Quantum Critical Regime Research Articles

Emergent Properties of the Periodic Anderson Model: A High-Resolution, Real-Frequency Study of Heavy-Fermion Quantum Criticality

We study paramagnetic quantum criticality in the periodic Anderson model (PAM) using cellular dynamical mean-field theory (CDMFT), with the numerical renormalization group (NRG) as a cluster impurity solver. The PAM describes itinerant c electrons hybridizing with a lattice of localized f electrons. At zero temperature, it exhibits a much-studied quantum phase transition from a Kondo phase to a Ruderman-Kittel-Kasuya-Yosida (RKKY) phase when the hybridization is decreased through a so-called Kondo breakdown quantum critical point (KB QCP). There, Kondo screening of f spins by c electrons breaks down, so that f excitations change their character from somewhat itinerant to mainly localized, while c excitations remain itinerant. Building on , which interpreted the KB transition as an orbital-selective Mott transition, we here elucidate its nature in great detail by performing a high-resolution, real-frequency study of various dynamical quantities (susceptibilities, self-energies, and spectral functions). NRG allows us to study the quantum critical regime governed by the QCP and located between two temperature scales, TFL<TNFL. In this regime, we find fingerprints of non-Fermi-liquid (NFL) behavior in several dynamical susceptibilities. Surprisingly, CDMFT self-consistency is essential to stabilize the QCP and the NFL regime. The Fermi-liquid (FL) scale TFL decreases toward and vanishes at the KB QCP; at temperatures below TFL, FL behavior emerges. At T=0, we find the following properties. The KB transition is continuous. The f quasiparticle weight decreases continuously as the transition is approached from either side, vanishing only at the KB QCP. Therefore, the quasiparticle weight of the f band is nonzero not only in the Kondo phase, but also in the RKKY phase; hence, the FL quasiparticles comprise c f electrons in both phases. The Fermi surface (FS) volumes in the two phases differ, implying a FS reconstruction at the KB QCP. Whereas the large-FS Kondo phase has a two-band structure as expected, the small-FS RKKY phase unexpectedly has a three-band structure. We provide a detailed analysis of quasiparticle properties of both the Kondo and, for the first time, also the RKKY phase and uncover their differences. The FS reconstruction is accompanied by the appearance of a Luttinger surface on which the f self-energy diverges. The volumes of the Luttinger and Fermi surfaces are related to the charge density by a generalized Luttinger sum rule. We interpret the small FS volume and the emergent Luttinger surface as evidence for f-electron fractionalization in the RKKY phase. Finally, we compute the temperature dependence of the Hall coefficient and the specific heat, finding good qualitative agreement with experiments. Published by the American Physical Society 2024

A Quenched Disorder in the Quantum-Critical Superconductor CeCoIn5.

Emergent inhomogeneous electronic phases in metallic quantum systems are crucial for understanding high-Tc superconductivity and other novel quantum states. In particular, spin droplets introduced by nonmagnetic dopants in quantum-critical superconductors (QCSs) can lead to a novel magnetic state in superconducting phases. However, the role of disorders caused by nonmagnetic dopants in quantum-critical regimes and their precise relation with superconductivity remain unclear. Here, the systematic evolution of a strong correlation between superconductive intertwined electronic phases and antiferromagnetism in Cd-doped CeCoIn5 is presented by measuring current-voltage characteristics under an external pressure. In the low-pressure coexisting regime where antiferromagnetic (AFM) and superconducting (SC) orders coexist, the critical current (Ic ) is gradually suppressed by the increasing magnetic field, as in conventional type-II superconductors. At pressures higher than the critical pressure where the AFM order disappears, Ic remarkably shows a sudden spike near the irreversible magnetic field. In addition, at high pressures far from the critical pressure point, the peak effect is not suppressed, but remains robust over the whole superconducting region. These results indicate that magnetic islands are protected around dopant sites despite being suppressed by the increasingly correlated effects under pressure, providing a new perspective on the role of quenched disorders in QCSs.

Correlation induced instability in topological nodal-line semimetal ZrSiS

Quantum phase transition hosts a quantum criticality around which the collective low-energy excitations are governed by quantum fluctuations. At this quantum critical regime, fluctuations alter the quasiparticle characteristics introducing some instabilities in the system. The experimental signatures of quantum criticality in topological Dirac materials are sparse. Here, we report the transport studies on nodal line semimetal ZrSiS, which is predicted to own excitonic instability at quantum criticality. Our quantum oscillation studies demonstrate a significant change in Berry phase at higher magnetic fields revealing a field-induced gap modification at the nodal line. Notably, the quasiparticle effective mass executes unique field-dependent oscillations, which is unexplainable from present theories. The temperature dependent oscillation amplitude dramatically departs from conventional Lifshitz–Kosevich theory. These unusual phenomena along with a zero field resistivity upturn collectively suggest the possibility of ZrSiS lying at the excitonic instability. Our findings will engender the systematic exploration of correlation induced phenomenon in topological materials.

Thermal bath effects in quantum quenches within quantum critical regimes

Thermal bath effects in quantum quenches within quantum critical regimes

Giant magnetoresistance of Dirac plasma in high-mobility graphene

The most recognizable feature of graphene’s electronic spectrum is its Dirac point, around which interesting phenomena tend to cluster. At low temperatures, the intrinsic behaviour in this regime is often obscured by charge inhomogeneity1,2 but thermal excitations can overcome the disorder at elevated temperatures and create an electron–hole plasma of Dirac fermions. The Dirac plasma has been found to exhibit unusual properties, including quantum-critical scattering3–5 and hydrodynamic flow6–8. However, little is known about the plasma’s behaviour in magnetic fields. Here we report magnetotransport in this quantum-critical regime. In low fields, the plasma exhibits giant parabolic magnetoresistivity reaching more than 100 per cent in a magnetic field of 0.1 tesla at room temperature. This is orders-of-magnitude higher than magnetoresistivity found in any other system at such temperatures. We show that this behaviour is unique to monolayer graphene, being underpinned by its massless spectrum and ultrahigh mobility, despite frequent (Planckian limit) scattering3–5,9–14. With the onset of Landau quantization in a magnetic field of a few tesla, where the electron–hole plasma resides entirely on the zeroth Landau level, giant linear magnetoresistivity emerges. It is nearly independent of temperature and can be suppressed by proximity screening15, indicating a many-body origin. Clear parallels with magnetotransport in strange metals12–14 and so-called quantum linear magnetoresistance predicted for Weyl metals16 offer an interesting opportunity to further explore relevant physics using this well defined quantum-critical two-dimensional system.

Variational quantum simulation of the quantum critical regime

The quantum critical regime marks a zone in the phase diagram where quantum fluctuation around the critical point plays a significant role at finite temperatures. While it is of great physical interest, simulation of the quantum critical regime can be difficult on a classical computer due to its intrinsic complexity. Herein, we propose a variational approach, which minimizes the variational free energy, to simulate and locate the quantum critical regime on a quantum computer. The variational quantum algorithm adopts an ansatz by performing an unitary operator on a product of a single-qubit mixed state, in which the entropy can be analytically obtained from the initial state, and thus the free energy can be accessed conveniently. With numeral simulation, using the one-dimensional Kitaev model as a demonstration we show that the quantum critical regime can be identified by accurately evaluating the temperature crossover line. Moreover, the dependencies of both the correlation length and the phase coherence time with temperature are evaluated for the thermal states. Our work suggests a practical way as well as a first step for investigating quantum critical systems at finite temperatures on quantum devices with few qubits.

Out-of-equilibrium finite-size scaling in generalized Kibble-Zurek protocols crossing quantum phase transitions in the presence of symmetry-breaking perturbations

We study the effects of symmetry-breaking perturbations in the out-of-equilibrium quantum dynamics of many-body systems slowly driven by a time-dependent symmetry-preserving parameter, across the quantum critical regime associated with a continuous quantum transition (CQT). For this purpose, we analyze the out-of-equilibrium dynamics arising from generalized Kibble-Zurek (KZ) protocols, within a dynamic renormalization-group framework allowing for finite-size systems. We show that the time dependence of generic observables develops an out-of-equilibrium finite-size scaling (FSS) behavior, arising from the interplay between the timescale ${t}_{s}$ of the parameter variations in the KZ protocol, the size $L$ of the system, and the strength $h$ of the symmetry-breaking perturbation, in the limit of large ${t}_{s}$ and $L$. Moreover, scaling arguments based on the first-order adiabatic approximation of slow variations in quantum systems allow us to characterize the approach to the adiabatic regimes for some limits of the model parameters (for example, when we take ${t}_{s}\ensuremath{\rightarrow}\ensuremath{\infty}$ before $L\ensuremath{\rightarrow}\ensuremath{\infty}$), predicting asymptotic power-law suppressions of the nonadiabatic behaviors in the adiabatic limits. This out-of-equilibrium FSS is supported by numerical analyses for the paradigmatic quantum Ising chain along generalized KZ protocols, with a time-dependent transverse field crossing its CQT, in the presence of a static longitudinal field breaking the ${\mathbb{Z}}_{2}$ symmetry.

Quantum Phase Transition in the One-Dimensional Water Chain.

The concept of quantum phase transitions (QPTs) plays a central role in the description of condensed matter systems. In this Letter, we perform high-quality wave-function-based simulations to demonstrate the existence of a quantum phase transition in a crucially relevant molecular system, namely, water, forming linear chains of rotating molecules. We determine various critical exponents and reveal the water chain QPT to belong to the (1+1)-dimensional Ising universality class. Furthermore, the effect of breaking symmetries is examined, and it is shown that, by breaking the inversion symmetry, the ground state degeneracy of the ordered quantum phase is lifted to yield two many-body states with opposite polarization. The possibility of forming ferroelectric phases together with a thermal stability of the quantum critical regime up to ∼10 K makes the linear water chain a promising candidate as a platform for quantum devices.

Superconductor-Insulator Transition in a Non-Fermi Liquid.

We present a model of a strongly correlated system with a non-Fermi liquid high temperature phase. Its ground state undergoes an insulator to superconductor quantum phase transition (QPT) as a function of a pairing interaction strength. Both the insulator and the superconductor are originating from the same interaction mechanism. The resistivity in the insulating phase exhibits the activation behavior with the activation energy, which goes to zero at the QPT. This leads to a wide quantum critical regime with an algebraic temperature dependence of the resistivity. Upon raising the temperature in the superconducting phase, the model exhibits a finite temperature phase transition to a Bose metal phase, which separates the superconductor from the non-Fermi liquid metal.

Finite-Size Scaling Theory at a Self-Dual Quantum Critical Point

The nondivergence of the generalized Grüneisen ratio (GR) at a quantum critical point (QCP) has been proposed to be a universal thermodynamic signature of self-duality. We study how the Kramers–Wannier-type self-duality manifests itself in the finite-size scaling behavior of thermodynamic quantities in the quantum critical regime. While the self-duality cannot be realized as a unitary transformation in the total Hilbert space for the Hamiltonian with the periodic boundary condition, it can be implemented in certain symmetry sectors with proper boundary conditions. Therefore, the GR and the transverse magnetization of the one-dimensional transverse-field Ising model exhibit different finite-size scaling behaviors in different sectors. This implies that the numerical diagnosis of self-dual QCP requires identification of the proper symmetry sectors.

Probing quantum many-body correlations by universal ramping dynamics

Ramping a physical parameter is one of the most common experimental protocols in studying a quantum system, and ramping dynamics has been widely used in preparing a quantum state and probing physical properties. Here, we present a novel method of probing quantum many-body correlation by ramping dynamics. We ramp a Hamiltonian parameter to the same target value from different initial values and with different velocities, and we show that the first-order correction on the finite ramping velocity is universal and path-independent, revealing a novel quantum many-body correlation function of the equilibrium phases at the target values. We term this method as the non-adiabatic linear response since this is the leading order correction beyond the adiabatic limit. We demonstrate this method experimentally by studying the Bose-Hubbard model with ultracold atoms in three-dimensional optical lattices. Unlike the conventional linear response that reveals whether the quasi-particle dispersion of a quantum phase is gapped or gapless, this probe is more sensitive to whether the quasi-particle lifetime is long enough such that the quantum phase possesses a well-defined quasi-particle description. In the Bose-Hubbard model, this non-adiabatic linear response is significant in the quantum critical regime where well-defined quasi-particles are absent. And in contrast, this response is vanishingly small in both superfluid and Mott insulators which possess well-defined quasi-particles. Because our proposal uses the most common experimental protocol, we envision that our method can find broad applications in probing various quantum systems.

The numerical value for a universal quantity of a two-dimensional dimerized quantum antiferromagnet

The numerical value of a universal quantity associated with the quantum critical regime, namely χuc2/T, for a two-dimensional (2D) dimerized spin-1/2 antiferromagnet is calculated using the quantum Monte Carlo simulations (QMC). Here χu, c, and T are the uniform susceptibility, the spin-wave velocity, and the temperature, respectively. By simulating large lattices at moderately low temperatures, we find χuc2/T∼0.32. Our estimation of χuc2/T deviates from the related analytic prediction but agrees with recent numerical calculations of other 2D dimerized spin-1/2 antiferromagnets.

Work statistics and thermal phase transitions.

Many previous studies have demonstrated that work statistics can exhibit certain singular behaviors in the quantum critical regimes of many-body systems at zero or very low temperatures. However, as the temperature increases, it is commonly believed that such singularities will vanish. Contrary to this common recognition, we report a nonanalytic behavior of the averaged work done, which occurs at finite temperature, in the Dicke model as well as the Lipkin-Meshkov-Glick model subjected to the sudden quenches of their work parameters. It is revealed that work statistics can be viewed as a signature of the thermal phase transition when the quenched parameters are tuned across the critical line that separates two different thermal phases.

Violation of the rule of parsimony: Mixed local moment and itinerant Fe magnetism in Fe3GeN

Ternary iron nitrides are of considerable interest due to their diverse magnetic properties. We find, based on first principles calculations, that the relatively minor structural distortion from the cubic antiperovskite structure in Fe$_3$GeN leads to unusual magnetic behavior. In particular, there is a separation into Fe sites with very different magnetic behaviors, specifically a site with Fe atoms having a stable local moment and a site where the Fe shows characteristics of much more itinerant behavior. This shows a remarkable flexibility of the Fe magnetic behavior in these nitrides and points towards the possibility of systems where minor structural and chemical changes can lead to dramatic changes in magnetic properties. The results suggest that, analogously to oxide perovskite materials, modulation of magnetic properties via chemical or strain control of octahedral rotation may be feasible. This may then lead to approaches for tuning magnetism to realize properties of interest, for example tuning magnetic transitions to quantum critical regimes or to proximity to metamagnetic transitions of interest for devices.

Spin-liquid signatures in the quantum critical regime of pressurized CePdAl

CePdAl is a prototypical frustrated Kondo lattice with partial long-range order (LRO) at ${T}_{\mathrm{N}}=2.7$ K. Previous bulk experiments under hydrostatic pressure found signatures for a quantum critical regime that extends from ${p}_{\mathrm{c}}\ensuremath{\approx}0.9$ GPa, where LRO disappears, up to $\ensuremath{\sim}1.7$ GPa. We employed extensive muon spin relaxation and rotation experiments under pressure. The continuous and complete suppression of LRO at ${p}_{\mathrm{c}}$ is confirmed. Above ${T}_{\mathrm{N}}(p)$ and beyond ${p}_{\mathrm{c}}$, an additional crossover scale ${T}^{*}(p)$ characterizes the change from pure to stretched exponential relaxation in zero field. Remarkably, ${T}^{*}(p)$ agrees with previously determined signatures of entropy accumulation above LRO. This coincidence microscopically evidences fluctuating frustrated spins at $T\ensuremath{\le}{T}^{*}$ with spin-liquid behavior. Power-law divergences of the temperature and longitudinal field dependences of the relaxation rate, with time-field scaling, at pressures between ${p}_{c}$ and 1.7 GPa characterize this regime as quantum critical.

Nematic Quantum Criticality in Dirac Systems.

We investigate nematic quantum phase transitions in two different Dirac fermion models. The models feature twofold and fourfold, respectively, lattice rotational symmetries that are spontaneously broken in the ordered phase. Using negative-sign-free quantum MonteCarlo simulations and an ε-expansion renormalization group analysis, we show that both models exhibit continuous phase transitions. In contrast to generic Gross-Neveu dynamical mass generation, the quantum critical regime is characterized by large velocity anisotropies, with fixed-point values being approached very slowly. Both experimental and numerical investigations will not be representative of the infrared fixed point, but of a quasiuniversal regime where the drift of the exponents tracks the velocity anisotropy.

Quantum Gutzwiller approach for the two-component Bose-Hubbard model

We study the effects of quantum fluctuations in the two-component Bose-Hubbard model generalizing to mixtures the quantum Gutzwiller approach introduced recently in [Phys. Rev. Research 2, 033276 (2020)]. As a basis for our study, we analyze the mean-field ground-state phase diagram and spectrum of elementary excitations, with particular emphasis on the quantum phase transitions of the model. Within the quantum critical regimes, we address both the superfluid transport properties and the linear response dynamics to density and spin probes of direct experimental relevance. Crucially, we find that quantum fluctuations have a dramatic effect on the drag between the superfluid species of the system, particularly in the vicinity of the paired and antipaired phases absent in the usual one-component Bose-Hubbard model. Additionally, we analyse the contributions of quantum corrections to the one-body coherence and density/spin fluctuations from the perspective of the collective modes of the system, providing results for the few-body correlations in all the regimes of the phase diagram.

Quantum many-body scars and quantum criticality

In this letter, we study the PXP Hamiltonian with an external magnetic field that exhibits both quantum scar states and quantum criticality. It is known that this model hosts a series of quantum many-body scar states violating quantum thermalization at zero magnetic field, and it also exhibits an Ising quantum phase transition driven by finite magnetic field. Although the former involves the properties of generic excited states and the latter concerns the low-energy physics, we discover two surprising connections between them, inspired by the observation that both states possess log-volume law entanglement entropies. First, we show that the quantum many-body scar states can be tracked to a set of quantum critical states, whose nature can be understood as pair-wisely occupied Fermi sea states. Second, we show that the partial violation of quantum thermalization diminishes in the quantum critical regime. We envision that these connections can be extended to general situations and readily verified in existing cold atom experimental platforms.

Critical Scaling of Entropy and Thermal Drude Weight in Anisotropic Heisenberg Antiferromagnets: A Thermodynamic Quest for Quantum Criticality

Up to now, probing the quantum phase transition (QPT) and quantum critical (QC) phenomena at finite temperatures in one-dimensional (1D) spin systems still lacks an in-depth understanding. Herein, we study the QPT and thermodynamics of 1D spin-1/2 anisotropic Heisenberg antiferromagnetic chains by Green’s function theory. The quantum phase diagram is renormalized by the anisotropy (∆), which manifests a quantum critical point (QCP) hc = 1 + ∆ signaling the transition from gapless Tomonaga–Luttinger liquid (TLL) to gapped ferromagnetic (FM) state, demonstrated by the magnetic entropy and thermal Drude weight. At low temperatures, it is shown that two crossover temperatures fan out a QC regime and capture the QCP via the linear extrapolation to zero temperature. In addition, around QCP, the QC scaling is performed by analyzing the entropy and thermal Drude weight to extract the critical exponents (α, δ, and β) that fulfill the Essamm–Fisher scaling law, which provides a novel thermodynamic means to detect QPT for experiment. Furthermore, scaling hypothesis equations with two rescaled manners are proposed to testify the scaling analysis, for which all the data points fall on a universal curve or two independent branches for the plot against rescaled field or temperature, implying the self-consistency and reliability of the obtained critical exponents.

Eigenstate entanglement scaling for critical interacting spin chains

With increasing subsystem size and energy, bipartite entanglement entropies of energy eigenstates cross over from the groundstate scaling to a volume law. In previous work, we pointed out that, when strong or weak eigenstate thermalization (ETH) applies, the entanglement entropies of all or, respectively, almost all eigenstates follow a single crossover function. The crossover functions are determined by the subsystem entropy of thermal states and assume universal scaling forms in quantum-critical regimes. This was demonstrated by field-theoretical arguments and the analysis of large systems of non-interacting fermions and bosons. Here, we substantiate such scaling properties for integrable and non-integrable interacting spin-1/2 chains at criticality using exact diagonalization. In particular, we analyze XXZ and transverse-field Ising models with and without next-nearest-neighbor interactions. Indeed, the crossover of thermal subsystem entropies can be described by a universal scaling function following from conformal field theory. Furthermore, we analyze the validity of ETH for entanglement in these models. Even for the relatively small system sizes that can be simulated, the distributions of eigenstate entanglement entropies are sharply peaked around the subsystem entropies of the corresponding thermal ensembles.