Protected Sites Research Articles

Estimating vital rate variation to assess early success of scrub mint translocations

AbstractSpecies translocations are increasingly common in rare plant conservation. Wild populations can provide basic ecological knowledge to improve their chance of success. In the heavily fragmented Florida scrub, USA, many listed species require translocations to persist, including Dicerandra christmanii. In 1994, we began monitoring the only protected population of D. christmanii growing both in gaps (open areas) within the shrub matrix and on roadsides. In 2010, we augmented this population by adding plants and seeds to unoccupied gaps. In 2012, we introduced plants to a separate protected site to create a new population. We evaluated early translocation success using generalized linear mixed‐effect models of vital rate variation among habitat types. Survival probability increased with size, peaking at 0.6–0.8, and was lowest in augmentations and highest in introductions. Growth increased with plant size across all habitat types, except for the largest adults which experienced senescence. Naturally recruited plants in gaps showed the highest reproduction probability and fecundity at smaller sizes, but larger plants in translocations had the highest fecundity. Yearling recruitment was higher in translocated plants relative to naturally recruited plants in gaps during the initial years following outplanting. Experimental components of translocations also affected outplanting performance with positive effects of fire. These analyses suggest a high potential for translocations to become established and contribute to species recovery.

Extending deep-sea benthic biodiversity inventories with environmental DNA metabarcoding

Inventories of biodiversity are crucial for helping support conservation and management efforts, yet the deep-sea, which is the largest biome on earth remains vastly understudied. Recent advances in molecular detection methods offer alternative techniques for studying inaccessible ecosystems, including those at depth. In this study we utilized environmental DNA metabarcoding, a first for studying deep-sea benthic environments in southern Africa, to assess biological diversity and to test the effects of depth and historical trawling activities on deep-sea communities. Utilising 29 sediment samples (thus focussing on predominantly meiofaunal and epifaunal biodiversity) and targeting a 313 bp region of the mtDNA cytochrome oxidase I gene, we recovered 444 OTUs across a wide array of species and genera. Even though many OTUs could only be assigned to higher taxonomic levels, results showed that biodiversity differed significantly across depth, suggesting that even at relatively small spatial scales (~ 6 km, across a depth gradient of 355 m to 515 m), eDNA derived biodiversity detected variation linked to the depth gradient. Comparison of the OTU database with known species inventories from the sampled area revealed little overlap, highlighting the need for expanding barcoding efforts of deep-sea species to aid future eDNA survey efforts. Overall our results suggest that within a South African context, increased barcoding efforts, in combination with eDNA metabarcoding and physical sampling could capture a greater proportion of benthic deep-sea biodiversity. This provides additional opportunities to underpin conservation and management decision-making in the region, such as evaluating potential sites for future protection.

Effect of surface preparation by high-temperature hydrogen annealing on the passivation of Ni-20 at.% Cr alloy in sulfuric acid

The effect of high-temperature annealing under hydrogen gas (H2) surface preparation on a binary polycrystalline Ni-20 at.% Cr alloy was investigated in comparison with conventional mechanical grinding surface preparation. Duplex surface films with inner Cr(III) oxide and outer Ni(II) and Cr(III) hydroxide layers natively formed before and after H2 annealing were characterized by X-ray photoelectron spectroscopy and time-of-flight secondary ion mass spectroscopy. A thinner and less homogeneous inner barrier layer formed after H2 annealing caused an oxidation peak at the active/passive transition in the linear sweep voltammetry measurement in a 0.5 M H2SO4 solution. Despite this high oxidation peak, passivation of the H2 annealed surface resulted in the formation of a more corrosion resistant inner layer than on the mechanically ground surface, as demonstrated by electrochemical impedance spectroscopy. The corrosion resistant passive film formation of the H2 annealed surface is attributed to the increased Cr enrichment of the inner layer caused by the selective Ni dissolution providing corrosion resistance to the initially weakly protected sites of the natively formed surface film.

Vanishing meadows — Quantitative analysis of factors driving population declines of endangered butterflies

There is a growing number of alarming reports indicating serious declines in biodiversity of invertebrates, mostly manifested through loss of local populations and abundances, and prognosing their regional extinctions. Proper defining of threats is crucial for the effective conservation of endangered species and valuable habitats. Nevertheless, while typically such threats are broadly recognized, their long-term quantitative assessments are rarely available. The aim of this study was to identify and quantify the main drivers of population dynamics and habitat loss of two endangered butterfly species of the genus Phengaris within an extensive semi-urban landscape with 70 initial habitat patches. Over two decades of the study, almost half of the habitat patches remained abandoned, whereas a quarter was directly destroyed through conversion to build-up areas. The latter process was most harmful to butterfly numbers, although it occurred only outside Natura 2000 protected sites. Besides, afforestation works, even if rare, caused significant declines in local populations of the investigated butterflies. Similarly, the meadow abandonment led to decrease in butterfly numbers and their local extinctions due to habitat loss. Meadows were threatened mostly by direct human destruction. The habitat area decreased nearly by 15 %, of which ca. 2/3 suffered direct destruction by built-up, especially in most recent years. As meadows are one of globally threatened terrestrial biodiversity hotspots, and meadow abandonment is partially reversible, there is an urgent need to implement conservation-oriented management of remaining fragments as an effective tool ensuring the persistence of these habitats and their species communities.

Conservation beyond boundaries: using animal movement networks in protected area assessment

AbstractProtected areas (PAs) are a core component of conservation policy and practice. However, many species for which they are designated are highly mobile, and may move among sites within and beyond PA boundaries. Environmental impacts on sites beyond those boundaries could thus impact the PA's protected populations, with the risk of adversely affecting its conservation objectives. Conservationists therefore urgently need tools to assess impacts on PAs and their populations of developments beyond their boundaries. We present a framework for using network analysis of observations of marked individuals to assess the protection footprint of PAs in the wider landscape and the impact footprint of developments within or neighboring PAs. We illustrate the use of this framework by assessing the impact of a current airport development proposal on a partially protected wetland, the Tagus estuary in Portugal, specifically by evaluating the extent of noise disturbance on the PA's population of Black‐tailed Godwits, a protected migratory wader species. By analyzing individual movements between sites and across seasons, we find disturbance impacts on up to 68.3% of individual Black‐tailed Godwits overall, greatly exceeding the estimates of 0.46–5.5% in the airport's Environmental Impact Assessments which derived from count data. We then compared the pre‐development network with simulated networks that represented two levels of site avoidance by removing sites predicted to receive noise in excess of two thresholds, 55 or 65 dB(A). Avoidance by Godwits of the potentially‐impacted sites is predicted to have a larger effect on network structure than removing the same number of sites at random, suggesting that an airport in the proposed location would operate as a barrier to connectivity in this wetland. We also highlight the role that network analyses of locations of marked individuals can play in assessing environmental impacts on protected sites and populations.

Marine birds: Vision-based wind turbine collision mitigation

Throughout their evolution seabirds have not had to contend with the collision risk posed by discrete objects that extend into their flight space above the water surface. However, the recent introduction of offshore wind turbines has significantly increased the potential for collisions. Bird collision risk with Offshore Wind Farm (OWF) turbines is now a major consenting consideration for OWF projects due to potential local population impacts on birds, especially those associated with protected sites. Therefore, the possibility of reducing those risks through a simple mitigation is highly desirable. Key elements for the design of vision-based mitigation measures aimed at reducing the collision of marine birds with wind turbines should be based upon knowledge of the vision of birds, not the vision of humans. May et al. (2020) tested a vision-based wind turbine mitigation measure and reported a modelled 70% reduction in annual turbine-blade collision mortality rate at a terrestrial location in a suite of 19 bird species. The aim of the present proposals is to extend this vision-based mitigation approach and increase its applicability to a broad suite of bird species considered vulnerable to collisions with wind turbines at sea. Key aspects of the vision, behaviour and ecology of marine birds which contribute to their collision risk under a range of natural viewing conditions are reviewed. The same information is then employed to give insights into the requirements of vision-based mitigation measures. We argue that the internal visual contrast of wind turbines should be increased using achromatic patterns applied to blades and pylons. These patterns should reduce the collision vulnerability of marine birds in general and should be effective under a range of visibility conditions determined by natural light levels and weather conditions. The measures should allow birds with different flight speeds and visual acuities to detect turbines sufficiently early to allow alteration of flight direction and avoid collision. The proposed mitigation requires changes to the appearance of wind turbines that can be implemented at the time of manufacture. They do not interfere with statutory requirements already required for the marking of turbines for the benefit of shipping and aircraft.

Cytosolic antibody receptor TRIM21 is required for effective tau immunotherapy in mouse models.

Aggregates of the protein tau are proposed to drive pathogenesis in neurodegenerative diseases. Tau can be targeted by using passively transferred antibodies (Abs), but the mechanisms of Ab protection are incompletely understood. In this work, we used a variety of cell and animal model systems and showed that the cytosolic Ab receptor and E3 ligase TRIM21 (T21) could play a role in Ab protection against tau pathology. Tau-Ab complexes were internalized to the cytosol of neurons, which enabled T21 engagement and protection against seeded aggregation. Ab-mediated protection against tau pathology was lost in mice that lacked T21. Thus, the cytosolic compartment provides a site of immunotherapeutic protection, which may help in the design of Ab-based therapies in neurodegenerative disease.

Combining Phage Display Technology with In Silico-Designed Epitope Vaccine to Elicit Robust Antibody Responses against Emerging Pathogen Tilapia Lake Virus.

Antigen epitope identification is a critical step in the vaccine development process and is a momentous cornerstone for the development of safe and efficient epitope vaccines. In particular, vaccine design is difficult when the function of the protein encoded by the pathogen is unknown. The genome of Tilapia lake virus (TiLV), an emerging virus from fish, encodes protein functions that have not been elucidated, resulting in a lag and uncertainty in vaccine development. Here, we propose a feasible strategy for emerging viral disease epitope vaccine development using TiLV. We determined the targets of specific antibodies in serum from a TiLV survivor by panning a Ph.D.-12 phage library, and we identified a mimotope, TYTTRMHITLPI, referred to as Pep3, which provided protection against TiLV after prime-boost vaccination; its immune protection rate was 57.6%. Based on amino acid sequence alignment and structure analysis of the target protein from TiLV, we further identified a protective antigenic site (399TYTTRNEDFLPT410) which is located on TiLV segment 1 (S1). The epitope vaccine with keyhole limpet hemocyanin (KLH-S1399-410) corresponding to the mimotope induced the tilapia to produce a durable and effective antibody response after immunization, and the antibody depletion test confirmed that the specific antibody against S1399-410 was necessary to neutralize TiLV. Surprisingly, the challenge studies in tilapia demonstrated that the epitope vaccine elicited a robust protective response against TiLV challenge, and the survival rate reached 81.8%. In conclusion, this study revealed a concept for screening antigen epitopes of emerging viral diseases, providing promising approaches for development and evaluation of protective epitope vaccines against viral diseases. IMPORTANCE Antigen epitope determination is an important cornerstone for developing efficient vaccines. In this study, we attempted to explore a novel approach for epitope discovery of TiLV, which is a new virus in fish. We investigated the immunogenicity and protective efficacy of all antigenic sites (mimotopes) identified in serum of primary TiLV survivors by using a Ph.D.-12 phage library. We also recognized and identified the natural epitope of TiLV by bioinformatics, evaluated the immunogenicity and protective effect of this antigenic site by immunization, and revealed 2 amino acid residues that play important roles in this epitope. Both Pep3 and S1399-410 (a natural epitope identified by Pep3) elicited antibody titers in tilapia, but S1399-410 was more prominent. Antibody depletion studies showed that anti-S1399-410-specific antibodies were essential for neutralizing TiLV. Our study demonstrated a model for combining experimental and computational screens to identify antigen epitopes, which is attractive for epitope-based vaccine development.

Geophysical survey at the frontier of medieval Iberia: The castles of Molina de Aragón and Atienza (Guadalajara, Spain)

AbstractThis paper presents the results of geophysical surveys conducted within two castles in central Iberia: the fortifications of Molina de Aragón and Atienza, both located within the modern province of Guadalajara in Spain. They represent essential case studies for understanding the transformations of the frontier societies of medieval south‐western Europe, because both were founded during the Andalusi period, both played a fundamental role at the time of the military confrontations between opposing Islamic and Christian states, and both became capitals within the feudal dependencies of the Crown of Castile during the Late Middle Ages. At present, these castles are uninhabited and protected archaeological sites, with no modern developments within their wards; the adjacent towns have developed on the outskirts of their outer walls. Although both castles have been the focus of uneven amounts of archaeological research, geophysical surveys, the first conducted at these sites, have proved to be a fundamental tool not only for planning future archaeological investigations but also for the data that they have provided on the potential roles of these castle wards.

Biomass and Leaf Nutrition Contents of Selected Grass and Legume Species in High Altitude Rangelands of Kashmir Himalaya Valley (Jammu & Kashmir), India.

The yield and nutritional profile of grass and legume species in Kashmir Valley's rangelands are scantly reported. The study area in this paper included three types of sites (grazed, protected, and seed-sown) divided into three circles: northern, central, and southern Kashmir. From each circle, three districts and three villages per district were selected. Most sites showed higher aboveground biomass (AGB) compared to belowground biomass (BGB), which showed low to moderate effects on biomass. The comparison between northern, central, and southern Kashmir regions revealed that AGB (86.74, 78.62, and 75.22 t. ha-1), BGB (52.04, 51.16, and 50.99 t. ha-1), and total biomass yield (138.78, 129.78, and 126.21 t. ha-1) were the highest in central Kashmir region, followed by southern and northern Kashmir regions, respectively. More precisely, AGB and total biomass yield recorded the highest values in the protected sites of the central Kashmir region, whereas BGB scored the highest value in the protected sites of southern Kashmir region. The maximum yield (12.5 t. ha-1) recorded among prominent grasses was attributed to orchard grass, while the highest crude fiber and crude protein contents (34.2% and 10.4%, respectively), were observed for Agrostis grass. The maximum yield and crude fiber content (25.4 t. ha-1 and 22.7%, respectively), among prominent legumes were recorded for red clover. The highest crude protein content (33.2%) was attributed to white clover. Those findings concluded the successful management of Kashmir rangelands in protected sites, resulting in high biomass yields along with the considerable nutritional value of grasses and legumes.

Coupling Relationship between Rural Settlement Patterns and Landscape Fragmentation in Woodlands and Biological Reserves—A Case of Nanshan National Park

Exploring the influence of settlement patterns on the landscape fragmentation in woodlands and biological reserves is key to achieving ecologically sustainable development. In this research, we chose the Nanshan National Park in Hunan Province, China, as a case study, to explore the influence mechanisms. First, we identified the biological reserves through the landscape security patterns of biological conservation. Second, we constructed a coupling coordination model to analyze the coupling relationship between the settlement patterns and landscape fragmentation in the woodlands and biological reserves. The analysis showed that, overall, the effect of the settlement area on the landscape fragmentation in the biological reserves was more pronounced, while the effect of the settlement spread and shape on the landscape fragmentation in the woodlands was more obvious. From a type-specific perspective, we analyzed the coupling relationship between the settlement patterns and (1) the landscape fragmentation in different woodlands and (2) the landscape fragmentation in the biological reserves, namely concerning Leiothrix lutea and Emberiza aureola. We found that the effect of the settlement patterns on the landscape fragmentation of the Leiothrix lutea biological reserve was more significant than that of the landscape fragmentation of its main habitat, the evergreen broad-leaved forest. The effect of settlement patterns on the landscape fragmentation of the Emberiza aureola biological reserve was more significant than that of the landscape fragmentation of its other habitats. In addition, the results demonstrated that the habitat protection of the woodlands was not a substitute for the systematic protection of biosecurity patterns. This research could assist in developing more efficient conservation measures for ecologically protected sites with rural settlements.

Nature Management and Protection of Archaeological Sites in Estonia

Archaeological monuments are mostly situated in the natural environment and in Estonia are sometimes also protected under the Nature Conservation Act, meaning they are double protected and double managed as well. The system has its challenges, benefits and dangers, since the protection regimes for nature or heritage protection sites are slightly different. In some cases, they complement each other, but there are cases where the protection regimes may diverge. The nature conservation-related management of archaeological monuments in Estonia is described and a few examples of such cases are discussed.

Growth rate and projected age at sexual maturity for immature hawksbill turtles and green turtles foraging in the remote marine protected area of Aldabra Atoll, Seychelles

Changes in marine ecosystems from human stressors, and concerns over how species will respond to these changes have emphasized the importance of understanding and monitoring crucial demographic parameters for population models. Long-lived, migratory, marine vertebrates such as sea turtles are particularly vulnerable to changes. Life-history parameters like growth-in-body size can be largely influenced by environmental processes which can impact population growth. We analyzed a 40-year (1981–2021) capture-mark-recapture dataset from the protected UNESCO World Heritage Site, Aldabra Atoll, Seychelles, to estimate key population parameters, including body growth, for immature green turtles (Chelonia mydas) and hawksbill turtles (Eretmochelys imbricata). Curved carapace length (CCL) range was 34.3–110.9 cm (mean ± SD: 51.0 ± 11.4 cm, n = 1191) for green turtles and 28.7–89.4 cm (47.7 ± 14.4 cm, n = 538) for hawksbill turtles. Recapture events, with an 11-month minimum period, revealed a mean annual growth rate of 3.2 ± 1.5 cm year−1 for green turtles (n = 75) and 2.8 ± 1.4 cm year−1 for hawksbill turtles (n = 110). Hawksbill turtles exhibited a non-monotonic growth rate while no significant growth-size relationship was detected for green turtles. Green turtle mean annual growth per 10-cm size class was highest in the larger size classes (50‒69.9 cm). Hawksbill turtle growth rate was highest in the larger size classes (50‒69.9 cm) then declined in the largest size class (70‒79.9 cm). Green turtles and hawksbill turtles may spend > 8 and 18 years, respectively, using Aldabra, Seychelles, as a foraging ground.

Predicting the Potential Distribution of the Endangered Plant Eucommia ulmoides in China under the Background of Climate Change

Eucommia ulmoides, a single extant species of Eucommiaceae, is a perennial deciduous tree distributed across central China. The bark of E. ulmoides is rich in chlorogenic acid and flavonoids that possesses high medicinal value, whereas its leaves and seeds contain abundant Eucommia ulmoides gum (EUG), which is a unique strategic resource in China that can be used as a substitute for natural rubber. Under the background of global warming, the evaluation of habitat suitability is of great significance for the protection and management of E. ulmoides. For this study, maximum entropy (MaxEnt) modeling was employed to simulate the potentially suitable region for E. ulmoides over four periods (current, 2050s, 2070s, and 2090s) under four climate change scenarios (SSP1-2.6, SSP2-4.5, SSP3-7.0, and SSP5-8.5), as well as to analyze changes in the spatial patterns of E. ulmoides and the essential environmental factors affecting the growth and distribution of E. ulmoides. The results revealed that the current potentially suitable region for E. ulmoides was 211.14 × 104 km2, which accounted for 21.99% of China’s territory. The low impact areas for E. ulmoides were distributed in Guizhou, Zhejiang, Sichuan, eastern Chongqing, southern Shaanxi, western Hubei, eastern Shandong, southern Anhui, southern Gansu, and northern Yunnan Provinces. The key bioclimatic variables affecting the distribution of E. ulmoides were mean diurnal range and mean temperature of the coldest quarter, with their contribution rates of 53.8% and 41.4%, respectively. Furthermore, core distributional shift analysis indicated that the center of the potentially suitable regions of E. ulmoides exhibited a general trend of shifting to the northwest and high latitudes. Finally, conservation strategies are proposed, such as the establishment of ex situ protection sites and germplasm resource collection. Future researchers can conduct further studies by integrating the quality of E. ulmoide herbs and environmental variables. In this study, for technical reasons, we only considered the effect of climate on species distribution without considering other biotic and abiotic factors, which can be further addressed by future researchers.

Species Composition and Diversity of Tree Species in Nanta Forest Region in Kota District, Rajasthan, India

The objective of this work was to study species composition and diversity of tree species between two vegetation stands, one is a protected vegetation stand and the other is a non-protected vegetation stand. The tree species composition and community structure were analyzed by field visits in Nanta forest region. Random sampling was done by using a standard size of quadrat i.e., 10x10m2. Results showed that a total of 30 species belonging to 25 genera and 11 families are present in the protected site whereas 8 species belonging to 7 genera and 5 families are present in the unprotected site. Anogeissus pendula (Edgew) and Dichrostachys cinerea (L.) were the most important species in protected and non-protected sites respectively. The Simpson’s index is higher in protected vegetation stands showing greater sample diversity. Family Fabaceae is dominant in both the vegetation stand which shows the ecological importance of this family.

Law Governance on Cultural Value for Regaining Bandar Senapelan Image as Kampung Melayu: A Review

The rapid development in a space of urban and economic changing shows a big gap in cultural value preservation. Bandar Senapelan with its cultural value consist of both urban and industrial development for Pekanbaru city has its potential to promote a wide range of diversities in occurance and growth of the capital. The history, landscape, even commercial, laid on the land called Bandar Senapelan. Due to its strategic location, attached to Siak River, the district has widely known for its initial born for Pekanbaru city history, diversity in multi ethnic community, and the trade centre for Central Sumatera’s rapid economic growth. The district’s potential and background was to encroaching and humiliating to be ignored. The city regional plan or (RTRW) statute by the government has not mention in detail the necessity of Bandar Senapelan to be a protected cultural site which should be preserve and conserve. There are several article written by law that confusing and need to be re-review. The image of the district as people has known it as Kampung Melayu slowly threatened. This paper will analyse the level of awareness with regard to cultural landscape conservation and protection in Pekanbaru policy from Pekanbaru RTRW statute. The research methodology will be done with qualitative analysis and descriptive method from relevant theory and studies. Both tangible and intangible identification will be reviewed to achieve the worthwile protection for the region to be conducted.

Exceptional Ozone Decomposition over δ-MnO2/AC under an Entire Humidity Environment.

Ozone (O3) pollution is highly detrimental to human health and the ecosystem due to it being ubiquitous in ambient air and industrial processes. Catalytic decomposition is the most efficient technology for O3 elimination, while the moisture-induced low stability represents the major challenge for its practical applications. Here, activated carbon (AC) supported δ-MnO2 (Mn/AC-A) was facilely synthesized via mild redox in an oxidizing atmosphere to obtain exceptional O3 decomposition capacity. The optimal 5Mn/AC-A achieved nearly 100% of O3 decomposition at a high space velocity (1200 L g-1 h-1) and remained extremely stable under entire humidity conditions. The functionalized AC provided well-designed protection sites to inhibit the accumulation of water on δ-MnO2. Density functional theory (DFT) calculations confirmed that the abundant oxygen vacancies and a low desorption energy of intermediate peroxide (O22-) can significantly boost O3 decomposition activity. Moreover, a kilo-scale 5Mn/AC-A with low cost (∼1.5 $/kg) was used for the O3 decomposition in practical applications, which could quickly decompose O3 pollution to a safety level below 100 μg m-3. This work offers a simple strategy for the development of moisture-resistant and inexpensive catalysts and greatly promotes the practical application of ambient O3 elimination.

Nature Management and Protection of Archaeological Sites in Estonia

Archaeological monuments are mostly situated in the natural environment and in Estonia are sometimes also protected under the Nature Conservation Act, meaning they are double protected and double managed as well. The system has its challenges, benefits and dangers, since the protection regimes for nature or heritage protection sites are slightly different. In some cases, they complement each other, but there are cases where the protection regimes may diverge. The nature conservation-related management of archaeological monuments in Estonia is described and a few examples of such cases are discussed.

Weichselian Glaciation of the Faroe Islands

This paper presents a new complete field mapping of glacial landscapes, landforms and sediments in the Faroe Islands, supplemented by observations from bathymetric maps of the Faroe Shelf. In addition, previous investigations of Quaternary and espe-cially the Weichselian glaciation of the archipelago are reviewed. New cosmogenic nuclide exposure ages indicate that the last extensive glaciation of the Faroe Islands occurred during the Late Weichselian, most likely during the Last Glacial Maximum (LGM; c. 26.5–19.0 cal. ka BP), although a Younger Dryas (c. 12.9–11.7 cal. ka BP) age cannot be entirely excluded. Geomorphological mapping provides a background for reconstructing the extent and type of the glaciation of the Faroe Islands. The reconstructed Weichselian glaciation appears to have had the character of an exten-sive valley glaciation, with several marine glacier termini. The present glaciation of southern Spitsbergen, Svalbard, represents a modern analogue of the reconstructed Weichselian glaciation in the Faroe Islands. The lack of raised coastal features in the Faroe Islands, also at protected sites, suggests that postglacial isostatic uplift was smaller than post-LGM eustatic sea level rise. Numerical glacier reconstructions carried out for different extents of the last extensive Faroese glaciation suggest that such limited postglacial isostatic crustal uplift requires that the Faroe Shelf was not extensively glaciated during the Late Weichselian, but it doubtless was so during at least one of the previous Quaternary glaciations.

NOx reduction against alkali poisoning over Ce(SO4)2-V2O5/TiO2 catalysts by constructing the Ce4+–SO42− pair sites

Commercial V2O5-based catalysts have been successfully applied in NH3 selective catalytic reduction (NH3-SCR) of NOx from power stations, but their poor alkali-resistance restrains the wider application in nonelectrical industries. In this study, NOx reduction against alkali poisoning over V2O5/TiO2 is greatly improved via Ce(SO4)2 modification. It has been originally demonstrated that Ce4+–SO42− pair sites play crucial roles in improving NOx reduction against alkali poisoning over V2O5/TiO2 catalysts. The strong interaction between V species and Ce sites of Ce4+–SO42− pairs triggers the reaction between NH4+species and gaseous NO via Eley-Rideal (E-R) reaction pathway. After K-poisoning, the SO42− sites of Ce4+–SO42− pairs as protective sites strongly bond with K and thus maintain the high reaction efficiency via the E-R reaction pathway. This work demonstrates an effective strategy to enhance NOx reduction against alkali poisoning over catalysts via constructing Ce4+–SO42− pair sites, contributing to developing alkali-resistant SCR catalysts for practical application in nonelectrical industries.