Optical chaos communication has a physical-layer security advantage but defends passively against a malicious attack. Here, we conduct a proof-of-concept experiment of detecting the attack proactively by observing performance degradation in optical chaos communication tapped with fiber bending. Influences of the curvature radius of the bent fiber on a chaos synchronization coefficient and bit error rate are investigated. Results show that the synchronization coefficient decreases from 0.958 to 0.904 and the bit error rate increases from 1.31 × 10-4 to 1.73 × 10-3 under a curvature radius of 10 mm, revealing the attack. Bending fiber to this extent leads to a power loss of 1.81%, which is difficult to detect by the optical time-domain reflectometer but causes significant interference to chaos communication due to the concurrent change in the light polarization, jointly decreasing the effective optical injection strength for yielding chaos synchronization.