Pyroclastic Flows Research Articles

A Unifying Model for Pyroclastic Surge Genesis and Pyroclastic Flow Fluidization

AbstractPyroclastic density currents (PDCs) are hot and fast ground‐hugging mixtures of volcanic fragments and gases, which represent a major threat to people living near explosive volcanoes. Mechanisms causing the separation into the concentrated (the pyroclastic flow) and dilute (the pyroclastic surge) layers, as well as the mechanism causing their remarkably high mobility are still unclear. Here, we present a conceptual model based on field observations of lava dome collapses, laboratory experiments, and numerical modeling that unifies these mechanisms. Our model shows that they are caused by the fall of fine volcanic particles onto steep, irregular topography. The ambient air entrapped during the fall both creates the pyroclastic surge through elutriation and induces high fluidity in the pyroclastic flow by increasing its pore pressure. Our conclusion reveals the importance of topography in the destructive capacity of PDCs.

Calibration strategies of PDC kinetic energy models and their application to the construction of hazard maps

The availability of computer tools able to describe the behavior of pyroclastic density currents (PDCs) with uncertainty quantification is of primary importance for the assessment of volcanic hazard. A common strategy to assess the intrinsic variability of these phenomena is based on the analysis of large sets of numerical simulations with variable input parameters. The use of models fast enough to allow for a large number of simulations, such as the so-called kinetic energy models, is thus advantageous. Due to the sensitivity of kinetic energy models to poorly constrained input parameters, the definition of their variation ranges is a critical step in the construction of hazard maps and a numerical calibration becomes necessary. We present a set of reproducible and structured calibration procedures of numerical models based either on a reference deposit or on the distribution of runout distance or inundation area of documented PDCs. In the first case, various metrics can be adopted to compare the model results with the reference PDC deposit (root mean square distance, Hausdorff distance, and Jaccard index), facilitating the development of scenario-based hazard assessments. Calibrations based on the distribution of runout distance or inundation area allow the construction of probabilistic hazard maps that are not conditioned on the occurrence of a specific scenario, but rather reflect the variability of the documented PDCs during the time window considered. Importantly, our calibration strategies allow one to set the input parameters considering their potential statistical dependence. These procedures have been implemented on the user-friendly versions of two kinetic energy models: ECMapProb 2.0 and BoxMapProb 2.0, whose functionalities are presented for the first time in this paper. The different calibration strategies and the functionalities of the two programs are illustrated by considering three case studies: El Misti (Peru), Merapi (Indonesia), and Campi Flegrei (Italy).

Construction and Destruction of Bontău Composite Volcano in the Extensional Setting of Zărand Basin during Miocene (Apuseni Mts., Romania)

The Eastern part of the Miocene Zărand extensional basin witnessed the generation and evolution of the largest composite volcano in Apuseni Mts., named recently Bontău. The volcano is filling the basin at the junction between the South and North Apuseni Mountains. The Bontău Volcano is known to be active roughly between ~14–10. In spite of heavily forested and poorly exposed volcanic deposits, it was possible to identify its complex evolution. The volcano suggests an original oval-shaped edifice base currently showing a north-oriented horseshoe-shaped debris avalanche eroded crater. The early effusive volcanic activity was contemporaneous with the emplacement of individual and/or clustered volcanic lava Domes. Late-stage summit dome generation was followed by several volcanic collapses all around the volcanic edifice producing large volcanic debris avalanche deposits (DADs), accompanied by numerous debris flows all around the volcano periphery. Thick pumice pyroclastic flow deposits found below DADs at the periphery may suggest that the slope failures were proceeded by a Plinian eruption. The debris avalanche crater is the last event in the volcano evolution exposing several intrusive andesitic-dioritic bodies and associated hydrothermal and mineralization processes, most probably including the former central vent area of the volcano. The volcano proximal effusive and explosive deposits display a change in the composition of the erupting magma (increased SiO2 from 53.4% to 60.6%) that resulted in an increase of viscosity and the construction of the summit lava domes. Such domes are however only found as various size blocks in DADs. The volcanism connects with the two steps of geotectonic evolution of the Zărand Basin: The initial construction period during regional extension started ~16 Ma up to 12.3–12.1 when the Bontău volcano and surrounding domes were generated. The second period, younger than 12 Ma, corresponds to NW-SE compressional tectonics developed only in the Bontău volcano with summit dome generation and, finally, assists volcano destruction and DADs generation. Newly performed geochemical and Sr and Nd isotopic data studies attest to a calc-alkaline character and suggest an evolution via assimilation-fractional crystallization processes of a dominant MORB-like mantle source magma. Also, they confirm the amphibole (±pyroxene) andesites to be the most evolved lithology. The stepwise changes in fracture propagation in the Zărand extensional setting along with a change to more hydrated and fractionated magma favored in ~4 Myrs of the evolution of the Bontău volcano lead to multiple pulses of the longest-lived magma chamber in the whole Miocene volcanism of the Apuseni Mts.

Paleomagnetism and rock magnetism as tools for volcanology

Paleomagnetic and rock magnetic methods for studying volcanoes and their products have been developed since the second half of the twentieth century. These methods have been used to find tephra in sediment cores, date volcanic eruptions and deposits, determine emplacement temperatures of volcanic deposits, and estimate flow directions of dikes, lava flows, and pyroclastic flow deposits. In the twenty-first century, these techniques have steadily improved and expanded, resulting in more probing and precise studies of volcanoes using paleomagnetism. We believe that continual improvement of existing techniques and the increased awareness and interest in paleomagnetic methods should allow more studies to enhance the understanding of volcanic processes.

Calibrating Carbonization Temperatures of Wood Fragments Embedded within Pyroclastic Density Currents through Raman Spectroscopy

The study of the structural order of charcoals embedded in pyroclastic density currents provides information on their emplacement temperature during volcanic eruptions. In the present work, a set of charcoals from three distinct pyroclastic density currents deposits whose temperatures have been previously estimated by charcoal reflectance analyses to lie between 250 °C and 550 °C, was studied by means of Raman spectroscopy. The analyses reveal a very disordered structural ordering of the charcoals, similar to kerogen matured under diagenetic conditions. Changes in Raman spectra at increasing temperatures reflect depolymerization and an increase of aromaticity and can be expressed by parameters derived from a simplified fitting method. Based on this approach, a second order polynomial regression with a high degree of correlation and a minimum error was derived to predict paleotemperatures of pyroclastic deposits. Our results show that Raman spectroscopy can provide a reliable and powerful tool for volcanological studies and volcanic hazard assessment given its advantage of minimum samples preparation, rapid acquisition processes and high precision.

Development characteristics and petroleum geological significance of Permian pyroclastic flow volcanic rocks in Western Sichuan Basin, SW China

By examining field outcrops, drilling cores and seismic data, it is concluded that the Middle and Late Permian “Emeishan basalts” in Western Sichuan Basin were developed in two large eruption cycles, and the two sets of igneous rocks are in unconformable contact. The lower cycle is dominated by overflow volcanic rocks; while the upper cycle made up of pyroclastic flow volcanic breccia and pyroclastic lava is typical explosive facies accumulation. With high-quality micro-dissolution pores and ultra-fine dissolution pores, the upper cycle is a set of high-quality porous reservoir. Based on strong heterogeneity and great differences of pyroclastic flow subfacies from surrounding rocks in lithology and physical properties, the volcanic facies and volcanic edifices in Western Sichuan were effectively predicted and characterized by using seismic attribute analysis method and instantaneous amplitude and instantaneous frequency coherence analysis. The pyroclastic flow volcanic rocks are widely distributed in the Jianyang area. Centering around wells YT1, TF2 and TF8, the volcanic rocks in Jianyang area had 3 edifice groups and an area of about 500 km2 which is the most favorable area for oil and gas exploration in volcanic rocks.

Threats to Contractor’s Cash Flow under Remeasured Public Works Contracts

AbstractCash flow constitutes the bloodstream for contractors. The contractual conditions along with the legal rules are used to set the expected cash flow and entitlements for the contractor consi...

Volcano-sedimentary processes at Las Derrumbadas rhyolitic twin domes, Serdán-Oriental Basin, Eastern Trans-Mexican Volcanic Belt

Abstract The eruption of the c. 10 km 3 rhyolitic Las Derrumbadas twin domes about 2000 years ago generated a wide range of volcano-sedimentary deposits in the Serdán-Oriental lacustrine basin, Trans-Mexican Volcanic Belt. Some of these deposits have been quarried, creating excellent exposures. In this paper we describe the domes and related products and interpret their mode of formation, reconstructing the main phases of the eruption as well as syn- and post-eruptive erosional processes. After an initial phreatomagmatic phase that built a tuff ring, the domes grew as an upheaved plug, lifting a thick sedimentary pile from the basin floor. During uplift, the domes collapsed repeatedly to form a first generation of hetero-lithologic hummocky debris avalanche deposits. Subsequent dome growth produced a thick talus and pyroclastic density currents. Later, the hydrothermally altered over-steepened dome peaks fell to generate second-generation, mono-lithologic avalanches. Subsequently, small domes grew in the collapse scars. From the end of the main eruptive episode onwards, heavy rains remobilized parts of the dome carapaces and talus, depositing lahar aprons. The Las Derrumbadas domes are still an important source of sediments in the basin, and ongoing mass-wasting processes are associated with hazards that should be assessed, given their potential impact on nearby populations.

Analysis of Coulomb Stress of Sumatera Earthquake Against Pyroclastic Flow of Mount Sinabung as Data Prone Volcano Disaster

The islands of Sumatra and Sinabung are located southwest of the Sundaland Continent which is a convergence route between the Indian-Australian Plate that infiltrates to the west of the Eurasian/Sundaland Plate. The increase in activity of Mount Sinabung was preceded by large earthquakes to the west and south while the eruption of Mount Sinabung produced pyroclastics. The purpose of this study is to find out the analysis of coulomb stress from the Sumatra Island earthquake to the pyroclastic flow of Sinabung as data on volcanic disasters. This study used the coulomb stress method with coulomb 3.3. The earthquake data analyzed was Mw, depth, and focal mechanism. The results of the analysis in the form of the direction of the spread of stress and the value of increased coulomb stress in Sinabung in 2014-2016. Sinabung's positive stress coulomb value in 2014 was 0.113 bar with a positive coulomb stress spread angle of 90o against sinabung pyroclastic flow. Sinabung's positive stress coulomb value in 2015 was 0.235 bar with a positive coulomb stress spread angle of 90o against sinabung pyroclastic flow. Sinabung's positive stress coulomb value in 2016 was 0.118 bar with a positive coulomb stress spread angle of 90o against sinabung pyroclastic flow. Coulomb stress analysis affects the direction of prioclastic flow by as far as 180o although it is not the same as the results in the field. This is because the peak of Sinabung has landslides in the southeast-south, thus opening a pyroclastic flow road to the southeast-south.

Influence of hydrothermal recharge on the evolution of eruption styles and hazards during the 2018\u20132019 activity at Kuchinoerabujima Volcano, Japan

The activity of the 2018–2019 eruption of Kuchinoerabujima Volcano in Japan changed from continuous ejection of ash-laden plumes between October 21 and the middle of December, to intermittent explosive activity accompanied by several pyroclastic density currents until January 2019. To understand the behaviors of magma and hydrothermal fluid that controlled the eruptive sequence, we carried out component analysis, X-ray diffractometry, and leachate analysis for ash samples. The proportion of non-altered volcanic ash particles is ~ 15% in the earlier phase, then it decreased to less than 10% in the later explosive phase. Accordingly, the mineral assemblage of the volcanic ash samples changed from plagioclase-dominant to sulfate minerals-dominant. Concentration of SO42− and Cl/SO4 values of the ash-leachates decreased toward the later activity. These results indicate that the proportion of fresh volcanic rocks decreased and sulfuric acid fluid-derived sulfate minerals increased toward the later activities. Consequently, the 2018–2019 eruption at Kuchinoerabujima Volcano changed from magmatic activity to phreatomagmatic activity. Weak glowing of the crater was observed during the magmatic activity, indicating the volcanic conduit was hot enough to dry up the sub-volcanic hydrothermal system. The following phreatomagmatic activity indicates that the hydrothermal fluid recharged after the magmatic eruption phase. Recharge of the hydrothermal fluid likely caused the variation of the eruption style, and is a process that may control the evolution of hazards during future eruption scenarios at similar active volcanoes in Japan and worldwide.Graphical

Coulomb Stress Analysis And Monte Carlo Simulation In Predicting Sinabung Pyroclastic Flow

Sinabung is a small stratovolcano located in northern Sumatra about 50 km northwest of the Toba caldera. On August 27, 2010, it was confirmed that Sinabung experienced a phreatic eruption for the first time in history. Initially the eruption formed a lava dome that fell out on January 10, 2014 forming pyroclastic density currents. An increase in pore fluid pressure in the crust supports Coulomb Failure Friction. Positive coulomb stress values ​​are thought to trigger Sinabung activity. The research uses a combination of Monte Carlo simulation to predict the next earthquake parameters and coulomb stress analysis to determine the direction and value of stress . The Monte Carlo simulation produces earthquake parameter prediction, longitude 98o latitude 3.175o depth 104.5 meters, Mw 6.0, strike 28.125 o, slip 42o, dip 44.17o. Coulomb Stress analysis of the combined 2001-2021 earthquake data produces an average coulomb value of 0.24 bar, 0.14 bar shear, 0.25 bar normal and the direction of the stress vector to the southwest of Mount Sinabung. The results of the combined coulomb stress analysis and Monte Carlo simulation predict the direction of pyroclastic flows to the northeast, east, and southeast of Mount Sinabung, in accordance with the direction that is inversely proportional to positive stress so that the area needs to receive early warning of volcanic eruption natural disasters in 2022.

Analysis of Coulomb Stress of Sumatera Earthquake Against Pyroclastic Flow of Mount Sinabung as Data Prone Volcano Disaster

Analysis of Coulomb Stress of Sumatera Earthquake Against Pyroclastic Flow of Mount Sinabung as Data Prone Volcano Disaster

Tephrostratigraphy and morphometry of Wum Maar Volcano (Oku Volcanic Group- Cameroon Volcanic line): Implications for complex monogenetic volcanoes

Field investigations of tephra deposits and morphometric characterisation were used to constrain the eruptive history and the complexity of the Wum Maar Volcano (WMV) on the Northwestern foot of the Oku Volcanic Group (Cameroon Volcanic Line). The WMV is a compound volcanic edifice made up of an irregular horse-shoe-shaped maar-crater bordered by overlapping scoria cones and a small lava flow field. The bulk ejecta volume computed using ArcGIS.10.3 and field topographic measurements is ∼0.133 km3. The deposits were subdivided into older volcanics, a pre-maar member composed of four Strombolian scoria cones and a maar-member made up of interbedded layers of lapilli-tephra, lapilli-ash, and ash-breccia deposits. The bedding characteristics (structure, bedding dip, direction, attitude, and contact relations) coupled with the componentry analysis of maar deposits indicate phreatomagmatic-derived fallouts and pyroclastic density currents emplaced under both dry and wet conditions due to variations in magma-water ratio during the different phreatomagmatic explosions. The thick paleosol between older volcanics and the pre-maar and the maar deposits suggests that before the formation of the WMV, an eruptive activity took place and comprised an effusive outpouring of a basaltic magma batch that exploited the network of fractures within the basement rocks to reach the surface. Long after this stage, other batches of basanitic and trachybasaltic magmas richer in volatiles erupted explosively (Strombolian eruptive dynamism) around the northern and southern rims of the maar crater, leading to the emplacement of several overlapping scoria cones. The last stage was characterised by the formation of the Wum maar crater through a phreatomagmatic explosion when batches of basanitic magma came in contact with groundwater. The volcanics are sub-aphyric and host mantle xenoliths. Although evenly distributed across the different maar units, these mantle xenoliths are frequent and large enough to suggest a rapid magma ascent. The center of the maar crater compared to the location of the scoria cones suggest that the explosion locus migrated eastwards. The relative proportion of lithic granite within the pyroclastic succession increases upward (highest in MU4), and the depth of the maar varies from <10 m at the western border to about 124 m at the eastern one, suggesting a vertical and a lateral migration of the explosion locus. The intensity of the phreatomagmatic explosion reduced with time as indicated by the clast-size distribution, with a progressive reduction in water availability wherein the eruption became more internally controlled, changing in style from phreatomagmatic to Strombolian at the end. We conclude that even with very small magma volumes, monogenetic eruptions can have very complex histories, as shown by the WMV, because of the taping system, multiple vents, change in eruptive style, vertical and lateral migration of eruption foci, and multiple magma batches.

Workflows for Construction of Spatio-Temporal Probabilistic Maps for Volcanic Hazard Assessment

Probabilistic hazard assessments for studying overland pyroclastic flows or atmospheric ash clouds under short timelines of an evolving crisis, require using the best science available unhampered by complicated and slow manual workflows. Although deterministic mathematical models are available, in most cases, parameters and initial conditions for the equations are usually only known within a prescribed range of uncertainty. For the construction of probabilistic hazard assessments, accurate outputs and propagation of the inherent input uncertainty to quantities of interest are needed to estimate necessary probabilities based on numerous runs of the underlying deterministic model. Characterizing the uncertainty in system states due to parametric and input uncertainty, simultaneously, requires using ensemble based methods to explore the full parameter and input spaces. Complex tasks, such as running thousands of instances of a deterministic model with parameter and input uncertainty require a High Performance Computing infrastructure and skilled personnel that may not be readily available to the policy makers responsible for making informed risk mitigation decisions. For efficiency, programming tasks required for executing ensemble simulations need to run in parallel, leading to twin computational challenges of managing large amounts of data and performing CPU intensive processing. The resulting flow of work requires complex sequences of tasks, interactions, and exchanges of data, hence the automatic management of these workflows are essential. Here we discuss a computer infrastructure, methodology and tools which enable scientists and other members of the volcanology research community to develop workflows for construction of probabilistic hazard maps using remotely accessed computing through a web portal.

Volcaniclastic lacustrine sedimentation in the Pleistocene Guayllabamba intermontane basin in the Ecuadorian Andes

Abstract In this work, we present a description of the sedimentary fill of a well-exposed lacustrine succession in the Ecuadorian Andes. The Guayllabamba basin is an intermontane basin located in the Andean range of Ecuador, and part of its sedimentary history is represented by a volcanically influenced c. 100 m-thick lacustrine unit of Pleistocene age. We create a stratigraphic cross-section from the eastern to western lake margins and identify 19 facies that were used to carry out a palaeoenvironmental reconstruction. The Guayllabamba palaeolake was developed in a tectonic depression surrounded by volcanoes and it was filled with sediments derived from the erosion of the volcanic edifices, the reworking of unconsolidated pyroclastic deposits and deposition of pyroclastic currents into the lake. The lake shows a deepening trend, passing from shallow deltaic sedimentation to varved diatomites with turbidites. Abundant ash-fall beds, monolithological pumiceous deltaic sequences and pumice-dominated thick ignimbrites show the impacts of volcanism on lacustrine sedimentation within this basin. Soft-sediment deformation and gravity flow deposits are common owing to the intrabasinal tectonic activity and to the intrusion of a lava body. Aulacoseira -rich diatomites dominate the background lake sedimentation. The outcrops of the Guayllabamba basin are outstanding examples of the interaction between volcaniclastic and lacustrine sedimentation.

Geochronology and geochemistry of the Huntington Formation, Olds Ferry terrane, Blue Mountains province, northern U.S. Cordillera: Implications for accreted terrane correlation and assembly

AbstractThe Olds Ferry terrane is the more inboard of two accreted volcanic arc terranes in the late Paleozoic–early Mesozoic Blue Mountains province of the northern U.S. Cordillera. We present geologic, geochronologic, and geochemical data from the volcano-sedimentary Huntington Formation of the Olds Ferry arc that place the terrane within a firm temporal and tectonomagmatic context, and establish its identity as a fringing arc terrane along the Triassic to Early Jurassic Cordilleran margin. The Huntington Formation is divided into two unconformity-bounded informal members: a Norian (ca. 220 Ma) lower member comprising a sequence of mafic-intermediate volcanics, massive volcaniclastic breccias, and minor carbonates deposited unconformably onto the 237.7 Ma Brownlee pluton and intruded by the 210.0 Ma Iron Mountain pluton; and a Rhaetian through Pleinsbachian (&amp;lt;210–187.0 Ma) upper member composed of massive conglomerates, abundant rhyodacite to rhyolite effusive and pyroclastic flows, and interlayered sandstone turbidites, deposited with angular unconformity onto the lower member. An erosional hiatus and regional tilting produced an angular unconformity separating the Huntington Formation from the overlying basal conglomerates of the late Early to Middle Jurassic Weatherby Formation of the Izee forearc basin transgressive onlap sequence. Huntington Formation volcanic rocks are isotopically enriched relative to depleted mantle and coeval igneous rocks in the outboard Wallowa terrane. A temporal evolution to more radiogenic 87Sr/86Sr ratios (0.7036–0.7057) and εNd values (+5.4 to +3.1) in the upper member volcanics suggests increasing involvement of continental-derived material in their petrogenesis. Precambrian xenocrystic zircons in both lower and upper member volcaniclastic rocks strongly support a proximal location of the Olds Ferry terrane to cratonal North America during much of its history. The chronology and tectonostratigraphic architecture of the Olds Ferry terrane allows its robust correlation to other fringing-arc terranes along the U.S. and Canadian Cordillera.

Ash fusion characteristics of biomass pellets during combustion

Combustion of biomass pellets is one of the essential approaches to biomass energy utilization. However, the ash produced from the combustion of pellets may melt and affect combustion efficiency. Therefore, this study evaluated the ash formation and melting evolution characteristics, as well as their causes, of several typical biomass fuels, such as peanut shell pellets, wheat straw pellets, and corn straw pellets, during high-temperature combustion. The ash fusion temperatures of the biomass ash ranged from 1100 °C to 1300 °C. Combined with scanning electron microscopy–energy-dispersive spectrometry and X-ray diffraction analysis, the irregular aggregation of KCl, K2SO4, and other fusible matters was identified as the main factor affecting the ash fusion of wheat straw and corn straw pellets. Ash melting inhibited the combustion reaction of the wheat straw and corn straw pellets, which have the highest amount of silicon content in their molten ash at 1100 °C. However, the ash completely melted at 1300 °C, and the Si, MgO, and CaO contents increased and formed low-melting-point eutectics that were widely distributed in the molten ash. Higher temperatures that exceeded the ash flow temperature promoted the formation of various structures and eutectic materials of molten ash and accelerated carbon conversion. At 1300 °C, the ash melting process improved the combustion reactivity of the three biomass pellets, among which the combustion reaction of the corn straw pellets was the most obvious. At 1100 °C, the ash melting process only improved the combustion reactivity of peanut shell pellets and inhibited the combustion reactivity of wheat straw pellets and corn straw pellets. This study has provided a basis for solving the problem of fuel ash melting affecting combustion in the combustion equipment of biomass pellets.

The spectrum of health hazards by a volcanic eruption and the need for an integrated approach to mental health and disaster preparedness

Mt. Nyiragongo in Goma, DR Congo, exploded on 22 May 2022. In the Philippines, on 1 July 2021, the Taal volcano, considered a restive volcano, spewed a 0.62 mile-high plume of gas and steam into the air, cascading a mass evacuation. Without any prior warning, Goma and central Manila were in a state of emergency, not knowing what to expect and how to react. Volcanoes provide a conduit by which magma – the earth's molten rock, gases and water – may interact with human biological systems. The importance of effective pre-disaster planning cannot be over-emphasised in such situations. The article dwells on the volcanic phenomena, which can cause many health hazards during the eruption and in between eruptions. The vast majority of volcanogenic fatalities in the past few centuries have resulted from events at the proximity – such as pyroclastic density currents, lahars and suffocation or building/roof collapse from ash or debris – and also distal events, such as tsunamis, which may travel for hundreds of miles from the active site, and indirect consequences of eruptions, such as famine or infectious disease outbreaks, including podoconiosis, fluorosis, geophagy, iodine deficiency disorders and rift valley fever. Although technology and geology can give a better lead time, predicting natural hazards and formulating, a plan in advance will obviously be very helpful for public health professionals. This paper is intended for health-care workers to understand the health problems faced due to a volcanic eruption, and this understanding, along with the recommendations given, will enable them to plan and prepare for the management of relief, rescue and medical care.

The Zn, S, and Cl isotope compositions of mare basalts: Implications for the effects of eruption style and pressure on volatile element stable isotope fractionation on the Moon

AbstractWe compare the stable isotope compositions of Zn, S, and Cl for Apollo mare basalts to better constrain the sources and timescales of lunar volatile loss. Mare basalts have broadly elevated yet limited ranges in δ66Zn, δ34S, and δ37ClSBC+WSC values of 1.27 ± 0.71, 0.55 ± 0.18, and 4.1 ± 4.0‰, respectively, compared to the silicate Earth at 0.15, –1.28, and 0‰, respectively. We find that the Zn, S, and Cl isotope compositions are similar between the low- and high-Ti mare basalts, providing evidence of a geochemical signature in the mare basalt source region that is inherited from lunar formation and magma ocean crystallization. The uniformity of these compositions implies mixing following mantle overturn, as well as minimal changes associated with subsequent mare magmatism. Degassing of mare magmas and lavas did not contribute to the large variations in Zn, S, and Cl isotope compositions found in some lunar materials (i.e., 15‰ in δ66Zn, 60‰ in δ34S, and 30‰ in δ37Cl). This reflects magma sources that experienced minimal volatile loss due to high confining pressures that generally exceeded their equilibrium saturation pressures. Alternatively, these data indicate effective isotopic fractionation factors were near unity.Our observations of S isotope compositions in mare basalts contrast to those for picritic glasses (Saal and Hauri 2021), which vary widely in S isotope compositions from –14.0 to 1.3‰, explained by extensive degassing of picritic magmas under high-P/PSat values (&amp;gt;0.9) during pyroclastic eruptions. The difference in the isotope compositions of picritic glass beads and mare basalts may result from differences in effusive (mare) and explosive (picritic) eruption styles, wherein the high-gas contents necessary for magma fragmentation would result in large effective isotopic fractionation factors during degassing of picritic magmas. Additionally, in highly vesiculated basalts, the δ34S and δ37Cl values of apatite grains are higher and more variable than the corresponding bulk-rock values. The large isotopic range in the vesiculated samples is explained by late-stage low-pressure “vacuum” degassing (P/PSat ~ 0) of mare lavas wherein vesicle formation and apatite crystallization took place post-eruption. Bulk-rock mare basalts were seemingly unaffected by vacuum degassing. Degassing of mare lavas only became important in the final stages of crystallization recorded in apatite—potentially facilitated by cracks/fractures in the crystallizing flow. We conclude that samples with wide-ranging volatile element isotope compositions are likely explained by localized processes, which do not represent the bulk Moon.

I-Channel FMCW Doppler Radar for Long-Range and High-Velocity Targets

Frequency-modulated continuous-wave (FMCW) radar is known for distance and velocity measurements of close and slow targets, i.e., targets with round-trip delays much shorter and Doppler periods much longer than the chirp repetition period. Solutions for distant targets have been presented for advanced FMCW radar architectures. Here, we analyze how a conventional homodyne I-channel FMCW radar can be used for a multitarget setting without the restrictions of close and slow targets. In a long-range setting, each target appears at two different ranges with opposite velocities. We develop a pure data processing solution to resolve this ambiguity and validate this approach through simulations and experimental results with a long-range moving test target. The work is motivated by our goal to use an off-the-shelf, low-power, and low-cost 24-GHz I-channel FMCW Doppler radar for continuous observation of volcanic eruptions and pyroclastic flows. These targets are moving at high speed and, for safety reasons, can only be observed from a greater distance, requiring the high-velocity long-range solution.