Abstract

The search for inexpensive and all-electric tunable methods for portable and fast recognition and discrimination between various chiral enantiomers, mainly those found in the gas phase, has been one of the most challenging tasks in the field of analytical chemistry. The current article reports on a chiral sensitive electric architecture (CSEA) of a helical polyaniline (PANI)@carbon nanotube (CNT) hybrid quantum-wire based field effect transistor (FET) platform. The CSEA architecture exhibits gate-controlled-channel-chirality modulation for the selective distinction of Limonene (S(+)/R(-)) at ≈12V intervals. Typical gate-modulated selectivity of S(+)-Limonene and R(-)-Limonene using two opposite helically turned hybrids, namely as,S-PANI@CNT and R-PANI@CNT are 6.5 and 2.8, respectively. Theoretical analysis and modelling relates the gas-phase chiral quantum probe with spin-channel modulation in CNT byRashba spin-orbit interaction. This is achieved by applied gate voltage, CNT's unique curved surface, adsorbed chiral adatom induced scattering center on the curved graphitic lattice and helicoid field from a synthetically prepared helical PANI@CNT hybrid interface.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call