Constructing MXene-based absorbers with multicomponent and multidimensional hierarchical architecture is crucial but it still remains a formidable challenge to address the serious electromagnetic radiation pollution issue. Herein, a multidimensional 0D/1D/2D NiMn-LDH@CNT/MXene (NCM) hierarchical architecture composed of 0D NiMn-LDH anchored on 1D CNT and then assembled with 2D MXene is rationally constructed for electromagnetic waves (EMW) absorption. The EMW absorption performance of the resultant NCM significantly enhances thanks to the coupling effects of multicomponent and multidimensions. The balanced impedance matching, enriched EMW attenuation behaviors and plentiful polarization loss combine to facilitate EMW absorption. The NCM3 realizes an impressive reflection loss as low as −55.7 dB (2.49 mm) and a wide effective absorption bandwidth (EAB) of 5.1 GHz (12.9–18.0 GHz) with a thin matching thickness of 1.51 mm. Moreover, the regulation of matching thickness could enable the EAB to almost cover the entire frequency range. Simulated radar cross section strongly verifies the practical application potential of NCM. This work provides a valuable guidance for the design and construction of EMW absorption materials with hierarchical architecture.
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