Quantum Dots In Proximity Research Articles

Tunable Floquet Majorana fermions in driven coupled quantum dots

We propose a system of coupled quantum dots in proximity to a superconductor and driven by separate ac potentials to realize and detect Floquet Majorana fermions. We show that the appearance of Floquet Majorana fermions can be finely controlled in the expanded parameter space of the drive frequency, amplitude, and phase difference across the two dots. While these Majorana fermions are not topologically protected, the highly tunable setup provides a realistic system for observing the exotic physics associated with Majorana fermions as well as their dynamical generation and manipulation.

Wavelength, Concentration, and Distance Dependence of Nonradiative Energy Transfer to a Plane of Gold Nanoparticles

Nonradiative energy transfer to metal nanoparticles is a technique used for optical-based distance measurements which is often implemented in sensing. Both Förster resonant energy transfer (FRET) and nanometal surface energy transfer (NSET) mechanisms have been proposed for emission quenching in proximity to metal nanoparticles. Here quenching of emission of colloidal quantum dots in proximity to a monolayer of gold nanoparticles is investigated. Five differently sized CdTe quantum dots are used to probe the wavelength dependence of the quenching mechanism as their emission peak moves from on resonance to off resonance with respect to the localized surface plasmon peak of the gold nanoparticle layer. The gold nanoparticle concentration and distance dependences of energy transfer are discussed. Photoluminescence quenching and lifetime data are analyzed using both FRET and NSET models and the extracted characteristic distances are compared with theory. Good agreement with FRET theory has been found for quantum dots with emission close to the localized surface plasmon resonance, though larger than expected Förster radii are observed for quantum dots with emission red-shifted with respect to the localized surface plasmon peak. Closer agreement between experimental and theoretical characteristic distances can be found across the full wavelength range within a NSET approach.

Single molecule photophysics near metallic nanostructures.

Metal-enhanced fluorescence (MEF) is useful in single molecule detection (SMD) by increasing the photostability, brightness and increase in radiative decay rates of fluorophores. We have investigated MEF from an individual fluorophore tethered to a single silver nanoparticle and also a single fluorophore between a silver dimer. The fluorescence lifetime results revealed a near-field interaction mechanism of fluorophore with the metal particle. Finite-difference time-domain (FDTD) calculations were employed to study the distribution of electric field near the metal monomer and dimer. The coupling effect of metal particles on the fluorescence enhancement was studied. We have also investigated the photophysics of FRET near metal nanoparticles and our preliminary results suggest an enhanced FRET efficiency in the presence of a metal nanoparticle. In total, our results demonstrate improved detectability at the single molecule level for a variety of fluorophores and quantum dots in proximity to the silver nanoparticles due to the near-field metal-fluorophore interactions.

Tunable energy transfer efficiency based on the composite of mixed CdSe quantum dots and elastomeric film

We demonstrate a facile and general approach to investigate the dependence of energy transfer on the separation distance between proximal mixed-size quantum dots. Without varying the mixed concentrations, the tunable energy transfer efficiency is achieved based on the composite of mixed quantum dots and elastomeric film by utilizing the inherent nature of the flexibility of elastomeric film. To demonstrate our working principle, the composite of mixed-size CdSe quantum dots and poly-dimethylsiloxane has been studied. The results clearly show that the energy transfer process between proximal quantum dots follows the Förster resonance energy transfer, in which the dependence of the transfer efficiency E as a function of the donor-acceptor distance R obeys E=1∕[1+(R∕R0)6].

Large Enhancement of Fluorescence Efficiency from CdSe/ZnS Quantum Dots Induced by Resonant Coupling to Spatially Controlled Surface Plasmons

Nanoengineered fluorescent response is reported from semiconductor core-shell (CdSe/ZnS) quantum dots in proximity to the surface plasmon polariton field of periodic Ag nanoparticle arrays. Tuning the surface plasmon polariton resonance to the quantum dot exciton emission band results in an enhancement of up to approximately 50-fold in the overall fluorescence efficiency, in a design where each Ag nanoparticle is interconnected by a continuous Ag thin film. Propagating modes of surface plasmon resonances have a direct impact on the fluorescence enhancement.