In this paper, a higher-order nonlinear Schrödinger–Maxwell–Bloch system with quintic terms is investigated, which describes the propagation of ultrashort optical pulses, up to the attosecond duration, in an erbium-doped fiber. Multi-soliton, breather and rogue-wave solutions are derived by virtue of the Darboux transformation and the limiting procedure. Features and interaction patterns of the solitons, breathers and rogue waves are discussed. (i) The solitonic amplitudes, widths and velocities are exhibited, and solitonic amplitudes and widths are proved to have nothing to do with the higher-order terms. (ii) The higher-order terms and frequency detuning affect the growth rate of periodic modulation and skewing angle for the breathers, except for the range of the frequency of modulation. (iii) The quintic terms and frequency detuning have the effects on the temporal duration for the rogue waves. (iv) Breathers are classified into two types, according to the range of the modulation instability. (v) Interaction between the two solitons is elastic. When the two solitons interact with each other, the periodic structure occurs, which is affected by the higher-order terms and frequency detuning. (vi) Interaction between the two Akhmediev-like breathers or two Kuznetsov–Ma-like solitons shows the different patterns with different ratios of the relative modulation frequencies, while the interaction area induced by the two breathers looks like a higher-order rogue wave.
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