An in-depth analysis of the decay process for β-emitting radionuclides highlights, for some of them, the existence of high-order effects usually not taken into account in literature as considered negligible in terms of energy and yield, and referred to as Internal Bremsstrahlung (IB). This set of β-radionuclides presents, besides their β spectrum, a continuous γ emission due to the Coulomb field braking action on the emitted electron following the decaying nucleus. 
In this work, we review the theoretical and experimental studies on the IB process focusing on its actual importance for the pure β emitters. It emerges that there is no satisfactory model able to reproduce the experimental IB distribution for most of the investigated beta emitters and the several measurements are sometimes at odds with each other. Moreover, as recently demonstrated, the IB process can give a relevant contribution to the physics of beta emitters thus requiring its inclusion in the physics of the beta decay.
A discussion on the importance of considering the IB process in both applicative fields such as nuclear medicine, industrial applications, and research or calibration laboratories, and in other relevant fields of particle physics or astrophysics, such as the research on dark matter or neutrino mass, is presented.