Quantum Probe Research Articles

Quantum view of Li-ion high mobility at carbon-coated cathode interfaces

Lithium-ion batteries (LIBs) are among the most promising power sources for electric vehicles, portable electronics and smart grids. In LIBs, the cathode is a major bottleneck, with a particular reference to its low electrical conductivity and Li-ion diffusivity. The coating with carbon layers is generally employed to enhance the electrical conductivity and to protect the active material from degradation during operation. Here, we demonstrate that this layer has a primary role in the lithium diffusivity into the cathode nanoparticles. Positron is a useful quantum probe at the electroactive materials/carbon interface to sense the mobility of Li-ion. Broadband electrical spectroscopy demonstrates that only a small number of Li-ions are moving, and that their diffusion strongly depends on the type of carbon additive. Positron annihilation and broadband electrical spectroscopies are crucial complementary tools to investigate the electronic effect of the carbon phase on the cathode performance and Li-ion dynamics in electroactive materials.

Gate-Controlled Chiral Recognition and Spin Assessment with All-Electric Hybrid Quantum Wire-Based Transistors.

The search for inexpensive and all-electric tunable methods for portable and fast recognition and discrimination between various chiral enantiomers, mainly those found in the gas phase, has been one of the most challenging tasks in the field of analytical chemistry. The current article reports on a chiral sensitive electric architecture (CSEA) of a helical polyaniline (PANI)@carbon nanotube (CNT) hybrid quantum-wire based field effect transistor (FET) platform. The CSEA architecture exhibits gate-controlled-channel-chirality modulation for the selective distinction of Limonene (S(+)/R(-)) at ≈12V intervals. Typical gate-modulated selectivity of S(+)-Limonene and R(-)-Limonene using two opposite helically turned hybrids, namely as,S-PANI@CNT and R-PANI@CNT are 6.5 and 2.8, respectively. Theoretical analysis and modelling relates the gas-phase chiral quantum probe with spin-channel modulation in CNT byRashba spin-orbit interaction. This is achieved by applied gate voltage, CNT's unique curved surface, adsorbed chiral adatom induced scattering center on the curved graphitic lattice and helicoid field from a synthetically prepared helical PANI@CNT hybrid interface.

Colossal Nernst power factor in topological semimetal NbSb2

Today solid-state cooling technologies below liquid nitrogen boiling temperature (77 K), crucial to quantum information technology and probing quantum state of matter, are greatly limited due to the lack of good thermoelectric and/or thermomagnetic materials. Here, we report the discovery of colossal Nernst power factor of 3800 × 10-4 W m-1 K-2 under 5 T at 25 K and high Nernst figure-of-merit of 71 × 10-4 K-1 under 5 T at 20 K in topological semimetal NbSb2 single crystals. The observed high thermomagnetic performance is attributed to large Nernst thermopower and longitudinal electrical conductivity, and relatively low transverse thermal conductivity. The large and unsaturated Nernst thermopower is the result of the combination of highly desirable electronic structures of NbSb2 having compensated high mobility electrons and holes near Fermi level and strong phonon-drag effect. This discovery opens an avenue for exploring material option for the solid-state heat pumping below liquid nitrogen temperature.

Anti-Zeno purification of spin baths by quantum probe measurements

The quantum Zeno and anti-Zeno paradigms have thus far addressed the evolution control of a quantum system coupled to an immutable bath via non-selective measurements performed at appropriate intervals. We fundamentally modify these paradigms by introducing, theoretically and experimentally, the concept of controlling the bath state via selective measurements of the system (a qubit). We show that at intervals corresponding to the anti-Zeno regime of the system-bath exchange, a sequence of measurements has strongly correlated outcomes. These correlations can dramatically enhance the bath-state purity and yield a low-entropy steady state of the bath. The purified bath state persists long after the measurements are completed. Such purification enables the exploitation of spin baths as long-lived quantum memories or as quantum-enhanced sensors. The experiment involved a repeatedly probed defect center dephased by a nuclear spin bath in a diamond at low-temperature.

Untwining multiple parameters at the exclusive zero-coincidence points with quantum control

In this paper we address a special case of ‘sloppy’ quantum estimation procedures which happens in the presence of intertwined parameters. A collection of parameters are said to be intertwined when their imprinting on the quantum probe that mediates the estimation procedure, is performed by a set of linearly dependent generators. Under this circumstance the individual values of the parameters can not be recovered unless one tampers with the encoding process itself. An example is presented by studying the estimation of the relative time-delays that accumulate along two parallel optical transmission lines. In this case we show that the parameters can be effectively untwined by inserting a sequence of balanced beam splitters (and eventually adding an extra phase shift on one of the lines) that couples the two lines at regular intervals in a setup that remind us a generalized Hong-Ou-Mandel interferometer. For the case of two time delays we prove that, when the employed probe is the frequency-correlated biphoton state, the untwining occurs in correspondence of exclusive zero-coincidence (EZC) point. Furthermore we show the statistical independence of two time delays and the optimality of the quantum Fisher information at the EZC point. Finally we prove the compatibility of this scheme by checking the weak commutativity condition associated with the symmetric logarithmic derivative operators.

Nanodiamond-Based Optical-Fiber Quantum Probe for Magnetic Field and Biological Sensing.

Owing to the unique electronic spin properties, nitrogen-vacancy (NV) centers hosted in diamond have emerged as a powerful quantum tool for detecting various physical parameters and biological species. In this work, an optical-fiber quantum probe, configured by chemically modifying nanodiamonds on the surface of a cone fiber tip, is developed. Based on the continuous-wave optically detected magnetic resonance method and lock-in amplification technique, it is found that the sensing performance of probes can be engineered by varying the nanodiamond dispersion concentration and modification duration during the chemical modification process. Combined with a pair of magnetic flux concentrators, the magnetic field detection sensitivity has reached 0.57 nT/Hz1/2@1 Hz, a new record among the fiber magnetometers based on nanodiamonds. Taking Gd3+ as the demo, the capability of probes in paramagnetic species detection is also demonstrated experimentally. Our work provides a new approach to develop NV centers as quantum probes featuring high integration, multifunction, high sensitivity, etc.

Probing quantum many-body correlations by universal ramping dynamics

Ramping a physical parameter is one of the most common experimental protocols in studying a quantum system, and ramping dynamics has been widely used in preparing a quantum state and probing physical properties. Here, we present a novel method of probing quantum many-body correlation by ramping dynamics. We ramp a Hamiltonian parameter to the same target value from different initial values and with different velocities, and we show that the first-order correction on the finite ramping velocity is universal and path-independent, revealing a novel quantum many-body correlation function of the equilibrium phases at the target values. We term this method as the non-adiabatic linear response since this is the leading order correction beyond the adiabatic limit. We demonstrate this method experimentally by studying the Bose-Hubbard model with ultracold atoms in three-dimensional optical lattices. Unlike the conventional linear response that reveals whether the quasi-particle dispersion of a quantum phase is gapped or gapless, this probe is more sensitive to whether the quasi-particle lifetime is long enough such that the quantum phase possesses a well-defined quasi-particle description. In the Bose-Hubbard model, this non-adiabatic linear response is significant in the quantum critical regime where well-defined quasi-particles are absent. And in contrast, this response is vanishingly small in both superfluid and Mott insulators which possess well-defined quasi-particles. Because our proposal uses the most common experimental protocol, we envision that our method can find broad applications in probing various quantum systems.

Quantum transport of strongly interacting fermions in one dimension far out of equilibrium

In the study of quantum transport, much has been known about dynamics near thermal equilibrium. However, quantum transport far away from equilibrium is much less well understood---the linear response approximation does not hold for physics far out of equilibrium in general. In this work, motivated by recent cold atom experiments on probing quantum many-body dynamics of a one-dimensional XXZ spin chain, where a transition from ballistic to diffusive dynamics has been established by increasing the interaction strengths, we study the strong interaction limit of the one-dimensional spinless fermion model, which is dual to the XXZ spin chain. We develop a highly efficient computation algorithm for simulating the nonequilibrium dynamics of this system exactly, and examine the nonequilibrium dynamics starting from a density modulation quantum state. We find ballistic transport in this strongly correlated setting and show that a plane-wave description emerges at long-time evolution. We also observe a sharp distinction between transport velocities in short and long times as induced by interaction effects and provide a quantitative interpretation for the long-time transport velocity. We expect our results to shed light on the understanding of the dynamics of the XXZ spin chain in the strong interaction regime.

Average quantum coherence and its use in probing quantum phase transitions

We investigate the average quantum coherence (AQC) defined to be the coherence of a state averaged over all reference bases. This is a basis-independent measure and for any single-qubit state, it is solely determined by the length of the Bloch vector of that state. Concerning its use for probing quantum phase transitions (QPTs), it has the merit of being free of a careful choice of specific spins. We validate this through quantum renormalization of the AQC in the spin-chain models. The scaling analysis shows that the position of the extremum of the AQC susceptibility for each block approaches the QPT point exponentially with the increasing system size, and the AQC susceptibility at the QPT point becomes singular in the thermodynamic limit.

Possibility of detecting the gravity of an object frozen in a spatial superposition by the Zeno effect

While quantum probes surely feel gravity, no source of gravity has been prepared in a delocalized quantum state yet. Two basic questions need to be addressed: how to delocalize a mass sufficiently large to generate detectable gravity; and, once that state has been prepared, how to fight localization by decoherence. We propose to fight decoherence by freezing the source in the desired state through the Zeno effect. Successful implementation can be verified by scattering a probe in the effective potential generated by the source. Besides putting forward the idea, we provide an estimation of the values of the parameters required for the proposal to be feasible. Overall, the proposal seems as challenging as other existing ones, although the specific challenges are different (e.g. no entanglement needs to be preserved or detected, but the Zeno freezing must be implemented).

O2-induced emission color changing/sensing via the combination of red-emitting COF and blue-emitting halogen-bridging Cu(I) phosphor: In-situ synthesis and performance

Covalent organic frameworks (COFs) have shown virtues of structural diversity and porous diversity, due to their versatile organic building blocks. These advantages make COFs a promising host for O2 gas sensors. In this work, a porous COF (denoted as COF-X, X = Br or Cl) having halogen ions (Br or Cl ions) in its micropores was firstly synthesized as host, then Cu clusters [Cu2(PPh3)3X2] were in-situ synthesized. The obtained composite structure was discussed in detail focusing on its photophysical parameters and optical oxygen sensing performance. Probe doping ratio was determined as 2:1 (C162H120N18O12X4@C54H45X2Cu2P3, X = Br or Cl). Host COF-X showed red emission around 628 nm, while probe Cu2(PPh3)3X2 exhibited blue emission around 436 nm with lifetime of 5.21 μs and quantum yield of 0.41 under pure N2 atmosphere. Upon pure O2 atmosphere, probe Cu2(PPh3)3Br2 lifetime and quantum yield were decreased to 1.16 μs and 0.09. Probe emission intensity followed a linear calibration curve with maximum sensitivity of 20.25 (a.u.) and response/recovery time of 9/41 s. This sensitivity was by far the highest one among phosphorescent Cu(I)-based sensors. The relative emission intensity variation between dopant blue emission and host red emission led to an emission color change between blue (under pure N2 atmosphere) and red (under pure O2 atmosphere).

Optimal strategy for multiple-phase estimation under practical measurement with multimode NOON states

Quantum multiple parameter estimation can achieve an enhanced sensitivity beyond the classical limit. Although a theoretical ultimate sensitivity bound for multiple phase estimation is given by the quantum Cramer-Rao bound (QCRB), experimental implementations to saturate the QCRB typically require an impractical setup including entangled measurements. Since it is experimentally challenging to implement an entangled measurement, the practical sensitivity is given by the Cramer-Rao bound (CRB) relevant to the measurement probabilities. Here, we consider the problem of practical sensitivity bound for multiple phase estimation with quantum probe states and a measurement setup without entanglement, which consists of a beam splitter followed by the photon-number-resolving measurement. In this practical measurement scheme, we show that lower CRB can be achieved with a quantum probe state even with higher QCRB.

Coherent and Dephasing Spectroscopy for Single-Impurity Probing of an Ultracold Bath.

We report Ramsey spectroscopy on the clock states of individual Cs impurities immersed in an ultracold Rb bath. We record both the interaction-driven phase evolution and the decay of fringe contrast of the Ramsey interference signal to obtain information about bath density or temperature nondestructively. The Ramsey fringe is modified by a differential shift of the collisional energy when the two Cs states superposed interact with the Rb bath. This differential shift is directly affected by the mean gas density and the details of the Rb-Cs interspecies scattering length, affecting the phase evolution and the contrast of the Ramsey signal. Additionally, we enhance the temperature dependence of the phase shift preparing the system close to a low-magnetic-field Feshbach resonance where the s-wave scattering length is significantly affected by the collisional (kinetic) energy. Analyzing coherent phase evolution and decay of the Ramsey fringe contrast, we probe the Rb cloud's density and temperature. Our results point at using individual impurity atoms as nondestructive quantum probes in complex quantum systems.

Gaussian theory for estimating fluctuating perturbations with backaction-evading oscillator variables

We apply a Gaussian state formalism to track fluctuating perturbations that act on the position and momentum quadrature variables of a harmonic oscillator. Following a seminal proposal by Tsang and Caves [Phys. Rev. Lett. 105, 123601 (2010)], Einstein-Podolsky-Rosen correlations with the quadrature variables of an ancillary harmonic oscillator are leveraged to significantly improve the estimates as relevant sensor variables can be arbitrarily squeezed while evading adverse effects from the conjugate, anti-squeezed variables. Our real-time analysis of the continuous monitoring of the system employs a hybrid quantum-classical description of the quantum probe and the unknown classical perturbations, and it provides a general formalism to establish the achievements of the sensing scheme and how they depend on different parameters.

Mm-wave Rydberg-Rydberg transitions gauge intermolecular coupling in a molecular ultracold plasma.

Out-of-equilibrium, strong correlation in a many-body system can trigger emergent properties that act to constrain the natural dissipation of energy and matter. Signs of such self-organization appear in the avalanche, bifurcation, and quench of a state-selected Rydberg gas of nitric oxide to form an ultracold, strongly correlated ultracold plasma. Work reported here focuses on the initial stages of avalanche and quench and uses the mm-wave spectroscopy of an embedded quantum probe to characterize the intermolecular interaction dynamics associated with the evolution to plasma. Double-resonance excitation prepares a Rydberg gas of nitric oxide composed of a single selected state of principal quantum number, n0. Penning ionization, followed by an avalanche of electron-Rydberg collisions, forms a plasma of NO+ ions and weakly bound electrons, in which a residual population of n0 Rydberg molecules evolves to a state of high orbital angular momentum, ℓ. Predissociation depletes the plasma of low-ℓ molecules. Relaxation ceases and n0ℓ(2) molecules with ℓ ≥ 4 persist for very long times. At short times, varying excitation spectra of mm-wave Rydberg-Rydberg transitions mark the rate of electron-collisional ℓ-mixing. Deep depletion resonances that persist for long times signal energy redistribution in the basis of central-field Rydberg states. The widths and asymmetries of Fano line shapes witness the degree to which coupling in the arrested bath (i) broadens the allowed transition and (ii) mixes the local network of levels in the ensemble.

Optimal Estimation of Conjugate Shifts in Position and Momentum by Classically Correlated Probes and Measurements

Multiparameter estimation is necessary for force sensing due to simultaneous and nontrivial small changes of position and momentum. The design of quantum probes that allow simultaneous estimation of all parameters is therefore an important task. The optimal methods for estimation of the conjugate changes of position and momentum of quantum harmonic oscillator employ probes in entangled or quantum non-Gaussian states. We show that the same results can be obtained in a significantly more feasible fashion by employing independent sets of differently squeezed Gaussian states classically correlated with position or momentum measurements. This result demonstrates an unexplored power of a classical correlation between the probe states and measurements directly applicable to force sensing.

Practical Sensitivity Bound for Multiple Phase Estimation with Multi‐Mode N00N$N00N$ States

AbstractQuantum enhanced multiple phase estimation is essential for various applications in quantum sensors and imaging. For multiple phase estimation, the sensitivity enhancement is dependent on both quantum probe states and measurement. It is known that multi‐mode states can outperform other probe states for estimating multiple phases. However, it is generally not feasible in practice to implement an optimal measurement to achieve the quantum Cramer–Rao bound (QCRB) under a practical measurement scheme using a multi‐mode beam splitter in interferometric phase estimation. Here, a strategy to achieve the best practical sensitivity by optimizing both mode‐amplitudes of multi‐mode states and a split ratio of a multi‐mode beam splitter is investigated. Then, it is experimentally demonstrated that the best sensitivity is achieved when an amplitude‐balanced multi‐mode state and a multi‐mode beam splitter with an unbalanced ratio are used in three‐mode interferometric phase estimation. The results show that the lower QCRB cannot guarantee better sensitivity under a practical measurement scheme, thus it is more desirable to enhance the practical sensitivity rather than the QCRB. It is believed that this strategy can provide a powerful tool for practical applications in multiple phase estimation.

Glioblastoma Associated Natural Killer Cell EVs Generating Tumour-Specific Signatures: Noninvasive GBM Liquid Biopsy with Self-Functionalized Quantum Probes.

Diagnosis of glioblastoma (GBM) poses a recurring struggle due to many factors, including the presence of the blood-brain barrier (BBB) in addition to the significant tumor heterogeneity. Natural killer (NK) cells of the innate immune system are the primary immune surveillance mechanism for GBM and identify GBM tumors without any previous sensitization. The metabolic reprogramming of NK cells during GBM association is expected to be reflected in its extracellular vesicles. Therefore, tracking the activity of NK cell vesicles in circulation (circulating immune vesicles, CIVs) has great potential for accurate GBM diagnosis. However, identification GBM associated CIVs in circulation is immensely challenging as there is no availability of clinically validated GBM-specific circulating biomarkers. Here, we present GBM associated CIV profiling for noninvasive GBM diagnosis. We investigated the feasibility of using the signals derived from GBM associated CIVs as a de novo methodology for GBM diagnosis. An ultrasensitive sensor and a marker-free approach were essential for the detection of rare signals of GBM associated CIVs. For this purpose, we designed GBM ImmunoProfiler platform using scalable ultrafast laser multiphoton ionization mechanism and adopted surface enhanced Raman spectroscopy (SERS) ensuring simultaneous detection of multiple CIV signals to identify GBM. We experimentally demonstrated that GBM associated CIVs carry unique, tumor-specific signals. The features of GBM associated CIVs were explored through machine learning identifying its similarity with GBM patient blood (without cell isolation) using a very small amount of peripheral blood (5 μL) with 96.82% sensitivity and 100% specificity. In addition, we demonstrated that a tumor associated CIV profile can classify between multiple brain cancer types (astrocytoma, oligodendroglioma, and glioblastoma). We also experimentally demonstrated significant variation in the immune checkpoint protein expression (PDL-1 and CTLA-4) between GBM associated CIVs and uninteracted CIVs. Preclinical analysis with serum specimens of GBM patients showed the possibility of using our technology for minimally invasive GBM diagnosis. With clinical validation, our technology has potential to improve GBM diagnostics with a useful, minimally invasive GBM liquid biopsy.

Statistics of projective measurement on a quantum probe as a witness of noncommutativity of algebra of a probed system

We consider a quantum probe $P$ undergoing pure dephasing due to its interaction with a quantum system $S$. The dynamics of $P$ is then described by a well-defined sub-algebra of operators of $S,$ i.e. the "accessible" algebra on $S$ from the point of view of $P.$ We consider sequences of $n$ measurements on $P,$ and investigate the relationship between Kolmogorov consistency of probabilities of obtaining sequences of results with various $n,$ and commutativity of the accessible algebra. For a finite-dimensional $S$ we find conditions under which the Kolmogorov consistency of measurement on $P,$ given that the state of $S$ can be arbitrarily prepared, is equivalent to the commutativity of this algebra. These allow us to describe witnesses of nonclassicality (understood here as noncommutativity) of part of $S$ that affects the probe. For $P$ being a qubit, the witness is particularly simple: observation of breaking of Kolmogorov consistency of sequential measurements on a qubit coupled to $S$ means that the accessible algebra of $S$ is noncommutative.

Advantage of Coherent States in Ring Resonators over Any Quantum Probe Single-Pass Absorption Estimation Strategy.

Quantum states of light have been shown to enhance precision in absorption estimation over classical strategies. By exploiting interference and resonant enhancement effects, we show that coherent-state probes in all-pass ring resonators can outperform any quantum probe single-pass strategy even when normalized by the mean input photon number. We also find that under optimal conditions coherent-state probes equal the performance of arbitrarily bright pure single-mode squeezed probes in all-pass ring resonators.