4.11 GHz. By comparing its dispersion relation with that of the conventional transmission line unit cell, the miniaturization capability of the proposed unit cell can be verified. In the BPF, loading a zigzag groove onto the central transmission line can be equivalently represented as an interdigital coupling structure, generating a stopband in the low-frequency range near 0 GHz. By deriving and analyzing its S-parameters, it is shown that the bandwidth of the low-frequency stopband can be flexibly adjusted by modifying the geometric dimensions of the zigzag groove. Additionally, loading another set of interdigital coupling structures onto the transmission line generates a notch at its resonant frequency of 3.4 GHz. It is noteworthy that in this configuration, the interdigital coupling structures along with the central transmission line can be represented equivalently as a set of CPW antennas. At the resonant frequency, the atructure radiates signals into free space, forming a reflectionless notch. Based on the simulations, a physical filter was fabricated and tested, showing excellent agreement between simulations and measurements.

Resistance standards with very small calculable AC-DC difference at frequencies up to 2 MHz for the calibration of precision LCR meters

Abstract We have developed novel impedance standards based on thin-film surface mount device (SMD) resistors. Due to the small dimensions of such resistors, the frequency dependence is very small and can be calculated from quantities that can be either measured or numerically calculated. For nominal resistance values in the 10 kΩ range, as for our application, the DC and AC properties of a single thin-film SMD resistor are not sufficient but can be greatly improved by connecting several thin-film SMD resistors in series. Then the calculated frequency dependence at frequencies up to 2 MHz amounts to only a few parts per million of the DC value, which is about four orders of magnitude smaller than for all conventional calculable AC-DC resistors with a similar nominal DC value. A precision inductance-capacitance-resistance (LCR) meter for frequencies up to 2 MHz, which has a resolution and a reproducibility of a few parts per million but a systematic uncertainty of up to 3000 parts per million, is used to measure two very different SMD-based resistance standards. This enables the verification of the model calculation as well as the calibration of the LCR meter and the correction of its systematic effects, both with a relative uncertainty of a few parts per million in the whole frequency range. This boost in precision enables new applications in this frequency range such as the verification of conventional calculable resistance standards, the calibration of impedance standards, and future measurements of the quantum Hall resistance.We have developed novel impedance standards based on thin-film surface mount device

Trans-retinal predictive signals of visual features are precise, saccade-specific and operate over a wide range of spatial frequencies.

Saccadic eye movements successively project the saccade target on two retinal locations: a peripheral one before the saccade, and the fovea after the saccade. Typically, performance in discriminating stimulus features changes between these two projections is very poor. However, a short (~ 200 ms) blanking of the target upon saccade onset drastically improves performance, demonstrating that a precise signal of the peripheral projection is retained during the saccade. While little is known about the nature of that transsaccadic signal, previous reports conjectured that it relies on information processed by the magnocellular system. Across two experiments, we investigated the feature blanking effect for a wide range of spatial frequencies (0.5 to 8 cycles per degree of visual angle, dva), stimulus sizes (1 to 4 dva) and eccentricities (6 to 10 dva). In each trial, participants executed a saccade to a high-contrast grating presented either left or right of fixation. During the saccade, the grating changed orientation (clockwise or counter-clockwise) either instantaneously or after a 200 ms blank, and participants reported the change's direction. We contrasted this saccade condition with a trans-retinal fixation condition mimicking the peripheral-then-foveal sequence of the target stimulus occurring across a saccade. Remarkably, blanking improved performance reliably for each spatial frequency, stimulus size, and eccentricity, but only in the saccade condition. Performance with blanking in saccade trials systematically exceeded performance in the fixation condition. Our results demonstrate a robust feature blanking effect across saccades, suggesting that transsaccadic processes involve low-level visual features beyond those processed in the magnocellular system.

Vanadium dioxide and a graphene-based ultra-wideband absorption and polarization conversion switchable terahertz device

A multifunctional terahertz functional device based on vanadium dioxide (VO2) and graphene is proposed, which can realize ultra-wideband absorption and polarization conversion. When the VO2 is in the insulating state, the device can achieve the polarization conversion function to convert the incident wave into the corresponding cross-polarized wave. Polarization conversion ratios (PCRs) can exceed 90% in the 2.1–8 THz frequency range; in the 3–7.5 THz range, the PCR can be more than 95%. When VO2 is in the metallic state and the graphene Fermi energy is 0.9 eV, the device can realize a broadband absorption function. An absorption rate of more than 90% can be achieved over a wide frequency range of 3.3–7.7 THz. In addition, the polarization conversion device can maintain high performance in broadband polarization conversion at incident angles no greater than 40°. The absorber device also exhibits insensitivity to both incident and polarization angles. These advantages which make the proposed multifunctional terahertz functional device have a wide range of applications in the fields of terahertz imaging, sensing, communication, and so on.

Triple notched coplanar waveguide-fed novel ultrawide band antenna with time domain analysis

This research proposition introduces a novel microstrip antenna design that features triple notches for ultra-wideband (UWB) applications. The antenna, measuring 35.4 mm × 28.82 mm × 1.57 mm, incorporates rectangular and semi-circular slots, as well as a pentagonal stub. A modified U-shaped slot on the pentagonal stub creates one notched frequency band at 3.3–3.7 GHz. Additionally, two Split Ring Resonators (SRRs) are integrated into the antenna’s rear surface, resulting in two more notched bands at 5.1–5.8 GHz and 7.1–7.8 GHz. Operating within a frequency range from 3 to 11.2 GHz with VSWR ≤ 2, the antenna effectively excludes the triple stop bands at 3.3–3.7 GHz (11.4%), 5.1–5.8 GHz (12.8%) and 7.1–7.8 GHz (9.4%). The proposed antenna has been successfully prototyped and verified. An extensive result analysis has been conducted, confirming that the developed antenna is suitable for application in a range of wireless systems. Moreover, the article includes the implementation of an equivalent circuit for the proposed antenna.

Rheology of Cellulosic Microfiber Suspensions Under Oscillatory and Rotational Shear for Biocomposite Applications

This study investigates the rheological behavior of cellulose microfiber suspensions derived from kahili ginger stems (Hedychium gardnerianum), an invasive species, in two adhesive matrices: a commercial water-based adhesive (Coplaseal®) and a casein-based adhesive made from non-food-grade milk, referred to as K and S samples, respectively. Rheological analyses were performed using oscillatory and rotational shear tests conducted at 25 °C, 50 °C, and 75 °C to assess the materials’ viscoelastic properties more comprehensively. Oscillatory tests across a frequency range of 1–100 rad/s assessed the storage modulus (G′) and loss modulus (G″), while rotational shear tests evaluated apparent viscosity and shear stress across shear rates from 0.1 to 1000 s−1. Fiber-free samples consistently showed lower moduli than fiber-containing samples at all frequencies. The incorporation of fibers increased the dynamic moduli in both K and S samples, with a quasi-plateau observed at lower frequencies, suggesting solid-like behavior. This trend was consistent in all tested temperatures. As frequencies increased, the fiber network was disrupted, transitioning the samples to fluid-like behavior, with a marked increase in G′ and G″. This transition was more pronounced in K samples, especially above 10 rad/s at 25 °C and 50 °C, but less evident at 75 °C. This shift from solid-like to fluid-like behavior reflects the transition from percolation effects at low frequencies to matrix-dominated responses at high frequencies. In contrast, S samples displayed a wider frequency range for the quasi-plateau, with less pronounced moduli changes at higher frequencies. At 75 °C, the moduli of fiber-containing and fiber-free S samples nearly converged at higher frequencies, indicating similar effects of the fiber and matrix components. Both fiber-reinforced and non-reinforced suspensions exhibited pseudoplastic (shear-thinning) behavior. Fiber-containing samples exhibited higher initial viscosity, with K samples displaying greater differences between fiber-reinforced and non-reinforced systems compared to S samples, where the gap was narrower. Interestingly, S samples exhibited overall higher viscosity than K samples, implying a reduced influence of fibers on the viscosity in the S matrix. This preliminary study highlights the complex interactions between cellulosic fiber networks, adhesive matrices, and rheological conditions. The findings provide a foundation for optimizing the development of sustainable biocomposites, particularly in applications requiring precise tuning of rheological properties.

Determination of Optical and Structural Parameters of Thin Films with Differently Rough Boundaries

The optical characterization of non-absorbing, homogeneous, isotropic polymer-like thin films with correlated, differently rough boundaries is essential in optimizing their performance in various applications. A central aim of this study is to derive the general formulae necessary for the characterization of such films. The applicability of this theory is illustrated through the characterization of a polymer-like thin film deposited by plasma-enhanced chemical vapor deposition onto a silicon substrate with a randomly rough surface, focusing on the analysis of its rough boundaries over a wide range of spatial frequencies. The method is based on processing experimental data obtained using variable-angle spectroscopic ellipsometry and spectroscopic reflectometry. The transition layer is considered at the lower boundary of the polymer-like thin film. The spectral dependencies of the optical constants of the polymer-like thin film and the transition layer are determined using the Campi–Coriasso dispersion model. The reflectance data are processed using a combination of Rayleigh–Rice theory and scalar diffraction theory in the near-infrared and visible spectral ranges, while scalar diffraction theory is used for the processing of reflectance data within the ultraviolet range. Rayleigh–Rice theory alone is sufficient for the processing of the ellipsometric data across the entire spectral range. We accurately determine the thicknesses of the polymer-like thin film and the transition layer, as well as the roughness parameters of both boundaries, with the root mean square (rms) values cross-validated using atomic force microscopy. Notably, the rms values derived from optical measurements and atomic force microscopy show excellent agreement. These findings confirm the reliability of the optical method for the detailed characterization of thin films with differently rough boundaries, supporting the applicability of the proposed method in high-precision film analysis.

In Situ Testing and Finite Element Analysis of a Discontinuous Mortise and Tenon Stone Bridge Under Natural Excitation

To study the dynamic response of multi-span mortise and tenon stone bridges under natural excitation, a bluestone multi-span stone bridge with a main span of 2.56 m in southern China was taken as the research object. Based on the collected pulsating signals of bridge piers and slabs, the natural frequencies and damping ratios of the main span bridge slab and pier were analyzed using the half-power broadband method (HPBM) and random decrement technique (RDT). Modal analysis was conducted using ANSYS, and the results were compared with those obtained from on-site experiments for further performance analysis. The research results of this article indicate that the natural frequency range of the 2.56-m bridge slab identified by measured signals is 48–49 Hz, and the damping ratio range is 33.33–36.61%. The natural frequency of the central pier is 75–76 Hz, and the damping ratio range is 26.39–27.83%. Through finite element modal analysis, the natural frequency of the bridge slab is 54.401 Hz, with an error of 10.5%. The natural frequency of the overall stone bridge is about 82.2 Hz, with an error of about 8.2%. The validated finite element model was subjected to normal water flow impact and erosion simulation. The results indicate that under erosion with fewer particles and lower flow rates, the upstream pier bottom at the center receives the highest relative erosion mass and displacement per unit area. The bridge deck near the main span also experienced relative displacement. Therefore, in the subsequent protection work, special attention should be paid to these components.

Modeling Thermal Impedance of IGBT Devices Based on Fractional Calculus Techniques

The thermal impedance characteristics of insulated gate bipolar transistor (IGBT) modules are critical for the thermal management and design of electronic devices. This paper proposes a fractional-order equivalent thermal impedance model, which is inspired by the correlation between multi-time-scale dissipation characteristics of heat conduction processes and fractional calculus. The fractional-order equivalent thermal impedance model is derived based on the connection between fractional-order calculus and the Foster thermal network model in mathematical operations, with only two parameters to be identified: heat capacity C and fractional order α. Moreover, this paper provides a parameter identification method for the proposed fractional-order equivalent thermal impedance model based on the multi-objective particle swarm optimization (MOPSO) algorithm. In order to validate the effectiveness and superiority of this work, experiments and comparative works are provided in this paper. The results indicate that the fractional-order equivalent thermal impedance model can accurately describe the frequency domain characteristic curves of the thermal impedance of the Foster thermal network model for IGBT modules, with the difference between the amplitude frequency characteristics not exceeding 1 dB and the difference between the phase frequency characteristics not exceeding 1° within the operating frequency range of (1 kHz, 1 MHz).

The proposed mechanism of glow of mesosphere clouds

The question of the physical mechanism of electromagnetic radiation scattering by mesospheric (noctilucent) clouds is considered. A hypothesis has been expressed about the special electromagnetic characteristics of nanometer-sized ice particles that make up mesospheric clouds. Particle ice consists of a recently discovered crystalline modification of water — ice 0, formed by the condensation of vapor on dust particles at temperatures of –140…–23°C. Ice 0 is a ferroelectric, and upon contact with a dielectric, a layer with high electrical conductivity is formed. Due to plasmon resonance in nanosized layers, strong scattering of electromagnetic radiation occurs over a wide frequency range. This mechanism causes the glow of noctilucent clouds when illuminated by the radiation of the Sun.

Improvement of microwave absorbing capability on the soft magnetic/hard magnetic/perovskite composites

Abstract This paper reports an increase in the ability to absorb microwaves from a composite made of combination between soft and hard magnetic materials, perovskite material, and an epoxy as matrix of composite, Ni0.5Zn0.5Fe2O4/Ba0.6Sr0.4Fe9.5Al0.5MnTiO19/FeTiO3/epoxy (NBFE) with a wt% ratio of 5:3:2:10. Composite samples were made using the mechanical alloying method with milling techniques and sintered at a temperature of 1000 °C for 5 h. NBFE composites were studied to increase the ability to absorb microwaves at 2–18 GHz frequencies with thickness variations of 1 mm and 2 mm. The results obtained, the composite sample Ni0.5Zn0.5Fe2O4/Ba0.6Sr0.4Fe9.5Al0.5MnTiO19/FeTiO3/epoxy has the ability to absorb microwaves with the best reflection loss value −37.47 dB with a bandwidth almost reaches 11.32 GHz in the 2–18 GHz frequency range.

Hybridization of Cockcroft-Walton and Dickson Voltage Multipliers for Maximum Output Through Effective Frequency Dedication in Harvesting Radio Frequency Energy

Objective: This study investigates solutions to the challenges of limited RF energy harvesting by designing a hybridized voltage multiplier system aimed at optimizing output across a wide frequency range. Theoretical Framework: The research centers on the principles and comparative efficiencies of the Cockcroft-Walton and Dickson voltage multipliers, known for their applications in RF energy harvesting. These multipliers’ performance was analyzed theoretically to guide a hybrid design that could adaptively respond to input frequency variations. Method: Voltage multipliers were designed and simulated in Multisim, with further analysis in MATLAB. Both the Cockcroft-Walton and Dickson voltage multipliers were subjected to a constant input of 1V across frequencies from 50 Hz to 5 GHz to assess their respective efficiencies. Subsequently, a hybrid voltage multiplier system was developed, combining an 8-stage Cockcroft-Walton and an 8-stage Dickson multiplier. A fast Fourier transform (FFT) frequency-selective algorithm, implemented in MATLAB, dynamically directed input voltages to the optimal multiplier based on frequency. Results and Discussion: Results showed that the Dickson multiplier excelled in the lower frequency range (50 Hz to 1 MHz), achieving a maximum output of 14.763V at 5 kHz and 10 kHz. In contrast, the Cockcroft-Walton multiplier was more effective in the higher frequency range (1 MHz to 5 GHz), reaching a peak output of 6.671V at 5 GHz. The hybrid system demonstrated efficient, frequency-dependent voltage multiplication and aligned well with anticipated performance metrics, suggesting an improvement in RF energy harvesting across the tested frequency range. Research Implications: This work contributes to the field of RF energy harvesting by introducing a frequency-adaptive system that enhances voltage output through targeted frequency routing. The results underscore the potential for hybrid designs to overcome limitations associated with individual voltage multipliers, presenting a versatile approach to harvesting RF energy effectively across broad frequency spectra. Originality/Value: By implementing a hybrid approach with a frequency-selective algorithm, this study offers an innovative solution for frequency-dependent RF energy harvesting. The findings provide a foundation for future research into adaptable energy harvesting systems that optimize voltage output across diverse frequencies, with practical implications for RF-powered devices and wireless energy transfer applications.

Broadband polarization-insensitive terahertz absorber based on Ta2O5 snowflake-like structure

Abstract In this paper, an ultra-broadband tantalum pentoxide (Ta2O5) all-dielectric metamaterial absorber is proposed from the far-infrared to the terahertz range, which exhibits polarization-insensitive and wide-angle characteristics. The absorber consistently demonstrates an impressive absorption rate exceeding 90% within the frequency range from 1.1 THz to 20 THz. Such an absorber can have a bandwidth and relative bandwidth ratio of 18.9 THz and 179.15%. We employ an equivalent circuit model to simulate the performance of the absorber using transmission line theory, which facilitates near-perfect absorption by finely tuning the geometrical parameters of the structure to match the input impedance with that of free space. Detailed calculations and analyses of the electric and magnetic field distributions, as well as power loss density, are presented to clarifying the underlying mechanisms of absorption. The design of the proposed absorber inherently provides insensitivity to polarization angles and sustains superior absorption efficiency at substantial incidence angles. An exhaustive exploration of the influence of structural variations on the performance of the absorber has been conducted. Looking ahead, the proposed absorber can be potential application in enhanced terahertz imaging, terahertz communication systems, novel energy harvesting solutions and broad scientific research endeavours.

Low-noise soliton molecule generation with an in-phase controllable pulse number by third- and second-order dispersion compensation in an all-fiber erbium-doped oscillator

We report on the experimental results of high-order soliton molecule (SM) generation in an erbium-doped oscillator. The generation of 14 solitons with an average power of 48 mW, a pulse duration of 508 fs, a separation of 2.59 ps between pulses, and a repetition rate of 19 MHz at 1560 nm central wavelength was demonstrated. The stability of this generation was also evidenced by its low relative intensity noise (0.08% in the frequency range [10 kHz–1 MHz]), and a low Allan deviation of frequency repetition rate of 1.98⋅10−9 at an interval of 1 s (during 10 h of free-running measurements). Moreover, the accurate manipulation of SM order by changing the pump power was investigated; we showed the ability to generate with four, six, seven, nine, 10, 11, 13, and 14 pulses with high stable states between solitons. The change in the number of pulses occurred repeatably by increasing and decreasing the pump power, offering a stable source of a controllable number of pulses for potential applications in quantum computing.

Comparison of a Quantum Cascade Laser and an Interband Cascade Laser for the Detection of Stable Carbon Dioxide Isotopes Using Tunable Laser Absorption Spectroscopy.

Quantum cascade lasers (QCLs) and interband cascade lasers (ICLs) are widely used as light sources in tunable laser absorption spectroscopy because they emit in the mid-infrared region where many strong and characteristic absorption bands are present. In this paper, we compare the performance of these lasers emitting at about 2310.1 cm-1 to determine an optimal light source for detecting isotopic ratios of carbon dioxide (CO2). Our results show that the QCL has a higher relative intensity noise of up to 15 dBc/Hz compared to the ICL over the entire measured frequency range. In addition, it has a higher frequency fluctuation. However, the maximum tuning range of the QCL is up to 5.2 cm-1 compared to up to 3.8 cm-1 for the ICL. Both lasers lose more than half of their tuning range when the tuning rate is increased to 10 kHz. When measuring the isotope ratio of CO2, an uncertainty in the value of ‰ was achieved with the ICL and of ‰ with the QCL, both at an integration time of 0.2 s. In summary, the QCL is more appropriate for applications that require a larger spectral tuning range, such as the measurement of a complex gas mixture, while the ICL has an excellent signal-to-noise ratio and is therefore better suited for applications that require higher precision.

Measuring Microplastic Concentrations in Water by Electrical Impedance Spectroscopy

Plastics are vital for society, but their usage has grown exponentially and contributes to the growth of pollution worldwide. The World Health Organization, WHO, already reported that microplastics (MPs) are found everywhere, in waste and fresh water, and in the air and soil. Regarding water effluents, waste-water treatment plants only minimize the problem, trapping only larger size particles. In contrast, smaller ones remain in oxidation ponds or sewage sludges, or are even released to aquifers environment. Classic procedures for MPs detection are still quite laborious, and are usually conducted off-line, involving several steps and expensive equipment. Electrical Impedance Spectroscopy, EIS, is a technique that allows the analysis of a system’s electrical response, yielding helpful information about its domain-dependent on physical-chemical properties. Due to the superficial electronegativity of MPs’ particles, EIS may allow to attain the purpose of the present work: to provide a fast and reliable method to detect/estimate MPs’ concentration in water effluents. Among the most common microplastics are Polyethylene, PE, and Polyvinyl Chloride, PVC. Using the developed setup and experimental data collection methodology, the authors could differentiate between MPs’ suspensions containing the same concentration of the different evaluated MPs, PVC and PE, and assess PVC concentration variation, in the interval between 0.03 to 0.5 g (w/w), with an error, estimated based on the obtained impedance modulus, around or below 3% for the entire stimulus signal frequency range (from 100 Hz to 40 MHz) for the PVC particles.