In this study, simulation and experimental studies are used to evaluate the temperature field distribution and process law for the pulsed laser processing of stainless steel. The numerical simulation is based on the theory of heat transfer. The temperature field distribution and change process of the stainless steel surface under the influence of laser is explained subjectively, and the morphology evolution law of stainless steel during the entire process is studied. The influence of insufficient laser spot overlap ratio and the variation of laser power on the machining quality is analyzed by comparing with the experimental results. The evolution law of machining morphology and size with the laser incident angle, scanning speed, repetition frequency, and laser power are evaluated. The results provide theoretical support for determining the high-quality processing of stainless steel by a pulsed laser, which can be used for the parameter optimization of laser processing, such as metal material cutting, surface microstructure preparation, and two-dimensional code marking.