Concrete is widely used in bridges, tunnels, nuclear power plants and other buildings, the damage of concrete will bring significant safety hazards for the building, therefore, detecting concrete damage is of great significance. In this paper, the propagation characteristics of guided waves in concrete plates are investigated, and finite element simulation is used to analyze the sensitivity of guided waves to the damage of concrete materials under different excitation frequencies. Simulation experiments on guided wave propagation are performed on concrete materials containing damage in the excitation frequency range from 25 to 100 kHz. The signals received by the sensors are analyzed in the time domain, while the reflected wave signals resulting from the contact of the signals with the damage are analyzed in the frequency domain. The results show that the excitation frequencies of 25 and 60 kHz are more sensitive to damage, and the quantitative identification of damage without reference can be realized by using the peak signals in the frequency domain at different excitation frequencies.