Pyroxene Megacrysts Research Articles

Meteoric depositions on a forest in southern Sardinia (Italy)

A strontium and neodymium isotopic investigation of plagioclase-rich cumulate rocks in the 1.43 Ga Laramie anorthosite complex (LAC) provides new insights into the evolution of magma chambers and underlying magma plumbing systems during the crystallization of Proterozoic anorthosites. The 725 km2 LAC intruded the boundary between Archean rocks of the Wyoming Province in the north and Proterozoic island arc terranes in the south, the Cheyenne belt, at pressures of 3–4 kilobars. Initial strontium and εND isotopic ratios from the three large composite anorthositic intrusions (Poe Mountain, Chugwater, and Snow Creek) and late troctolitic intrusions range from 0.7034–0.7055 and +0.9 to −4.9, respectively. The isotopic ratios in the cumulates vary as a result of (1) the isotopic composition of the parental mantle-derived high-Al gabbroic magmas, (2) the amount of contamination by Archean rocks during ascent through the crust, and (3) mixing of replenishing magmas and resident magmas with different isotopic compositions in the magma chamber at the final level of emplacement.Strontium isotopic and normative An variations across the 5–7 km thick stratigraphic section of layered plagioclase-rich cumulates in the 200 km2 Poe Mountain anorthosite indicate that multiple inputs of magma are needed to construct even relatively small intrusions in Proterozoic anorthosites. The earliest and stratigraphically lowest intrusion was emplaced as a plagioclase-rich magma that crystallized large volumes of compositionally homogeneous anorthosite. At least three subsequent chamber-wide episodes of magma replenishment, followed by mixing, are indicated by abrupt shifts in ISr and/or normative An in the stratigraphically higher levels of the Poe Mountain anorthosite. Strontium and neodymium isotopic disequilibrium between a high-Al clinopyroxene megacryst and the layered cumulates is consistent with a high-pressure origin for Al-rich pyroxene megacrysts in Proterozoic anorthosites. The megacryst crystallized in a magma chamber at pressures of 10–12 kilobars from relatively uncontaminated basaltic parent magma (high-Al gabbro) and was transported through the crust in progressively contaminated anorthositic magma.The range of observed isotopic compositions in the anorthositic rocks is nearly identical to that of high-Al gabbroic dikes in the LAC, supporting the proposition that high-Al gabbros are parental to anorthosite (Mitchell et al., 1995). The isotopic data require that the anorthositic parental magmas were contaminated during ascent through the crust by Archean orthogneisses and/or metapelitic rocks. Decreasing ISr and increasing εNd with a relative decrease in age of the intrusions (Snow Creek → Poe Mountain/Chugwater → troctolites) indicates that the magma conduit became increasingly insulated from crustal contamination over time.This study indicates that the strontium and neodymium isotopic systems can be used to distinguish between processes that occurred at lower crustal/upper mantle pressures, during the ascent of magma diapirs, and within individual magma chambers in Proterozoic anorthosites, and underscores the need for stratigraphic control when addressing the origin of plagioclase-rich cumulates.

Petrological and geochemical relationships between pyroxene megacrysts and associated alkali-basalts from Massif Central (France)

Major, trace element, and REE analyses, as well as Sr isotopic ratios, have been obtained on twelve clinopyene megacrysts and phenocrysts and their alkali-basalt hosts from the French Massif Central. Equilibrium between crystals and host was examined based on petrographic and geochemical data. Two types of pyroxenes are recognized: the acmite-bearing clinopyroxenes, rich in incompatible elements and the salitic clinopyroxenes, poor in incompatible elements. 87Sr/ 86Sr isotopic data reveal no significant difference between clinopyroxenes and host lavas: they are in apparent isotopic equilibrium. The Sr isotopic ratios of the two types of pyroxenes are also quite similar. However pyroxene crystals from the first group are not in equilibrium with their host; they have crystallized at high-pressure from differentiated alkali-lavas and have been incorporated in a more primitive magma. Pyroxene crystals from the second group are in apparent equilibrium with their host lava; they have crystallized at various pressures. For the latter, distribution coefficients are proposed for compatible elements, trace elements and REE.

Mineralogy of the Nandewar Volcano, northeastern New South Wales, Australia

AbstractThe paper discusses the mineralogy of eruptives from the Nandewar Volcano, which range in composition from hawaiite and trachyandesite to comendite via tristanite and mafic and peralkaline trachyte. Olivine, Ca-rich pyroxene, and amphibole display marked decreases in 100 Mg/(Mg + Fe) ratios in the sequence trachyandesite to comendite, reflecting variation in host rock compositions. The presence of tscher-makitic subcalcic pyroxene and aluminous bronzite megacrysts in several trachyandesites indicates that these experienced intratelluric crystallization at elevated pressures (6–8 kbar). Some titanomagnetite and plagioclase phenocrysts in trachyandesites may also be moderate pressure cognate precipitates. Groundmass pyroxenes of some trachytes and comendites are strongly acmitic. The presence or absence of coexisting alkali amphiboles and aenigmatite appears to reflect stability over a relatively broad range of fO2 conditions. Aenigmatite rims on titanomagnetite and ilmenite microphenocrysts in several peralkaline eruptives provides support for a ‘no-oxide’ field in T-fO2 space. The Fe-Ti oxide compositional data indicate that magmas spanning the spectrum trachy-andesite-comendite crystallized under conditions of decreasing T and fO2 which broadly coincided with the FMQ synthetic buffer curve. However, a voluminous group of slightly older associated rhyolites appear to have crystallized under significantly more oxidizing conditions.

Possible high-temperature origin of pyroxenite lenses within garnet peridotite, northern Italy

A garnet websterite lens carrying pyroxene megacrysts with unmixing texture and a garnet clinopyroxenite lens are described from within the garnet peridotite body at Seefeld Aim, Ultimo valley, northern Italy. Texture, bulk rock and mineral chemical data suggest that the garnet pyroxenites resulted from exsolution and recrystallization from originally monomineralic pyroxenite that consisted of aluminous and subcalcic clinopyroxenes and small amount of probable silicate melt. From extremely high temperatures of crystallization, that is, > 1 450 °C as inferred from the pre-exsolution composition of the pyroxene megacrysts, it was suggested that the primary pyroxenes were igneous precipitates from a magma that had injected into a solid peridotite probably in the upper mande.

Origin of ultramafic inclusions and megacrysts in a monchiquite dyke at Streap, inverness-shire, Scotland

Spinel lherzolite nodules, composed of olivine (Fo 88.7−89.2), clinepyroxene (6.5% Al 2O 3) and Al-rich spinel, and websterite nodules as well as megacrysts of clinopyroxene, orthopyroxene and magnetite occur in a monchiquite at Streap, Scotland. Petrographic data are given and microprobe analyses of coexisting phases in six spinel lherzolite nodules and one websterite nodule are reported, along with analyses of both types of pyroxene megacrysts. The spinel lherzolites show internal chemical homogeneity, and their mineral chemistries suggest equilibrium conditions of 1100–1200°C and 14–23 kb. The websterite nodules are, on the basis of mineral chemistry and petrography, considered to be crustal material. The megacrysts constitute a separate group, differing in composition from analogous phases in associated lherzolites and websterites as well as from monchiquite phenocryst phases, and show systematic chemical variations corresponding to low pressure crystal fractionation processes.

Exsolved garnet-bearing pyroxene megacrysts from some South African kimberlites

Clinopyroxene and orthopyroxene megacrysts containing garnet lamellae up to 1.2 mm thick as an exsolved phase are found rarely in kimberlites from Frank Smith and Bellsbank. Chemically the clinopyroxenes are characteristically subcalcic, being within the range of 100 Ca/Ca + Mg + Fe = 27 to 36, and the orthopyroxenes are characterized by high Al 2O 3 and Cr 2O 3. Immediately after crystallization during very slow cooling, clinopyroxene and orthopyroxene exsolve wide-spaced orthopyroxene and clinopyroxene phases parallel to (100) of the host phases, respectively, then both host and exsolved phases exsolve garnet lamellae. Topotactic relations between pyroxenes and garnet are determined by X-ray for the first time. Partitioning of major and minor elements among the coexisting clinopyroxene, orthopyroxene and garnet in pyroxene megacrysts is the same as that of the granular-type garnet peridotite xenoliths in Lesotho and South African kimberlies. Mineralogy and chemistry indicate that subcalcic clinopyroxene and orthopyroxene megacrysts contain respectively about 10 and 3 mole % of the garnet molecule in solid solution.

Tholeiitic andesite of high-pressure origin from the tweed shield volcano, northeastern New South Wales

A high-alumina tholeiitic andesite from the southern portion of the Tweed Shield Volcano in northeastern New South Wales contains abundant megacrysts of plagioclase (Ab50An46Or4) and “megacrysts” of aluminian bronzite (Ca4Mg71Fe25) and relatively Ca-poor aluminian augite (Ca36Mg41Fe20). The pyroxenes commonly occur as inclusions in the plagioclase megacrysts. Electron probe microanalyses of the pyroxene megacrysts indicate that they differ in character and composition from the groundmass ferromagnesian phases, namely a more Al- and Na-poor augite (Ca41Mg42Fe17) and olivine (Fa53). The bulk composition of the plagioclase megacrysts is slightly more Ab-rich than that of the groundmass plagioclase, but differences in the two compositions are extended by microanalyses of groundmass plagioclases. Evaluation of the megacryst compositions in the light of experimental data and analogous occurrences in alkaline volcanics leads to the interpretation that the megacrysts represent cognate precipitates formed at pressures broadly equivalent to the crust-mantle boundary. More important, they provide strong evidence for the high pressure origin of tholeiitic andesites, customarily interpreted as the products of low pressure fractional crystallization of tholeiitic magma.