Motivated by the phenomenon that compatible Poisson structures on a cluster algebra play a key role on its quantization (that is, quantum cluster algebra), we introduce the 2nd-stage quantization of a quantum cluster algebra, which means the correspondence between compatible Poisson structures of the quantum cluster algebra and its 2nd-stage quantized cluster algebras. Based on this observation, we find that a quantum cluster algebra possesses a mutually alternating quantum cluster algebra such that their 2nd-stage quantization can be essentially the same.As an example, we give the 2nd-stage quantized cluster algebra Ap,q(SL(2)) of FunC(SLq(2)) in §7.1 and show that it is a non-trivial 2nd-stage quantization, which may be realized as a parallel supplement to two parameters quantization of the general quantum group. As another example, we present a class of quantum cluster algebras with coefficients which possess a non-trivial 2nd-stage quantization. In particular we obtain a class of quantum cluster algebras from surfaces with coefficients which possess non-trivial 2nd-stage quantization.Finally, we prove that the compatible Poisson structure of a quantum cluster algebra without coefficients is always a locally standard Poisson structure. Following this, it is shown that the 2nd-stage quantization of a quantum cluster algebra without coefficients is in fact trivial.
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