Proterozoic Shales Research Articles

Petrophysical interpretation and reservoir characterisation on Proterozoic shales in National Drilling Initiative Carrara 1, Northern Territory

The Proterozoic succession in the National Drilling Initiative Carrara 1 drill hole, Northern Territory, is dominated by tight shales, siltstones and calcareous clastic rocks. As part of Geoscience Australia’s Exploring for the Future program, this study aimed to improve the Proterozoic shale gas reservoir characterisation by derivation of porosity, permeability and gas content from laboratory testing and machine learning approaches to wireline log interpretation. The Proterozoic Lawn Hill Formation is divided into four chemostratigraphic packages. The middle two packages are further divided into seven internal units according to principal component analysis and self-organising map clustering on well logs and inorganic geochemical properties. Artificial neural networks were then applied to interpret the mineral compositions, porosity and permeability from well logs, density and neutron-density crossplot interpretations. Gas content was estimated from the interpreted porosity, gas saturation, total organic carbon and clay contents. Petrophysical interpretation results are summarised for all chemostratigraphic packages and units. P2 (1126.3–1430.1 m) has the highest potential among the four chemostratigraphic packages. P2U1 (1126.3–1271 m) and P2U3 (1335.5–1430.1 m) units have the most favourable petrophysical properties for organic-rich shales, with average total gas contents of 1.213 and 1.315 cm3/g, geometric mean permeability of 6.6 and 25.31 µD and net shale thickness of 53.5 and 83.3 m, respectively. P3U4 (687.9–697.9 m) has high gas content and permeability, with a net shale thickness of 35.9 m. The tight non-organic-rich siltstone and shale reservoirs in package P1 (below 1430.1 m) have an average gas saturation of 17.4% and a geometric mean permeability of 0.48 µD.

Organic matter sulfurization and organic carbon burial in the Mesoproterozoic

Throughout the Proterozoic Era, sedimentary organic carbon burial helped set the pace of global oxygenation and acted as a major modulator of atmospheric CO2 and climate. Although Proterozoic rocks generally contain low concentrations of organic matter (OM), there are key exceptions to this rule, including the relatively OM-rich Arctic Bay shales from Baffin Island, Canada (Bylot Supergroup, Borden Basin, ∼1.05 Ga). The mechanisms driving elevated OM concentrations in these and other Proterozoic shales remain poorly understood. In the Mesozoic and Cenozoic, organic matter sulfurization can be a major driver of enhanced OM burial across a range of redox conditions comparable to those inferred for many Proterozoic environments. Therefore, in this study, we evaluate the role of sulfurization in driving OM preservation in the Mesoproterozoic Borden Basin and discuss its relevance to Proterozoic systems in general. We present the first evidence for syngenetic-to-early-diagenetic OM sulfurization in a Proterozoic basin, which begins to fill a several-billion-year gap in our record of organic S across Earth history. We find that OM sulfurization was particularly extensive in shales from a relatively shallow-water section (Alpha River) but less extensive in shales deposited in deeper water (Shale Valley), which is consistent with models that infer sulfidic ‘wedges’ or O2-minimum-zone-type structures on shelf margins at least intermittently at this time. At the shallower site, organic S and pyrite are similarly 34S-depleted and thus likely formed at roughly the same time near the sediment–water interface under conditions previously interpreted to have been ferruginous to intermittently sulfidic. In contrast, at the deeper-water site, large S-isotope differences between pyrite and organic S along with low apparent OM sulfurization intensities indicate that pyrite formation was favored over OM sulfurization during early sedimentation under variable but primarily ferruginous conditions. Although Mesoproterozoic biomass can be substantially sulfurized, indicators of sulfurization intensity are not correlated with OM concentrations, and therefore sulfurization does not appear to have been the primary driver of enhanced OM concentrations in Arctic Bay Formation shales. The link between sulfurization and total OM preservation may have been modulated during the deposition of Arctic Bay Formation shales by differences in iron availability, nutrient cycling, and particle dynamics in the Mesoproterozoic.

Constraining the geothermal parameters of in situ Rb–Sr dating on Proterozoic shales and their subsequent applications

Abstract. Recent developments in tandem laser ablation mass spectrometer technology have demonstrated the capacity for separating parent and daughter isotopes of the same mass online. As a result, beta-decay chronometers can now be applied to the geological archive in situ as opposed to through traditional whole-rock digestions. One novel application of this technique is the in situ Rb–Sr dating of Proterozoic shales that are dominated by authigenic clays such as illite. This method can provide a depositional window for shales by differentiating signatures of early diagenetic processes versus late-stage secondary alteration. However, the hydrothermal sensitivity of the Rb–Sr isotopic system across geological timescales in shale-hosted clay minerals is not well understood. As such, we dated the Mesoproterozoic Velkerri Formation from the Altree 2 well in the Beetaloo Sub-basin (greater McArthur Basin), northern Australia, using this approach. We then constrained the thermal history of these units using common hydrocarbon maturity indicators and modelled effects of contact heating due to the intrusion of the Derim Derim Dolerite. In situ Rb–Sr dating of mature, oil-prone shales in the diagenetic zone from the Velkerri Formation yielded ages of 1448 ± 81, 1434 ± 19, and 1421 ± 139 Ma. These results agree with previous Re–Os dating of the unit and are interpreted as recording the timing of an early diagenetic event soon after deposition. Conversely, overmature, gas-prone shales in the anchizone sourced from deeper within the borehole were dated at 1322 ± 93 and 1336 ± 40 Ma. These ages are younger than the expected depositional window for the Velkerri Formation. Instead, they are consistent with the age of the Derim Derim Dolerite mafic intrusion intersected 800 m below the Velkerri Formation. Thermal modelling suggests that a single intrusion of 75 m thickness would have been capable of producing a significant hydrothermal perturbation radiating from the sill top. The intrusion width proposed by this model is consistent with similar Derim Derim Dolerite sill thicknesses found elsewhere in the McArthur Basin. The extent of the hydrothermal aureole induced by this intrusion coincides with the window in which kerogen from the Velkerri Formation becomes overmature. As a result, the mafic intrusion intersected here is interpreted to have caused kerogen in these shales to enter the gas window, induced fluids that mobilize trace elements, and reset the Rb–Sr chronometer. Consequently, we propose that the Rb–Sr chronometer in shales may be sensitive to temperatures of ca. 120 ∘C in hydrothermal reactions but can withstand temperatures of more than 190 ∘C in thermal systems not dominated by fluids. Importantly, this study demonstrates a framework for the combined use of in situ Rb–Sr dating and kerogen maturation indicators to help reveal the thermochronological history of Proterozoic sedimentary basins. As such, this approach can be a powerful tool for identifying the hydrocarbon potential of source rocks in similar geological settings.

Concurrent 17. Presentation for: Resource potential of the Carrara Sub-basin from the deep stratigraphic well NDI Carrara 1

Presented on Wednesday 18 May: Session 17 NDI Carrara 1 is a deep stratigraphic well completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI), in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first stratigraphic test of the Carrara Sub-basin, a newly discovered depocentre in the South Nicholson Region. The well intersected Proterozoic sediments with numerous hydrocarbon shows, likely to be of particular interest due to affinities with the known Proterozoic plays of the Beetaloo Sub-basin and the Lawn Hill Platform, including two organic-rich black shales and a thick sequence of interbedded black shales and silty-sandstones. Alongside an extensive suite of wireline logs, continuous core was recovered from 283.9 m to total depth at 1750.8 m, providing high-quality data to support comprehensive analysis. Presently, this includes geochronology, geochemistry, geomechanics and petrophysics. Rock-Eval pyrolysis data demonstrate the potential for several thick black shales to be a source of hydrocarbons for conventional and unconventional plays. Integration of these data with geomechanical properties highlights potential brittle zones within the fine-grained intervals where hydraulic stimulation is likely to enhance permeability, identifying prospective Carrara Sub-basin shale gas intervals. Detailed wireline log analysis further supports a high potential for unconventional shale resources. Interpretation of the L210 and L212 seismic surveys suggests that the intersected sequences are laterally extensive and continuous throughout the Carrara Sub-basin, potentially forming a significant new hydrocarbon province and continuing the Proterozoic shale play fairway across the Northern Territory and northwest Queensland. To access the presentation click the link on the right. To read the full paper click here

Petrographical and Geochemical Study of Syn-Rift Sediments, Pranhita-Godavari Intracratonic Gondwana Basin, India: Genesis and Paleo-Environmental Implications

The approximately 2 km thick fluvio-lacustrine deposits of Pranhita-Godavari Gondwana syn-rift basin, ranging in age from 235 to 196 Ma, track the compositional changes from the Middle Triassic to Early Jurassic. Mineralogical and geochemical investigations, as well as paleocurrent data of the siliciclastic deposits of the four conformable formations—Yerrapalli, Bhimaram, Maleri and Dharmaram—trace the source of sediments to the south and southwest of the Gondwana basin. The dominance of arkosic to sub-arkosic sandstones in all the formations suggests mostly felsic sources. The high value of Zr/Sc, as well a high content of Hf, reflects the addition of zircon by sediment recycling. The index of compositional variability (ICV) and chemical index of alteration (CIA) values of these Gondwana samples suggest intermediate weathering of Proterozoic shales, granites and gneisses. The concentration of Cr and Ni, ratios of Eu/Eu* and (GdN/YbN) suggest a dominant post-Archean source. The insignificant variation in ICV and CIA values across the studied Mesozoic formations corroborates the continuation of syn-rift tectonics of the Pranhita-Godavari Gondwana basin since the Late Paleozoic. Sandstone samples show a gradual shift from arkose to subarkose in Yerrapalli, Barakar and Maleri formations, and to sublithic arenite sandstones in the younger Dharmaram formation, indicating recycling. However, the insignificant variation of feldspar and/or quartz content throughout these Mesozoic formations suggests lesser tectonic activity. The paleocurrent direction, shifting from NNW to NE direction, suggests a change in basin tectonism and/or sediment supply, which is corroborated by mineralogical and geochemical data.

Geochemical and paleoenvironmental characteristics of upper Neoproterozoic ore-hosting black shales in the Bafq metallogenic zone, Central Iran

The black shales of the Koushk series in the Bafq metallogenic zone, which are part of the upper Neoproterozoic shales of Central Iran, are typically comparable with the Proterozoic Shale signature but comprehensive information about formational conditions and geochemical characteristics is scarce. In this study, the chemical composition, provenance, tectonic setting, climatic conditions during the weathering of source rocks and paleoredox depositional environments for Koushk shales are investigated. Compared with ‘Post Archean Average Shale’, the samples are depleted in Fe2O3, MgO, TiO2, K2O, Na2O, Sc, Co, Th, V and Cr, owing to the chemical composition and degree of weathering of the source rocks. The provenance study implies that the sediments originated from felsic igneous rocks with a moderate degree of weathering in a semiarid to arid climate. The ratios of redox-sensitive elements [e.g. V/Cr, V/(V + Ni)] revealed that the studied black shales were deposited under moderately anoxic conditions. Furthermore, trace-element ratios (e.g. La–Th–Sc) suggest a continental arc setting for the provenance, which is consistent with the tectonic evolutionary history of Central Iran throughout the late Neoproterozoic. KEY POINTS Neoproterozoic black shales of the Koushk series in the Bafq metallogenic zone host a Zn–Pb SEDEX deposit with 13 Mt, averaging 7 wt% Zn and 3 wt%. The provenance discrimination diagram of the black shales suggests their derivation from felsic source rocks. The black shales were deposited under a moderately anoxic environment. Trace-element ratios reveal a continental arc setting for the source rocks.

Resource potential of the Carrara Sub-basin from the deep stratigraphic well NDI Carrara 1

NDI Carrara 1 is a deep stratigraphic well completed in 2020 as part of the MinEx CRC National Drilling Initiative (NDI), in collaboration with Geoscience Australia and the Northern Territory Geological Survey. It is the first stratigraphic test of the Carrara Sub-basin, a newly discovered depocentre in the South Nicholson Region. The well intersected Proterozoic sediments with numerous hydrocarbon shows, likely to be of particular interest due to affinities with the known Proterozoic plays of the Beetaloo Sub-basin and the Lawn Hill Platform, including two organic-rich black shales and a thick sequence of interbedded black shales and silty-sandstones. Alongside an extensive suite of wireline logs, continuous core was recovered from 283.9 m to total depth at 1750.8 m, providing high-quality data to support comprehensive analysis. Presently, this includes geochronology, geochemistry, geomechanics and petrophysics. Rock-Eval pyrolysis data demonstrate the potential for several thick black shales to be a source of hydrocarbons for conventional and unconventional plays. Integration of these data with geomechanical properties highlights potential brittle zones within the fine-grained intervals where hydraulic stimulation is likely to enhance permeability, identifying prospective Carrara Sub-basin shale gas intervals. Detailed wireline log analysis further supports a high potential for unconventional shale resources. Interpretation of the L210 and L212 seismic surveys suggests that the intersected sequences are laterally extensive and continuous throughout the Carrara Sub-basin, potentially forming a significant new hydrocarbon province and continuing the Proterozoic shale play fairway across the Northern Territory and northwest Queensland.

Unravelling the histories of Proterozoic shales through in situ Rb-Sr dating & trace element laser ablation analysis

Authigenic components in marine sediments are important archives for past environment reconstructions. However, defining reliable age constraints and assessing the effects of post depositional overprints in Precambrian sequences are challenging. We demonstrate a new laserbased analytical approach that has the potential to rapidly and accurately evaluate the depositional and alteration histories of Proterozoic shales. Our study employs a novel application of in situ Rb-Sr dating coupled with simultaneous trace-element analysis using reaction-cell laser ablation– inductively coupled plasma–tandem mass spectrometry (LA-ICPMS/MS). We present results from shales sourced from two wells in the Proterozoic McArthur Basin, northern Australia. These rocks have been widely used by previous studies as a key section for ancient biogeochemical and paleoredox reconstructions. Shales from well UR5 yielded initial ⁸⁷Sr/⁸⁶Sr ratios, Rb-Sr ages, and rare earth element plus yttrium (REEY) patterns similar to those of a dolerite sampled from the same core. We propose that the UR5 samples chronicle hydrothermal alteration instigated by the dolerite intrusion. In contrast, a correlative shale from well UR6 yielded an age consistent with the expected depositional age (1577 ± 56 Ma) with REEY and initial ⁸⁷Sr/⁸⁶Sr ratios similar to ca. 1.5 Ga seawater. We suggest that this sample records the minimum depositional age and early marine diagenetic history for this unit. This new technique can date Proterozoic shales quickly, cheaply, and with minimum sample preparation. Importantly, ages are triaged to differentiate between those recording primary marine versus secondary processes. This novel approach provides a potentially powerful tool for dating and fingerprinting the vast array of ancient marine shales for further studies of Earth systems through deep time.

Unraveling the histories of Proterozoic shales through in situ Rb-Sr dating and trace element laser ablation analysis

Abstract Authigenic components in marine sediments are important archives for past environment reconstructions. However, defining reliable age constraints and assessing the effects of post-depositional overprints in Precambrian sequences are challenging. We demonstrate a new laser-based analytical approach that has the potential to rapidly and accurately evaluate the depositional and alteration histories of Proterozoic shales. Our study employs a novel application of in situ Rb-Sr dating coupled with simultaneous trace-element analysis using reaction-cell laser ablation–inductively coupled plasma–tandem mass spectrometry (LA-ICP-MS/MS). We present results from shales sourced from two wells in the Proterozoic McArthur Basin, northern Australia. These rocks have been widely used by previous studies as a key section for ancient biogeochemical and paleo-redox reconstructions. Shales from well UR5 yielded initial 87Sr/86Sr ratios, Rb-Sr ages, and rare earth element plus yttrium (REEY) patterns similar to those of a dolerite sampled from the same core. We propose that the UR5 samples chronicle hydrothermal alteration instigated by the dolerite intrusion. In contrast, a correlative shale from well UR6 yielded an age consistent with the expected depositional age (1577 ±56 Ma) with REEY and initial 87Sr/86Sr ratios similar to ca. 1.5 Ga seawater. We suggest that this sample records the minimum depositional age and early marine diagenetic history for this unit. This new technique can date Proterozoic shales quickly, cheaply, and with minimum sample preparation. Importantly, ages are triaged to differentiate between those recording primary marine versus secondary processes. This novel approach provides a potentially powerful tool for dating and fingerprinting the vast array of ancient marine shales for further studies of Earth systems through deep time.

Analysis on geological characteristics and resources potential of the Middle-Upper Proterozoic shale oil and gas: Taking North Hebei Depression in Yanshan area as an example

Analysis on geological characteristics and resources potential of the Middle-Upper Proterozoic shale oil and gas: Taking North Hebei Depression in Yanshan area as an example

Authigenic uranium isotopes of late Proterozoic black shale

The evolution of early life is intimately related to environmental changes on Earth, and in particular, the accumulation of oxygen in the atmosphere and oceans. However, the record of environmental O2 abundance in the middle to late Proterozoic Eon, during which many new eukaryotic lineages emerged, is sparse and controversial. Here we present a uranium (U) isotope record from late Proterozoic shales from northwestern Canada, Arctic Canada (Baffin Island), Svalbard, and Greenland, coupled with a novel approach for inferring authigenic U isotope values (δ238Uauthigenic). A compilation comprising our new data and available literature data (854 δ238Uauthigenic values) through geologic time indicates a consistent rise in δ238Uauthigenic values following the Great Oxidation Event. This gradual increase in δ238U can be interpreted as an increase in the frequency of transient oxygenation events and also as a variation of U isotope fractionation factors between authigenic uptake and seawater (Δ238U) associated with different redox conditions occurring over the Earth's history. In conjunction with the U isotopic signature, we used previously published Fe speciation data from our samples to infer local controls on U incorporation and isotopic fractionation. The results suggest that late Proterozoic oceans were dominantly ferruginous, punctuated by periods of transient oxygenation. During these transient oxic conditions, high U isotope fractionation resulted in Δ238U values as high as ~1.2‰ relative to the δ238Ucrust. However, under ferruginous conditions, smaller isotopic fractionation led to Δ238U values <0.6‰. Integrating conclusions from our study with other geochemical studies suggests the occurrence of several spatially localized oxygenation events across the globe during the late Proterozoic. These conclusions help to better integrate geochemical and fossil records in the context of early evolution of complex life.

Isotopic and geochemical constraints on the protolith, redox state and paleo-tectonic setting of the Malagarasi Supergroup of north-western Tanzania

We report detrital zircon U–Pb ages, radiogenic Sm–Nd isotopic compositions, major and trace element compositions of the intra-plate extensional rhomb-shaped Neoproterozoic Malagarasi Supergroup of north-western Tanzania in order to elucidate the paleo-tectonic setting, source rocks chemistry and paleo-oxygenation in the basin. Assuming that provenance trace element proxy ratios, including the rare earth elements (REE) contents, behave as closed systems during sedimentation and diagenesis, we suggest that the detritus for the Malagarasi Supergroup originated from more felsic rocks than those for upper crustal composites (i.e. Post-Archean Australian Shale; PAAS, Proterozoic Shale; PS). This observation is also supported by enriched chondrite-normalized light REE (La/SmCN = 2.36–7.84; mean = 3.85), overall negative Eu anomalies (Eu/Eu* = 0.56–0.93; mean = 0.69) and flat heavy REE patterns (Gd/YbCN = 1.01–2.04; mean = 1.47). Paleo-weathering proxies using the Chemical Index of Alteration (CIA ~59–78%) protocol indicate an overall moderate weathering intensity in the basin. V/Cr ratios (mean = 1.18; range = 0.48–1.69) coupled with intra-sample Ce anomalies reveal an overall oxidizing state during deposition. Mantle extraction ages (TDM = 1594–2394 Ma) suggest a diverse mixing of protolith terranes including Archean (Tanzania craton), Eburnian (Ubendian Belt) and possibly the nearby Mesoproterozoic Kibaran Belt. Radiogenic laser ablation detrital zircon U–Pb ages of between 1826 and 2656 Ma may preclude contribution from the Kibaran. Given that Nd systematics in sedimentary rocks provide mixing ages of different hinterland source rocks (1594–2394 Ma; in our study), we suggest relatively juvenile sources such as the local post-orogenic effusive bodies farther south of the basin in the realm of Rodinia Supercontinent. Thus, a northerly flow direction of the of the proto/paleo river system in the region is inferred.

Metallogenesis and depositional environment of the Archean-Proterozoic carbonaceous phyllites from the Dharwar Craton, India

Organic carbon rich meta-sedimentary rocks are important repositories of gold, PGE and vestiges of the biogeochemical cycles that prevailed during the Precambrian time. In this study, we report gold, PGE and δ34S concentrations of carbonaceous phyllites from Neoarchean Chitradurga, Gadag greenstone belts of western Dharwar Craton and Mangampeta of Proterozoic Cuddapah basin, eastern Dharwar Craton to understand their metallogenesis and depositional environments. Chitradurga phyllites (avg. Au = 180 ppb) show elevated concentrations of refractory gold compared to Gadag (avg. Au = 38 ppb) and Mangampeta shales (avg. Au = 23 ppb). The Archean carbonaceous phyllites display three generations of pyrites and their mineral chemistry suggests hydrothermal imprints while Proterozoic shales have two generations of diagenetic pyrites. Gadag has high PGE concentration (ΣPGE = 55 ppb) compared to Chitradurga (ΣPGE = 37 ppb) and Mangampeta (ΣPGE = 27 ppb). The PGE geochemistry is characterized by enrichment of PPGE over IPGE with Au > Pt > Pd and the Au/Pd, Pd/Pt, Ru/Ir, Ir/Pd ratios coupled with negative Pt (Pt/Pt*) anomalies indicate hydrothermal source. The Chitradurga and Gadag samples yielded low sulphur isotopic signatures (δ34S = 1.8–2 and 1.3–2‰ respectively) whereas the Proterozoic Mangampeta samples have comparatively higher values (δ34S = 8.4–34.3‰) suggesting hydrothermal and sea water sulphate sources respectively. Sulphate present in Archean and Proterozoic sea water was converted to sulphur by bacterial sulphate reduction which led to the formation of pyrites. In the Archean phyllites, the metal bearing bisulphide complexes were adsorbed into the pyrites while the Proterozoic shales are characterized by the partitioning of organo-metallic complexes into the pyrite during the diagenesis. Strong positive correlations of transition metals, redox sensitive elements with PGE indicate hydrothermal source and V/(V + Ni), U/Th, Th/U, authigenic U attest euxinic paleo-redox conditions. Thus, biogenically mediated redox depositional environments which prevailed during Archean and Proterozoic times have enhanced the metal sequestration processes that subsequently resulted in the ore formation in these carbonaceous phyllites.

Fluid Inclusion Evidences for the P-T Conditions of Quartz Veins Formation in the Black Shale-Hosted Gold Deposits, Bodaybo Ore Region, Russia

The P-T conditions of auriferous and barren quartz veins from Kopylovsky, Kavkaz and Krasnoye gold deposits in Proterozoic black shales of Bodaybo ore region are presented the first time in this study. Fluid inclusions trapped in auriferous quartz are aqueous Na±K-Mg chloride with salinity of 6 wt.%–8.8 wt.% NaCleqv. Homogenization temperatures vary from 260 to 350 °С, and calculated trapping pressures are 1.2–1.6 kbar. The fluids trapped in barren quartz have more complicated compositions with Na, K, Mg and Fe chlorides, salinity up to 13 wt.% NaCleqv, and homogenization temperatures ranging between 140 and 280 °С. The volatiles in fluids are dominated by H2O, followed by CO2 with minor amounts of CH4 and N2. We suppose that auriferous and barren quartz veins have been formed due to the basic metamorphogenic fluid as evidenced by the close slat and gas fluid composition.

Base metal mineralization of the Kolyma terrain in Northeast Russia: Overview and genetic classification

Research subject. The Prikolyma terrain located in the Northeastern part ofRussia constitutes a long-lived Precambrian thrust-faulted structure hosting numerous Cu, Pb and Zn deposits of different types.Materials and methods. The mineralization of the terrain was examined during a course of research and exploration works over the 2007–2012. The rock geochemistry was studied using ICP-OES analysis at the Stuart Geochemistry and Essay laboratory (Moscow). The microprobe analysis of minerals was carried out at the facilities of the Far Eastern Branch of the Russian Academy of Sciences (Magadan) using a Camebax X-ray microanalyzer. The isotopic ratios of sulphur in sulphides were measured using a Finnigan MAT 253 isotope mass spectrometer.Results. The porphyry-copper deposit Nevidimka is represented by skarns and sulphide-quartz stockworks embedded in porphyry granites. The vein deposits Opyt and Glukhoye constitute sulphide-carbonate-quartz veins, the composition of which corresponds to copper-polymetallic ores of the peripheral parts of the copper-porphyry formation. These deposits feature a similar geochemistry and composition of sulphides and sulphur isotopes, which is characteristic of the Riphean complexes of the Prikolyma terrain. The stratiform Pb-Zn veins Nadezhda-3 and Khaya enclosed in Proterozoic dolomites represent parallel-bedding disseminated sulphides. The composition of these ores indicates their diagenetic origin. Tne stratiform copper deposit Oroyok is embedded in Proterozoic shales and can be referred to sediment-hosted copper deposits of a transgressive type.Conclusions. The diversity of Cu-Pb-Zn mineralization types in the Prikolyma terrain is established to have resulted from multiple cyclic changes of the geodynamic ore formation regime. During each such cycle, syngenetic mineralization was followed first by epigenetic and then by vein mineralization. The mobile, thrust-faulted structure caused repeated rejuvenation of ores, which inherited the geochemical features of hosting rocks.

The Archaean to Proterozoic igneous rocks of the Pilbara region, Western Australia –internationally significant geology of a globally unique potential geopark

The Pilbara region of Western Australia, covering some 500 km × 500 km, provides a diversity of Archaean to Proterozoic igneous rocks in a relatively compact area that records a younging southward crustal history of igneous activity, sedimentation, early life, tectonics, and metamorphism from the Archaean (3.6–2.7 Ga) to Proterozoic (2.5–1.8 Ga). The igneous rocks are variable in age, types of rocks, and mode of occurrence and, throughout the Precambrian, record varying igneous rock activity that appear related to several age-related geological settings: to north, the Archaean Pilbara Craton consists of a granitoid-and-greenstone complex; in the central region, there are Proterozoic sequences of volcanic rock, volcaniclastic rock, ironstone, chert, dolomite, shale, and intrusive dolerite sills and cross-cutting dolerite dykes; to the south, there are Proterozoic shale, dolomite, and chert with isolated granitic batholiths. Igneous activity begins in the Archaean with mafic and ultramafic volcanism alternating with sedimentation, and then granitoid cratonisation. This was followed by Proterozoic volcanic crustal accretion with mafic volcanic and volcaniclastic rocks, and by dolerite and gabbro sill and dyke intrusions, ending with isolated granite batholithic intrusions.Igneous rocks in the Pilbara region are diverse: komatiite; mafic volcanic/volcaniclastic rocks; basalt; tuff/volcanic breccia/accretionary lapilli; dolerite, gabbro, leucogabbro, pegmatitic gabbro, granite, and adamellite; xenolithic dolerite/gabbro; andesite, dacite, rhyodacite, rhyolite; granitoids: adamellite, monzogranite, syenogranite, granodiorite, tonalite, granite; granophyre; felsic dykes; and felsic porphyry. They are expressed as granitoid batholiths, komatiite and basalt sheets/lenses, mafic volcanic/volcaniclastic rocks in sheets, sills of dolerite, gabbro, ultramafic rocks, and diorite, dykes of dolerite, gabbro, and felsic rocks, structurally-oriented dolerite dyke swarms, tuff/volcanic breccia/accretionary lapilli in sheets/lenses, sheets of dacite, rhyodacite, rhyolite, and andesite, gabbroic plugs, apophyses, and a variety of host-rock to xenolith relationships. Today, the Pilbara region is arid, hence outcrop is excellent and many of these geological features are well exposed. The diversity of Archaean to Proterozoic igneous rocks in a relatively compact and well-exposed area and qualifies it as a globally unique potential Precambrian igneous-rock geopark.

Geochemistry of Archean–Proterozoic shales, Dharwar Craton, India: Implications on depositional environment

Shales are significant sedimentary units in the Archean greenstone belts and Proterozoic Cuddapah sequence of Dharwar Craton. We present the geochemical studies of the Archean shales from the Chitradurga greenstone belt and the Proterozoic Vempalle Formation of the Cuddapah Basin to evaluate their chemical composition, weathering, provenance, and depositional conditions. The Archean shales are depleted in transition metals (Ni and Co) but enriched in V, Cr, and Sc relative to upper continental crust, while the Proterozoic shales are depleted in Cr, Co, Ni, Sc, and V compared with Post‐Archean Australian shale reflecting on negligible mafic source during their deposition. The REE patterns of these shales are uniform with moderately flat LREE and negative to positive Ce anomalies reflecting on marine conditions of their deposition. The presence of both positive and negative Ce anomalies indicate fluctuating oxic and anoxic conditions. The Archean and Proterozoic shales show negative and positive Eu anomalies, respectively, along with slightly enriched HREE. Compositional variation is observed in the Archean shales, whereas the Proterozoic counterparts were affected by sediment recycling as displayed by the Th/Sc and Zr/Sc relationship. Th/U and Th along with (Gd/Yb)n ratios display significant heavy mineral enrichment in these shales. The chemical index of alteration (CIA) and chemical index of weathering (CIW) of these shales suggest moderate to intense chemical weathering during the Archean and low to moderate weathering during Proterozoic times. The overall geochemical signatures collectively indicate granitic and tonalitic provenance for the Archean and Proterozoic shales, which were deposited in an active and passive continental margins.

Anoxic ecosystems and early eukaryotes.

Through much of the Proterozoic Eon (2.5-0.54 billion years ago, Ga), oceans were dominantly anoxic. It is often assumed that this put a brake on early eukaryote diversification because eukaryotes lived only in oxygenated habitats, which were restricted to surface waters and benthic environments near cyanobacterial mats. Studies of extant microbial eukaryotes show, however, that they are diverse and abundant in anoxic (including sulfidic) environments, often through partnerships with endo- and ectosymbiotic bacteria and archaea. Though the last common ancestor of extant eukaryotes was capable of aerobic respiration, we propose that at least some, and perhaps many, early eukaryotes were adapted to anoxic settings, and outline a way to test this with the microfossil and redox-proxy record in Proterozoic shales. This hypothesis might explain the mismatch between the record of eukaryotic body fossils, which extends back to >1.6 Ga, and the record of sterane biomarkers, which become diverse and abundant only after 659 Ma, as modern eukaryotes adapted to anoxic habitats do not make sterols (sterane precursors). In addition, an anoxic habitat might make sense for several long-ranging (>800 million years) and globally widespread eukaryotic taxa, which disappear in the late Neoproterozoic around the time oxic environments are thought to have become more widespread.

Reflectance Spectroscopy of Organic Matter in Sedimentary Rocks at Mid-Infrared Wavelengths

AbstractReflectance spectroscopy is a rapid, non-destructive technique capable of characterizing mineral and organic components within geologic materials at spatial scales that range from μm to km. The degree to which reflectance spectra can be used to provide quantitative information about organic compounds remains poorly understood, particularly for rocks with low organic content that are common in the Earth’s ancient rock record and that may be present on other planetary bodies, such as Mars. In the present study, reflectance spectra (0.35–25 μm) were acquired for a suite of Proterozoic shales and the kerogen was isolated to assess how spectral properties of aliphatic and aromatic C-H absorption bands can be used to predict organic matter abundance (total organic content, TOC, and H/C ratio). A number of spectral parameters were evaluated for organic absorption bands observed in the 3–4 μm wavelength region for comparison with independently measured TOC and H/C values. Ratios of the strengths of aliphatic to aromatic absorption bands were directly correlated to H/C values, but the reflectance spectra for pure kerogens with H/C &lt; 0.2 lacked clear evidence for C-H absorption bands in this spectral region. Organic absorption bands are routinely observed for bulk rock powders with &gt;1 wt.% TOC, but the detection limits of reflectance spectra for TOC may be &lt;1 wt.% or as high as 10 wt.%. Organic detection limits for reflectance spectra are, thus, controlled by both TOC and H/C values, but these parameters can be predicted for clay-rich, kerogen-dominated samples for a range of values that are relevant to drill cores, outcrops, meteorites, and planetary surfaces.

Geochemistry and Sm-Nd systematics of the 1.67 Ga Buanji Group of southwestern Tanzania: Paleo-weathering, provenance and paleo-tectonic setting implications

We present major and trace and Nd-isotopic data of the ∼1.67 Ga Buanji Group of southwestern Tanzania in order to constrain the nature of their protolith and the intensity of chemical weathering in the source terranes and make inferences on the nature of climatic conditions during the late Paleoproterozoic in the region. Major and trace element contents of the shales from three stratigraphic formations are comparable to those of the post-Archaean Australian Shale (PAAS) and the average Proterozoic Shale (PS). They are characterized by enrichments in LREE relative to HREE ((La/Yb)CN = 9.07–13.2; (Gd/Yb)CN=1.51–1.85) and negative Eu anomalies (Eu/Eu* = 0.61–0.81); features which are comparable to those of PAAS and PS, indicating upper continental sources. Provenance proxy ratios, together with abundances of Cr, Ni, Co and V that increase up-stratigraphy suggest a decreasing input of felsic detritus up-stratigraphy. Chemical Indices of Alteration (CIA) for the lower, middle and upper Buanji formations are 81, 76 and 79, respectively. These indices largely indicate intermediate (ca. 60–80) to extreme (>80) weathering intensities of the precursor rocks. These observations may suggest the prevalence of warm, humid climates during the late Paleoproterozoic in the region.The lower Buanji Formation yielded a depleted mantle Nd model age (TDM) of ∼2100 Ma which indicates an Eburnean parentage. TDM ages of 2486–2155 Ma and 2535–2379 Ma obtained from middle and upper Buanji formations, respectively, suggest a progressive increase of sedimentary input from the Tanzania Craton up-stratigraphy. The Eburnean TDM ages of the lower Buanji rocks are attributed to their derivation through denudation of a decaying topographic high composed predominantly of rocks that were generated during the Palaeoproterozoic Ubendian orogenesis, possibly in the realm of Columbian Supercontinent assembly. Overlapping TDM ages between the middle and upper Buanji formations suggest multiple sources involving mixing of detritus from Archaean cratonic rocks and the Palaeoproterozoic Ubendian belt. However, the Archaean signal is relatively more pronounced in the upper Buanji Formation, suggesting sediments derivation from the craton, to the north of the basin. The middle Buanji Formation suggests more diverse protolith, given the relatively larger spread in the TDM ages. The Nb/Ta, Zr/Sm and Ce/Pb ratios coupled with the negative Nb and Ta anomalies, relative to primitive mantle, suggest that the tectonic setting of the source rocks for the Buanji sediments was a subduction zone akin to that generating modern Island Arc Basalts. Thus, we suggest that the Buanji's palaeogeography is consistent with an extensional continental backarc basin during the late Paleoproterozoic.